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Enhanced performance of photocatalytic oxidation of indoor toluene over Pd/TiO2 catalyst by tuning surface defect concentrations

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Chemosphere 2024年 366卷 143409页

作者： Wang, Gehui Wu, Cong Liu, Qinglong Wan, Haiqin Dong, Lin State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

An effective approach for the elimination of indoor gaseous toluene through photocatalytic oxidation involves the engineering of surface defects on catalysts. In this study, the concentrations of surface oxygen defects in PdTi-xN (x = 10, 30) catalysts were controlled using the sodium borohydride solid-phase reduction method, and their performances in the photocatalytic oxidation of indoor gaseous toluene were evaluated. PdTi–10 N demonstrated high photocatalytic efficiency for toluene oxidation, achieving 84% toluene conversion and approximately 75% CO2 mineralization. Characterization results indicated that surface oxygen defects can enhance the separation of photo-generated electrons and holes, facilitating their interaction with Pd0 species to form Ti3+ species. More reactive oxygen species (·OH-and ·O2−) were generated on PdTi–10 N due to the synergistic effect of surface oxygen defect and Ti3+ species, which played a significant role as the toluene oxidation. This work provides a new insight for the design and development of high-performance Pd/TiO2 catalysts in the field of indoor VOCs treatment. © 2024 Elsevier Ltd

关键词： Toluene

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Organic peroxyl radicals from biacetyl accelerated the visible-light degradation of steroid estrogens in aqueous solution

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Chemosphere 2024年 351卷 141195页

作者： Jia, Yulu Zhang, Chengyang Zheng, Hongcen Zhang, Guoyang Zhang, Shujuan State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

Indirect photodegradation is an important pathway for the reduction of steroid estrogens in sunlit surface waters. Nevertheless, the kinetics and mechanisms governing the interaction between coexisting carbonyl compounds and estrogens under visible light (Vis) remain unexplored. This study systematically investigates the Vis-induced photodegradation of 17β-estradiol (E2) in the presence of five specific carbonyl compounds—biacetyl (BD), acetone, glyoxal, pyruvic acid, and benzoquinone. The results demonstrate that, among these compounds, only BD significantly enhanced the photodegradation of E2 under Vis irradiation (λ > 400 nm). The pseudo-first order photodegradation rate constants (k1) of E2 in the Vis/BD system were 0.025 min−1 and 0.076 min−1 in ultrapure water and river water, respectively. The enhancing effect of BD was found to be pH-dependent, increasing the pH from 3.0 to 11.0 resulted in a 76% reduction in the k1 value of E2 in the Vis/BD system. Furthermore, the presence of humic acid, NO3−, or HCO3− led to an increase of more than 35% in the k1 value of E2, while NO2− exerted a pronounced inhibitory effect, resulting in a 92% decrease. Peroxyacetyl and peroxymethyl radicals, derived from BD in a yield ratio of 9, played a crucial role in the degradation of E2. These peroxyl radicals primarily targeted electron-rich hydroxyl sites of E2, initiating hydroxylation and ring-opening reactions that culminated in the formation of acidic byproducts. Notably, toxicity evaluation indicates that these hydroxylated and acidic products exhibited lower toxicity than the parent compound E2. This study highlights the important role of peroxyl radicals in estrogen degradation within aquatic environment, and also helps to design efficient visible light-responsive photo-activators for the treatment of estrogen-contaminated waters. © 2024 Elsevier Ltd

关键词： Photolysis

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Reproductive Toxicities of Tetradecyltrimethylammonium Chloride and Tetradecyltrimethylammonium Bromide on Caenorhabditis elegans over Four Consecutive Generations

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Chemical Research in Chinese Universities 2024年第6期40卷 1060-1067页

作者： ZHANG Jing DING Ruoqi YU Zhenyang Ecological Technique and Engineering College Shanghai Institute of TechnologyShanghai 201418P.R.China Jiaxing Tongji Institute for Environment Jiaxing 314051P.R.China State Key Laboratory of Pollution Control and Resource Reuse Key Laboratory of Yangtze River Water EnvironmentMinistry of EducationCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092P.R.China

