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Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting

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Nano Research 2023年第5期16卷 6584-6592页

作者： Dongdong Wang Yue Liu Lili Liu Dongfang Shan Guixin Shen Shanlong Peng Heng Zhang Xindong Wang State Key Laboratory of Advanced Metallurgy School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China Energy Storage Science and Engineering School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China

The design and preparation of cost-effective and durable catalysts for electrochemical water splitting are significant for the development and application of hydrogen ***,inspired by the underwater superaerophobicity of fish scales,a three-dimensional multilevel nanoarray electrode with superaerophobicity was designed and fabricated by the hydrothermal method to solve the bubble shielding effect in electrochemical *** from the high specific surface area,superaerophobic properties,Al doping,the Al-CoS_(2)nanosheets(NSs)/nickel foam(NF)-30 exhibits outstanding electrocatalytic activity and superior durability for electrochemical water splitting in 1 M ***,the Al-CoS_(2)NSs/NF-30 only required extremely low overpotential of 176 mV for oxygen evolution reaction(OER)to reach a current density of 10 mA·cm^(-2).Al-CoS_(2)NSs/NF-30 was employed as bifunctional electrode for electrochemical water splitting with a cell voltage of 1.58 V at 10 mA·cm^(-2).Meanwhile,Al-CoS_(2) NSs/NF-30 exhibited excellent durability(250 h@10 mA·cm^(-2)and 50 h@100 mA·cm^(-2)).The cobalt-based catalyst(Al-CoS_(2) NSs/NF-30)with superaerophobicity exhibits excellent performance in activity and durability,therefore is a promising electrochemical water splitting catalyst.

关键词： oxygen evolution reaction biomimetic structure superaerophobicity hydrogen evolution reaction

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Enhancing solid-state lithium metal battery performance via indium-based modification of electrolytes and lithium metal surfaces:mechanistic insights and optimization

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Science China Chemistry 2025年第3期68卷 1144-1158页

作者： Zhongkai Wu Chen Liu Ziling Jiang Lin Li Siwu Li Chaochao Wei Qiyue Luo Xia Chen Long Zhang Shijie Cheng Chuang Yu State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China Interdisciplinary Research Center of Smart Sensors Academy of Advanced Interdisciplinary ResearchXidian UniversityXi’an 710126China College of Physics and Energy Fujian Normal UniversityFuzhou 350117China

Argyrodite-based solid-state lithium metal batteries exhibit significant potential as next-generation energy storage ***,their practical applications are constrained by the intrinsic poor stability of argyrodite towards Li metal and exposure to air/***,an indium-involved modification strategy is employed to address these *** optimized doping yields a high Li-ion conductivity of 7.5 mS cm^(-1)for Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte,accompanied by enhanced endurance against air/moisture and bare Li *** retains 92.0%of its original conductivity after exposure to air at a low dew point of-60℃in dry ***,a composite layer comprising Li-In alloy and Li F phases is generated on the surface of lithium metal anode via the reaction between InF_(3)and molten *** layer effectively mitigates Li dendrite growth by creating a physical barrier from the robust LiF phase,while the Li-In alloy induces uniform Li-ion deposition and accelerates Li transport dynamics across the interphase between the solid electrolyte/Li ***,the In-doped electrolyte facilitates the in-situ generation of Li-In alloy within its voids,reducing local current density and further inhibiting lithium dendrite ***,the combination of the Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte and the InF_(3)@Li anode provides exceptional electrochemical performances in both symmetric cells and solid-state lithium metal batteries across different operating ***,the LiNbO_(3)@LiNi_(0.7)Co_(0.2)Mn_(0.1)O_(2)/Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)/InF_(3)@Li cell delivers a high discharge capacity of 167.8 mAh g^(-1)at 0.5 C under 25℃and retains 80.0%of its initial value after 400 *** work offers a viable strategy for designing functional interfaces with enhanced stability for sulfide-based solid-state lithium batteries.

