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Kinetic investigation of the energy storage process in graphene fiber supercapacitors:Unraveling mechanisms,fabrications,property manipulation,and wearable applications

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Carbon Energy 2025年第1期7卷 133-173页

作者： Juan Zhang Wenwen Liu Minzhi Du Qingli Xu Minren Hung Ruifang Xiang Meng Liao Xinhou Wang Bingjie Wang Aiping Yu Kun Zhang Key Laboratory of Textile Science and Technology(Donghua University) Ministry of EducationCollege of TextilesDonghua UniversityShanghaiChina Department of Chemical Engineering Waterloo Institute for NanotechnologyUniversity of WaterlooWaterlooONCanada Laboratory of Advanced Materials State Key Laboratory of Molecular Engineering of PolymersDepartment of Macromolecular ScienceFudan University2205 Songhu RdShanghai 200438China College of Mechanical Engineering Donghua UniversityShanghai 201620China

Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving ***,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate *** existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in *** review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of *** theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage *** particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte *** on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are *** on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile *** conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.

关键词： fiber-shaped supercapacitor graphene ion storage ion transport wearable application

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Analysis of DOA Estimation Under Mixed-resolution Based on Conformal Arrays 16

Analysis of DOA Estimation Under Mixed-resolution Based on C...

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16th International Conference on Signal Processing Systems, ICSPS 2024

作者： Gu, Shenao Guo, Muran Key Laboratory of Advanced Marine Communication and Information Technology AVIC United Technology Center for Electromagnetic Spectrum Collaborative Detection and Intelligent cognition College of Information and Communication Engineering Harbin Engineering University Harbin150001 China

ISBN: (纸本)9781510689251

Conformal antennas typically utilize short dipoles to reduce space occupation. Conformal antenna arrays are essentially polarization-sensitive arrays with broad applicability and enhanced anti-interference capabilities. However, a practical issue that needs to be addressed is the high power consumption and resource usage resulting from high-resolution analog-to-digital converters (ADCs). In this paper, we introduce the mixed-resolution quantization method into the conformal array to alleviate the pressure on resource transmission by partially reducing the quantization resolution. The receive signal model is constructed in this paper, and a rank-deficient MUSIC algorithm suitable for the proposed scheme is developed. The direction of arrival (DOA) parameters, as well as the polarization parameters, are estimated with considerable accuracy. The power consumption and system cost are effectively reduced with a small sacrifice on parameter estimation accuracy. Numerical simulations validate the feasibility of proposed mixed-quantized conformal array. © 2025 SPIE.

关键词： Direction of arrival

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Enhancing rheology and mechanical properties of DLP 3D-printed Si_(3)N_(4)materials via composition optimization and gas-pressure sintering

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International Journal of Minerals,Metallurgy and Materials 2025年第5期32卷 1220-1233页

作者： Qing Qin Gang Xiong Lin Han Yujuan Zhang Zhen Shen Changchun Ge Institute of Powder Metallurgy and Advanced Ceramics School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China State Key Laboratory of Multimodal Artificial Intelligence Systems Beijing Engineering Research Center of Intelligent Systems and TechnologyInstitute of AutomationChinese Academy of SciencesBeijing 100190China

Digital light processing(DLP)is a crucial additive manufacturing(AM)technique for producing high-precision ceramic *** study aims to optimize the formulation of Si_(3)N_(4)slurry to enhance both its performance and manufacturability in the DLP process,and investigate key factors such as particle size distribution,photopolymer resin monomer ratios,and dispersant types to im-prove the slurry’s rheological *** these optimizations,a photosensitive Si_(3)N_(4)slurry with 50vol%solid content was de-veloped,exhibiting excellent stability,and low viscosity(2.48 Pa·s at a shear rate of 12.8 s^(-1)).The effects of gas-pressure sintering on the material’s phase composition,microstructure,and mechanical properties were further explored,revealing that this technique significantly increases the flexural strength of the green sample from(109±10.24)to(618±42.15)*** sintered ceramics exhibited high hard-ness((16.59±0.05)GPa)and improved fracture toughness((4.45±0.03)MPa·m^(1/2)).Crack trajectory analysis revealed that crack deflec-tion,crack bridging,and the pull-out of rod-likeβ-Si_(3)N_(4)grains,are the main toughening mechanisms,which could effectively mitigate crack *** these mechanisms,crack deflection and bridging were particularly influential,significantly enhancing the frac-ture toughness of the Si_(3)N_(4)***,this research highlights how monomer formulation and gas-pressure sintering strengthen the performance of Si_(3)N_(4)slurry in the DLP three-dimensional printing *** work is expected to provide new insights for fabricat-ing complex Si_(3)N_(4)ceramic components with superior mechanical properties.

