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Enhanced preparation of dendritic metallic vanadium in recyclable NaCl-KCl-VCl_(2) molten salt by V_(2)CO electrolysis

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Rare Metals 2024年第8期43卷 3961-3973页

作者： Jia-Liang An Ming-Yong Wang Yong-Zheng Jia Jin-Tao Zhang Bao-Yan Feng Shu-Qiang Jiao State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China College of Material Science and Engineering Hebei Province Laboratory of Inorganic Nonmetallic MaterialsNorth China University of Science and TechnologyTangshan 063210China

A promising method for the preparation of pure metallic vanadium via V_(2)CO anode electrolysis was proposed and *** simple and controllable synthesis of a molten chloride salt containing VCl_(2) by an insitu reaction between VCl_(3) and metallic vanadium was verified through thermodynamic analysis and ***-KCl-VCl_(2) molten salt exhibited excellent recycling performance and could be repetitively used to prepare metallic vanadium by V_(2)CO *** V^(2+) ions remained in the molten salt after *** electrolysis conditions,such as the cathode diameter,current density,V^(2+) ion concentration,and temperature,were optimised to maximise the current *** was also simulated to reveal the regulatory *** highest current efficiency was 85%.The purity of metallic vanadium was up to 99.8%.In this study,an easy and efficient preparation of pure metallic vanadium was achieved.

关键词： V_(2)CO Metallic vanadium Current efficiency Molten salt electrolysis

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Effect of Particle Size on Silicon Nitride Ceramic Slurry by Stereolithography

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Journal of Wuhan University of technology(Materials Science) 2023年第3期38卷 514-519页

作者：汪春柳 ZHANG Jinyong 雷丽文 School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070China

The effects of particle size,gradation and solid loading of silicon nitride (Si_(3)N_(4)) on the rheological behavior and curing properties of ceramic slurry are studied by stereolithography (SLA).The results show that the particle size of Si_(3)N_(4) powder has a signif icant influence on the rheological properties and stability of the *** m_(D50=1.3μm):m_(D50=2.3μm)=3:7,the slurry viscosity is low and the sedimentation is *** most important thing is that with the increase of the solid loading of the slurry,the viscosity of the slurry increases,the stability becomes higher,and the curing thickness *** curing thickness of Si_(3)N_(4) ceramic slurry with solid loading of 50 vol% can reach nearly 50μ*** above results finally show that the process optimizes the formulation of the slurry in rheological and curing properties.

关键词： silicon nitride stereolithography dispersion stability

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Design and experimental study of a field-reversed configuration plasma thruster prototype

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Plasma Science and technology 2025年第3期27卷 118-126页

作者： Yuxuan HUANG Ming ZHANG Yong YANG Fangwei LYU Xiaopeng YI Chaofan LYU Yisong ZHANG Bo RAO State Key Laboratory of Advanced Electromagnetic Technology International Joint Research Laboratory of Magnetic Confinement Fusion and Plasma PhysicsSchool of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China National Key Laboratory of Science and Technology on Vacuum Technology and Physics Lanzhou Institute of PhysicsLanzhou 730000People’s Republic of China

The field-reversed configuration(FRC)plasma thruster driven by rotating magnetic field(RMF),abbreviated as the RMF-FRC thruster,is a new type of electric propulsion technology that is expected to accelerate the deep space *** experimental prototype,including diagnostic devices,was designed and constructed based on the principles of the RMF-FRC thruster,with an RMF frequency of 210 kHz and a maximum peak current of 2 *** the rated operating conditions,the initial plasma density was measured to be 5×10^(17)m^(-3),and increased to 2.2×10^(19)m^(-3)after the action of *** coupling efficiency of RMF was about 53%,and the plasma current reached 1.9 *** axial magnetic field changed in reverse by 155 Gauss,successfully reversing the bias magnetic field of 60 Gauss,which verifies the formation of FRC *** optimization research,it was found that when the bias magnetic field is 100 Gauss,the axial magnetic field reverse variation caused by FRC is the highest at 164 *** experimental results are discussed and strategies are proposed to improve the performance of the prototype.

