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Emerging Liquid Crystal Technologies XX 2025

作者： Zhou, Le Liu, Yuanfeng Neyts, Kristiaan Shen, Yang Sun, Jingbo Zhou, Ji Physics Department Colorado School of Mines 1523 Illinois St. GoldenCO80401 United States School of Materials Science and Engineering State Key Laboratory of New Ceramics and Fine Processing Tsinghua University Beijing100084 China Department of Electronic and Computer Engineering State Key Laboratory of Advanced Displays and Optoelectronics Technologies The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong

ISBN: (纸本)9781510685222

Structured light refers to the light field tailored by various degrees of freedom including intensity, phase, and polarization states in both spatial and temporal domains, which may greatly vitalize the technologies in both optics, such as the next-generation optical communication as well as imaging and the materials science in both fabrications and characterizations. The structured characteristics of the structure light need materials also with structured optical properties that can generate or manipulate structured light in a straightforward way, which can be well satisfied by liquid crystals or glassy liquid crystals such as special spherulites. © 2025 SPIE.

关键词： Degrees of freedom (mechanics)

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Ab-initio insight into electrochemical characteristic of Zr2N monolayer as sodium ion battery by O and Se functional group strategy

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Journal of Molecular Liquids 2025年 429卷

作者： Yin, Jiangtao Li, Lingxia Zhang, Wenbo Gong, Shengli Ren, Junqiang Liu, Maocheng Lu, Xuefeng State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals School of Materials Science and Engineering Lanzhou University of Technology Lanzhou730050 China

As a novel type of two-dimensional electrode material, MXene with versatile surface functional groups can provide additional active sites, exhibiting high pseudo capacitance and large specific capacity. This article uses first principles to investigate the electrochemical properties of oxygen and halogen elements modified Zr2N as anode materials for sodium ion batteries. The results indicate that O and Se functionalized Zr2N material is more suitable as an anode material for sodium ion batteries compared to other functionalized materials. Zr2NT2 (Zr2NO2 and Zr2NSe2) have low diffusion barriers to facilitate the diffusion of sodium ions, with a theoretical capacity of 293.29 mAh/g and 151.29 mAh/g, respectively. The open circuit voltage is in the range of 0–1 V, which can prevent the formation of lithium dendrites and ensure the safe operation of the battery. These characteristics are attributed to the redistribution of surface charges for functionalized Zr2N, which results in uniform interaction forces between adsorbed atoms and the matrix, thereby improving the adsorption stability of sodium ions. In summary, this study reveals the energy storage performance mechanism of O and Se functionalized MXene electrode materials at the microscale, laying a solid foundation for subsequent experimental preparation. © 2025 Elsevier B.V.

关键词： Active material Electronic properties First-principles calculations MXene Sodium-ion batteries

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A Positive and Negative-Sequence Equivalent Circuit Model for Linear Induction Machine Adapted to Urban Rail Transit

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IEEE Transactions on Transportation Electrification 2025年

作者： Guo, Yingcong Xu, Wei Ge, Jian Shangguan, Yongdao Xiao, Han Tang, Yirong Southwest Jiaotong University School of Electrical Engineering Chengdu610031 China Beijing100190 China University of Chinese Academy of Sciences School of Electronic Electrical and Communication Engineering Beijing101408 China Huazhong University of Science and Technology State Key Laboratory of Advanced Electromagnetic Technology School of Electrical and Electronic Engineering Wuhan430074 China

The equivalent circuit model is a crucial tool for estimating the performance of linear induction machines (LIMs), and it is widely used in design, optimization, etc. However, the conventional model which does not account for the asymmetrical current is not as precise in certain scenarios. Such asymmetrical current is caused by the inherent end effect in LIMs, which persists even when the machine is powered by a symmetrical voltage source. In this paper, a novel equivalent circuit model is proposed to enhance the precision of analyzing LIMs performance under asymmetrical current. Firstly, the relationship between current, back electro-motive force (EMF) and voltage is established by analyzing the positive and negative-sequence airgap magnetic field. Secondly, the excitation source is converted from symmetrical phase voltage to positive and negative-sequence current by solving the circuit constraint equation. Finally, a positive and negative-sequence equivalent circuit model is constructed and the LIM performance is further analyzed. The proposed model is thoroughly validated through comparison with other methods and experimental data. © 2015 IEEE.

