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Highly electrically conductive MOF/conducting polymer nanocomposites toward tunable electromagnetic wave absorption

材料科学技术（英文版） 2025年第2期205卷 258-269页

作者： Xin Wu Peiyuan Kang Yinghan Zhang Haocheng Guo Shuoying Yang Qi Zheng Lianjun Wang Wan Jiang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Engineering Research Center of Advanced Glasses Manufacturing Technology Ministry of EducationDonghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Institute of Functional Materials Donghua UniversityShanghai 201620China

Metal-organic frameworks(MOFs)have attracted significant interest as self-templates and precursors for the synthesis of carbon-based composites aimed at electromagnetic wave(EMW)***,the utilization of high-temperature treatments has introduced uncertainties regarding the compositions and microstructures of resulting ***,complete carbonization has led to diminished yields of the produced carbon composites,significantly limiting their practical ***,the exploration of pristine MOF-based EMW absorbers presents an intriguing yet challenging endeavor,primarily due to inherently low electrical *** this study,we showcase the utilization of struc-turally robust Zr-MOFs as scaffolds to build highly conductive Zr-MOF/PPy composites via an inner-outer dual-modification approach,which involves the production of conducting polypyrrole(PPy)both within the confined nanoporous channels and the external surface of Zr-MOFs via post-synthetic *** interconnection of confined PPy and surface-lined PPy together leads to a consecutive and extensive conducting network to the maximum *** therefore entails outstanding conductivity up to～14.3 S cm-1 in Zr-MOF/PPy composites,which is approximately 1-2 orders of magnitude higher than that for conductive MOF nanocomposites constructed from either inner or outer *** from the strong and tunable conduction loss,as well as the induced dielectric polarization originated from the porous structures and MOF-polymer interfaces,Zr-MOF/PPy exhibits excellent microwave attenuation capabilities and a tunable absorption frequency ***,with only 15 wt.％loading,the mini-mum reflection loss(RLmin)can reach up to-67.4 dB,accompanied by an effective absorption bandwidth(EAB)extending to 6.74 ***,the microwave absorption characteristics can be tailored from the C-band to the Ku-band by adjusting the loading of *** work provide

关键词： Conductive mof nanocomposites electromagnetic wave absorption MOF/conducting polymer Electrical conductivity Zr-MOF/PPy

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Janus MXene film with gradient structure for highly efficient terahertz and infrared electromagnetic absorption

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Nano Research 2025年第1期18卷 434-442页

作者： Shaodian Yang Weiqiang Huang Zhiqiang Lin Zibo Chen Rongliang Yang Yi Jia Xuebin Liu Rui Wang Zhiping Zeng Yougen Hu Huanjun Chen Xuchun Gui11 State Key Laboratory of Optoelectronic Materials and Technologies School of Electronics and Information TechnologySun Yat-sen UniversityGuangzhou 510275China National Key Laboratory of Materials for Integrated Circuits Shenzhen Institute of Advanced Electronic MaterialsShenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China China Academy of Aerospace Science and Innovation Beijing 100176China Guangdong Province Key Laboratory of Display Material and Technology Guangzhou 510275China School of Materials Science and Engineering Sun Yat-sen UniversityGuangzhou 510275China

electromagnetic interference (EMI) shielding inhigh-frequency range, especially the rapidly growing terahertz(THz) frequency range, attracts increasing attention due tothe potential application of terahertz in 6G wirelesscommunication, and security inspection. However, traditionalconductive EMI films typically achieve high shieldingeffectiveness through strong reflection, which may causesecondary pollution to other devices. Here, a gradientstructure strategy was proposed to constructTi_(3)C_(2)Tx/hydroxypropyl methyl cellulose (HPMC) film, in whichthe content of Ti_(3)C_(2)Tx gradually increases along the thicknessdirection, resulting in different conductivity of the two surfaces(surface-M and surface-H) for the film. The obtained gradientfilmexhibits an EMI shielding efficiency of over 48.5 dB in theTHz range (0.2-1.6 THz) at a thickness of 40 μm. Especially,as the THz waves incident from the surface-H to the film, the absorption effectiveness reaches 48.2 dB (average absorbedpower loss up to 91.4%), and the reflection effectiveness is only 0.3 dB. In additions, the gradient-film also demonstrates ahigh absorption rate of 95.5% in the infrared band (2.5-16.7 μm). Moreover, the gradient-film exhibits an excellent tensilestress and Young’s modulus value of 173.1 MPa and 2.8 GPa, respectively. Therefore, the gradient-film proposed in thiswork, with excellent electromagnetic absorption in both THz and infrared band, provides a promising candidate for the nextgenerationEMI shielding applications.

