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Approaching high oxygen evolution reaction performance by synergetic dual-ion leaching

Nano Research 2024年第9期17卷 7975-7983页

作者： Hancheng Ma Yao Ding Jianqi Li Wei Peng Liqiang Mai School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Self-reconstruction of catalysts during oxygen evolution reaction(OER)is crucial for the development of energy conversion ***,the relationship between the specific atomic structure of pre-catalysts and their electrocatalytic behavior after reconstruction via dual-ion leaching has not been extensively *** this work,we design a highly effective non-noble metal OER catalyst with heterointerface through continuous self-reconstruction of Co_(2)(OH)_(3)Cl@NiMoO_(4)as pre-catalyst by a straightforward dual-ion(***_(4)^(2-)and Cl^(-))***-situ Raman and in-situ Fourier transform infrared(FT-IR)spectroscopy have precisely identified the progressive phase transformation of the pre-catalyst during self-reconstruction,which results in a stable heterojunction of CoOOH and NiOOH(CoOOH@NiOOH).Further calculations based on density functional theory(DFT)of CoOOH@NiOOH evident that more electrons will be aggregated in the Fermi level of ***,Gibbs free energy(ΔG)for different OER steps of CoOOH@NiOOH exhibit lower energy costs of all intermediates,implying the well catalytic ***,the catalyst derived from dual-ion leaching displays outstanding OER performance,characterized by an overpotential of 275 mV at a current density of 10 mA·cm^(-2)and exceptional stability over 12 h *** work successfully paves a way of finding high-performance OER catalysts based on non-noble metal through dual-ion leaching during self-reconstruction.

关键词： dual-ion leaching oxygen evolution reaction chemical reconstruction NiMoO_(4) Co_(2)(OH)_(3)Cl

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Effect of Fluoride on the Ion-association of Calcium Phosphate and Crystallization of Hydroxyapatite

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Journal of Wuhan University of technology(Materials Science) 2024年第4期39卷 831-838页

作者：宋昊月 CAI Meng 袁萍邹朝勇 School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Using a titration setup to accurately control the reaction conditions and in situ monitor the reaction,we showed that fluoride exhibited negligible effects on the ion association process of calcium and phosphate and the formation of ACP nanospheres in a buffer solution with constant ionic ***,the stability of ACP increased with increasing fluoride concentration,which was ascribed to the inhibitory effect of fluoride on the aggregation of ACP nanospheres and the nucleation of nanocrystals on the surface of ACP ***,fluoride could inhibit the lateral growth of HAP nanosheets and promote the formation of rod-like *** results further improve our understanding of the crystallization pathway of HAP crystals and the regulatory effects of fluoride.

关键词： crystallization amorphous calcium phosphate hydroxyapatite fluoride

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Mitigated lattice distortion and oxygen loss of Li-rich layered cathode materials through anion/cation regulation by Ti^(4+)-substitution

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Chinese Chemical Letters 2024年第2期35卷 548-552页

作者： Kaicheng Zhang Yu Tian Xuanjin Chen Shan Hu Zelang Jian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China

Lithium-rich layered cathode material(LLM)can meet the requirement of power lithium-ion energy storage devices due to the great energy ***,the de/intercalation of Li+will cause the irreversible loss of lattice oxygen and trigger transition metal(TM)ions migrate to Li+vacancies,resulting in capacity *** we brought Ti4+in substitution of TM ions in Li_(1.2)Mn_(0.54)Ni_(0.13)Co_(0.13)O_(2),which could stabilize structure and expand the layer spacing of ***,optimized Ti-substitution can regulate the anions and cations of LLM,enhance the interaction with lattice oxygen,increase Ni^(3+) and Co^(3+),and improve Mn^(4+) coordination,improving reversibility of oxygen redox activation,maintaining the stable framework and facilitating the Li^(+) ***,we found 5%Ti-substitution sample delivered a high discharge capacity of 244.2 mAh/g at 50 mA/g,an improved cycling stability to 87.3%after 100 cycles and enhanced rate *** Ti-substitution gives a new pathway to achieve high reversible cycle retention for LLMs.

