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SSRN 2022年

作者： Lu, Jianfeng Lv, Pin Yang, Yufei Li, Neng Zhang, Yuxi Hu, Min Huang, Bo Zhu, Yanqing Li, Bin Pan, Junye Wang, Shifeng Huang, Fuzhi Cheng, Yi-Bing State Key Laboratory of Silicate Materials for Architectures Wuhan University of Technology Wuhan430070 China School of Electronic and Electrical Engineering Hubei Province Engineering Research Center for Intelligent Micro-Nano Medical Equipment and Key Technologies Wuhan Textile University Wuhan430200 China Foshan Xianhu Laboratory The Advanced Energy Science and Technology Guangdong Laboratory Foshan528216 China Innovation Laboratory of Materials for Energy and Environment Technologies Institute of Oxygen Supply Tibet University Lhasa850000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

Tin oxide (SnO2) has been demonstrated as a promising electron transport material for high efficiency perovskite solar cells (PSCs) that made entirely via solution processing at low temperature (2|perovskite lead to a large voltage loss and performance variation. Herein, we present a facile and effective method to simultaneously reduce the interfacial defects and enhance the charge transfer via modification of SnO2 by hypervalent potassium xanthate. The presence of Lewis acidic centers of the sulfur ligands, gives rise to a strong hypervalent interactions with both Pb2+ on the perovskite and Sn4+ on the SnO2 surface, which accelerates the interfacial charge transfer and suppresses the recombination reaction. As a result, solar cells with a power conversion efficiency of 23.4% with negligible hysteresis are fabricated in light of significantly increased voltage in comparison with the relevant controls. Moreover, a stabilized efficiency of 18.8% for large-area (active area: 48.0 cm2) perovskite solar modules is achieved. The modules retain 90% of their initial performance after aging at ambient for 600 hours, which is substantially improved in comparison with the modules based on pristine SnO2 © 2022, The Authors. All rights reserved.

关键词： Perovskite solar cells

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In Situ Crosslinked Side Chain Polybenzimidazole Based Anion Exchange Membranes for High Performance Alkaline Direct Methanol Fuel Cells

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SSRN 2022年

作者： Liu, Guoliang Wang, Ailian Ji, Wenxi Zhang, Fangfang Wu, Jianing Zhang, Taoyi Tang, Haolin Zhang, Haining State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Nr. 122 Luoshi Rd. Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan528200 China Research Institute of Chemical Industry Co. Ltd Beijing100013 China School of Nuclear Technology and Chemistry & Biology Hubei University of Science and Technology Nr. 88 Xianning Avenue Xianning437100 China

The practical application of quaternized polybenzimidazole (PBI) as anion exchange membranes (AEMs) is limited by the crosslinking side reaction induced low hydroxide conductivity during the operation process. In this work, the in situ crosslinking side reaction is ingeniously controlled during the membrane preparationto achieve the balance between mechanical properties and ionic conductivity of quaternized PBI based AEMs with high ion exchange capacity. The results reveal that the in situ crosslinking can not only greatly improve the mechanical properties of quaternized PBI membranes, but the high quaternization degree of ammonium hydroxide end-functionalized alkyl chain also guarantees the reasonable hydroxide conduction. The formed quaternized PBI based membrane with quaternization degree of 190% exhibits the tensile strength of 21.0 MPa under hydrated state with ion exchange capacity of 2.65 mmol g -1 and hydroxide conductivity of 82.4 mS cm -1 at 80 o C. In addition, the membrane maintains 79.7% of its initial conductivity after treating with 1 M KOH at 80 o C for 360 h. The thus-assembled alkaline direct methanol fuel cell delivers a maximum power density of 152.6 mW cm -2 using 5 M KOH and 3 M methanol fuels at 80 o C. After chronopotentiometry test at 450 mA cm -2 for 150 h, the observed 8.7% of voltage loss indicates its potential application in fuel cells. © 2022, The Authors. All rights reserved.

关键词： Ion exchange membranes

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The Impact Failure and Energy Dissipation Mechanism of Polyethylene Laminates

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Journal of Wuhan University of technology(materials Science) 2019年第3期34卷 723-727页

作者： SHU Zaiqin ZHANG Jinyong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Institute of Material Science and EngineeringWuhan University of TechnologyWuhan430070China System Design Institute of Hubei Aerospace Technology Academy Wuhan430040China

The damage mechanism and energy dissipation of the Polyethylene (PE) laminates in impacting was investigated. It was found that the dissipated energy of the impacting sphere bullet by the 1-mmthick PE plate firstly increased with the impacting velocity increasing from 50 to about 300 m/s, and then decreased with the impacting velocity increasing up to 600 m/s. According to the measured deformation and damage degree, a numerical simulation of the dissipated energy was made and obvious offset was found with the experimental results. The quasi-static properties of the PE fibers, decreasing with increase in tensile velocity, may be the main reason for the offset.