关键词： electromagnetic interference shielding Janus film terahertz MXene

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Advancements in Poly(ionic liquid) composites with carbon nanomaterials

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advanced Industrial and engineering Polymer Research 2025年第2期8卷 196-210页

作者： Li, Hui Gao, Jie Li, Zhiyong Zhang, Yan Zhang, Jun Zhang, Shiguo College of Materials Science and Engineering State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle Hunan University Changsha410004 China School of Chemistry and Chemical Engineering Henan Normal University Xinxiang453007 China

Carbon nanomaterials have become essential in modern daily life. Their porous nature and good electrical conductivity are critical for composite applications. However, their inherent van der Waals forces and π-π interactions often result in spontaneous aggregation, which significantly hinders the uniform dispersion of carbon materials in polymer matrices. Establishing interactions between poly(ionic liquid) (PIL) and carbon materials ensures excellent compatibility. Integrating carbon materials with PIL markedly enhances mechanical strength, electrical conductivity, and thermal stability, benefiting the electronics, energy storage, and automotive industries. A thorough understanding of the physical and chemical properties of PILs is crucial for tailoring composite materials to specific applications, enhancing processing capabilities, and boosting performance. This article reviews recent advancements in PIL composites incorporating carbon nanomaterials and outlines future challenges in their development. © 2024 Kingfa Scientific and Technological Co. Ltd.

关键词： Automotive industry

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First-principles calculations study of valley polarization in antiferromagnetic bilayer systems

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Physical Review B 2025年第14期111卷 L140404-L140404页

作者： San-Dong Guo Ping Li Guangzhao Wang School of Electronic Engineering Xi'an University of Posts and Telecommunications Xi'an 710121 China State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 China Key Laboratory of Extraordinary Bond Engineering and Advanced Materials Technology of Chongqing School of Electronic Information Engineering Yangtze Normal University Chongqing 408100 China

Superior to ferromagnetic (FM) valleytronics, antiferromagnetic (AFM) counterparts exhibit ultradense and ultrafast potential due to their intrinsic advantages of zero stray field, terahertz dynamics, and compensated moments of antiferromagnets. However, the physics of spontaneous valley polarization is mainly rooted in FM hexagonal lattices and is rarely used to explore the simultaneous spin and valley polarizations in AFM materials. Here, we propose a general stacking method to achieve valley polarization in AFM bilayer systems. The hexagonal ferrovalley material is used as the basic building unit, and then the space-inversion centrosymmetric bilayer system with interlayer AFM ordering is constructed by horizontal mirror and twofold rotational operations, which can exhibit spontaneous valley polarization. In this construction process, the rarely explored layer-locked hidden valley polarization, hidden Berry curvature, and layer Hall effect are involved, and an out-of-plane electric field can be used to detect hidden valley polarization and to realize layer-locked anomalous valley Hall effect. We use three examples to illustrate our proposal. First, the Janus GdBrI is used to illustrate concepts and effects involved in our design process. Second, the RuBr2 is used to demonstrate other phenomena, including valley polarization transition and near-ideal quantum spin Hall insulators. Finally, we use our design principles to understand the valley polarization of experimentally synthesized MnSe from a new perspective. Our works establish a robust general scheme to achieve valley polarization in AFM bilayer systems, thereby opening up new avenues for AFM valleytronics.

关键词： Landforms

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Divertor heat flux challenge and mitigation in the EHL-2 spherical torus

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Plasma Science and technology 2025年第2期27卷 97-109页

作者： Fuqiong WANG Xiang GU Jiankun HUA Yumin WANG Xiaokun BO Bo CHEN Yuejiang SHI Shuai XU Erhui WANG Yunfeng LIANG the EHL-2 Team College of Physics Donghua UniversityShanghai 201620People’s Republic of China Hebei Key Laboratory of Compact Fusion Langfang 065001People’s Republic of China ENN Science and Technology Development Co. Ltd.Langfang 065001People’s Republic of China International Joint Research Laboratory of Magnetic Confinement Fusion and Plasma Physics State Key Laboratory of Advanced Electromagnetic Engineering and TechnologySchool of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China Forschungszentrum Jülich GmbH Institute of Fusion Energy and Nuclear Waste Management-Plasma PhysicsJülich 52425Germany

The divertor design is critical to heat load handling and thus to achievements of highperformance plasma operations in the EHL-2(ENN He-Long 2)*** paper presents the design of an X-point target(XPT)divertor,featuring a conventional inner divertor and an XPT outer divertor,aimed at the effective control of heat loads,which may be extremely high during high ion temperature *** divertor target plates are made from carbon-based materials,which can handle heat loads of up to 5 MW/m².Divertor performances,including the heat load controllability,the onset of detachment and the in-out/up-down asymmetry,etc.,are evaluated using both the simple particle-tracking strategy and the complicated SOLPS-ITER *** attention is paid to the drift effects on particle/heat transport in the divertor/scrape-off layer region and on the divertor heat loads,focusing on the semi-detached/detached operation *** from SOLPS-ITER simulations demonstrated that the currently designed magnetic equilibrium and divertor configuration can effectively handle the power heat load in EHL-2.