关键词： Li_(5.5)PS_(4.5)Cl_(1.5)solid electrolyte In_(2)O_(3)dual-doping InF_(3)surface-modification chemical/electrochemical stability electrochemical performance

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Degradation mechanisms and stabilization strategies of ruthenium-based catalysts for OER in the proton exchange membrane water electrolyzer

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Progress in Natural Science:Materials International 2024年第1期34卷 207-222页

作者： Ming Yang Hongxiang Wu Zhaoping Shi Yibo Wang Jiahao Yang Jing Ni Pengbo Wang Yuqing Cheng Ziang Wang Meiling Xiao Changpeng Liu Wei Xing Laboratory of Advanced Power Sources Changchun Institute of Applied Chemistry Chinese Academy of Sciences School of Applied Chemistry and Engineering University of Science and Technology of China Jilin Province Key Laboratory of Low Carbon Chemical Power Sources State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences

Designing economical oxygen evolution reaction(OER) electrocatalysts with high activity and long-term stability is essential to promote the scale-up applications of proton exchange membrane water electrolyzer(PEMWE) for hydrogen production. Ruthenium(Ru)-based materials with high intrinsic activity are hailed as the most promising catalysts, but still infeasible for practical application considering their long unresolved poor stability(only dozens of lifespan). Thus, tremendous efforts have been devoted to uncovering the degradation mechanisms and developing stabilization strategies for the Ru-based catalysts. In this review, starting from summarizing the fundamental understanding of deactivation mechanisms, a picture of the stability issue of Ru-based catalysts is proposed, which is followed by a detailed discussion on the recently developed strategies and progress made on enhancing durability. Finally, insights on the prospects for the future development of stable and practical Rubased OER catalysts are provided.

关键词： OER Ru-based catalysts PEMWE Degradation mechanisms Stabilization strategies

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Distribution network gray-start and emergency recovery strategy with pumped storage unit under a typhoon

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Global Energy Interconnection 2025年第1期8卷 121-133页

作者： Zhenguo Wang Hui Hou Chao Liu Shaohua Wang Zhengtian Li Xiangning Lin Te Li Research Institute of State Grid Zhejiang Electric Power Company Hangzhou 310014PR China School of Automation Wuhan University of TechnologyWuhan 430070PR China State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and TechnologyWuhan 430074PR China

Typhoons can cause large-area blackouts or partial outages of distribution *** define a partial outage state in the distribution network as a gray state and propose a gray-start strategy and two-stage distribution network emergency recovery framework.A phase-space reconstruction and stacked integrated model for predicting wind and photovoltaic generation during typhoon disasters is proposed in the first *** provides guidance for second-stage post-disaster emergency recovery *** emergency recovery scheduling model is established in the second stage,and this model is supported by a thermal power-generating unit,mobile emergency generators,and distributed *** generation includes wind power generation,photovoltaics,fuel cells,***,we con-sider the gray-start based on the pumped storage unit to be an important first step in the emergency recovery *** model is val-idated on the improved IEEE 33 node system,which utilizes data from the 2022 super typhoon“Muifa”in Zhoushan,Zhejiang,*** indicate the superiority of a gray start with a pumped storage unit and the proposed emergency recovery strategy.

关键词： Wind and photovoltaic generation prediction Pumped storage unit Gray-start Distribution network Emergency recovery strategy

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Catalytic recycling of plastics into value-added products

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Nano Research 2024年第11期17卷 9428-9445页

作者： Tianyu Wei Pengcheng Zhou Wenxian Liu Xijun Liu Tairong Kuang Functional Polymers and Advanced Materials (FPAM) Lab Zhejiang Key Laboratory of Plastic Modification and Processing Technology College of Materials Science and Engineering Zhejiang University of Technology Hangzhou 310014 China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Nonferrous Metals and Featured Materials MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials School of Resources Environment and Materials Guangxi University Nanning 530004 China

The overuse and ineffective management of plastics have led to significant environmental pollution. Catalytic upcycling into value-added chemicals has emerged as a promising solution. This review provides a comprehensive overview of recent advances in catalytic upcycling, focusing on the cleavage of chemical bonds such as carbon-carbon (C-C), carbon-oxygen (C-O), and carbon-hydrogen (C-H) in plastics. It systematically discusses plastics conversion via electrocatalysis, thermal catalysis, and photocatalysis. Additionally, it explores the conversion of plastics into value-added chemicals and functional polymers. The review also addresses the challenges in this field and aims to offer insights for developing sustainable and effective plastics upcycling technologies.