关键词： polyethylene ballistic impact energy dissipation strain rate

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Yolk–shell vanadium pentoxide integrated electrode for high-performance stretchable lithium metal battery

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Journal of Energy Storage 2024年 98卷

作者： Nathan, Muthu Gnana Theresa Yeon, Seon-Young Lee, Jae Seob Jo, Min Su Hwang, Gil Chan Kim, Hong-Il Wu, Fanglin Kim, Guk-Tae Liu, Ying Kim, Jin-Hee Cho, Jung Sang Kim, Jae-Kwang Department of Energy Convergence Engineering Cheongju University 258 Daeseong-ro Chungbuk Cheongju28503 Korea Republic of Department of Engineering Chemistry Chungbuk National University Chungbuk 28644 Korea Republic of Department of Earth System Sciences Yonsei University Seoul03722 Korea Republic of State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Department of Biomedical Laboratory Science College of Health Science Cheongju University Chungbuk Cheongju28503 Korea Republic of Biomedical Research Institute Chungbuk National University Hospital Chungbuk 361-763 28644 Korea Republic of

Vanadium pentoxide (V2O5) stands out as a preferred cathode material for stretchable lithium-ion batteries due to its high specific capacity, robust structural stability, cost-effectiveness, and ease of synthesis. However, its practical application is limited by a low Li+ diffusion coefficient (10−12–10−13 cm2 s−1) and poor electrical conductivity. To address these challenges, we have developed an innovative yolk-shell V2O5 architecture using a facile synthesis method involving spray pyrolysis followed by thermal treatment. This yolk-shell V2O5 is coated with a poly(ethylene oxide) (PEO) electrolyte to enhance ion transport contact areas and flexibility. The yolk-shell V2O5@PEO is then integrated with a PEO-based polymer electrolyte in a thin film configuration, paired with zig-zag truncated lithium metal anodes for stretchable lithium metal batteries. The integrated film demonstrates superior electrochemical performance due to highly reversible Li+ insertion/extraction and enhanced Li ion diffusion. The unique design of the stretchable Li-yolk-shell V2O5@PEO battery achieves an excellent specific discharge capacity of 261 mAh g−1, compared to 158 mAh g−1 for pure V2O5 at 0.1C. Additionally, the stretchable Li-yolk-shell V2O5@PEO cell exhibits a discharge capacity of 250 mAh g−1 under zero-strain conditions and 233.7 mAh g−1 under 40 % strain at 0.1C and 40 °C. Characterization through X-ray diffraction (XRD) and scanning electron microscopy (SEM) confirms the nano-sized morphology and high crystallinity of the yolk-shell V2O5. X-ray photoelectron spectroscopy (XPS) analysis reveals the transformation of yolk-shell V2O5@PEO into α-V2O5, Ε-Li0.5V2O5, δ-LiV2O5, and γ-Li2V2O5 phases during lithium-ion (de)intercalation. This cutting-edge battery design paves the way for the development of high-performance, stretchable, and flexible batteries, ideal for next-generation portable electronic devices. © 2024 Elsevier Ltd

关键词： Scanning electron microscopy

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Cu在纳米结构PtNi上的表面可控锚定用于高效海水产氢

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中国科学：材料科学（英文版） 2023年第10期66卷 3887-3894页

作者：杨雄肖宇轩陈江波余菲田歌蒲福飞章嵩 Susana I.Córdoba de Torresi Mark D.Symes Christoph Janiak 阳晓宇 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & International School of Materials Science and Engineering and Processing Wuhan University of Technology Wuhan 430070 China School of Chemical Engineering and Technology Sun Yat-sen University Zhuhai 519082 China Instituto de Química Universidade de Sao Paulo Av. Prof. Lineu Prestes 748 05508-080 São Paulo SP Brazil WestCHEM School of Chemistry University of Glasgow Glasgow G12 8QQ United Kingdom Institut für Anorganische Chemie und Strukturchemie Heinrich-Heine-Universität Düsseldorf Düsseldorf 40204 Germany

