检索结果-内蒙古大学图书馆

An Environment‑Tolerant Ion‑Conducting Double‑Network Composite Hydrogel for High‑Performance Flexible Electronic Devices

引用

Nano-Micro Letters 2024年第5期16卷 352-369页

作者： Wenchao Zhao Haifeng Zhou Wenkang Li Manlin Chen Min Zhou Long Zhao State Key Laboratory of Advanced Electromagnetic Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074People’s Republic of China

High-performance ion-conducting hydrogels(ICHs)are vital for developing flexible electronic ***,the robustness and ion-conducting behavior of ICHs deteriorate at extreme tempera-tures,hampering their use in soft *** resolve these issues,a method involving freeze–thawing and ionizing radiation technology is reported herein for synthesizing a novel double-network(DN)ICH based on a poly(ionic liquid)/MXene/poly(vinyl alcohol)(PMP DN ICH)*** well-designed ICH exhibits outstanding ionic conductivity(63.89 mS cm^(-1) at 25℃),excellent temperature resistance(-60–80℃),prolonged stability(30 d at ambient temperature),high oxidation resist-ance,remarkable antibacterial activity,decent mechanical performance,and ***,the ICH performs effectively in a flexible wireless strain sensor,thermal sensor,all-solid-state supercapacitor,and single-electrode triboelectric nanogenerator,thereby highlighting its viability in constructing soft electronic *** highly integrated gel structure endows these flexible electronic devices with stable,reliable signal output *** particular,the all-solid-state supercapacitor containing the PMP DN ICH electrolyte exhibits a high areal specific capacitance of 253.38 mF cm^(-2)(current density,1 mA cm^(-2))and excellent environmental *** study paves the way for the design and fabrication of high-performance mul-tifunctional/flexible ICHs for wearable sensing,energy-storage,and energy-harvesting applications.

关键词： Ionic liquids Double-network hydrogels Temperature tolerance Multifunctionality Flexible electronic devices

来源：评论

学校读者我要写书评

暂无评论

Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline)tetradentate ligands

引用

Chinese Journal of Structural Chemistry 2024年第9期43卷 46-51页

作者： Hao Jiang Yuan-Yuan He Hai-Chao Liang Meng-Jia Shang Han-Han Lu Chun-Hua Liu Yin-Shan Meng Tao Liu Yuan-Yuan Zhu State Key Laboratory of Fine Chemicals Dalian University of Technology2 Linggong RoadDalian116024China School of Chemistry and Chemical Engineering Hefei University of Technology and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei230009China

Organic ligands play a pivotal role in lanthanide luminescence by acting as sensitizers for energy absorption and transfer,a phenomenon known as the fluorescence antenna ***,we introduce two tetradentate nitrogen ligands renowned for their efficient sensitization of lanthanide luminescence,with their luminous efficacy finely adjustable through subtle modifications to their *** the synthesis of four Eu(Ⅲ)/Tb(Ⅲ)mono-nuclear complexes via the complexation of ligands 6,6'-bis(4,5-dihydrooxazol-2-yl)-2,2'-bipyridine(bpybox,L^(1))and 6,6'-bis(4,5-dihydrothiazol-2-yl)-2,2'-bipyridine(thio-bpybox,L^(2))with europium/terbium trifluorosulfonate,structural analysis reveals that the lanthanide ion coordinates with eight nitrogen atoms from two ligands and one oxygen atom from *** them,two Eu(Ⅲ)complexes([Eu(L^(1))_(2)(SO_(3)CF_(3))](SO_(3)CF_(3))_(2) EuL^(1) and[Eu(L^(2))_(2)(SO_(3)CF_(3))](SO_(3)CF_(3))_(2) EuL^(2))and one Tb(Ⅲ)complex([Tb(L^(1))_(2)(SO_(3)CF_(3))](SO_(3)CF_(3))_(2) TbL^(1))exhibit lumi-nosity,displaying characteristic lanthanide metal ion luminescence characterized by high fluorescence quantum yields and prolonged excited state *** contrast,TbL^(2)([Tb(L^(2))_(2)(SO_(3)CF_(3))](SO_(3)CF_(3))_(2))is non-luminous,with the sole structural distinction being the substitution of oxygen atoms with sulfur atoms within the *** minor alteration significantly impacts the triplet(^(3)T)state energy level of the ligands,thereby influencing their sensitizing effect on Tb(Ⅲ)*** findings underscore the remarkable efficiency of bpybox-type ligands as sensitizers for Ln(Ⅲ)luminescence,with their structural versatility enabling effective modula-tion of luminous capacities and efficiency.

