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Simultaneously improving the strength and ductility of AZ91/GNPs composites through decorating graphene nanoplatelets with MgO

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Journal of Materials Science & Technology 2024年第16期183卷 133-151页

作者： Pingbo Wang Jun Shen Tijun Chen Jiqiang Ma Qinglin Li Shaokai Zheng State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050China

Magnesium matrix composites(MgMCs)have always suffered low strengthening efficiency and poor ductility due to the difficulties in pursuing the well-bonded ***,graphene nanoplatelets(GNPs)were decorated with magnesium oxide nanoparticles(MgO NPs)through chemical co-precipitation and then incorporated into AZ91 alloy to fabricate MgMCs via powder *** effect of MgO on the interface of the Mg/graphene system was investigated based on the first-principles calculations,and the result indicated that modifying GNPs with MgO NPs was helpful in improving the Mg-GNP interface *** interface structural analysis revealed that the MgO NPs were firmly bonded with both GNPs andα-Mg through the distortion area bonding and semi-coherent interfacial bonding,severing as a bridge to fasten the interface bonding of *** addition,the MgO NPs on GNPs acted as a barrier to prevent GNPs from seriously reacting with the AZ91 *** a result,the AZ91/MgO@GNPs composite was endowed with enhancements of 31%and 10%in the yield strength,and increments of 71%and 61%in elongation compared with the AZ91 alloy and AZ91/GNPs composite,respectively,exhibiting a more significant potential in optimizing the strength-toughness tradeoffcompared with the AZ91/***,the possible strengthening and toughening mechanisms were also discussed in *** work offers a relatively novel surface modification strategy to modulate the Mg-GNP interface for a simultane-ous improvement of strength and ductility.

关键词： Graphene nanoplatelets Magnesium oxide First-principles calculations Magnesium matrix composites Powder thixoforging

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Regulation of bimodal structure and mechanical properties of powder-thixoformed GO/ZK60 magnesium matrix composite through adjusting GO content

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Journal of Materials Science & Technology 2023年第31期162卷 74-89页

作者： Lingyun Wang Tijun Chen State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

Although remarkable strength enhancements can be achieved in graphene oxide(GO)/graphene nanoplatelets(GNPs)reinforced Mg matrix composites by using the available techniques,their ductility is always quite poor due to the difficultly avoided strength-ductility *** conquer this dilemma,GO/ZK60 composites with bimodal-grain structure were fabricated using powder thixoforming in this *** results indicate that the grain size and volume fraction of coarse grains(CGs)first decrease as the GO content increases to 0.2 wt.%and then increase again as the content increases to 0.3 wt.%,while the grain size in the fine grains(FGs)almost does not ***,the strength of the composites is improved with increasing GO content and reaches the peak values at the content of 0.2 wt.%.The composite with 0.1 wt.%GO content exhibits significantly increased tensile yield strength up to 177±2 MPa while maintaining a high elongation of 23.1%±2.5%,being equivalent to that of the ZK60 matrix *** increased FGs volume fraction,together with the promoted dislocation accumulation and storage via GO and grain refinement of large-sized CGs lead to the improvement of strain hardening ability,thus rendering the composite an excellent ***,the deformation of the GO/ZK60 composites occurs progressively from the FGs to the CGs,which is opposite to the status of the milled ZK60 matrix *** view of the microstructure characteristics of the composites,a new complex calculation model was proposed and it could well predict the strength of the bimodal GO/ZK60 *** study provides a new insight into the microstructure design and fabrication technology of GO/GNPs reinforced metal-based composites with high strength and ductility.

关键词： Graphene oxide Bimodal structure Magnesium matrix composites Mechanical properties Powder thixoforming

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Formation of intermetallic compounds during reaction between Ti and Al-Mg alloys with various Mg contents

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Journal of Materials Science & Technology 2023年第28期159卷 225-243页

作者： Min Gao Tijun Chen State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