关键词： rotating magnetic field(RMF) field-reversed configuration(FRC) plasma thrusters plasma current

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Rapid Self-healing and Strong Adhesive Elastomer via Supramolecular Aggregates from Core-shell Micelles of Silicon Hydroxyl-functionalized cis-Polybutadiene

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Chinese Journal of Polymer Science 2023年第1期41卷 84-94页

作者： Ying-Ying Zheng Han Zhu Yi Tan Feng-Yi-Qi Liu Yi-Xian Wu State Key Laboratory of Chemical Resource Engineering Beijing Advanced innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing100029China

Liquid trimethoxy silane-functionalized cis-polybutadiene(cis-PB-Si(OMe)3),possessing number-average molecular weights of cis-PB segments(Mn,PB)ranging from 1800 g/mol to 5400 g/mol,with cis-1,4 content of ca.80%and high functionality(>96%)could be synthesized by coordination copolymerization of living cis-PB chain ends with ethenyltrimethoxy-silane with neodymium-based catalytic *** silicon hydroxyl-functionalized cis-polybutadiene(cis-PB-Si(OH)_(3))-based micelles in water have been achieved by in situ hydrolysis of cis-PB-Si(OMe)_(3)in hexane/water mixture(pH=6.8)at 70℃and by sequential removal of residue *** size of the above micelles with soft elastic cis-PB cores could be remarkably enlarged by loading SiO_(2)nanoparticles on their surfaces via hydrogen bonding *** supramolecular long chain aggregates or networks formed by hydrogen bonding interaction and possible O—Si—O chemical bonds between cis-PB-Si(OH)3-based micellar surfaces had relatively large size and thus precipitated from water after several months of storage,leading to production of cis-PB-Si(OH)_(3)solid elastomer with extremely low T_(g)at−107.0℃.The left cis-PB-Si(OH)_(3)-based micelles in water with relatively small size gradually formed the water-insoluble cis-PB-Si(OH)_(3)-based supramolecular aggregates or *** cis-PB-Si(OH)_(3)-based supramolecular elastomer exhibited excellent self-healing property within 60 s at 25℃.The elastomer(20 mg)in a joint of 25 mm×30 mm(2.7 mg/cm^(2))provided very strong adhesion for two pieces of glass and the bound glass keep unchanged at room temperature for 98 h even hung with 100 g of steel column *** cis-PB-Si(OH)3-based supramolecular elastomer would have potential applications in adhesives,self-healing materials,damping materials and elastic materials.

关键词： Amphiphilicity Polybutadiene Core-shell micelles Supramolecular aggregates

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Improving the reliability of classical molecular dynamics simulations in battery electrolyte design

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Journal of Energy Chemistry 2025年第2期101卷 34-41,I0002页

作者： Xin He Yujie Zhang Haomiao Li Min Zhou Wei Wang Ruxing Wang Kai Jiang Kangli Wang State Key Laboratory of Advanced Electromagnetic Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina State Key Laboratory of Materials Processing and Die&Mould Technology College of Materials Science and EngineeringHuazhong University of Science and Technology Wuhan 430074HubeiChina Hubei Collaborative Innovation Center for High-efficiency Utilization of Solar Energy Hubei University of TechnologyWuhan 430068HubeiChina

Explorations into new electrolytes have highlighted the critical impact of solvation structure on battery performance,Classical molecular dynamics(CMD)using semi-empirical force fields has become an essential tool for simulating solvation ***,mainstream force fields often lack accuracy in describing strong ion-solvent interactions,causing disparities between CMD simulations and experimental *** some empirical methods have been employed in some of the studies to address this issue,their effectiveness has been *** CMD research,supported by quantum chemical calculations and experimental data,reveals that the solvation structure is influenced not only by the charge model but also by the polarization *** empirical approaches that focused solely on adjusting ion-solvent interaction strengths overlooked the importance of polarization *** on this insight,we propose integrating the Drude polarization model into mainstream force fields and verify its feasibility in carbonate,ether,and nitrile *** experimental results demonstrate that this approach significantly enhances the accuracy of CMD-simulated solvation *** work is expected to provide a more reliable CMD method for electrolyte design,shielding researchers from the pitfalls of erroneous simulation outcomes.