关键词： Lanthanide Luminescence Antenna effect Europium Terbium

来源：评论

学校读者我要写书评

暂无评论

A new thiol-sulfur click chemistry for lithium-organosulfide batteries

引用

The Innovation 2025年第2期6卷 42-48,41页

作者： Rong Zou Wenwu Liu Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Department of Polymeric Materials EngineeringSchool of Materials Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

Click chemistry is a rapid,reliable,and powerful function and a highly selective organic reaction that facilitates the efficient synthesis of various molecules by joining small *** approach has found widespread applications in fields such as drug development,chemical synthesis,and molecular *** recent years,the reaction of alkali-catalyzed polymerization of thiol and sulfur has been employed to prepare various sulfur-containing polymers,which are applied as electrochemical active electrode materials in the pursuit of good *** this study,it is surprising to find that the reaction mechanism exhibits characteristics of both the alkali-catalyzed sulfhydryl Micheal addition reaction and thiol-epoxy click chemistry;for the first time,thiol-sulfur click chemistry is defined in detail,providing a comprehensive description of its underlying scientific *** introduction of this new reaction pathway holds significant potential for advancing research and the development of sulfur-containing *** on this novel click chemistry,a new sulfur-containing polymer,polydivinylthioether hexasulfide,has been designed and successfully applied as a cathode material in lithium-organosulfide *** material demonstrates excellent electrochemical performance,achieving an initial capacity that reaches 790.5 mAh g−1(82.6%of theoretical capacity),and in a long-term cycle test,the capacity decay rate is only 0.063%after 1,000 cycles.

关键词： electrochemical active electrode mater thiol sulfur click chemistry molecular biologyin lithium organosulfide batteries synthesis various molecules organic reaction click chemistry joining small unitsthis

来源：评论

学校读者我要写书评

暂无评论

Study on the Phase Evolution of High Temperature Sintering Process of ZnO@Bi2O3 Core-Shell Structure Varistor Ceramic 19th

Study on the Phase Evolution of High Temperature Sintering P...

引用

19th Annual Conference of China Electrotechnical Society, ACCES 2024

作者： Yao, Chengfeng Song, Li Zhou, Benzheng He, Junjia State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819613786

The core-shell structure formed by coating can enhance the uniformity of particles within ZnO varistors, which is conducive to the improvement of their microstructure and comprehensive performance. In this study, the ZnO@Bi2O3 core-shell structure powder was prepared by chemical precipitation and calcination purification, and doped with Sb2O3 to form the ZnO@Bi2O3-Sb2O3 (ZBS) system powder, which was then compared with the doped sample. The alloying method was combined with high-temperature X-ray diffraction (HT-XRD) to investigate the phase evolution and its pattern, while scanning electron microscopy (SEM) and X-ray fluorescence (XRF) were employed to characterise the microstructure and elemental distribution. It was observed that the phase evolution of the ZBS system can be divided into two main stages: the generation of pyrochlore and its subsequent transformation to spinel. It is observed that Bi₂O₃ in the core-shell structure samples exhibits a certain selectivity for the reaction that generates the pyrochlore phase. Furthermore, the onset temperature of pyrochlore-to-spinel transformation is lower than that of the doped samples by 80–100 °C, and the reaction rate is faster. Base on the microstructural results, it was found that the core-shell structure powder spinel was more uniformly distributed with a smaller average grain size up to 5.074 μm and a more well-distributed particle size. The influence of the core-shell structure on the high-temperature sintering of ZnO varistor ceramics was discussed in terms of phase situation and microstructure. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Sintering

来源：评论

学校读者我要写书评

暂无评论

The Difference of High-Temperature Sintering Between Surface-Coated and Mechanically Mixed ZnO Composite Powders

The Difference of High-Temperature Sintering Between Surface...