关键词： Urban transportation

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Recent Advances in Wide-Range Temperature Metal-CO_(2)Batteries:A Mini Review

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Nano-Micro Letters 2025年第4期17卷 435-453页

作者： Xuejing Zhang Ning Zhao Hanqi Zhang Yiming Fan Feng Jin Chunsheng Li Yan Sun Jiaqi Wang Ming Chen Xiaofei Hu School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003People’s Republic of China Engineering Research Center of Energy Storage Materials and Devices Ministry of EducationSchool of ChemistryXi’an Jiaotong UniversityXi’an 710049People’s Republic of China State Key Laboratory for Strength and Vibration of Mechanical Structures Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for Petroleum and Chemical Industry of China School of Chemistry and Life SciencesSuzhou University of Science and TechnologySuzhou 215009People’s Republic of China Department of Chemistry and Biochemistry Northern Illinois UniversityDeKalbIL 60115USA School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002People’s Republic of China

The metal-carbon dioxide batteries,emerging as high-energy-density energy storage devices,enable direct CO_(2)utilization,offering promising prospects for CO_(2)capture and utilization,energy conversion,and ***,the electrochemical performance of M-CO_(2)batteries faces significant challenges,particularly at extreme *** such as high overpotential,poor charge reversibility,and cycling capacity decay arise from complex reaction interfaces,sluggish oxidation kinetics,inefficient catalysts,dendrite growth,and unstable *** significant advancements at room temperature,limited research has focused on the performance of M-CO_(2)batteries across a wide-temperature *** review examines the effects of low and high temperatures on M-CO_(2)battery components and their reaction mechanism,as well as the advancements made in extending operational ranges from room temperature to extremely low and high *** discusses strategies to enhance electrochemical performance at extreme temperatures and outlines opportunities,challenges,and future directions for the development of M-CO_(2)batteries.

关键词： M-CO_(2)batteries Wide-range temperature Electrolytes Interfaces Electrode reactions

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Boosting aqueous nickel-zinc battery stability with bimetallic ion-integrated 1D metal-organic nanowires

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Science China Chemistry 2025年第06期 2378-2387页

作者： Yihao Chen Jin Liang Yichun Su Guoyin Zhu Hengyue Xu Hongye Ding Guangxun Zhang Dianheng Yu Zizhou Shen Yizhou Zhang Wei Huang Huan Pang School of Chemistry and Chemical Engineering Yangzhou University Key Laboratory of Flexible Electronics (KLoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Institute of Advanced Materials and Flexible Electronics (IAMFE) School of Chemistry and Materials Science Nanjing University of Information Science & Technology Department of Chemistry Tsinghua University State Key Laboratory of Coordination Chemistry Nanjing University

Limited by low conductivity,designing cathode materials with excellent electron transfer efficiency for high-performance nickel-zinc batteries （NZBs） remains *** this study,a series of bimetallic metal-organic nanowires were fabricated by doping M ions in NiNTA,resulting in NiMNTA (M=Mg2+,Mn2+,Co2+,Zn2+,Ag+),and NixCo6-xNTA （x=1,2,3,4,5）.The proportions and types of metal ions can be modified without altering the initial coordination structure.X-ray absorption fine structure spectroscopy （XAFS） revealed that only M–O bonds,not metal bonds,were present in the *** performance of Ni2Co4NTA as the cathode for aqueous NZBs was significantly improved,achieving the maximum energy density of 279.17Wh kg-1with the high cycle stability （retention rate of 72.0%after 1,000 cycles）.The flexible Ni2Co4NTA//Zn@carbon cloth battery employing gel electrolyte also exhibits the excellent Coulombic efficiency of 96%after 350 *** approach shows considerable potential for designing one-dimensional materials with bimetallic modifications,providing new strategies for developing cathode materials for NZBs with high specific capacity and cycle stability.