关键词： Lithium-rich layered cathode material Ti-substitution Anion/cation regulation Structural stability Cycling stability

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Insight into slag-enhanced thermal desorption at the organo-mineral interface of clay soils

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Pedosphere 2025年第2期35卷 312-324页

作者： Juan ZHANG Xin WANG Xinyue DU Shukai FAN Hui LIU Minghua ZHANG State Key Laboratory of Advanced Metallurgy School of Metallurgical and Ecological Engineering University of Science and Technology Beijing State Key Laboratory of Mineral Processing Environmental Engineering InstituteBGRIMM Technology Group Shandong Institute of Geophysical & Geochemical Exploration College of Agricultural and Environmental Sciences University of California

Multiple active components in steel slags can optimize soil texture and catalyze the thermal desorption of refractory organic pollutants,especially polycyclic aromatic hydrocarbons （PAHs）.In this study,a safety and risk assessment was conducted on toxic metals present in collected steel slags,and the refining slag with a high content of free-Ca O from the XG iron and steel plant （XGRS） was selected and used to regulate the plasticity index （PI） of clay *** the clay soil with high liquid limit and high plasticity （CH）,the PI reduced from 34.3% to 24.8% with steel slags at an addition ratio of 10%（mass percent）,and for the clay soil with low liquid limit （CL）,the PI decreased from 22.8% to 16.5%,resulting in silt soil with optimal thermal *** thermal removal efficiency of PAHs in CH decreased from 81.9% to 74.0% at 350°C as the soil water content increased from 0 to 150 g kg-1,due to the hydration and swelling of clay minerals and the heat loss associated with dehydroxylation and *** efficiency further decreased to 68.7% using 2%（mass percent） Ca O as an additive due to the delayed dehydr（oxyl）ation of clay minerals and enhanced aromatization of soil organic *** contrast,addition of 2% high-content titania-bearing slag （HTBS） enhanced the removal efficiency of high-ring PAHs,with the efficiency increasing for 5-ring from 52.6% to 59.7% and for 6-ring from 76.6% to 81.8%.This is due to the presence of amorphous TiO2and crystalline CaTiO3in HTBS,which can degrade water to produce reactive oxygen *** 2% XGRS addition facilitated the complete removal of PAHs by air-supplemented lattice oxygen,leading to the oxidation of C–C bonds in CH to C–O,C=O,and O–C=O functional *** study provides valuable insights into the use of additives to enhance the thermal remediation of PAH-contaminated clay soils via activating oxygen species and oxidizing C–C bonds in organo-mineral complexes within clay soils.

关键词： catalytic degradation clay dehydration origanic pollutants polycyclic aromatic hydrocarbons reactive oxygen species remediation steel slags

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Low-carbon Operation of Combined Heat and Power Integrated Plants Based on Solar-assisted Carbon Capture

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Journal of Modern Power Systems and Clean Energy 2022年第5期10卷 1138-1151页

作者： Xusheng Guo Suhua Lou Yaowu Wu Yongcan Wang State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and TechnologyWuhan 430074China State Grid Sichuan Electric Power Research Institute Chengdu 610041China

Accelerating the development of renewable energy and reducing CO_(2)emissions have become a general consensus and concerted action of all countries in the world. The electric power industry, especially thermal power industry, is the main source for fossil energy consumption and CO_(2)emissions. Since solvent-based post-combustion carbon capture technology would bring massive extra energy consumption, the application of solar-assisted carbon capture technology has attracted extensive attention. Due to the important role of coal-fired combined heat and power plants for serving residential and industrial heating districts, in this paper, the low-carbon operation benefits of combined heat and power integrated plants based on solar-assisted carbon capture(CHPIP-SACC) are fully evaluated in heat and power integrated energy system with a high proportion of wind power. Based on the selected integration scheme, a linear operation model of CHPIP-SACC is developed considering energy flow characteristics and thermal coupling interaction of its internal modules. From the perspective of system-level operation optimization, the day-ahead economic dispatch problem based on a mix-integer linear programming model is presented to evaluate the low-carbon benefits of CHPIP-SACC during annual operation simulation. The numerical simulations on a modified IEEE 39-bus system demonstrate the effectiveness of CHPIP-SACC for reducing CO_(2)emissions as well as increasing the downward flexibility. The impact of different solar field areas and unit prices of coal on the low-carbon operation benefits of CHPIP-SACC is studied in the section of sensitivity analysis.