引用

International Conference of Electrical, Electronic and Networked Energy Systems, EENES 2024

作者： Song, Li Zhou, Benzheng Yao, Chengfeng He, Junjia State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819618552

ZnO varistors prepared by surface coating technology show certain potential in reducing grain size, refining microstructure, and improving electrical properties. The sintering process after powder preparation also has a decisive influence on the performance of the varistor. In this study, based on the simplest binary formulation of ZnO, the common additives SiO2 and Bi2O3 were selected to form ZS and ZB binary system. The surface-coated composite powder and mechanically mixed composite powder were prepared in two kinds of system. The differences of coated powder and mixed powder in sintering process at high temperature were compared from three aspects: powder morphology, thermal analysis, and phase analysis. The results can provide a reference for the sintering process optimization of ZnO coated powder. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Sintering

来源：评论

学校读者我要写书评

暂无评论

Electrochemical converting ethanol to hydrogen and acetic acid for large scale green hydrogen production

引用

Nano Research 2024年第3期17卷 1542-1551页

作者： Yufeng Zhang Wei Zhu Jinjie Fang Zhiyuan Xu Yanrong Xue Jiajing Pei Rui Sui Xingdong Wang Xuejiang Zhang Zhongbin Zhuang State Key Lab of Organic-Inorganic Composites and Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing 100029China Laboratory of Advanced Functional Materials of Nanjing Nanjing Xiaozhuang UniversityNanjing 211171China Beijing Key Laboratory of Energy Environmental Catalysis Beijing University of Chemical TechnologyBeijing 100029China

Electrochemical coupling hydrogen evolution with biomass reforming reaction(named electrochemical hydrogen and chemical cogeneration(EHCC)),which realizes green hydrogen production and chemical upgrading simultaneously,is a promising method to build a carbon-neutral ***,we analyze the EHCC process by considering the market *** ethanol to acetic acid and hydrogen approach is the most feasible for large-scale hydrogen *** develop AuCu nanocatalysts,which can selectively oxidize ethanol to acetic acid(>97%)with high long-term *** isotopic and in-situ infrared experiments reveal that the promoted water dissociation step by alloying contributes to the enhanced activity of the partial oxidation reaction path.A flow-cell electrolyzer equipped with the AuCu anodic catalyst achieves the steady production of hydrogen and acetic acid simultaneously in both high selectivity(>90%),demonstrating the potential scalable application for green hydrogen production with low energy consumption and high profitability.

关键词： selective ethanol electrooxidation gold alloy catalyst electrochemical-coupled hydrogen production market assessment interfacial water activation

来源：评论

学校读者我要写书评

暂无评论

Fabrication of dense SiBCN monolith at a lower temperature and its high-temperature performance

引用

Journal of advanced Ceramics 2024年第8期13卷 1198-1211页

作者： Zi-Bo Niu Daxin Li Dechang Jia Zhihua Yang Kunpeng Lin Yan Wang Paolo Colombo Ralf Riedel Yu Zhou Institute for Advanced Ceramics School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150080China Key Laboratory of Advanced Structural-Function Integrated Materials and Green Manufacturing Technology Ministry of Industry and Information TechnologyHarbin 150080China State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150080China Department of Industrial Engineering University of PadovaPadova 3513iItaly Department of Materials Science and Engineering The Pennsylvania State UniversityUniversity Park 16802USA Institute of Materials Science Darmstadt University of TechnologyDarmstadt 64287Germany School of Materials Science and Engineering Harbin Institute of Technology(Shenzhen)Shenzhen 518055China