The reactions between Ti and Al-Mg alloys were systematically investigated by heating the Ti/Al-Mg al-loy powder mixture compacts with Mg contents ranging from 5.09 to 40.36 wt.%at 660°*** element in the Al-Mg alloys contributed to the breakage of the oxide films on the surfaces of the Ti and Al-Mg alloy powders,thus,promoting the *** the samples with Mg contents varying from 5.09 wt.%to 25.93 wt.%,the first-formed intermetallic compound was Al_(18)Ti_(2)Mg_(3),and then Al_(3)Ti generated at the Al_(18)Ti_(2)Mg_(3)/Ti *** the Mg content in the Al-Mg melts decreased during the subsequent heat-ing process,the previously formed Al_(18)Ti_(2)Mg_(3)in the Ti/Al-5.09Mg sample transformed into Al_(3)Ti accom-panied by the reaction of Al with Ti to newly form Al_(3)Ti,generating a single Al_(3)Ti *** contrast,the new formation of Al_(3)Ti and its transformation to Al_(18)Ti_(2)Mg_(3)proceeded continuously in the Ti/Al-13.54Mg and Ti/Al-25.94Mg samples,resulting in a mixture of Al_(18)Ti_(2)Mg_(3)and a little Al_(3)Ti *** the Ti/Al-40.54Mg sample,Al_(3)Ti was the unique reaction product throughout the heating *** final Al_(3)Ti particles in the Ti/Al-5.09Mg sample were in a blocky shape,while they were in a plate-like form in the Ti/Al-40.54Mg sample,which was caused by the enhanced growth anisotropy due to the de-creased interfacial energy between Al_(3)Ti particles and Al-Mg melts with the increase of Mg content.A twin plane re-entrant mechanism was suggested for the growth of Al_(18)Ti_(2)Mg_(3)particles,weakening the anisotropic growth caused by the directional supply of Ti atoms,and contributing to the blocky mor-phology of Al_(18)Ti_(2)Mg_(3)*** addition,the volume difference between the formed Al_(18)Ti_(2)Mg_(3)and consumed Ti was greater than that between the Al_(3)Ti and Ti,and the Al_(18)Ti_(2)Mg_(3)has worse plasticity than the Al_(3)Ti,resulting in the Al_(18)Ti_(2)Mg_(3)reaction product fracturing more easily d

关键词： Mg content Intermetallic compound Phase transformation Morphology Twin

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Extraction and recycling technologies of cobalt from primary and secondary resources:A comprehensive review

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International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 628-649页

作者： Yukun Huang Pengxu Chen Xuanzhao Shu Biao Fu Weijun Peng Jiang Liu Yijun Cao Xiaofeng Zhu ZhongYuan Critical Metals Laboratory Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

Cobalt has excellent electrochemical,magnetic,and heat *** a strategic resource,it has been applied in many hightech ***,the recent rapid growth of the battery industry has substantially depleted cobalt resources,leading to a crisis of cobalt resource *** paper examines cobalt ore reserves and distribution,and the recent development and consumption of cobalt resources are summarized as *** addition,the principles,advantages and disadvantages,and research status of various methods are discussed *** can be concluded that the use of diverse sources(Cu-Co ores,Ni-Co ores,zinc plant residues,and waste cobalt products)for cobalt production should be enhanced to meet developmental ***,in recovery technology,the pyro-hydrometallurgical process employs pyrometallurgy as the pretreatment to modify the phase structure of cobalt minerals,enhancing its recovery in the hydrometallurgical stage and facilitating high-purity cobalt ***,it represents a promising technology for future cobalt ***,based on the above conclusions,the prospects for cobalt are assessed regarding cobalt ore processing and sustainable cobalt recycling,for which further study should be conducted.

关键词： cobalt recovery copper-cobalt ore nickel-cobalt ore zinc plant residue waste cobalt products

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Designing carboxymethyl cellulose based hydrogel electrolyte membranes enhanced by inorganic nanoparticle toward stable zinc anode

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Green Energy & Environment 2025年第3期10卷 537-550页

作者： Xiangye Li Yuan Li Yu Jiang Dahui Wang Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Department of Polymeric Materials EngineeringSchool of Material Science and EngineeringLanzhou University of TechnologyLanzhou730050China