关键词： additive manufacturing Si_(3)N_(4)slurry low viscosity pressure sintering

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Visible-light-induced controllable transformations of cumulative aryldienes through an energy transfer process

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Science China Chemistry 2025年第3期68卷 987-1001页

作者： Ling Qian Ziqi Yu Jiaxin Liu Yin Wei Min Shi Key Laboratory for Advanced Materials and Institute of Fine Chemicals Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research CenterSchool of Chemistry&Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Organometallic Chemistry Center for Excellence in Molecular SynthesisUniversity of Chinese Academy of SciencesShanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials Shanghai Institute of Organic ChemistryUniversity of Chinese Academy of SciencesChinese Academy of SciencesShanghai 200032China

In this work,we report a visible light-induced energy transfer process related photochemical protocol of cumulative diene containing compounds for the construction of benzocyclohexene skeletons or the corresponding aromatized structures through an energy transfer process,1,5-hydrogen atom transfer and a 6πelectrocyclization or demethoxylation in the presence of different photocatalysts such as[Ir(dF(Me)ppy)_(2)(dtbbpy)]PF_(6) or *** newly developed photochemical strategy is characterized by mild conditions,broad substrate applicability,good functional group tolerance and good *** mechanistic paradigm was clarified by deuterium labeling,kinetic,photophysical and electrochemical analyses,control experiments and density functional theory(DFT)*** transformation of the obtained product to the drug-like molecules such as Sertraline and the luminescent conjugated aromatic compounds has also been disclosed.

关键词： visible-light photocatalysis EnT process 1,5-HAT remote C(sp^(3))-H bond activation

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Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification

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Chinese Chemical Letters 2025年第1期36卷 272-276页

作者： Jiahao Li Guinan Chen Chunhong Chen Yuanyuan Lou Zhihao Xing Tao Zhang Chengtao Gong Yongwu Peng College of Materials Science and Engineering Zhejiang University of TechnologyHangzhou 310014China State Key Laboratory of Organic Electronics and Information Displays&Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China

Controlled synthesis of two-dimensional covalent organic frameworks(2D COFs),including stoichiometric and sub-stoichiometric variations,is a topic of growing interest due to its potential in gas separation *** this study,we successfully synthesized three distinct 2D COFs by carefully adjusting solvent compositions and monomer ratios during the synthesis of[4+4]type *** included a stoichiometric[4+4]type COF and two sub-stoichiometric[4+2]type COFs,featuring unreacted amino or formyl *** resulting COFs exhibit different gas adsorption and separation ***,sub-stoichiometric COF-DA with residual amino groups shows comparable adsorption capacity for C_(2)H_(2),C_(2)H_(4),and CO_(2)to stoichiometric *** contrast,sub-stoichiometric COF-Py with residual formyl groups displays enhanced adsorption selectivity for C_(2)H_(2)/C_(2)H_(4)and C_(2)H_(2)/CO_(2)separation,with the C_(2)H_(2)/C_(2)H_(4)selectivity being the highest among reported COFs,attributed to increased pore polarity resulting from the presence of formyl *** study not only offers an additional example of substoichiometric COF synthesis but also advocates for further exploration of sub-stoichiometric COF materials,particularly in the field of gas adsorption and separation.

关键词： Two-dimensional covalent organic frameworks Stoichiometric and sub-stoichiometric Residual functional groups Ethylene purification

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Developing High-Energy, Stable All-Solid-state Lithium Batteries Using Aluminum-Based Anodes and High-Nickel Cathodes

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Nano-Micro Letters 2025年第1期17卷 1-15页

作者： Wu, Xin Wang, Meiyu Pan, Hui Sun, Xinyi Tang, Shaochun Zhou, Haoshen He, Ping Center of Energy Storage Materials & Technology Department of Energy Science and Engineering College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing210093 China Department of Materials Science and Engineering College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing210093 China