表面组分调控及建立多功能活性位点是提高Pt基催化剂性能的有效途径.通过将Cu可控地锚定在纳米结构PtNi表面(Cu/PtNi)可以精确控制Pt基催化剂表面元素的化学计量比,其中亲氧的非贵金属Ni能加速水的解离,Pt由于具有适中的H吸附能,可有效... 详细信息

表面组分调控及建立多功能活性位点是提高Pt基催化剂性能的有效途径.通过将Cu可控地锚定在纳米结构PtNi表面(Cu/PtNi)可以精确控制Pt基催化剂表面元素的化学计量比,其中亲氧的非贵金属Ni能加速水的解离,Pt由于具有适中的H吸附能,可有效地将游离态的H转换成氢气,Cu由于具有正的H吸附吉布斯自由能(AGH*),有助于H2的脱附.其中具有最优组分比例的Cu/PtNi电催化剂在海水中表现出优异的电化学析氢活性和稳定性,在碱性海水中,10 mA cm-2下的过电位为23 mV(在70 mV过电位下,其质量活性是商用Pt/C的5倍).同时,密度泛函理论结果进一步验证了在碱性海水中Pt,Ni和Cu多功能金属活性位点可提高HER的H2O解离、H*吸附和H2脱附的过程.

关键词： Cu/PtNi seawater hydrogen evolution surface adjustment multifunction sites hierarchical structure

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Co Gradient Li-Rich Cathode Relieving the Capacity Decay in Lithium-Ion Batteries

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SSRN 2022年

作者： Wang, Hong Liu, Fang Yu, Ruohan Xiao, Zhitong Zhu, Zhu Zhou, Liang Wu, Jinsong Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China School of Mathematics and Physics Jingchu University of Technology Jingmen448000 China Shenzhen Institute Wuhan University of Technology Guangdong Shenzhen518000 China

Lithium-rich layered oxides (LLOs) are one of the promising cathode materials for next generation energy storage devices, but structural degradation and severe capacity decay during cycling have hindered applications. Here, we find cobalt effectively mitigate structural degradation and develop a simple and novel metal organic framework (MOF) treatment and surface reconstruction method to fabricate Co gradient layer on LLOs. In situ and ex situ microstructural studies show the capacity decay is mainly originated from the formation of microstructural defects such as voids and pores, continuous oxygen release and formation of spinel and rock-salt structure initiated from the surface. The reconstruction leads to the formation of an artificial layer of Co rich and Li poor spinel (Co3O4) and rock-salt (CoO) structure on surface, suppressing the diffusion of cations and O−1/O−2 anions toward the surface during cycling. The LLO-Co cathode exhibits enhanced cycling stability with a capacity retention of 94.4% at 0.2 C after 100 cycles and a high capacity of 183 mAhg−1 at 1 C, in comparison with those of untreated LLO (80.5% and 153 mAhg−1). This work sheds lights on better utilize rare Co resource in the development of high capacity and cyclability cathode materials for lithium-ion batteries. © 2022, The Authors. All rights reserved.

关键词： Cathodes

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The Self-Assembling Growth of Copper Nanowires for Transparent Electrodes

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Journal of Wuhan University of technology(materials Science) 2019年第1期34卷 145-149页

作者： WU Junqing HUANG Fuzhi State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology School of Aerospace Transport and Manufacturing Cranfield University

Long(15-40 μm), thin(diameter of 20 ± 5 nm), and well-dispersed CuNWs Cu nanowires were prepared. The high-resolution TEM and selected area electron diffraction showed that the CuNWs were single-crystalline. To investigate the growth mechanism, we examined the microstructure of these CuNWs at different reaction time. It was found that the CuNWs were actually formed through the self-assembling of Cu nanoparticles along the [110] direction. The transparent electrodes fabricated using the CuNWs achieved a high transparency of 76 % at 31±5 Ω/□.