Quaternary ammonium compounds (QACs) become emerging pollutants and their toxicities earn increasing *** far,their reproductive toxicities were poorly investigated,and their effects over generations were even less *** the present study,reproductive toxicities of two QACs,i.e.,tetradecyltrimethylammonium chloride (TTAC);tetradecyltrimethylammonium bromide (TTAB) were studied on Caenorhabditis elegans with a consecutive exposure over four generations (from F1 to F4).The effects of TTAC on total and initial reproduction showed stimulation and inhibition,which oscillated from F1 to *** effects of TTAB on the total reproduction commonly showed stimulation over generations with the greatest stimulation in F2,and it inhibited the initial reproduction but stimulated the reproduction *** exploration demonstrated that TTAC and TTAB significantly disturbed the levels of spermatocyte protein 8 (SPE8);sperm transmembrane protein 9 (SPE9);vitellogenin (Vg);major sperm protein (MSP);ephrin receptor protein tyrosine kinase (VAB-1);the expressions of vab-1,ceh-18,set-2,met-2 and *** disturbances demonstrated that both QACs impacted the reproductive processes via oocyte meiosis,gonadal support and germline ***,the effects of TTAC and TTAB in parents were connected with those in the offspring,which highlighted the roles of reproduction in connecting *** addition,different effects between TTAC and TTAB demonstrated the anionic influences on the QACs’ toxicities.

关键词： Multigenerational effect Oocyte meiosis Gonadal support Germline development Anionic influence

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A novel structure of quasi-monolayered NiCo-bimetal-phosphide for superior electrochemical performance

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Journal of Energy Chemistry 2022年第11期31卷 203-211,I0007页

作者： Long Zhao Ming Wen Yakun Tian Qingsheng Wu Yongqing Fu School of Chemical Science and Engineering Shanghai Key Laboratory of Chemical Assessment and SustainabilityState Key Laboratory of Pollution Control and Resource ReuseTongji UniversityShanghai 200092China Faculty of Engineering and Environment Northumbria UniversityNewcastle upon TyneNE18STUnited Kingdom

Bimetallic transition metal phosphides(TMPs)as potential candidates for superior electrochemical performance are still facing great challenges in the controllable preparation of two-dimensional(2 D)structures with high aspect ***,a novel structure of quasi-monolayered NiCo-bimetal-phosphide(NiCoP)has been designed and successfully synthesized by the newly developed process combined with ultrasonic-cavitation and *** is the first time to break through the controllable preparation of 2 D bimetal-phosphides with a thickness of 0.98 nm in *** on the advantages of 2 D quasi-monolayer structure with dense crystalline-amorphous interface and the reconfigured electronic structure between Ni^(δ+)/Co^(δ+)and P^(δ-),the optimized Ni_(5%)CoP exhibits an outstanding bifunctional performance for electrocatalyzing both hydrogen evolution reaction and oxygen evolution reaction in an alkaline ***_(5%)CoP presents lower overpotentials and voltage of 84 mV&259 mV and1.48 V at the current density of 10 mA cm^(-2)for HER&DER and overall water splitting,respectively,which are superior to most other reported 2 D *** work provides a new strategy to optimize the performance of electrolytic water for bimetal-phosphates and it may be of significant value in extending the design of other ultrathin 2 D structured catalysts.

关键词： 2D quasi-monolayer Hydrogen evolution reaction Bimetal phosphide Oxygen evolution reaction Ultrasonic-cavitation

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A MISR-Based Method for the Estimation of Particle Size Distribution:Comparison with AERONET over China

Journal of Remote Sensing

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Journal of Remote Sensing 2023年第1期3卷 97-109页

作者： Yanchuan Shao Riyang Liu Weihan Li Jun Bi Zongwei Ma State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjingJiangsuChina Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Nanjing University of Information Science&TechnologyNanjingJiangsuChina

Aerosol particle size has a crucial impact on the environment and public *** satellite-based regression models focus on the total amount of particles and are limited by surface *** study proposes an algorithm to derive the long-term normalized volume size distribution(VSD)of aerosol particles,which is independent of ground *** size distribution and aerosol optical depth of Multi-angle Imaging SpectroRadiometer(MISR)components are *** find the estimated MISR VSD is consistent with Aerosol Robotic Network(AERONET)observations,with R=0.56,0.54,0.59,and 0.68 for daily,monthly,seasonal,and annual *** stratified validations of radius,stations,and years further confirm the stable performance of derived VSD(R=0.28 to 0.73).The application of the random forest model demonstrates the potential improvements of predicted VSD by 10-fold cross-validation R=0.86 at the monthly *** apply MISR VSD to quantify the normalized volume of fractional aerosol particles at a resolution of 0.2°×0.2°during 2004 to 2016 in *** also calculate the proportion of small and medium particles to indicate the contribution of anthropogenic *** highest ratios are concentrated in the northeastern regions especially during winter while relatively lower in the Taklamakan Desert of western *** case study demonstrates that the application of MISR data can yield valuable and resolved size distributions of aerosol particles.