In this study,a crack-free pyrolysis process of partially cured precursor powder compacts was developed to prepare dense silicon boron carbonitride(SiBCN)monoliths at much lower temperatures(1300℃),thereby circumventing the challenges of sintering densification(>1800℃).Unlike the elastic fracture in over-cured precursors or the viscoelastic deformation in under-cured precursors,the partially cured precursor,exhibiting elastic-plastic deformation behavior,facilitates limited nanoscale pore formation in a dense structure,achieving a balance between crack-free pyrolysis and *** to SiBCN derived from the over-cured precursor(σ=~159 MPa,K_(IC)=1.9 MPa:m^(1/2),Vickers hardness(HV)=7.8 GPa,and E=122 GPa),the resulting SiBCN monolith exhibited significantly improved mechanical properties(σ=~304 MPa,K_(IC)=3.7 MPa-m12,HV=10.6 GPa,and E=161 GPa)and oxidation *** addition,this study investigated the high-temperature performance of SiBCN monoliths,including crystallization and oxidation,and determined the oxidation kinetics induced by pore structure healing and the different oxidation mechanisms of Si-C-N and B-C-N clusters in the amorphous *** to its unique composition and structure,the SiBCN ceramic oxide layer exhibits exceptional self-healing effects on repairing the nanoporous system in the initial stage and shows outstanding high-temperature stability during prolonged oxidation,mitigating adverse effects from bubble formation and *** to the nanoporous structure,the oxidation rate is initially controlled by gas diffusion following a linear law before transitioning to oxide layer diffusion characterized by a parabolic ***,due to different valence bond configurations,Si-C-N transforms into an amorphous SiCNO structure after phase separation,unlike the nucleation and growth of residual B-N-C.

关键词： silicon boron carbonitride(SiBCN)ceramics crack-free pyrolysis amorphous structure oxidation mechanisms kinetic law

来源：评论

学校读者我要写书评

暂无评论

Mg-gallate metal-organic framework-based sprayable hydrogel for continuously regulating oxidative stress microenvironment and promoting neurovascular network reconstruction in diabetic wounds

引用

Bioactive Materials 2024年第8期38卷 181-194页

作者： Chenxi Lian Jiawei Liu Wenying Wei Xiaopei Wu Takashi Goto Haiwen Li Rong Tu Honglian Dai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China National Energy Key Laboratory for New Hydrogen-ammonia Energy Technologies FoshanXianhu LaboratoryFoshan528200China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China

Chronic diabetic wounds are the most common complication for diabetic *** to high oxidative stress levels affecting the entire healing process,treating diabetic wounds remains a ***,we present a strategy for continuously regulating oxidative stress microenvironment by the catalyst-like magnesium-gallate metal-organic framework(Mg-GA MOF)and developing sprayable hydrogel dressing with sodium alginate/chitosan quaternary ammonium salts to treat diabetic *** quaternary ammonium salts with antibacterial properties can prevent bacterial *** continuous release of gallic acid(GA)effectively eliminates reactive oxygen species(ROS),reduces oxidative stress,and accelerates the polarization of M1-type macrophages to M2-type,shortening the transition between inflammation and proliferative phase and maintaining redox ***,magnesium ions adjuvant therapy promotes vascular regeneration and neuronal formation by activating the expression of vascular-associated *** hydrogel dressings with antibacterial,antioxidant,and inflammatory regulation rapidly repair diabetic wounds by promoting neurovascular network reconstruction and accelerating re-epithelialization and collagen *** study confirms the feasibility of catalyst-like MOF-contained sprayable hydrogel to regulate the microenvironment continuously and provides guidance for developing the next generation of non-drug diabetes dressings.