关键词： heat flux divertor EHL-2

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Kinetics of hydrogen sulfide removal from coke oven gas over faujasite zeolite: Experimental and modeling studies

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Chinese Journal of Chemical engineering 2025年 78卷 232-244页

作者： Gao, Feng Zhu, Sixiao Chang, Liping Bao, Weiren Ma, Jinghong Liao, Junjie State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of Technology Taiyuan030024 China Key Laboratory of Coal Science and Technology Ministry of Education Taiyuan University of Technology Taiyuan030024 China School of Chemistry and Chemical Engineering Taiyuan University of Technology Taiyuan030024 China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan030024 China

The removal of H2S from coke oven gas (COG) is an important issue for the further utilization of COG. Zeolites could be used for industrial desulfurization owing to their high thermal stability and regenerability. However, further analysis on the kinetics of deep desulfurization using zeolites is necessary to provide relevant information for industrial design. In this study, the desulfurization breakthrough curves of faujasite (FAU) zeolite in COG were measured using a fixed bed reactor. The adsorption isotherm was investigated using the Langmuir, Freundlich, Temkin, Dubinin-Radushkevich models. The adsorption saturated capacity of H2S was inversely related to the temperature. The results show that the Langmuir model best fits the adsorption isotherm with a lower value of root-mean-square-error (RMSE) and Chi-Square (χ2), and the calculated activation energy is 14.62 kJ·mol−1. The adsorption kinetics were investigated using pseudo-first-order (PFO), pseudo-second-order (PSO), Bangham and Weber-Morris models. The Bangham model fitted the kinetic data well, indicating that pore diffusion is an influential factor in the adsorption process. The Weber-Morris model suggests that the adsorption rate was not solely determined by the pore diffusion, but was also influenced by the active site on the FAU zeolite. The adsorption breakthrough curves under different gas flow rates were fitted using the bed depth service time (BDST) model, and it provides an accurate prediction of the breakthrough time with a small relative error. The results of thermodynamic analysis demonstrated the feasibility and spontaneity (ΔG2S under COG. © 2024 Chemical Industry and engineering Society of China (CIESC) and Chemical Industry Press Co., Ltd. (CIP)

关键词： Desulfurization

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Mechanisms and Mitigation Strategies of Gas Generation in Sodium-Ion Batteries

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Nano-Micro Letters 2025年第8期17卷 17-48页

作者： Xingyan Li Xi Chen Meng Li Haoran Wei Xuming Yang Shenghua Ye Liewu Li Jing Chen Xiangzhong Ren Xiaoping Ouyang Jianhong Liu Xiangtong Meng Jieshan Qiu Biwei Xiao Qianling Zhang Jiangtao Hu Graphene Composite Research Center College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhen 518060People’s Republic of China GRINM(Guangdong)Research Institute for Advanced Materials and Technology Foshan 528051GuangdongPeople’s Republic of China School of Materials Science and Engineering Xiangtan UniversityXiangtan 411105People’s Republic of China College of Chemical Engineering State Key Laboratory of Organic-Inorganic CompositesState Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China

The transition to renewable energy sources has elevated the importance of SIBs(SIBs)as cost-effective alternatives to lithium-ion batteries(LIBs)for large-scale energy *** review examines the mechanisms of gas generation in SIBs,identifying sources from cathode materials,anode materials,and electrolytes,which pose safety risks like swelling,leakage,and *** such as CO_(2),H_(2),and O_(2) primarily arise from the instability of cathode materials,side reactions between electrode and electrolyte,and electrolyte decomposition under high temperatures or *** mitigation strategies,encompassing electrolyte design,buffer layer construction,and electrode material optimization,are deliberated ***,subsequent research endeavors should prioritize long-term high-precision gas detection to bolster the safety and performance of SIBs,thereby fortifying their commercial viability and furnishing dependable solutions for large-scale energy storage and electric vehicles.

关键词： Sodium-ion batteries Gas evolution mechanism Inhibition strategies of gas generation High-performance sodium-ion battery roadmap

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Fluorinated Electrolyte-Assisted Dry Nano LLZO Composite Solid-state Electrolytes for Lithium-Metal Batteries 3

Fluorinated Electrolyte-Assisted Dry Nano LLZO Composite Sol...