关键词： Electrolyte Classical molecular dynamics Solvation structure Simulations

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Enhanced formic acid production for CO_(2)photocatalytic reduction over Pd/H-TiO_(2) catalyst

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Frontiers of Chemical Science and engineering 2024年第11期18卷 347-357页

作者： Huimin Gao Jinpeng Zhang Fangyuan Zhang Jieying Jing Wen-Ying Li State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030000China

The photocatalytic reduction of CO_(2)into formic acid is a feasible approach to alleviate the effects of global climate change and achieve chemical energy *** is important to design highly active photocatalysts to improve the selectivity and yield of formic *** this study,TiO_(2)-based catalysts were prepared and loaded with Pd nanoparticles via an impregnation *** Pd/H-TiO_(2)catalyst demonstrated superior CO_(2)reduction activity and a high formic acid production rate of 14.14 mmolcat·g^(-1)·h^(–1).The excellent catalytic performance observed in the presence of a Pd/H-TiO_(2)catalyst is ascribed to the synergy between Ov and *** presence of Ov led to increase in CO_(2)adsorption while Pd loading enhanced the photogenerated electron-hole pair *** transfer from H-TiO_(2)to Pd also contributed to CO_(2)activation.

关键词： CO_(2)reduction formic acid photocatalysis TiO_(2)catalyst

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Low-cost biodegradable lead sequestration film for perovskite solar cells

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Journal of Energy Chemistry 2023年第9期84卷 311-320页

作者： Yiming Xiong Haoyu Cai Wang Yue Wenjian Shen Xuehao Zhu Juan Zhao Fuzhi Huang Yi-Bing Cheng Jie Zhong State Key Laboratory of Advanced Technology of Materials Composite Technology Wuhan University of TechnologyWuhan 430070HubeiChina Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528216GuangdongChina School of Automobile Engineering Wuhan University of TechnologyWuhan 430070HubeiChina

Despite the high efficiency that has been achieved for the perovskite solar cells(PSCs),the hazardous lead leakage from the perovskite absorber layer is one of the crucial barriers still hindering its penetration into the commercial market for a large-scale ***,we report a novel low-cost and biodegradable lead sequestration layer with high compatibility for up-scalable encapsulation of *** a precisely designed cross-linking reaction of chemical agents,the as-made biodegradable chitosan composite film shows enhanced mechanical strength,chemical stability,and lead adsorption *** designed encapsulation strategy reduces over 99.99% lead leakage to <2 ppb under varied simulations of weather conditions(hail,rain,or flood),which meet the safe level of drinking water set by the US Environmental Protection Agency(EPA).Moreover,the PSC efficiency is improved from 21.91% to22.82% due to the improved light absorption from the printed biodegradable lead absorption ***,we present a prototype process of accumulation and recycling of lead compounds in PSCs derbies via the biodegradation *** on the low-cost biodegradable lead sequestration film,this environmental-friendly encapsulation strategy could address the lead leakage issue for further commercialization of PSCs.

关键词： Lead sequestration Cross-linking Perovskite solar cells Biodegradable Recycling

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Iron recovery and dephosphorization behaviors from high-phosphorus oolitic hematite by gas-based direct reduction and magnetic separation

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Journal of Iron and Steel Research International 2025年第3期32卷 550-563页

作者： Fang Liu Yi-chi Zhang Wang Zeng Jun Ni Yun-peng Si Heng Zhou Tian-xiang Zhang Sheng-li Wu Ming-yin Kou State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China School of Automation and Electrical Engineering University of Science and Technology BeijingBeijing100083China

With the depletion of high-quality iron ore resources,high-phosphorus oolitic hematite(HPOH)has attracted great attention due to its large reserve and relatively high iron ***,HPOH is very difficult to be used in ironmaking process due to its special structure.A two-step method of gas-based direct reduction and magnetic separation was thus proposed to recover iron and reduce *** results showed that the powdery reduced iron produced contained 92.31%iron and 0.1%phosphorus,and the iron recovery was 92.65%under optimum reduction condition,which is suitable for following *** apatite will be reduced under long reduction time and a large reducing gas flow rate,resulting in more phosphorus found in the metallic *** the hydrogen–carbon ratio will inhibit the formation and growth of iron particles and prevent the breakage of oolitic *** adjustment of reduction temperature is recommended as it affects the oolitic structure and reduction.