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Polyoxometalated metal-organic framework superstructure for stable water oxidation

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Science (New York, N.Y.) 2025年第6745期388卷 430-436页

作者： Yue, Kaihang Lu, Ruihu Gao, Mingbin Song, Fei Dai, Yao Xia, Chenfeng Mei, Bingbao Dong, Hongliang Qi, Ruijuan Zhang, Daliang Zhang, Jiangwei Wang, Ziyun Huang, Fuqiang Xia, Bao Yu Yan, Ya State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai China School of Chemistry and Chemical Engineering State Key Laboratory of Materials Processing and Die & Mould Technology Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology (HUST) Wuhan China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China School of Chemical Sciences University of Auckland Auckland New Zealand National Engineering Laboratory for Methanol to Olefins Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian China Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai Synchrotron Radiation Facility Shanghai China Center for High Pressure Science and Technology Advanced Research Shanghai China Key Laboratory of Polar Materials and Devices (MOE) Department of Electronics East China Normal University Shanghai China Multiscale Porous Materials Center Institute of Advanced Interdisciplinary Studies and School of Chemistry and Chemical Engineering Chongqing University Chongqing China College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University Hohhot China State Key Lab of Metal Matrix Composites School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai China Center for Next-Generation Energy Materials and School of Chemical Engineering Sungkyunkwan University (SKKU) Seobu-ro Jangan-guGyeonggi-do Suwon South Korea

Stable, nonprecious catalysts are vital for large-scale alkaline water electrolysis. Here, we report a grafted superstructure, MOF@POM, formed by self-assembling a metal-organic framework (MOF) with polyoxometalate (POM). In situ electrochemical transformation converts MOF into active metal (oxy)hydroxides to produce a catalyst with a low overpotential of 178 millivolts at 10 milliamperes per square centimeter in alkaline electrolyte. An anion exchange membrane water electrolyzer incorporating this catalyst achieves 3 amperes per square centimeter at 1.78 volts at 80°C and stable operation at 2 amperes per square centimeter for 5140 hours at room temperature. In situ electrochemical spectroscopy and theoretical studies reveal that the synergistic interactions between metal atoms create a fast electron-transfer channel from catalytic iron and cobalt sites, nickel, and tungsten in the polyoxometalate to the electrode, stabilizing the metal sites and preventing dissolution.

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The multifaceted role of post-translational modifications of LSD1 in cellular processes and disease pathogenesis

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Genes & Diseases 2025年第3期12卷 168-179页

作者： Yinrui Li Bo Wang Yichao Zheng Huiqin Kang Ang He Lijuan Zhao Ningjie Guo Hongmin Liu Adil Mardinoglu M.A.A.Mamun Ya Gao Xiaobing Chen Department of Oncology The Affiliated Cancer Hospital of Zhengzhou University&Henan Cancer HospitalHenan Engineering Research Center of Precision Therapy of Gastrointestinal Cancer&Zhengzhou Key Laboratory for Precision Therapy of Gastrointestinal CancerZhengzhouHenan 450008China State Key Laboratory of Esophageal Cancer Prevention&Treatment Key Laboratory of Advanced Drug Preparation TechnologiesMinistry of Education of ChinaKey Laboratory of Henan Province for Drug Quality Control and EvaluationZhengzhouHenan 450001China Institute of Drug Discovery and Development School of Pharmaceutical SciencesZhengzhou UniversityZhengzhouHenan 450001China Henan Institute of Medical and Pharmaceutical Sciences State Key Laboratory for Esophageal Cancer Prevention and TreatmentZhengzhou UniversityZhengzhouHenan 450001China Science for Life Laboratory KTH e Royal Institute of TechnologyStockholm SE-10044Sweden Faculty of Dentistry Oral&Craniofacial SciencesCentre for Host-Microbiome InteractionsKing’s College LondonLondon WC2R 2LSUK