关键词： plastics recycling catalysis chemical recycling value-added chemicals functional polymers

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A Transparent Polymer-Composite Film for Window Energy Conservation

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Nano-Micro Letters 2025年第7期17卷 9-19页

作者： Xianhu Liu Haoyu Zhang Yamin Pan Jun Ma Chuntai Liu Changyu Shen College of Materials Science and Engineering State Key Laboratory of Structural AnalysisOptimization and CAE Software for Industrial EquipmentNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou University Uni SA STEM and Future Industries Institute University of South Australia

As living standards improve, the energy consumption for regulating indoor temperature keeps increasing. Windows, in particular, enhance indoor brightness but also lead to increased energy loss, especially in sunny weather. Developing a product that can maintain indoor brightness while reducing energy consumption is a challenge. We developed a facile, spectrally selective transparent ultrahigh-molecular-weight polyethylene composite film to address this trade-off. It is based on a blend of antimony-doped tin oxide and then spin-coated hydrophobic fumed silica, achieving a high visible light transmittance(> 70%) and high shielding rates for ultraviolet(> 90%) and near-infrared(> 70%). When applied to the acrylic window of containers and placed outside, this film can cause a 10 ℃ temperature drop compared to a pure polymer film. Moreover, in building energy simulations, the annual energy savings could be between 14.1% ～ 31.9% per year. The development of energy-efficient and eco-friendly transparent films is crucial for reducing energy consumption and promoting sustainability in the window environment.

关键词： Composite Energy conservation Polymer Radiative cooling Transparent films

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Sulfur/nitrogen/oxygen tri-doped carbon nanospheres as an anode for potassium ion storage

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Journal of Energy Chemistry 2023年第2期77卷 338-347,I0009页

作者： Xiaoyan Chen Wang Zhou Jilei Liu Yingpeng Wu Zhigang Liu Advanced Catalytic Engineering Research Center of the Ministry of Education College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082HunanChina State Key Laboratory of Chem/Bio-Sensing and Chemometrics Advanced Catalytic Engineering Research Center of the Ministry of EducationCollege of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082HunanChina College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan Province Key Laboratory for Advanced Carbon Materials and Applied TechnologyHunan UniversityChangsha 410082HunanChina

Carbonaceous materials are considered as ideal anode for potassium ion batteries(PIBs)due to their abundant resources and stable physical and chemical ***,improvements of reversible capacity and cycle performance are still needed,aiming to the practical ***,S/N/O tridoped carbon(SNOC)nanospheres are prepared by in-situ vulcanized *** S/N/O tridoped carbon matrix provides abundant active sites for potassium ion adsorption and effectively improves potassium storage ***,the SNOC nanospheres possess large carbon interlayer spacing and high specific surface area,which broaden the diffusion pathway of potassium ions and accelerate the electron transfer speed,resulting in excellent rate *** an anode for PIBs,SNOC shows attractive rate performance(438.5 mA h g^(-1) at 50 mA g^(-1) and 174.5 mA h g^(-1) at2000 mA g^(-1)),ultra-high reversible capacity(397.4 mA h g^(-1) at 100 mA g^(-1) after 700 cycles)and ultra-long cycling life(218.9 mA h g^(-1) at 2000 mA g^(-1) after 7300 cycles,123.1 mA h g^(-1) at3000 mA g^(-1) after 16500 cycles and full cell runs for 4000 cycles).Density functional theory calculation confirms that S/N/O tri-doping enhances the adsorption and diffusion of potassium ions,and in-situ Fourier-transform infrared explores explored the potassium storage mechanism of SNOC.

关键词： Potassium ion batteries S/N/O tri-doped Carbon nanospheres Anode

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Oxidation resistant low-alloyed Ti alloys with good ductility

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Rare Metals 2024年第8期43卷 3921-3936页

作者： Meng Li Zhang-Zhi Shi Jun-Yi Xu Fu-Zhi Dai Xiang-Min Li Zi-Lin Li Lu-Ning Wang Beijing Advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advance Metals and MaterialsSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijingBeijing 100083China Institute of Materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China

Oxidation resistance enhancement of pure Ti often comes at the cost of reduced ductility,which is frequently the problem through alloying with sole Al,Si,W,Mo and *** overcome the short coming of single element alloying,this paper proposes a multi-element low-alloying strategy to take advantage of synergistic effects and resolve the conflict between oxidation resistance and *** demonstrates that the addition of a small quantity of Ta(0.51wt%)can boost both oxidation resistance and ductility in comparison to pure ***,the combined addition of a small amount(0.54 wt%)of Ta,Nb and Si not only preserves good ductility of pure Ti,but also reduces mass gains to 14%-67%of pure Ti during 100 h oxidation at 650-850℃in *** indicates even better oxidation resistance than that obtained through the use of Ta,Nb,or Nb+Ta *** Ta+Nb+Si alloying creates an oxide layer that is less porous and more resistant to stratification and ***,a 3-μm N-rich layer can form in the Ti substrate beneath the oxide scale,in which phase transformation generates coherent Ti_(2)N with(0001)_(Ti)as the habit plane,with N atoms prefers to diffuse along■than along[0001]_(Ti).The completely transformed Ti_(2)N region or partially transformed Ti+Ti_(2)N region can effectively impede oxygen ***,the multielement low-alloying strategy is promising for enhancing both oxidation resistance and mechanical properties of metallic materials in the future.

