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Exploring a new path of green and efficient utilization of sinter return fine to produce composite pellets

Journal of Iron and Steel Research International 2024年第7期31卷 1610-1622页

作者： Yan-biao Chen Wen-guo Liu Hao Guo Jing-song Wang Qing-guo Xue Hai-bin Zuo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China MCC Capital Engineering and Research Incorporation Limited Beijing 100176China

Efficient utilization of sinter return fine is an important measure to reduce cost,increase efficiency,save energy and reduce emission.A new path of green and efficient utilization of return fine was proposed to produce composite *** metallurgical properties of composite pellets under the condition of hydrogen-rich blast furnace were *** experimental results indicate that the coated concentrate was consolidated for the composite pellets through normal Fe_(2)O_(3) *** the surface of core return fine,the liquid phase formed due to its low-melting point,assimilated the adjacent concentrate,and then consolidated with the temperature *** with regular pellets,the com-pressive strength and reduction swelling index of composite pellets were decreased,but the reducibility index and softening-melting properties were *** addition,the reduction degradation index of composite pellets was sig-nificantly higher than that of ***,adding composite pellets was conducive to indirect reduction in blast furnace,reducing fuel ratio and improving production *** to the effect of the roasting system on the metallurgical properties,the roasting temperature and time were determined as 1250℃and 30 min,*** composite pellets can be produced under the traditional pelletizing process.

关键词： Sinter Return fine Composite pellet Roasting system Metallurgical property Hydrogen-rich blast furnace

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3D-printable Boron Nitride/Polyacrylic Hydrogel Composites with High Thermal Conductivities

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Journal of Wuhan University of technology(Materials Science) 2024年第5期39卷 1303-1310页

作者： DAI Jialei XUE Bingyu QIAN Qi HE Wenhao ZHU Chenglong LEI Liwen WANG Kun XIE Jingjing Hubei Longzhong Laboratory Xiangyang 441000China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Polyacrylic acid(PAA)hydrogel composites with different hexagonal boron nitride(h-BN)fillers were synthesized and successfully 3D-printed while their thermal conductivity was systematically *** the content of h-BN increasing from 0.1 wt%to 0.3 wt%,the thermal conductivity of the 3D-printed composites has been ***,through the shear force given by the 3D printer,a complete thermal conductivity path is obtained inside the hydrogel,which significantly improves the thermal conductivity of the h-BN hydrogel *** maximum thermal conductivity is 0.8808 W/(m·K),leading to a thermal conductive enhancement of 1000%,compared with the thermal conductivity of pure PAA *** study shows that using h-BN fillers can effectively and significantly improve the thermal conductivity of hydrogelbased materials while its 3D-printable ability has been maintained.

关键词： hydrogel composites boron nitride 3D printing thermal conductivity

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Effects of a novel refiner Al-3Ti-4.35La combined with Sr on microstructure and mechanical properties of as-cast A356 alloy

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China Foundry 2024年第6期21卷 641-650页

作者： Mei Xu Wan-wu Ding Li-wen Hu Shi-hao Chen Hai-xia Zhang Hai-cun Yu Wen-jun Zhao School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

It is a practically significant issue to refine and modify industrial Al-Si casting alloy to improve its *** the present study,a novel refiner Al-3Ti-4.35La alloy,prepared by a melt-reaction method,was used,combined with Sr to refine the as-cast A356 *** effects on the as-cast microstructures and mechanical properties of A356 alloy were *** results indicate that the combined addition of Al-3Ti-4.35La intermediate alloy and Sr can improve the microstructure and enhance the mechanical properties of A356 *** adding 0.3wt.%Al-3Ti-4.35La and 0.03wt.%Sr to the as-cast A356 alloy,the average grain size ofα-Al decreases from 693.47μm to 264.13μm(a decrease of 61.91%),the secondary dendrite arm spacing(SDAS)is decreased by 47.8%from 32.09μm to 16.75μm,and the eutectic Si is transformed from an acicular structure to short rods and a granular *** ultimate tensile strength(UTS)and elongation(EL)of the as-cast A356 alloy modified by Al-3Ti-4.35La and Sr reach 216.3 MPa and 10.6%,which are enhanced by 29.54%and 134.66%compared with the unmodified alloy,*** fracture mode is transformed from transgranular fracture to intergranular fracture,and the ductile toughness of the alloy is *** adding the Al-3Ti-4.35La and Sr,the undercooling for the nucleation ofα-Al and eutectic Si increases,leading to an accelerated nucleation rate and an increased number of nuclei,which shortens the duration of the eutectic reaction and consequently inhibits grain growth.