关键词： AERONET aerosol MISR

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Cotransport of nanoplastics with nZnO in saturated porous media:From brackish water to seawater

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Journal of Environmental Sciences 2025年第2期148卷 541-552页

作者： Yuanzhang Hou Yange Wang Yidi Zhang Zhibo Lu Zhenbo Zhang Zhiqiang Dong Yuping Qiu Department of Environmental Science College of Environmental Science and EngineeringTongji UniversityState Key Laboratory of Pollution Control and Resources ReuseShanghai Institute of Pollution Control and Ecological SecurityShanghai 200092China School of Medicine Tongji UniversityShanghai 200065China Municipal Environmental Protection Engineering Co. Ltd of CERC Shanghai GroupShanghai 201906China China Railway Engineering Group Co. Beijing 100039China

The ocean serves as a repository for various types of artificial ***(NPs)and nano zinc oxide(nZnO),which are frequently employed in personal care products and food packaging materials,are likely simultaneously released and eventually into the ocean with surface ***,their mutual influence and shared destiny in marine environment cannot be *** study examined how nanomaterials interacted and transported through sea sand in various salinity *** showed that NPs remained dispersed in brine,while nZnO formed *** seawater of 35 practical salinity units(PSU),nZnO formed heteroaggregates with NPs,inhibiting NPs mobility and decreasing the recovered mass percentage(Meff)from 24.52%to 12.65%.In 3.5 PSU brackish water,nZnO did not significantly aggregate with NPs,and thus barely affected their ***,NPs greatly enhanced nZnO transport with Meff increasing from 14.20%to 25.08%,attributed to the carrier effect of higher mobility *** from brackishwater to seawater was simulated in salinity change experiments and revealed a critical salinity threshold of 10.4 PSU,below which the mobility of NPs was not affected by coexisting nZnO and above which nZnO strongly inhibited NP *** study highlights the importance of considering the mutual influence and shared destiny of artificial nanoparticles in the marine environment and how their interaction and cotransport are dependent on changes in seawater salinity.

关键词： Homoaggregate Heteroaggregate Transport Sea sand Salinity threshold

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Coupling magnetic particles with flocculants to enhance demulsification and separation of waste cutting emulsion for engineering applications

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Journal of Environmental Sciences 2021年第7期33卷 173-183页

作者： Yongjiao Xiong Baoqiang Wu Xiangfeng Huang Chenlu Li Bin Lu Jia Liu Lijun Lu Shiyang Li Kaiming Peng College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resource ReuseMinistry of Education Key Laboratory of Yangtze River Water EnvironmentShanghai Institute of Pollution Control and Ecological SecurityTongji UniversityShanghai 200092China

Magnetic particles were coupled with a flocculant to enhance the demulsification and separation of waste cutting *** optimal magnetic particle size and critical magnetic field conditions were investigated to achieve large-scale engineering application of magnetic demulsification separation for waste cutting emulsion *** micro-scale magnetic particles were found to show comparable effects to nano-scale magnetic particles on enhancing the demulsification and separation of cutting emulsions,which are beneficial for broadening the selectivity of low-cost magnetic *** critical magnetic separation region was determined to be an area 40 mm from the magnetic field *** to the flocculant demulsification,the magnetic demulsification separation exhibited a significant advantage in accelerating flocs-water separation by decreasing the separation time of flocs from 180-240 min to less than 15 min,compressing the flocs by reducing the floc volume ratio from 60%-90%to lower than 20%,and showing excellent adaptability to the variable properties of waste cutting *** with the design of the magnetic disk separator,continuous demulsification separation of the waste cutting emulsion was achieved at 1.0 t/hr for at least 10 hr to obtain clear effluent with 81%chemical oxygen demand removal and 89%turbidity *** study demonstrates the feasibility of applying magnetic demulsification separation to large-scale continuous treatment of waste ***,it addresses the flocs-water separation problems that occur in practical flocculant demulsification engineering applications.