关键词： Cu nanowires growth mechanism self-assembling transparent electrodes

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Exploring Cu0–Cu+ Sites for Enhancing Non-Enzymatic Photoelectrochemical Glucose Sensing Performance

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SSRN 2023年

作者： Ren, Xiaohui Xu, Feicui Chen, Rongsheng Ma, Feng Shi, Li Liu, Huating Ren, Long Zhang, Hua Ni, Hongwei Xie, Zhongjian The State Key Laboratory of Refractories and Metallurgy Faculty of Materials Wuhan University of Science and Technology Wuhan430081 China Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics Collaborative Innovation Center for Optoelectronic Science and Technology Key Laboratory of Optoelectronic Devices and Systems Ministry of Education and Guangdong Province Shenzhen University Shenzhen518060 China Institute of Advanced Materials and Nanotechnology School of Chemistry and Chemical Engineering Wuhan University of Science and Technology Wuhan430081 China School of Materials Science and Chemical Engineering Ningbo University Zhejiang Ningbo315211 China School of Electrical and Electronic Engineering Wuhan Polytechnic University Wuhan430023 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China Institute of Pediatrics Shenzhen Children's Hospital Shenzhen518038 China

Photoelectrochemical (PEC) sensing platforms demonstrate outstanding performances towards enzyme-free glucose detection, and exploring glucose reactive electrodes with efficient active sites and enhanced carrier transport/separation behavior would be beneficial for PEC glucose detection. Herein, we fabricated two-dimensional Cu3(PO4)2 nanosheets as the photoactive material for glucose detection. The morphology and structural characterizations prove the existence of balanced Cu0–Cu+ active sites which has been regarded as the key factor on improving PEC performance for fast glucose detection. The photoelectric current of Cu3(PO4)2 nanosheets peeled from Cu3(PO4)2 bulk is three times that of 0 µM at 50 µM, and the response performance is increased by ~9 times compared to Cu3(PO4)2 bulk. Under light conditions, the limit of detection (LOD) as low as 17.68 µM at low concentrations of 20-100 µM, and LOD of 131.69 µM at high concentrations of 100-1000 µM can be achieved. This work might provide the basic understanding and new opportunities in applying two-dimensional Cu3(PO4)2 nanosheets for glucose detection. © 2023, The Authors. All rights reserved.

关键词： Copper compounds

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Thickness Dependence of Structural and Optical Properties of Chromium Thin Films as an Infrared Reflector for Solar-thermal Conversion Applications

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Journal of Wuhan University of technology(materials Science) 2019年第6期34卷 1239-1247页

作者： LI Qingyu GONG Dianqing CHENG Xudong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China

The thermal emittance of Cr film, as an IR reflector, was investigated for the use in SSAC. The Cr thin films with different thicknesses were deposited on silicon wafers, optical quartz and stainless steel substrates by cathodic arc ion plating technology as a metallic IR reflector layer in SSAC. The thickness of Cr thin films was optimized to achieve the minimum thermal emittance. The effects of structural, microstructural, optical, surface and cross-sectional morphological properties of Cr thin films were investigated on the emittance. An optimal thickness about 450 nm of the Cr thin film for the lowest total thermal emittance of 0.05 was obtained. The experimental results suggested that the Cr metallic thin film with optimal thickness could be used as an effective infrared reflector for the development of SSAC structure.

关键词： thermal emittance chromium thin film solar selective absorbing coating cathodic arc ion plating

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PTCDA/CuS cathode enabling stable sulfide-based all-solid-state batteries

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Journal of Materiomics 2025年

作者： Zhixing Wan Shuo Wang Yahao Mu Ruihua Zhou Hang Liu Tingwu Jin Di Wu Jianlong Xia Ce-Wen Nan Center of Smart Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Material Science and Engineering Wuhan University of Technology Wuhan 430070 China School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan 430070 China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 China

Organic cathode materials have garnered significant attention for their potential application in lithium-ion batteries due to their lightweight nature, tunable structures, high energy density, and environmental friendliness. However, the dissolution of organic cathodes in liquid electrolytes often leads to poor cycling stability, which limits their practical application. In this study, a composite cathode was prepared by ball milling the PTCDA/CuS (perylene-3,4,9,10-tetracarboxylic dianhydride, PTCDA) with a sulfide-based electrolyte and carbon nanotubes. By optimizing the component ratios, the assembled all-solid-state batteries (ASSBs) show a high discharge capacity of 210 mA⸱h/g after 200 cycles without any capacity degradation at a current density of 33.0 mA/g. Through comprehensive characterization techniques including X-ray diffraction (XRD), Raman spectroscopy, Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS), the coordination of Cu 2+ and the formation of sulfur-linked polymers during the charge-discharge processes are elucidated, and the reversibility of the electrochemical reactions has been confirmed. This work highlights the excellent compatibility between organic cathodes and sulfide-based electrolytes, providing a new way for the development of high-performance ASSBs with high energy density and extended lifespan.

关键词： PTCDA/CuS lithium argyrodite organic cathode all-solid-state battery

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