关键词： A356 alloy Al-3Ti-4.35La Sr refiner grain refinement microstructure mechanical properties

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Defect chemistry engineering of Ga-doped garnet electrolyte with high stability for solid-state lithium metal batteries

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Chinese Physics B 2024年第8期33卷 560-567页

作者：陈思汗黎俊刘可可孙笑晨万京伟翟慧宇唐新峰谭刚健 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science&Engineering Wuhan University of TechnologyWuhan 430070China

Ga-doped Li_(7)La_(3)Zr_(2)O_(12)(Ga-LLZO)has long been considered as a promising garnet-type electrolyte candidate for all-solid-state lithium metal batteries(ASSLBs)due to its high room temperature ionic ***,the typical synthesis of Ga-LLZO is usually accompanied by the formation of undesired LiGaO_(2) impurity phase that causes severe instability of the electrolyte in contact with molten Li metal during half/full cell *** this study,we show that by simply engineering the defect chemistry of Ga-LLZO,namely,the lithium deficiency level,LiGaO_(2) impurity phase is effectively inhibited in the final synthetic ***,defect chemistry engineered Ga-LLZO exhibits excellent electrochemical stability against lithium metal,while its high room temperature ionic conductivity(~1.9×10^(-3)S·cm^(-1))is well *** assembled Li/Ga-LLZO/Li symmetric cell has a superior critical current density of 0.9 mA·cm^(-2),and cycles stably for 500 hours at a current density of 0.3 mA·cm^(-2).This research facilitates the potential commercial applications of high performance Ga-LLZO solid electrolytes in ASSLBs.

关键词： Ga-doped Li_7La_3Zr_2O_(12)(Ga-LLZO) defect chemistry engineering high room temperature ionic conductivity electrochemical stability

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Thermodynamics aided design of hBN-capsulated diboride powders from novel nitrate precursors for high entropy ceramics

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Journal of Materials Science & technology 2024年第11期178卷 133-142页

作者： Hailing Yang Ji Zou Zhimin Xiong Jingjing Liu Weimin Wang Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Xiangyang 441000China

Hexagonal BN-coated powders have been widely used in various engineering sectors,however,their pro-ductions are restricted by the complexity of gas-solid *** this study,guided by thermodynamics,a novel approach to synthesize Layer-structured hexagonal BN(hBN)-coated high entropy diboride pow-ders in vacuum was developed,using metal salt Zr(NO_(3))4·5H_(2)O,HfCl_(4),NbC_(15),TaC_(15),C_(16)H_(36)O_(4)Ti,boric acid,and sucrose as raw *** adjusting the ratio of carbon to metal source(C/M),powders only consisting of two boride solid solutions and hBN were finally obtained,under an optimal process-ing condition of C/M=5.5 and synthesis temperature of 1400 ℃.Parts of hBN were found to coat on high-entropy metal diborides ceramic(HEB)particles,corresponding formation mechanism for core-shell structured powders was investigated,together with the liquid precursor assisted boro/carbothermal re-duction *** from as-synthesized core-shell powders,(Ti_(0.2)Zr_(0.2)Hf_(0.2)Nb_(0.2)Ta_(0.2))B2-11 vol%hBN ceramics were densified at 1900 ℃ under 50 MPa without holding,with a high relative density of 97.3%.

关键词： High entropy boride Boro/carbothermal reduction Sol-gel Core-shell powders Densification

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An Optimal Direct Torque Control Scheme for DC-biased Vernier Reluctance Machine Drives

An Optimal Direct Torque Control Scheme for DC-biased Vernie...

引用

2023 IEEE Energy Conversion Congress and Exposition, ECCE 2023

作者： Li, Zimin Kong, Wubin Qu, Ronghai Huazhong University of Science and Technology State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Wuhan430074 China

ISBN: (纸本)9798350316445

An optimal direct torque control (OPT-DTC) scheme is proposed for DC-biased vernier reluctance machines (VRMs) to improve the steady and dynamic performance of drive system. Firstly, the nonlinear model of DC-biased VRM is proposed in synchronous rotating frame. Then, the optimal control theory is employed to the model by designing an optimal torque controller with the ability of regulating zero-sequence current. The feedforward control terms are designed to improve the dynamic response, and the feedback control terms are designed to improve the steady performance. An optimal load torque observer is designed for speed control. Finally, comparative experiments with conventional DTC schemes for DC-biased VRMs are carried out to verify the superior performance of the proposed method, including higher accuracy of torque and flux and faster dynamic response. © 2023 IEEE.

关键词： direct torque control Optimal control reluctance machines

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A Longitudinal and Lateral Coordinated Control Method of Autonomous Vehicles Considering Time-varying Delay

IEEE Transactions on Intelligent Vehicles

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IEEE Transactions on Intelligent Vehicles 2024年 1-15页

作者： Qin, Zhaobo Liang, Wang Zang, Zuoxu Chen, Liang Hu, Manjiang Cui, Qingjia Bian, Yougang State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle College of Mechanical and Vehicle Engineering Hunan University Changsha China

In order to improve the control accuracy and stability of autonomous vehicles under large delay conditions, the paper proposes a longitudinal and lateral coordinated control method considering fixed sensor delay, actuator lag, and timevarying CAN communication delay. An adaptive all-pass filter time-delay estimator (AAPF-TDE) based on finite impulse response (FIR) and its improved strategies are designed to realize accurate online estimation of CAN communication delay. According to the estimated delay, a longitudinal and lateral coupling time-delay dynamics model with prediction revision and delay augmentation is constructed. A model predictive controller (MPC) combined with Lyapunov asymptotic stability constraints is then designed. CarSim/Simulink co-simulation and vehicle experiment results show that the proposed controller can improve the vehicle stability effectively while ensuring the longitudinal and lateral control accuracy under large delay conditions compared with the controller without considering delay or only considering fixed delay. IEEE

