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Niobium oxide/MXene heterostructure for simultaneous production of ammonia and energy via rechargeable Zn-N2 battery system

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Journal of Energy Chemistry 2025年第4期103卷 448-457页

作者： Xinyu Dai Wei Zhang Ying Sun Zhenyi Du Zhanliang Tao Jingang Wang Wenhui Fang Xuehan Xing Yang Chen Hui Li Hao Zheng Jieshan Qiu Tianyi Ma Institute of Clean Energy Chemistry Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials of Liaoning Province College of ChemistryLiaoning University State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of Technology Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Renewable Energy Conversion and Storage Center College of Chemistry Nankai University College of Science Liaoning Petrochemical University College of Chemical Engineering State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Centre for Atomaterials and Nanomanufacturing (CAN) School of Science RMIT University ARC Industrial Transformation Research Hub for Intelligent Energy Efficiency in Future Protected Cropping (E2Crop) College of Chemical State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology

Aqueous Zn-N2batteries with unique configuration are of potential for simultaneous N2electro reduction and electricity generation,in which the electrocatalysts are critical for improving the NH3yield and the energy ***,a heterostructure Nb2O5/Nb2CTXwith abundant exposed Nb active sites and tuned electron density has been synthesized by in situ formation and anchoring of Nb2O5nanoparticles on the surface of Nb2CTXMXene,which shows an enhanced N2adsorption/activation *** heterostructure Nb2O5/Nb2CTXwas used as the cathode of Zn-N2battery that can deliver a peak power density of 1.25 mW cm-2in 1.0 M KOH and can continuously produce NH3with a yield of3.62 μg *** NH3formed in the battery system can be easily collected as a net product without circulating the ***,the Nb2O5/Nb2CTXhas a long durability,evidenced by 70 h of operation at-0.4 V *** hydrogen electrode,which is the highest among the MXene-based electrocatalysts reported thus *** work may provide a new methodology based on Zn-N2battery for sustainable and large-scale NH3production with minimal energy consumption.

关键词： NH 3 production Zn-N 2 battery N 2 Electroreduction Nb 2 O 5 /Nb 2 CT X heterostructure

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Nonflammable electrolyte with weak-solvation structure for stable NCM811 cathode under high temperature

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Journal of Energy Chemistry 2025年第5期104卷 111-117页

作者： Dawei Xu Chao Yang Ailing Yang Xiaowei Liu Meilong Wang Jin Han Tiefeng Liu Ya You State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology International School of Materials Science and Engineering School of Materials Science and Microelectronics Wuhan University of Technology College of Chemical and Biological Engineering Zhejiang University Quzhou Institute of Power Battery and Grid Energy Storage

High-nickel cathode LiNi0.8Co0.1Mn0.1O2（NCM811） could enable lithium-ion batteries （LIBs） with high energy ***,excessive decomposition of the electrolyte would happen in the high operating voltage *** addition,the utilization of flammable organic solvents would increase safety risks in the high temperature ***,an electrolyte consisting of flame-retardant solvents with lower highest occupied molecular orbital （HOMO） level and LiDFOB salt is proposed to address above two *** a result,a thin and robust cathode-electrolyte interface containing rich LiF and Li-B-O compounds is formed on the cathode to effectively suppress electrolyte decomposition in the high operating *** NCM811||Li cell paired with this designed electrolyte possesses a capacity retention of 72% after 300 cycles at 55℃.This work provides insights into developing electrolyte for stable high-nickel cathode operated in the high temperature.

关键词： Electrolyte engineering High temperature High-nickel cathode Safety Weak solvation

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Numerical Study of the Current Density on the Armature and Rail Interface with Dynamic Contact

Numerical Study of the Current Density on the Armature and R...

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International Conference of Electrical, Electronic and Networked Energy Systems, EENES 2024

作者： Xu, Jinghan Xia, Shengguo Chen, Lixue Ministry of Education Hubei Wuhan430074 China State Key Laboratory of Advanced Electromagnetic Engineering and Technology Hubei Wuhan430074 China School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819620791

The electrical contact between the armature and rail is acknowledged as imperfect electrical contact (ImPEC), exhibiting characteristics distinct from bulk behavior. It is important to understand the current distribution of the ImPEC for future design and optimization. This paper proposes ImPEC boundary conditions by combining the contact layer model (CLM) and the Cooper-Mikic-Yoranovich model (CMYM), and the current distribution is numerically studied. Variations in the contact pressure and current density with time are analyzed. The results show a rapid increase in the contact pressure and area during the current ramp-up stage, being constant in the flat stage, and a gradual decline in the current ramp-down stage. The current path changes with the contact area, and the current shifts from the trailing edge to the leading edge over time. Additionally, comparative calculations are performed to analyze current variations under dynamic contact. Results suggest that the current distribution is influenced by magnetic diffusion and forced shifts of current caused by dynamic contact. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Threshold current density