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2024 3rd International Youth Scientist Forum - Academic Symposium on New Energy and New Material, IYSF-NENM 2024

作者： Han, Qigao Wang, Fuhe Wang, Fengqian Ji, Shuaijing Zhong, Jun Du, Jinqiao Tian, Jie Zhang, Weixin Tang, Shun Cao, Yuancheng Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Wuhan430074 China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China Shenzhen Power Supply Co. Ltd. Shenzhen518001 China

Li7La3Zr2O12 composite solid-state electrolytes (LLZO CSSEs) face severe application challenges due to the effect of grain boundary impedance. For this reason, the ionic conduction blocking effect caused by the polymer is mitigated by a dry process while reducing the polymer content. When paired with the designed fluorinated electrolyte, the ionic conductivity of the LLZO CSSEs reach 1.52 mS cm-1, exhibiting a significant ionic conduction synergistic effect. The wide electrochemical stabilization window and better flame retardancy can guarantee the stable application of LLZO CSSEs in lithium-metal batteries, and the lithium symmetric batteries can be stably cycled more than 1000 hours under the current density of 1 mA cm-2. The Li|LiNi0.8Co0.1Mn0.1O2 solid-state batteries achieved a better rate performance with the specific capacity of 128.50 mAh g-1 under the current of 5 C. These results indicate that LLZO CCSEs have the potential for further applications and are contributed to the development of lithium-metal batteries. © 2025 Institute of Physics Publishing. All rights reserved.

关键词： Solid-state Batteries

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Reduced graphene oxide-induced in-situ uniform growth of hydrated WO_(3) film for enhanced electrochromic performance

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Nano Research 2025年第4期18卷 569-577页

作者： Rui Fang Yang Liu Chunyu Shi Huihui Jin Zibo Chen Haohao Sun Ben Lv Daping He Xusheng Zheng Yuli Xiong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China School of Science Wuhan University of TechnologyWuhan 430070China National Synchrotron Radiation Laboratory University of Science and Technology of ChinaHefei 230029China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China

WO_(3)-graphene electrochromic materials are widely used in electrochromic devices including smart windows and electronic displays,due to their ability to adjust optical transmittance in the visible and near-infrared ranges under low electrode ***,the uniformity of the film remains a challenge for the widely used physical mixing-coating *** this study,we present a two-dimensional material-assisted synthesis of a porous hydrated WO_(3) film(WH-rGO)based on reduced graphene oxide(rGO)nanosheets and WO_(3)(rGO-WO_(3))seed layer via a hydrothermal *** incorporation of rGO not only promotes the uniform growth of hydrated WO_(3) film,enhancing ion transport but also introduces oxygen vacancies,creating an efficient conduction pathway for charge *** resulting WH-rGO film exhibits impressive performance,achieving 71% optical modulation at 700 nm,with bleaching and coloring times of 4.2 and 1.0 *** coloration efficiency is calculated at 156.11 cm^(2)·C^(-1),and the optical modulation is maintained at 93% of the initial optical modulation after 1000 cycles applied in the +1.0 and -1.1 V potential *** work offers new insights into the role of oxygen vacancies in enhancing the electrochromic properties of hydrated WO_(3) films through the addition of *** also provides a promising approach for the synthesis of electrochromic materials,facilitating their application in smart window technologies.

关键词： electrochromic film hydrated tungsten oxide reduced graphene oxide oxygen vacancy

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Fatigue failure analysis and heat treatment strategy optimization of torsion bar spring for automobile suspension system used in light vehicles

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Journal of Iron and Steel Research International 2025年第3期32卷 799-811页

作者： Jia-xing Liu Yong-jin Wu Chao-lei Zhang Wan-li Sun Wen-bin Ding Shuai-jun Dong Institute for Carbon Neutrality School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing100083China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing100083China Institute of Steel Sustainable Technology Liaoning Academy of MaterialsShenyang110167LiaoningChina

The failure analysis was conducted on unqualified torsion bar spring in automobile suspension system used for light vehicles during engine *** effects of through hardening,surface induction hardening,quenching and tempering,and tempering temperature on the microstructure and fatigue life of 45CrNiMoVA steel torsion bars were also *** showed that only the torsion bar spring after through quenching and tempering is subjected to surface induction quenching and tempering to achieve the fatigue life of the qualified torsion *** fatigue life of torsion bar spring reaches 3×10^(5) cycles more than the required 2×10^(5) *** is because the distribution of gradient microstructure was helpful to relieve the applied stress during the fatigue *** microstructure of the non-hardened region,which consists of tempered sorbite regardless of whether it is tempered at 330 or 430℃,contributes to minimizing the impact of temper brittleness on the fatigue life of the torsion ***,the fatigue life of the torsion bar is relatively unaffected by temper brittleness due to the presence of tempered sorbite in its non-hardened *** the reason for the unqualified fatigue life was that the depth and hardness of the hardened region did not meet the standard requirements of 5–7 mm and 47–52 HRC,respectively.

关键词： Fatigue life Torsion bar Tempering temperature 45CrNiMoVA steel Fracture

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