关键词： Time delay

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Anion-Regulated Weakly Solvating Electrolytes for High-Voltage Lithium Metal Batteries

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Energy & Environmental Materials 2023年第6期6卷 259-265页

作者： Zhipeng Jiang Jisheng Mo Chen Li Haiwen Li Qingan Zhang Ziqi Zeng Jia Xie Yongtao Li School of Materials Science and Engineering&Low-Carbon New Materials Research Center Anhui University of TechnologyMaanshan 243002China Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials of Ministry of Education Anhui University of TechnologyMaanshan 243002China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China Hefei General Machinery Research Institute Hefei 230031China

Development of advanced high-voltage electrolytes is key to achieving high-energy-density lithium metal batteries(LMBs).Weakly solvating electrolytes(WSE)can produce unique anion-driven interphasial chemistry via altering the solvating power of the solvent,but it is difficult to dissolve the majority of Li salts and fail to cycle at a cut-off voltage above 4.5 ***,we present a new-type WSE that is regulated by the anion rather than the solvent,and the first realize stable cycling of dimethoxyethane(DME)at 4.6 V without the use of the“solvent-in-salt”*** relationships between the degree of dissociation of salts,the solvation structure of electrolytes,and the electrochemical performance of LMBs were systematically *** found that LiBF_(4),which has the lowest degree of dissociation,can construct an anion-rich inner solvation shell,resulting in anion-derived anode/cathode *** to such unusual solvation structure and interphasial chemistry,the Li-LiCoO_(2)full cell with LiBF_(4)-based WSE could deliver excellent rate performance(115 mAh g^(-1)at 10 C)and outstanding cycling stability even under practical conditions,including high loading(10.7 mg cm^(-2)),thin Li(50μm),and limited electrolyte(1.2μL mg^(-1)).

关键词： high-voltage LiCoO_(2) lithium metal batteries solvation structure weakly solvating electrolyte

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Promising thermal photonic management materials for sustainable human habitat

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Nano Research 2024年第1期17卷 112-131页

作者： Houze Yao Qihua Liao Huhu Cheng Liangti Qu Key Laboratory of Organic Optoelectronics&Molecular Engineering Ministry of EducationDepartment of ChemistryLaboratory of Flexible Electronics TechnologyTsinghua UniversityBeijing 100084China State Key Laboratory of Tribology in Advanced Equipment(SKLT) Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China

The spectral characteristics of outdoor structures,such as automobiles,buildings,and clothing,determine their energy interaction with the environment,from broad-spectrum absorption of light energy to high-efficiency thermal *** developed spectrally selective absorption(SSA)materials permit the reduction of energy loss from human habitat eco-system in the sustainable way and further reduce the utilization of fossil energy to achieve carbon *** we review recent advances in SSA materials that enable rational and efficient management of thermal energy and provide new solutions for the resource base that supports human life like comfortable heat management,electricity production,and water *** basic principles of thermal photonic management,the regulation of SSA materials,and functional properties are *** outlook discussing challenges and opportunities in SSA material energy management for comfortable living environments is finally presented,which expects the enormous potential of this interdisciplinary research in solving growing resource-shortage of human society.

关键词： spectrally selective absorption passive cooling solar power eco-system

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Thermal cycling on microstructure and mechanical properties of laser powder bed fusion manufactured IN738LC alloy

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Rare Metals 2024年第12期43卷 6649-6672页

作者： Yong Hu Hui-Bin Jia Yong-Qi Hu Cheng Chu Xu Zhang Li-Hua Wang Dong Zhang School of Material Science and Engineering Lanzhou University of TechnologyLanzhou730050China State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of TechnologyLanzhou730050China State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization Jinchang737100China

This study investigated the impact of thermal cycling effects on the microstructure and mechanical properties of IN738LC alloy manufactured by laser powder bed fusion,considering different volumetric energy densities(VEDs)and interlayer times(ILTs)as part of the experimental *** results show that low VED and long ILT samples displayed superior quality,with an average grain size of 10.97μm and relatively low strain accumulation *** contrast,samples with high VED and long ILT exhibit increased cracking and porosity,the average grain size is 14.63μm and present higher strain accumulation *** nano-primary MC phase within the alloy transformed into a spherical secondary MC phase inside the grain and a polygonal secondary MC phase on the grain *** the low VED and long ILT,the mean equivalent diameter(MED)of MC carbide within the grain and on the grain boundary was 63 and 140 nm,respectively,the tensile strength was 1072±21 *** contrast,for the high VED and long ILT,the MED of MC carbide in the grain and on the grain boundary were 47 and105 nm,respectively,and the tensile strength was794±31 *** tensile strength of high VED and long ILT decreased by 26%compared with low VED and long ILT.

关键词： Laser powder bed fusion(L-PBF) IN738LC alloy Thermal cycling Microstructure Mechanical properties

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