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Hierarchical hollow microspheres assembled from carbon nanosheets integrated with molybdenum carbide nanoparticles for boosting microwave absorption properties

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Nano Research 2025年第1期18卷 10-20页

作者： Zongsheng Chen Yahui Wang Yi Liu Zhigang Li Xiangyin Lv Liping Liu Yajing Chang Jiaming Shi Xiao Zhang State Key Laboratory of Pulsed Power Laser Technology School of Electronic EngineeringNational University of Defense TechnologyHefei 230037China Anhui Provincial Laboratory of Advanced Laser Technology School of Electronic EngineeringNational University of Defense TechnologyHefei 230037China Centre for Environmental and Energy Nanomaterials Anhui Key Laboratory of Nanomaterials and NanotechnologyCAS Centre for Excellence in NanoscienceInstitute of Solid State PhysicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China

Hierarchical hollow structure has demonstrated potential for enhancing electromagnetic(EM)attenuation and improving impedance matching,garnering significant attention for ***,we have successfully implemented compositional and structural engineering to fabricate hollow Mo2C/C microspheres with controllable composition by coupling interaction between dopamine hydrochloride and ammonium *** the synergistic effect of composition and hollow structure,the strongest reflection loss intensity and broadest effective absorption of the optimized sample reach-70.2 dB and 6.2 GHz,*** formation of hollow heterogeneous structures not only favors impedance matching feature,but also generates considerable contribution to EM attenuation ***,radar cross-section simulation data indicate that hollow Mo2C/C microspheres with compositional optimization and heterogeneous structures have broad prospects for practical applications.

关键词： electromagnetic absorption Mo2C/C microwave absorption hollow structure

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Microstructure and mechanical properties of nickel-based wrought superalloys under thermal-mechanical coupling: A review with Inconel 718,625 as main cases

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Progress in Natural Science:Materials International 2025年第1期35卷 65-82页

作者： Kai Cao Jiangkun Fan Xudong Liu Jianing Zhang Dian Jiao Yuelin Song Fulong Chen Jun Wang Bin Tang Hongchao Kou Jinshan Li State Key Laboratory of Solidification Processing Northwestern Polytechnical University National & Local Joint Engineering Research Center for Precision Thermoforming Technology of Advanced Metal Materials Chongqing Innovation Center Northwestern Polytechnical University AVIC Manufacturing Technology Institute

The typical processing and in-service behaviors of nickel-based wrought superalloys involve complex thermal-mechanical coupling effects, including elastic and plastic deformations, phase transformations, and other microstructural evolutions, directly impacting the mechanical properties. This review article provides an in-depth discussion on the microstructural evolution of these superalloys under thermal-mechanical coupling, focusing on two key aspects: the thermoplastic deformation behavior, and the phase transformation behavior in temperature/stress coupled field. The dynamic recrystallization(DRX) behavior during hot deformation and its improvement strategies are discussed in detail. The differences in phase precipitation behavior under conventional heat treatment and thermal-mechanical coupling conditions are compared. The mechanisms driving changes in precipitate characteristics are explored, enabling precise control of precipitates. This article further investigates the intricate relationship between the mechanical properties of nickel-based wrought superalloys and the characteristics of their precipitates, offering guidance for current and future optimizations. It also delves into the latest research advancements in precisely tailoring the precipitates through thermal-mechanical coupling methods to optimize these mechanical properties. Finally, it outlines several promising future research directions in this field.

关键词： Dynamic recrystallization

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Simulation and Experimental Analysis of Contactless Chip Pickup Process Based on a Vortex Flow Gripper

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IEEE Transactions on Semiconductor Manufacturing 2025年第2期38卷 324-331页

作者： Zhai, Peiran Xu, Zhoulong Yin, Zhouping Li, Xiaohang Xie, Bin Wu, Hao Huazhong University of Science and Technology Institute for Advanced Electronics Manufacturing State Key Laboratory of Intelligent Manufacturing Equipment and Technology Wuhan430074 China Wuhan Chiplet Technology Co. Ltd Wuhan430074 China King Abdullah University of Science and Technology Advanced Semiconductor Laboratory Saudi Arabia Huazhong University of Science and Technology Institute for Advanced Electronics Manufacturing State Key Laboratory of Intelligent Manufacturing Equipment and Technology School of Mechanical Science and Engineering School of Integrated Circuits Wuhan430074 China