关键词： Ti alloys Multi-element Co-alloying Oxidation resistance Mechanical properties

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Contact-reactive brazing mechanism of Al_(0.3)CoCrFeNi high-entropy alloys using a niobium interlayer

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Journal of Iron and Steel Research International 2024年第10期31卷 2546-2554页

作者： Yu Lei Yi-nan Li Xiao-guo Song Sheng-peng Hu Wei-min Long Hai-chuan Shi Zu-bin Chen School of Mechanical and Automotive Engineering Qingdao University of TechnologyQingdao266000ShandongChina State Key Laboratory of Precision Welding and Joining of Materials and Structures Harbin Institute of TechnologyHarbin150001HeilongjiangChina State Key Laboratory of Advanced Brazing Filler Metals and Technology Zhengzhou Research Institute of Mechanical EngineeringZhengzhou450001HenanChina School of Materials Science and Engineering Shanghai University of Engineering ScienceShanghai201620China Yantai Research Institute Harbin Engineering UniversityYantai264006ShandongChina

The contact-reactive brazing of Al_(0.3)CoCrFeNi high-entropy alloys with a Nb interlayer was *** effects of Nb thickness and brazing temperature on the interfacial microstructure and mechanical properties of Al_(0.3)CoCrFeNi joints were *** results show that with Nb thickness increasing from 10 to 100μm,the average width of Al_(0.3)CoCrFeNi joints is increased from 127 to 492μm and the erosion volume of Al_(0.3)CoCrFeNi base metals(BMs)by face-centered cubic-Nb eutectic liquid is enlarged *** increasing brazing temperature from 1280 to 1360℃,the intergranular penetration of eutectic liquid into Al_(0.3)CoCrFeNi BMs becomes more severe and lamellar Laves phase is broken-up and *** shear strength of joint is increased gradually from 374 to 486 MPa and then decreased to 475 *** maximum shear strength value of 486 MPa is obtained when brazing at 1340℃ for 10 min,reaching about 78% of the shear strength of Al_(0.3)CoCrFeNi ***,the brazing mechanism was analyzed in details.

关键词： Contact-reactive brazing High-entropy alloy Intergranular penetration Shear strength Mechanism

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Integration of flexible,recyclable,and transient gelatin hydrogels toward multifunctional electronics

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Journal of Materials Science & technology 2023年第14期145卷 83-92页

作者： Rui Yin Chen Zhang Jian Shao Youyou Chen Ao Yin Qiang Feng Shuqin Chen Fei Peng Xing Ma Cheng-Yan Xu Feihua Liu Weiwei Zhao Sauvage Laboratory for Smart Materials School of Materials Science and EngineeringHarbin Institute of Technology(Shenzhen)Shenzhen 518055China Shenzhen Key Laboratory of Flexible Printed Electronics Technology Harbin Institute of Technology(Shenzhen)Shenzhen 518055China State Key Laboratory of Advanced Welding&Joining Harbin Institute of TechnologyHarbin 150001China

Facing the challenges posed by exponentially increasing e-waste,the development of recyclable and tran-sient electronics has paved the way to an environmentally-friendly progression strategy,where electron-ics can disintegrate and/or degrade into eco-friendly end products in a controlled *** polymers possess cost and energy efficiency,easy modification,and fast degradation,all of which are ideal prop-erties for transient *** is especially attractive due to its unique thermoreversible gelation processes,yet its huge potential as a multifunctional electronic material has not been well-researched due to its limited mechanical strength and low ***,we explored versatile applications of gelatin-based hydrogels through the assistance of multifunctional additives like carbon nanotubes to enhance their electromechanical *** optimized gelatin hydrogel displays not only a high conductivity of 0.93 S/m,electromagnetic shielding effectiveness of 39.6 dB,and tensile stress tolerance of 263 kPa,but also shows a negative permittivity phenomenon,which may find versatile applications in novel *** a proof of concept,hydrogels were assembled as wearable sensors to sensitively de-tect static and dynamic pressures and strains generated by solids,liquids,and airflow,as well as diverse body ***,the recyclability,biocompatibility,and degradability of gelatin-based hy-drogels were well studied and *** work outlines a facile method to design multifunctional transient materials for wearable,sustainable,and eco-friendly electronics.

关键词： Gelatin hydrogels Carbon nanotubes Negative permittivity Electromagnetic interference shielding Wearable sensor

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