关键词： Chronic diabetic wounds Bioactive MOF Antioxidant Anti-inflammation Enzymatic catalysis Neurovascular network reconstruction

来源：评论

学校读者我要写书评

暂无评论

Passive on-chip isolators based on the thin-film lithium niobate platform

引用

Chinese Physics B 2025年第3期34卷 408-413页

作者： Jiacheng Liu Gongyu Xia Qilin Hong Pingyu Zhu Kai-Kai Zhang keyu Xia Ping Xu Shiqiao Qin Zhihong Zhu College of Advanced Interdisciplinary Studies&Hunan Provincial Key Laboratory of Novel Nano Optoelectronic Information Materials and Devices National University of Defense TechnologyChangsha 410073China Institute for Quantum Information and State Key Laboratory of High-Performance Computing College of Computer Science and TechnologyNational University of Defense TechnologyChangsha 410073China College of Engineering and Applied Sciences National Laboratory of Solid State Microstructuresand Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210023China

Optical isolators,the photonic analogs of electronic diodes,are essential for ensuring the unidirectional flow of light in optical systems,thereby mitigating the destabilizing effects of back ***-film lithium niobate(TFLN),hailed as“the silicon of photonics,”has emerged as a pivotal material in the realm of chip-scale nonlinear optics,propelling the demand for compact optical *** report a breakthrough in the development of a fully passive,integrated optical isolator on the TFLN platform,leveraging the Kerr effect to achieve an impressive 10.3 dB of isolation with a minimal insertion loss of 1.87 *** theoretical simulations have demonstrated that our design,when applied to a microring resonator with a Q factor of 5×10^(6),can achieve 20 dB of isolation with an input power of merely 8 *** advancement underscores the immense potential of lithium niobate-based Kerr-effect isolators in propelling the integration and application of high-performance on-chip lasers,heralding a new era in integrated photonics.

关键词： thin-film lithium niobate Kerr effect optical isolator

来源：评论

学校读者我要写书评

暂无评论

Multifunctional dual-anion compensation of amphoteric glycine hydrochloride enabled highly stable perovskite solar cells with prolonged carrier lifetime

引用

Nano Research 2024年第6期17卷 5131-5137页

作者： Lina Qin Mengfei Zhu Yuren Xia Xingkai Ma Daocheng Hong Yuxi Tian Zuoxiu Tie Zhong Jin State Key Laboratory of Coordination Chemistry MOE Key Laboratory of Mesoscopic ChemistryMOE Key Laboratory of High Performance Polymer Materials and TechnologyJiangsu Key Laboratory of Advanced Organic MaterialsSchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Nanjing Tieming Energy Technology Co.Ltd. Nanjing 210093China Suzhou Tierui New Energy Technology Co.Ltd. Suzhou 215228China

Throughout years,the two-step spin-coating process is the most common method to prepare organic lead halide perovskite ***,the short reaction time of dropping the solution at the second step means that PbI2 cannot be completely transformed into perovskite *** solve this problem,we report the introduction of glycine hydrochloride(GlyHCl)into the second step of the two-step spin-coating process to prepare a FA_(0.9)MA_(0.1)PbI_(3-x)%-GlyHCl perovskite material(namely FAMA-x%-GlyHCl,where FA=formamidinium,MA=methylammonium,and x%stands for the molar ratio of GlyHCl added in FA iodide/MA iodide(FAI/MAI)precursor solution).The Cl−ion in GlyHCl assists the formation ofα-phase perovskite,and the-COO−group coordinates with Pb2+cation in a bridging way,making up for the anion vacancy in perovskite lattice and resulting in high absorption *** perovskite solar cells(PSCs)based on FAMA-9%-GlyHCl achieve a long carrier lifetime(527.0 ns),a photoelectric conversion efficiency(PCE)of 19.40%and good thermal stability,maintaining 85.8%of the initial PCE after being continuously heated at 60℃for 500 *** study helps to solve the problem of incomplete reaction in the two-step spin-coating process and puts forward a new solution for preparing high coverage perovskite films with large grain size.

关键词： dual-anion compensation glycine hydrochloride perovskite solar cells carrier lifetime thermal and moisture stability

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：