As the preceding process of chip-to-wafer (C2W) hybrid bonding, die pick-up, and transfer are critical in 3D heterogeneous integration (3D HI) technique. Especially, with the ever-shrinking die thickness and ever-increasing bumps on the die surface, mechanical scratches and electrostatic interference on chips caused by the traditional contact-type pickup process cannot be tolerated. Therefore, it is the trend to implement contactless pickup head to realize damage-free chip transfer. Herein, a contactless, pneumatic pickup head based on vortex flow was designed for the efficient and contactless grab of 50 lm ultrathin chips. A baffle structure on the four corners of pickup head was designed, which can achieve stable noncontact pickup of target chip and maintain the position under multiangle loading conditions. Furthermore, we optimized baffle structure to reduce the oscillation of the chip by more than 50 underlying mechanism of pneumatic noncontact pickup through computational fluid dynamics (CFD) simulation by three turbulence models. Further, a high-precision vortex platform was built to investigate the pickup force characteristics, radial pressure distribution, and oscillations for different intake pressure and their influence on the noncontact pickup effect. Eventually, the simulation and experimental results indicate that the optimal intake pressure for stable non-contact pickup is between 20 and 30 kPa. This study provides design and optimization methods for stable noncontact picking of microchips, offering theoretical and experimental basis for selecting the optimal air intake pressure in practical applications. © 1988-2012 IEEE.

关键词： Vortex flow

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Nonlinear optical response of BiVO4 and its application for ultrafast pulsed fiber lasers

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Optics Express 2025年第3期33卷 6559-6566页

作者： Du, Ruonan Shi, Aokun Lian, Yudong Fang, Huajing Qi, Yaoyao Bai, Zhenxu Wang, Yulei Huang, Feng Ding, Jie Lu, Zhiwei Center for Advanced Laser Technology Hebei University of Technology Tianjin300401 China Hebei Key Laboratory of Advanced Laser Technology and Equipment Tianjin300401 China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong University Xi’an710049 China College of Mechanical Engineering and Automation Fuzhou University Fuzhou350108 China

Herein, we present aN Er-doped all-fiber laser with BiVO4 as the saturable absorber (SA). To illustrate the nonlinear optical response, a two-dimensional model of monoclinic and its electronic structure was calculated. The nonlinear absorption properties were evaluated utilizing the Z-scan technique, and a saturable absorber was fabricated for integration into a fiber laser, resulting in a stable Q-switched output. At a maximum pump power of 600 mW, the fiber laser achieved an average output power of 25.23 mW and a pulse energy of 330.76 nJ. This research confirms that BiVO4 material exhibits outstanding nonlinear optical characteristics, thereby broadening its scope of application in the realm of ultrafast pulsed fiber lasers. © 2025 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement.

关键词： Optical depth

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The effect of room temperature magnetic field on photoluminescence of Mn:CsPbBr_(3) quantum dots prepared by one-pot method in air

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Nano Research 2025年第4期18卷 561-568页

作者： Mengwei Chen Chenguang Shen Wei Huang Yingping Yang Jie Shen Department of Physics School of Physics and MechanicsWuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China

The generation and manipulation of spin-polarized electrons at room temperature are essential for the development of advanced spin-optoelectronic *** this work,a one-pot method was used to successfully synthesize homogenous Mn:CsPbBr_(3) perovskite quantum dots in air with particle sizes of 7−8 *** effects of Mn doping on the structure,optical and magnetic properties of CsPbBr_(3) quantum dots were *** findings demonstrated proper Mn doping improved the crystallinity and photoluminescence(PL)of quantum *** prepared quantum dots have a narrow full width at half maximum emission(FWHM)of about 17−20 *** magnetic properties of the doped samples and the effect of the magnetic field on the PL spectra properties were *** results show that trace Mn doping can improve the room-temperature ferromagnetism of CsPbBr_(3) quantum *** with magnetic elements makes CsPbBr_(3) quantum dots more responsive to the applied magnetic *** at a lower 50 mT magnetic field,the PL peak of Mn:CsPbBr_(3) still declined 5.91%.Mn:CsPbBr_(3) quantum dots are a new type of multifunctional material that is beneficial to spintronics *** work demonstrates a low-cost synthesis *** should make all-inorganic perovskite quantum dots a promising material for room-temperature spin optoelectronic devices.