Post-translational modifications(PTMs)of proteins play a crucial role in living organisms,altering the properties and functions of *** are over 450 known PTMs involved in various life ***1(lysine-specific demethylase 1)is the first identified histone demethylase that can remove monomethylation or dimethylation modifications from histone H3 lysine K4(H3K4)and histone H3 lysine K9(H3K9).This ability of LSD1 allows it to inhibit or activate ***1 has been found to abnormally express at the protein level in various tumors, making it relevant to multiple diseases. As a PTM enzyme, LSD1 itself undergoes various PTMs, including phosphorylation, acetylation, ubiquitination, methylation, SUMOylation, and S-nitrosylation, influencing its activity and function. Dysregulation of thesePTMs has been implicated in a wide range of diseases, including cancer, metabolic disorders,neurological disorders, cardiovascular diseases, and bone diseases. Understanding the speciesof PTMs and functions regulated by various PTMs of LSD1 provides insights into its involvementin diverse physiological and pathological processes. In this review, we discuss the structuralcharacteristics of LSD1 and amino acid residues that affect its enzyme activity. We also summarize the potential PTMs that occur on LSD1 and their involvement in cellular ***, we describe human diseases associated with abnormal expression of LSD1. Thiscomprehensive analysis sheds light on the intricate interplay between PTMs and the functionsof LSD1, highlighting their significance in health and diseases.

关键词： Enzyme activity Histone demethylase Human diseases LSD1 Post-translational

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Two-Stage Hand-Eye Calibration based on Variance Minimization Principle

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IEEE Transactions on Instrumentation and Measurement 2025年 74卷

作者： Ding, Tao Tian, Dazhuang Wu, Hao Zhu, Dahu Li, Wenlog Wuhan University of Technology Hubei Key Laboratory of Advanced Technology for Automotive Components School of Automotive Engineering Wuhan430070 China Wuhan University of Technology Hubei Digital Manufacturing Key Laboratory School of Mechanical and Electronic Engineering Wuhan430070 China Wuhan University of Technology Hubei Key Laboratory of Advanced Technology for Automotive Components Hubei Provincial Engineering Research Center of Robot and Intelligent Manufacturing Wuhan430070 China Huazhong University of Science and Technology State Key Laboratory of Intelligent Manufacturing Equipment and Technology Wuhan430074 China

Hand-eye calibration in industrial scenarios greatly determines the efficiency and effectiveness of 3D vision-guided robotic tasks. Most of the existing hand-eye calibration methods, however, rely on collecting large-scale point cloud samples to guarantee high measurement accuracy, which is time-consuming and particularly influenced by measurement defects such as local missing, noise, and uneven density. To overcome this challenging problem, we present a novel two-stage hand-eye calibration method based on the variance minimization principle. In the first stage, a robust function weighted variance minimization (RFWVM) registration algorithm is proposed for fine registration of defective point clouds, aiming at solving the coarse hand-eye calibration matrix with few-shot point clouds. In the second stage, an objective function of the calibration error correction algorithm is established via the point-to-plane distance variance minimization, which is intended to suppress the influence of measurement defects. Through these two stages, the globally optimal hand-eye matrix is solved by iteratively correcting the coarse hand-eye calibration matrix. A series of experiments validate the universality, accuracy, and robustness of the proposed method. © 1963-2012 IEEE.