关键词： Solar-assisted carbon capture CO_(2)emission reduction combined heat and power integrated plant heat and power integrated energy system wind power

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Main Protection Optimization Scheme for Generator Parallel Operation of Rotating Asynchronous Machine in Nuclear Power Plants

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IEEE Transactions on Power Delivery 2025年第3期40卷 1480-1492页

作者： Wang, Yikai Xu, Chaozheng Qiao, Jian Dai, Zhihui Tan, Liming Yin, Xianggen State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources Baoding071003 China State Grid Hunan Electric Power Company Limited Research Institute Changsha410208 China Huazhong University of Science and Technology State Key Laboratory of Advanced Electromagnetic Technology Wuhan430074 China

The Rotating Asynchronous Machine (RAM) system of a nuclear power plant provides a stable and reliable power supply for the control rod drive mechanism (CRDM) through two parallel generators. At present, the main protection of the generators in the RAM system is only configured with longitudinal differential protection, which cannot reflect the interturn short circuit fault and interbranch short circuit fault of the stator winding. Based on the characteristics of parallel connection of RAM generators in nuclear power plants, this article proposes a dual-generator split phase transverse differential protection and a dual-generator incomplete longitudinal differential protection. Through the internal fault set of the generator and the internal fault potential splitting model of the generator, the quantitative analysis of different main protection configuration schemes is carried out. It is concluded that the existing longitudinal differential protection and the incomplete longitudinal differential protection of two parallel generators can correctly reflect the vast majority of internal short-circuit faults. Finally, the dynamic experiment is carried out to prove the feasibility of the protection method in the actual unit operation. © 1986-2012 IEEE.

关键词： Nuclear power plants

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Relationships of Internal Voltage Dependence on Power Imbalance Illustrating Characteristics and Roles in System Dynamics of Inertial-Controlled DFIG-based Wind Turbines

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CSEE Journal of Power and Energy Systems 2022年第3期11卷 1107-1117页

作者： Wan, Minhui Yuan, Xiaoming Hu, Jiabing The State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China

Frequency and voltage dynamics, as the focus of power systems, depends more and more on the frequency and amplitude response characteristics of renewable energy devices being subjected to power imbalance. Doubly-fed induction generator (DFIG)-based wind turbine (WT) is representative of renewable energy devices and shows different characteristics from those of conventional synchronous generator (SG). Unfortunately, the individual characteristics ofWT during system frequency and voltage dynamics are not intuitively illustrated by the existing structure-oriented models. Therefore, this paper aims to propose a function-oriented modeling methodology by representing inertia-controlled DFIG-based WT as internal voltage frequency and amplitude solely stimulated by active and reactive power imbalance. The individuality of characteristics is demonstrated that with grid voltage detection-based controls the internal voltage depends yet solely on power imbalance of WT, just like the case of SG. Through the infinity gain equivalence of the fast-electromagnetic loops, a simplified analytical model illustrating the electromechanical characteristics ofWT is further proposed. Based on the model, the similarities and differences between the characteristics of WT and SG are recognized. Simulation results for verification are also presented. © 2022 China Electric Power Research Institute. All rights reserved.

关键词： Wind turbines

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Bottlebrush Random Copolymers at Oil-Oil Interfaces

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Chinese Journal of Chemistry 2025年第2期43卷 139-145页

作者： Yaxin Wang Yunhui Wen Yuzheng Luo Shuailong Li Jiaqiu Luo Shaowei Shi State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing100029 China

Oil-in-oil nonaqueous emulsions are of great interest for developing emulsion-templated polymers and encapsulation systems that are incompatible with water-sensitive ***-made amphiphilic block copolymers are by far the most efficient stabilizers for oil-in-oil emulsions while less attention is given to copolymers with more complex ***,we report the stabilization of DMSO-silicone oil interface by bottlebrush random copolymers(BRCPs)containing norbornene backbones with densely grafted poly(methyl methacrylate)(PMMA)and polystyrene(PS)side *** assembly kinetics of BRCPs at the DMSO-silicone oil interface can be divided into three processes,including diffusion,reconfiguration and reorganization,and can be varied by tuning the degree of polymerization of the backbone(NB).Due to the high efficiency of BRCPs in reducing the interfacial tension,when using BRCPs as stabilizers,stable silicone oil-in-DMSO traditional emulsions and high internal phase emulsions(HIPEs)can be successfully obtained,while no stable emulsions can be achieved with linear PMMA-b-PS serving as the *** study,for the first time,underscores the great potential of amphiphilic bottlebrush copolymers in preparing oil-in-oil *** the advances in polymerization strategy,a broad variety of amphiphilic bottlebrush copolymers are expected to be synthesized and applied in the stabilization of nonaqueous biphasic systems.