Aqueous zinc metal batteries have garnered substantial attention ascribing to affordability,intrinsic safety,and environmental benignity Nevertheless,zinc metal batteries yet are challenged with potential service life issues resulted from dendrites and side *** this paper,a strategy of nanoparticles doped hydrogel is proposed for constructing carboxymethyl cellulose/graphite oxide hybrid hydrogel electrolyte membranes with exceptional ionic conductivity,anti-swelling property,and simultaneously addressing the dendrites and parasitic *** pivotal functions of the carboxymethyl cellulose/graphite oxide hydrogel electrolyte in mitigating hydrogen evolution and fostering accelerated Zn deposition have been elucidated based on principles of thermodynamic and reaction *** carboxymethyl cellulose/graphite oxide hydrogel electrolyte endows exceptional cycling longevity (800 h at 1 mA cm^(-2)/1 mAh cm^(-2)) for Znjj Zn battery,as well as high Coulombic efficiency for Znjj Cu battery (averagely 99.14%within 439 cycles at 1 mA cm^(-2)/1 mAh cm^(-2)).The assembled Znjj NH_(4)V_(4)O_(10)battery delivers a high reversible specific capacity of 328.5 mAh g^(-1)at 0.1 A g^(-1).Moreover,the device of Znjj NH_(4)V_(4)O_(10)pouch battery remains operational under severe conditions like bending and *** work provides valuable reference in developing inorganic nanoparticle hybrid hydrogel electrolyte for realizing high-performance zinc metal batteries.

关键词： Carboxymethyl cellulose Graphite oxide Hydrogel electrolyte Anti-swelling

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Vanadium nitride quantum dots@carbon skeleton anode material synthesized via in situ oxidation initiation strategy

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Tungsten 2024年第3期6卷 561-573页

作者： Yi-Han Fu Yuan-You Peng Lei Zhao Tian-Qi He Mei-Mei Yuan Hao Dang Rui Liu Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals School of Materials Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

Vanadium nitride(VN)has received significant attention as a potential negative electrode material due to its remarkable theoretical and physical ***,the electrochemical performance needs to be improved due to its low specific surface area and the issue of being easily dissolved in *** have shown that the composite structure of carbon-coated nano sc ale VN particles could significantly increase the specific surface area of VN,and more importantly,and the carbon matrix can effectively restrain the dissolution of VN particles in the electrolyte,thereby improving its chemical and electrochemical performance,including specific capacity and cycling ***,VN quantum dots are synthesized and protected by uniformly coating the carbon skeleton on its surface via an in situ strategy of oxidation initiation,which initiates dopamine polymerization,forming a crystalline complex of polydopamine and *** heat treatment,the product is a composite material with VN quantum dots embedded in the amorphous carbon *** resulting smallsized and crosslinked carbon particles formed a graded pore structure,more reasonable channels provided for electrolyte ions transport *** the composite material was used as the negative electrode material for supercapacitors,it exhibits the specific capacity of 391.9 F·g^(-1)at a current density of 0.5 A·g^(-1)and excellent capacity retention rate of 83.6%after *** synthesis method of this quantum dot could be applied to other metal compounds and has potential applications in catalysis,environmental protection,and other fields.

关键词： In situ initiation Vanadium nitride Quantum dots Anode Supercapacitors

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Bioabsorbable fabrication of molybdenum nitride/carbon nanocomposites for supercapacitors and metal ion batteries with robust stability

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Rare Metals 2023年第12期42卷 4212-4225页

作者： Qiang-Hong Wu Huan-Zhong Zeng You-Zhi Wu Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals School of Materials Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

Metal nitride is one of the best anode materials of the energy storage device;however,the low stability of the pure metal nitride limits its wide *** this work,a new method of bioabsorbable fabrication was developed for preparing molybdenum nitride that corporates into the porous carbon *** molybdenum ions in pollutions could be easily absorbed by Ligustrum quihoui,and the transportation,accumulation,and circulation of molybdenum ions in Ligustrum quihoui were *** obtained composite material of biochar and molybdenum nitride is employed as anode material of supercapacitors and batteries which exhibits good electrochemical performance,especially the rate and long lifespan ***,it is found that the specific capacity is344 F·g^(-1)at current density of 0.5 A·g^(-1)in 2 mol·L^(-1)KOH,and the capacitance retention and coulomb efficiency are above 90%after 10,000 *** should be noted that the novel approach combines fabricating anode materials with advanced nanostructure and suppressing the environmental problems with metal pollution at the same time.