关键词： High-phosphorus oolitic hematite Iron recovery Dephosphorization Gas-based direct reduction Magnetic separation

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High temperature lubrication performance of chlorophenyl silicone oil

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Friction 2024年第8期12卷 1716-1727页

作者： Yan MENG Xiangli WEN Jie CHENG Pengpeng BAI Yonggang MENG Yu TIAN School of Mechanical and Electrical Engineering China University of Mining and Technology-BeijingBeijing 100083China Department of Mechanical Engineering State Key Laboratory of Tribology in Advanced EquipmentTsinghua UniversityBeijing 100084China

Most studies of liquid lubricants were carried out at temperatures below 200°***,the service temperature of lubricants for aerospace and aeroengine has reached above 300°*** order to investigate the friction mechanism and provide data for high temperature lubrication,the friction and wear properties of chlorophenyl silicone oil(CPSO)-lubricated M50 steel and Si3N4 friction pairs were investigated ***-on-disk experimental results show that the lubrication performance of CPSO varies significantly with *** 150°C,coefficient of friction(COF)remains at 0.13–0.15 after the short running-in stage(600 s),while the COF in the running-in stage is 0.2–*** 200°C and above,the running-in time is much longer(1,200 s),and the initial instantaneous maximum COF can reach *** this condition,the COF gradually decreases and finally stabilizes at around 0.16–0.17 *** phenomenon is mainly due to the different thickness of boundary adsorption *** importantly,the wear rate of M50 steel increases significantly with the temperature,while the wear rate barely changes at temperatures above 200°*** anti-wear mechanism is explained as tribochemical reactions are more likely to occur between CPSO and steel surface with the increased temperature,generating the FeCl2 protective film on the metal ***,FeCl2 tribochemical film improves the lubrication and anti-wear capacity of the *** high temperatures(200–350°C),FeCl2 film becomes thicker,and the contact region pressure becomes lower due to the larger wear scar size,so the wear rate growth of M50 steel is much smaller compared with that of low temperatures(22–150°C).The main findings in this study demonstrate that CPSO lubricant has good anti-wear and lubrication capacity,which is capable of working under temperatures up to 350°C.

关键词： chlorophenyl silicone oil(CPSO) liquid lubricant anti-wear high temperature

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Designing high-area-loading lithium metal batteries with in-situ polymerized electrolyte featuring gradient molar mass

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Journal of Energy Chemistry 2025年第4期103卷 383-392页

作者： Mengjun Sun Zhi Wang Zhe Sheng Xiang Zhen Juhui Jiang Xiaobing Wang Jia Xie School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiang 453007HenanChina State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina

In-situ polymerized solid-state lithium metal batteries have garnered significant attention due to their conformal interface contact and continuous pathways for lithium ion(Li^(+))***,their electrochemical performance is often hindered by slow Li^(+)transport within high-area-loading *** study presents an in-situ poly(ε-caprolactone)electrolyte with gradient molar mass(iGPCE)through lithium metal anode(LMA)-induced anionic ring-opening *** electrochemical and kinetic analyses reveal that the iGPCE,characterized by low molar mass(M),significantly enhances Li~+diffusion within high-area-loading cathodes and bulk electrolytes,thereby reducing concentration polarization and promoting uniform electrochemical ***,the high M region on LMA side acts as artificial solid electrolyte interphases,stabilizing the stripping and plating of ***,Li//LFP(20 mg cm^(-2))and Li//NCM622(7.4 mg cm^(-2))utilizing iGPCE exhibit stable charge/discharge *** study offers a fresh approach to accelerate Li~+diffusion kinetics of high-area-loading batteries and suggests broad applicability in other systems.

关键词： Gradient molar mass High-area-loading cathode In-situ polymerization Fast Li^(+)transport kinetics Lithium metal batteries

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