关键词： Waste cutting emulsion Magnetic particles Demulsification and separation Magnetic disk separator Large-scale treatment

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High-solid anaerobic digestion of sewage sludge:achievements and perspectives

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Frontiers of Environmental Science & Engineering 2021年第4期15卷 1-18页

作者： Ying Xu Hui Gong Xiaohu Dai State Key Laboratory of Pollution Control and Resource Reuse School of Environmental Science and EngineeringTongji UniversityShanghai200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092China

High-solid anaerobic digestion(HS-AD)has been applied extensively during the last few decades for treating various organic wastes,such as agricultural wastes,organic fractions of municipal solid wastes,and kitchen ***,the application of HS-AD to the processing of sewage sludge(SS)remains limited,which is largely attributable to its poor process stability and *** research has been conducted to attempt to surmount these *** this review,the main factors affecting process stability and performance in the HS-AD of SS are comprehensively reviewed,and the improved methods in current use,such as HS sludge pre-treatment and anaerobic co-digestion with other organic wastes,are ***,this paper also discusses the characteristics of substance transformation in the HS-AD of SS with and without thermal *** has shown that the HS effect is due to the presence of high concentrations of substances that may inhibit the function of anaerobic microorganisms,and that it also results in poor mass transfer,a low diffusion coefficient,and high ***,knowledge gaps in the current research on HS-AD of SS are *** on these,it proposes that future efforts should be devoted to standardising the definition of HS sludge,revealing the law of migration and transformation of pollutants,describing the metabolic pathways by which specific substances are degraded,and establishing accurate mathematical ***,developing green sludge dewatering agents,obtaining high value-added products,and revealing effects of the above two on HS-AD of SS can also be considered in future.

关键词： High-solid effect Anaerobic fermentation Methane production Biodegradability Sludge treatment

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In situ polymerized quasi-solid polymer electrolytes enabling void-free interfaces for room-temperature sodium-sulfur batteries

Energy Materials and Devices

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Energy Materials and Devices 2024年第4期2卷 67-77页

作者： Jiafang Huang Zhengguang Song Junxiong Wu Yuhui Miao Manxian Li Danjing Lin Kai Zhu Xiaochuan Chen Xiaoyan Li Yuming Chen Engineering Research Center of Polymer Green Recycling of Ministry of Education Fujian Key Laboratory of Pollution Control&Resource ReuseCollege of Environmental and Resource Sciences and College of Carbon Neutral Modern IndustryFujian Normal UniversityFuzhou 350117China

Rechargeable room-temperature(RT)sodium–sulfur(Na–S)batteries hold great potential for large-scale energy storage owing to their high energy density and low ***,their practical application is hindered by challenges such as polysulfide shuttling and Na dendrite *** this study,a dual salt-based quasi-solid polymer electrolyte(DS–QSPE)was developed via in situ polymerization,achieving high ionic conductivity(4.8×10^(-4) S·cm^(-1) at 25°C),a high sodium-ion transference number(0.73),and effective polysulfide *** calculations and experimental results indicate that the enhanced Na-ion transport is attributed to the strengthened coordination of anions with the polydioxolane chain and the increased dissociation of sodium ***,the DS–QSPE forms an interconnected network structure in the sulfurized polyacrylonitrile(SPAN)*** provides abundant and seamless electrochemical reaction interfaces that facilitate efficient and uniform ion transport *** a result,the Na||SPAN battery with DS–QSPE delivers a high capacity of approximately 327.4 mAh·g^(-1)(based on the mass of SPAN)after 200 cycles at 0.2 A·g^(-1),retaining 81.4%of its initial *** performance considerably surpasses that of batteries using liquid *** study offers a straightforward approach to addressing the inter-facial challenges in solid-state Na–S batteries.

关键词： sodium–sulfur batteries sulfurized polyacrylonitrile in situ polymerization quasi-solid polymer electrolyte shuttle effect

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Red mud-based catalysts for the catalytic removal of typical air pollutants: A review

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Journal of Environmental Sciences 2023年第5期127卷 628-640页

作者： Jiawei Chen YaoWang Zhiming Liu State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Beijing Center for Environmental Pollution Control and Resource Recovery Beijing University of Chemical TechnologyBeijing 100029China Beijing Key Laboratory of Energy Environmental Catalysis Beijing University of Chemical TechnologyBeijing 100029China

Red mud,as a solid waste produced during the alumina production,can cause severe ecoenvironmental pollution and health risks to ***,the resourcing of this type of solid waste is an effective way for the sustainable *** paper reviews the recent progress on red mud-based catalysts for the removal of typical air pollutants,such as the catalytic reduction of nitrogen oxides(NO_(x))by NH_(3)(NH_(3)-SCR)and the catalytic oxidation of CO and volatile organic compounds(VOCs).The factors influencing the catalytic performance and the structure–activity relationship have been *** prospects and directions for the development of such catalysts are also *** review would benefit for the high value-added utilizations of red mud in mitigating atmospheric pollutions.

关键词： Red mud Catalyst NH_(3)-SCR Catalytic oxidation Air pollutants

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