关键词： Bottlebrush copolymers Oil-oil interfaces|Emulsions Surfactants Assembly dynamics

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Deliberate design of MOF-based pre-catalyst rationalizing the structural reconstruction toward efficient oxygen evolution reaction

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Science China Chemistry 2025年第6期68卷 2388-2398页

作者： Yunhui Chen Meng Tian Zhongqi Zhang Guangzhao Wang Yan Guo Jing Wu Dawei Qi Zhenhua Yan Xiangyu Liu Xi Liu State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering College of Chemistry and Chemical EngineeringNingxia University Key Laboratory of Extraordinary Bond Engineering and Advanced Materials Technology of Chongqing School of Electronic Information Engineering Yangtze Normal University Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources College of Chemistry Nankai University School of Chemistry and Chemical Engineering In-situ Center for Physical Sciences Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University

Metal-organic frameworks（MOFs）, that have emerged as promising electrocatalysts in oxygen evolution reaction（OER）,usually undergo structural reconstruction to form metal hydroxides as active sites. However, it remains a great challenge to design and synthesize ideal MOF-based pre-catalysts for properly cognizing and utilizing the reconstruction process toward efficient OER activity. Herein, the well-defined MOF-808 is post-modified by 2-hydroxyphosphonoacetic acid（HPAA） to form a micro-adsorber that enables to capture of metal ions effectively. Fe3+and Ni2+ions are synergistically anchored into the microadsorber, developing a Fe/Ni-containing pre-catalyst that can be dynamically electrooxidized to be an active and stable dual-site electrocatalyst denoted by R-MOF-HPAA@Fe Ni with abundant metal sites. As a result, R-MOF-HPAA@Fe Ni exhibits an excellent OER performance with a low overpotential of 272 m V and Tafel slope of 35.9 m V dec-1, as well as long-term stability over 300 h at 10 m A cm-2. Experiments and theoretical calculations suggest the resulting catalyst mainly follows a lattice oxygen mechanism（LOM） of dual-metal-site mechanism（DMSM）. Owing to the chelating role of HPAA, the post-synthesized MOFHPAA behaves as a trap to uniformly and firmly adhere Fe3+and Ni2+ions, leading to a functionalized MOF-based pre-catalyst which can be structurally evolved into atomic level-distributed OER electrocatalysts.

关键词： metal-organic frameworks functionalization electrochemical reconstruction electrocatalyst oxygen evolution reaction

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Construction of Ni single-atom coordinated with doped N and S elements for mild hydrogenation of methyl acrylate to methyl propionate

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Nano Research 2025年第1期18卷 217-224页

作者： Taolue Sun Chen Jian Gang Wang Hui Zhao Guoliang Zhang Zengxi Li Chunshan Li State Key Laboratory of Mesoscience and Engineering CAS Key Laboratory of Green Process and EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China Huizhou Institute of Green Energy and Advanced Materials Huizhou 516081China Advanced Energy Science and Technology Guangdong Laboratory Huizhou 516081China

Although the nickel-based catalyst is able toexhibit comparative catalytic activity to noble metal formethyl acrylate hydrogenation,it requires strict reactioncondition,which can be improved by regulation ofcoordination *** this study,we constructed akind of Ni single-atom coordinated with N and S(Ni-NSC)through the pyrolysis of organic Ni-based precursors at600℃.The existence and fine structure of Ni single-atom were confirmed by the spherical electron microscopicobservation in combination with the X-ray absorption spectroscopy(XAS)*** addition,the catalytichydrogenation assessment suggested that the as-prepared Ni-NSC catalyst exhibited higher activity and stability than theNi/NSC supported catalyst prepared by incipient wetness impregnation *** remarkable catalytic activity was dueto the high dispersion and density of Ni single-atom and weak adsorption energy of intermediates on these Ni sites.

关键词： methyl acrylate mild hydrogenation Ni single-atom coordination environment adsorption energy

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