Aluminum (Al) exhibits excellent electrical conductivity, mechanical ductility, and good chemical compatibility with high-ionic-conductivity electrolytes. This makes it more suitable as an anode material for all-solid-state lithium batteries (ASSLBs) compared to the overly reactive metallic lithium anode and the mechanically weak silicon anode. This study finds that the pre-lithiated Al anode demonstrates outstanding interfacial stability with the Li6PS5Cl (LPSCl) electrolyte, maintaining stable cycling for over 1200 h under conditions of deep charge–discharge. This paper combines the pre-lithiated Al anode with a high-nickel cathode, LiNi0.8Co0.1Mn0.1O2, paired with the highly ionic conductive LPSCl electrolyte, to design an ASSLB with high energy density and stability. Using anode pre-lithiation techniques, along with dual-reinforcement technology between the electrolyte and the cathode active material, the ASSLB achieves stable cycling for 1000 cycles at a 0.2C rate, with a capacity retention rate of up to 82.2%. At a critical negative-to-positive ratio of 1.1, the battery’s specific energy reaches up to 375 Wh kg−1, and it maintains over 85.9% of its capacity after 100 charge–discharge cycles. This work provides a new approach and an excellent solution for developing low-cost, high-stability all-solid-state batteries. (Figure presented.) © The Author(s) 2025.

关键词： Solid-state Batteries

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A Novel High Torque Density Spoke-Array Permanent Magnets Vernier Machine with Magnets Bridge

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IEEE Transactions on Industry Applications 2025年

作者： Zhang, Yuwei Zhao, Yu Li, Dawei Qu, Ronghai Huazhong University of Science and Technology State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Wuhan430074 China

In recent years, permanent magnet vernier machine (PMVM) has drawn more attention due to their high torque density. To further improve torque capability, Spoke-array (SA) PM having better flux focusing effect are applied. However, SAPMVM suffers from a considerable torque reduction due to the deteriorated low order working flux harmonics caused by flux barrier effect. Especially, the higher pole ratio (PR), i.e., the ratio of PM pole-pair to armature pole-pair, the severer torque drop of SAPMVM. In this paper, a novel SAPMVM is proposed, where the magnets bridge is introduced, which can effectively restrict the flux barrier effect. As a result, both the working flux harmonics and torque density of SAPMVM are enhanced. To analyze the operating principle of proposed SAPMVM with magnets bridge, an equivalent magnet circuit model is established. Moreover, the electromagnetic performances of the proposed SAPMVM are compared with regular SAPMVM by FEA, where the torque of proposed SAPMVM has increased by 43.3% and 175.6% under rated-load when the PR is selected as 5 and 11. © 1972-2012 IEEE.

关键词： Permanent magnets

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engineering design of feedstock powder and relevant thermal-mechanical performance of thermal/environmental barrier coatings

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Journal of advanced Ceramics 2025年第2期14卷 37-56页

作者： Xinchang Feng Fangwei Guo Lirong Luo Yuzhang Wang Yun Long Xiaofeng Zhao Fei Pan Lei Guo Qingfeng Zeng Jing Feng Chunlei Wan Shanghai Key Laboratory of Advanced High-temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China National Engineering Research Center of Special Equipment and Power System for Ship and Marine Engineering Shanghai 200030China School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Advanced Nuclear Energy Technology Nuclear Power Institute of ChinaChengdu 610213China Innovative Sensor Technology IST AG Ebnat-Kappel 9642Switzerland School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianmushan Laboratory Hangzhou 311115China School of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

The development of aeroengine with a high thrust-weight ratio poses great challenges for current top-coating thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs) in service. Medium/high-entropy ceramics are highly promising candidate material for advanced TBCs/EBCs owing to their low thermal conductivity, high melting point, high-temperature stability, and calcium–magnesium–alumino–silicate (CMAS) resistance. Most feedstock powder used for medium/high-entropy TBCs/EBCs is prepared via traditional spray drying, which cannot fully exploit the advantages of multicomponent ceramics. The density, sphericity, inner structure, and flowability of feedstock powder affect their melting state during the thermal spraying process, which strongly affects the microstructure and properties of the deposited coatings. Therefore, the deposited coatings exhibit phase segregation, amorphous phases, and microstructure defects owing to unpredictable variations in feedstock powder with random morphologies and structures. Here, the structure and properties of feedstock powder prepared by state-of-the-art granulation technologies and their influences on the deposited coatings were systematically investigated, which can provide guidance for configuration optimization of feedstock powder and the manufacturing accuracy of the deposited coating. This review aims to bridge the gap between cutting-edge ceramics and advanced engineering technologies, thus providing concrete background knowledge and crucial guidelines for designing and developing TBCs/EBCs.