关键词： Error correction

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Reconfigurable Converter-Formed Soft Open Point- Assisted Dynamic Restoration for Distribution Systems with Cold-load Pickup

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IEEE Transactions on Sustainable Energy 2025年

作者： Yang, Xiaodong Li, Zihao Ding, Lijian Hu, Zhengli Fang, Hui Sun, Wei Wu, Qiuwei Wen, Jinyu Hefei University of Technology State Key Laboratory of High Efficiency and High Quality Electric Energy Conversion Hefei230009 China State Grid Anhui Ultra High Voltage Company Hefei230022 China Tsinghua University Tsinghua-Berkeley Shenzhen Institute Tsinghua Shenzhen International Graduate School Shenzhen518055 China Huazhong University of Science and Technology State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Wuhan430074 China

Improving the power supply resilience under extreme conditions is an important construction goal faced by modern distribution systems (DSs). In this paper, we develop a dynamic restoration framework for renewable DSs with cold-load pickup (CLPU), assisted by the reconfigurable converter-formed multi-terminal soft open point (R-SOP) to minimize the de-energized loads and renewables curtailment under extreme weather events. Traditional SOP often designed as symmetric capacity topology, which may limit the DS restoration quality by the converter capacity of symmetric SOPs. To address this, a dynamic network reconfiguration model of DSs is established that embedded with R-SOP, whose typical feature is the asymmetric converter capacity design while keeping the total port capacity unchanged compared with traditional SOP. On this basis, a multi-period distribution service restoration model is formulated integrating the converter reconfiguration of R-SOP, DS topology changes and coordinated actions of flexible resources to enhance the restoration level and improve the renewable energy utilization. Moreover, restoration strategies that ignore the CLPU phenomenon may face remarkable gap from the realistic system operating conditions. Accordingly, a frequency-constrained dynamic restoration model is proposed in a faster-timescale to respond to the CLPU and restore the DS in a reliable and adaptable manner. Numerical simulations on two modified IEEE test systems and an actual distribution system verify the effectiveness of the developed framework. © 2010-2012 IEEE.

关键词： Restoration

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Self-Adaptive Reflectance Film for Passive Temperature Regulation in Diverse Environments

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advanced Science 2025年

作者： Yang, Shuo Tang, Sizhe Cai, Yufeng Ye, Zhiming Zou, Xiangbin Yuan, Xueyu Song, Yujie Li, Bing Tang, Dongyan Liu, Ming School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin150001 China State Key Laboratory of Special Functional Waterproof Materials Beijing Oriental Yuhong Waterproof Technology Co. Ltd Beijing101111 China Engineering Laboratory of Advanced Energy Materials Ningbo Institute of Materials Technology & Engineering Chinese Academy of Sciences Ningbo315201 China Advanced Energy Science and Technology Guangdong Laboratory Huizhou516000 China State Key Laboratory of Advanced Welding and Joining Harbin Institute of Technology Harbin150001 China

Passive thermal-regulation strategies have become increasingly important due to the strain alleviated on power grids for temperature management. Designing a system capable of automatically switching between cooling and heating modes in response to changing ambient conditions presents several specific challenges that engineers and researchers are actively addressing. In this research, a CaCl2 incorporated PNIPAM coated fluorinated poly(aryl ether) (FPAE) porous film with tunable reflectance is developed. The aim is to mitigate the reliance on active cooling systems, which consume significant amounts of energy. The moisture-temperature dual sensitive film exhibits a tunable reflectance range between 91.1% and 39.1% via phase change of the PNIPAM layer. Coupled with an infrared emissivity of 96.0%, a daytime cooling of 10 °C compared to the control experiment is achieved. Coating the film with a photothermal layer results in an adaptive Janus film that is capable of autonomous switching between heating and cooling, and demonstrates a heating of 22.5 °C in a cold environment. The facile preparation method, excellent cyclic stability, mechanical properties, and UL-94 V-0 rating enable promising applications of the smart film under diverse living environments. © 2025 The Author(s). advanced Science published by Wiley-VCH GmbH.

关键词： Self tuning control systems

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