关键词： CsPbBr_(3)quantum dots Mn doping one-pot method ferromagnetism magnetic field

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Fe doping 1T phase MoS_(2)with enhanced zinc-ion storage ability and durability for high-performance aqueous zinc-ion batteries

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Rare Metals 2025年第1期44卷 253-263页

作者： Jing-Yi Liu Rong-Jie Zhe Zhan-Hong Peng Yi-Hui Song Lin-Xuan Yang Chen Qing Jun-Ling Guo Jin-Ping Liu Yunnan Key Laboratory of Opto-Electronic Information Technology College of Physics and Electronic Information TechnologyYunnan Normal UniversityKunming650000China Country State Center for International Cooperation on Designer Low-Carbon and Environmental Materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou450001China School of Chemistry Chemical Engineering and Life ScienceState Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan430070China

As a promising cathode material for aqueous zinc-ion batteries,1T-MoS_(2)has been extensively investigated because of its facile two-dimensional ion-diffusion channels and high electrical ***,the limited number of available Zn storage sites,i.e.,limited capacity,hinders its application because the inserted Zn^(2+),which form strong electrostatic interactions with 1T-MoS_(2),preventing subsequent Zn^(2+)***,the approach of enlarging the interlayer distance to reduce electrostatic interactions has been commonly used to enhance the capacity and reduce Zn^(2+)migration ***,an enlarged interlayer spacing can weaken the van der Waals force between 1T-MoS_(2)monolayers,easily disrupting the structural ***,to address this issue,an effective strategy based on Fe doping is proposed for 1T-MoS_(2)(Fe-1T-MoS_(2)).The theoretical calculations reveal that Fe doping can simultaneously moderate the rate of decrease in the adsorption energy after gradually increasing the number of stored atoms,and enhance the electron delocalization on metal-O ***,the experiment results show that Fe doping can simultaneously activate more Zn storage sites,thus enhancing the capacity,and stabilize the structural stability for improved cycling ***,Fe-1T-MoS_(2)exhibits a larger capacity(189 mAh·g^(-1)at 0.1 A·g^(-1))and superior cycling stability(78%capacity retention after 400 cycles at 2 A·g^(-1))than pure 1T-MoS_(2).This work may open up a new avenue for constructing high-performance MoS_(2)-based cathodes.

关键词： Aqueous zinc-ion battery 1T-MoS_(2) Fe doping More Zn storage sites Enhanced structural stability

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Machinability of elliptical ultrasonic vibration millingγ-TiAl:Chip formation,edge breakage,and subsurface layer deformation

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Chinese Journal of Aeronautics 2025年第3期38卷 624-644页

作者： Ziwen XIA Chenwei SHAN Menghua ZHANG Wengang LIU Minchao CUI Ming LUO Key Laboratory of High Performance Manufacturing for Aero Engine Ministry of Industry and Information TechnologyNorthwestern Polytechnical UniversityXi’an 710072China Engineering Research Center of Advanced Manufacturing Technology for Aero Engine Ministry of EducationNorthwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Cemented Carbide Zhuzhou 412000China

Superior strength and high-temperature performance make γ-TiAl vital for lightweight aero-engines. However, its inherent brittleness poses machining problems. This study employed Elliptical Ultrasonic Vibration Milling (EUVM) to address these problems. Considering the influence of machining parameters on vibration patterns of EUVM, a separation time model was established to analyze the vibration evolutionary process, thereby instructing the cutting mechanism. On this basis, deep discussions regarding chip formation, cutting force, edge breakage, and subsurface layer deformation were conducted for EUVM and Conventional Milling (CM). Chip morphology showed the chip formation was rooted in the periodic brittle fracture. Local dimples proved that the thermal effect of high-speed cutting improved the plasticity of γ-TiAl. EUVM achieved a maximum 18.17% reduction in cutting force compared with CM. The force variation mechanism differed with changes in the cutting speed or the vibration amplitude, and its correlation with thermal softening, strain hardening, and vibratory cutting effects was analyzed. EUVM attained desirable edge breakage by achieving smaller fracture lengths. The fracture mechanisms of different phases were distinct, causing a surge in edge fracture size of γ-TiAl under microstructural differences. In terms of subsurface deformation, EUVM also showed strengthening effects. Noteworthy, the lamellar deformation patterns under the cutting removal state differed from the quasi-static, which was categorized by the orientation angles. Additionally, the electron backscattering diffraction provided details of the influence of microstructural difference on the orientation and the deformation of grains in the subsurface layer. The results demonstrate that EUVM is a promising machining method for γ-TiAl and guide further research and development of EUVM γ-TiAl.

关键词： γ-TiAl Elliptical ultrasonic vibration millingi Chip formation Edge breakage Microstructure

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