关键词： thermal/environmental barrier coatings(TBCs/EBCs) spraying ceramic powder multiscale structure control high-entropy ceramics thermal-mechanical performance

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Dielectric Mechanism and Spectrum Prediction Model for Insulating Paper Based on Three-Dimensional Frequency-Domain Spectroscopy

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IEEE Transactions on Dielectrics and Electrical Insulation 2025年

作者： Liu, Ruiqi Wang, Shengkang Lin, Fuchang Li, Hua Ministry of Education State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Wuhan430074 China

Moisture is a serious concern for transformers, as it will degrade insulation properties and accelerate aging. The dielectric mechanisms of oil-immersed paper (OIP) and the influence of moisture still remains contentious in existing studies, which prevents the application of Frequency-Domain Spectroscopy (FDS) technology in moisture assessment of transformers. OIP is a biphasic composite material composed of oil and paper, and the existence of oil would complicate the understanding of the dielectric mechanisms in solid insulation. Therefore, this study focuses on investigating the dielectric properties of non-immersed insulating paper using FDS. Firstly, the spectra of paper with different moisture content were analyzed, and the relationship between dielectric parameters and moisture was quantified through the proposed dielectric model of insulating paper. Then, a three-dimensional dielectric model for spectrum prediction was established, and the feasibility and universality of model was verified. Results show three distinct dielectric response processes in insulating papers: the hopping conduction (RI), the low-frequency relaxation polarization (RII), and the high-frequency relaxation polarization (RIII). With increasing moisture content, RI and RII processes shift synchronously and exponentially towards higher frequencies with the dielectric curve shape maintained, while RIII process is unaffected. Moreover, the proposed spectrum prediction model can accurately predict the spectrum of insulating paper with varying moisture content. The dielectric response mechanism and three-dimensional dielectric model of insulating paper identified in this study provide the theoretical basis and data support for subsequent studies of the dielectric mechanism and moisture assessment of oil-immersed paper. © 1994-2012 IEEE.

关键词： Frequency domain analysis

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Impact of Hard Segment Structures on Fatigue Threshold of Casting Polyurethane Using Cutting Method

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Chinese Journal of Polymer Science 2025年第2期43卷 303-315页

作者： Guang-Zhi Jin Le-Hang Chen Yu-Zhen Gong Peng Li Run-Guo Wang Fan-Zhu Li Yong-Lai Lu State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing100029China Engineering Research Center of Elastomer Materials Energy Conservation and Resources Ministry of EducationBeijing100029China Key Laboratory of Carbon Fiber and Functional polymers Beijing University of Chemical TechnologyBeijing100029China Center of Advanced Elastomer Materials College of Material Science and EngineeringBeijing University of Chemical TechnologyBeijing100029China

The fatigue resistance of casting polyurethane(CPU)is crucial in various sectors,such as construction,healthcare,and the automotive *** its importance,no studies have reported on the fatigue threshold of *** study employed an advanced Intrinsic Strength Analyzer(ISA)to evaluate the fatigue threshold of CPUs,systematically exploring the effects of three types of isocyanates(PPDI,NDI,TDI)that contribute to hard segment structures based on the cutting *** multiple advanced characterization techniques(XRD,TEM,DSC,AFM),the results indicate that PPDI-based polyurethane exhibits the highest fatigue threshold(182.89 J/m^(2))due to a highest phase separation and a densely packed spherulitic structure,although the hydrogen bonding degree is the lowest(48.3%).Conversely,NDI-based polyurethane,despite having the high hydrogen bonding degree(53.6%),exhibits moderate fatigue performance(122.52 J/m^(2)),likely due to a more scattered ***-based polyurethane,with the highest hydrogen bonding degree(59.1%)but absence of spherulitic structure,shows the lowest fatigue threshold(46.43 J/m^(2)).Compared to common rubbers(NR,NBR,EPDM,BR),the superior fatigue performance of CPU is attributed to its well-organized microstructure,polyurethane possesses a higher fatigue threshold due to its high phase separation degree and orderly and dense spherulitic structure which enhances energy dissipation and reduces crack propagation.

关键词： Casting polyurethane Fatigue threshold Cutting method Hard segment structures Materials characterization

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