关键词： Metal pollution Ligustrum quihoui Supercapacitors Metal ions batteries Anode materials

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Electronic modulation towards MOFs as template derived CoP via engineered heteroatom defect for a highly effcient overall water splitting

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Journal of Energy Chemistry 2025年第2期101卷 598-607,I0012页

作者： Meijie Ding Zhiqiang Wei Dexue Liu Wenhua Zhao Qiang Lu Zhiming Li Qingsong Yu Chenggong Lu Hua Yang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina School of Science Lanzhou University of TechnologyLanzhou 730050GansuChina

The reasonable design of material morphology and eco-friendly electrocatalysts are essential to highly efficient water *** is proposed that a promising strategy effectively regulates the electronic structure of the d-orbitals of CoP using cerium doping in this paper,thus significantly improving the intrinsic property and conductivity of CoP for water *** a result,the as-synthesize porous Ce-doped CoP micro-polyhedron composite derived from Ce-ZIF-67 as bifunctional electrocatalytic materials exhibits excellent electrocatalytic performance in both the oxygen evolution reaction(OER)and the hydrogen evolution reaction(HER),overpotentials of about 152 mV for HER at 10 mA cm^(-2)and about 352 mV for OER at 50 mA cm^(-2),and especially it shows outstanding long-term ***,an alkaline electrolyzer,using Ce0.04Co0.96P electrocatalyst as both the anode and cathode,delivers a cell voltage value of1.55 V at the current density of 10 mA cm^(-2).The calculation results of the density functional theory(DFT)demonstrate that the introduction of an appropriate amount of Ce into CoP can enhance the conductivity,and can induce the electronic modulation to regulate the selective adsorption of reaction intermediates on catalytic surface and the formation of O*intermediates(CoOOH),which exhibits an excellent electrocatalytic *** study provides novel insights into the design of an extraordinary performance water-splitting of the multicomponent electrocatalysts.

关键词： Hydrogen evolution Cerium Phosphides Oxygen evolution Water splitting

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Effects of infill patterns on properties of slurry extrusion-based additive manufactured shell moulds

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China Foundry 2025年

作者： Jiao Liu Hong-jun Liu Guo-liang Su Ya-min Li State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of Technology

Investment casting shell moulds are widely applied to cast alloys, but how to efficiently form a hierarchical porous structure inside the wall is an innovation and challenge. In this research, porous shell moulds with three infill patterns(rectilinear, grid, and honeycomb) were prepared using bauxite slurry and slurry extrusionbased additive manufacturing technology, and the effects of infill patterns on the properties were evaluated. The hierarchical pores inside the wall are composed of the macropores formed by infills and the micropores among bauxite particles. Different infill patterns result in changes in distribution and shape of pores, thereby affecting the properties of the shell moulds. The honeycomb pattern has more comprehensive advantages compared to the other two infill patterns. The samples prepared with the honeycomb pattern exhibit the highest bending strength(11.62 MPa) and porosity(41.6%), as well as good heat-transfer ability, with an average shrinkage rate within 2.0%.This work provides an attractive feasibility for fabricating shell moulds with hierarchical porous walls.

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Effects of a novel refiner Al-3Ti-4.35La combined with Sr on microstructure and mechanical properties of as-cast A356 alloy

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China Foundry 2024年第6期21卷 641-650页

作者： Mei Xu Wan-wu Ding Li-wen Hu Shi-hao Chen Hai-xia Zhang Hai-cun Yu Wen-jun Zhao School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

It is a practically significant issue to refine and modify industrial Al-Si casting alloy to improve its *** the present study,a novel refiner Al-3Ti-4.35La alloy,prepared by a melt-reaction method,was used,combined with Sr to refine the as-cast A356 *** effects on the as-cast microstructures and mechanical properties of A356 alloy were *** results indicate that the combined addition of Al-3Ti-4.35La intermediate alloy and Sr can improve the microstructure and enhance the mechanical properties of A356 *** adding 0.3wt.%Al-3Ti-4.35La and 0.03wt.%Sr to the as-cast A356 alloy,the average grain size ofα-Al decreases from 693.47μm to 264.13μm(a decrease of 61.91%),the secondary dendrite arm spacing(SDAS)is decreased by 47.8%from 32.09μm to 16.75μm,and the eutectic Si is transformed from an acicular structure to short rods and a granular *** ultimate tensile strength(UTS)and elongation(EL)of the as-cast A356 alloy modified by Al-3Ti-4.35La and Sr reach 216.3 MPa and 10.6%,which are enhanced by 29.54%and 134.66%compared with the unmodified alloy,*** fracture mode is transformed from transgranular fracture to intergranular fracture,and the ductile toughness of the alloy is *** adding the Al-3Ti-4.35La and Sr,the undercooling for the nucleation ofα-Al and eutectic Si increases,leading to an accelerated nucleation rate and an increased number of nuclei,which shortens the duration of the eutectic reaction and consequently inhibits grain growth.

关键词： A356 alloy Al-3Ti-4.35La Sr refiner grain refinement microstructure mechanical properties

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