Permittivity and anti-voltage ability commonly determined the energy storage density of material. Although composite could be molded easier than ceramic, its lower energy storage density prevented the material from ap...
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Permittivity and anti-voltage ability commonly determined the energy storage density of material. Although composite could be molded easier than ceramic, its lower energy storage density prevented the material from application since the polymer usually took on poor dielectric constant. In order to enhance the energy storage performance of composite, PAn was introduced to PVDF by emulsion polymerization. SEM of the co-polymers showed that they could construct continuous media till the concentrate of aniline reached 25% while polymerizing. The permittivity of polymer rose along with the concentrate increasing of aniline and pH falling value of retreating solution. The permittivity and anti-voltage strength of composite also charged correspondingly. As a consequence, the energy storage density innovated much higher than ever. The maximum energy storage density could approach 0.9185Johr/cc.
In this paper, the lower and upper bounds of Young's modulus and Poisson ratio are determined by the effective stress method and effective strain method from material mechanics. The effective heat flux method base...
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In this paper, the lower and upper bounds of Young's modulus and Poisson ratio are determined by the effective stress method and effective strain method from material mechanics. The effective heat flux method based on the hypothesis of equivalent temperature difference and the effective temperature difference method based on the hypothesis of equivalent heat flux are proposed, the lower and upper bounds of the thermal conductivity of ceramic/metal composite material are determined similarly. The result shows that the property values of ceramic/metal composites calculated from current theoretical property formulas are within the lower and upper bounds determined by the above methods.
Four Coating schemes and two substrate materials are designed to evaluate the characteristics of the ceramic/metal gradient thermal barrier coating. The gradient coating is successfully prepared by plasma spray with s...
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Four Coating schemes and two substrate materials are designed to evaluate the characteristics of the ceramic/metal gradient thermal barrier coating. The gradient coating is successfully prepared by plasma spray with single torch and single feeder. The coating performance is evaluated by observing microstructure, measuring thermal shock resistance and thermal residual stress. The coating microstructure is observed by scanning electron microscope (SEM). Diffractive peaks for the gradient coating are got at different zone by X-ray spectroscopy (XRS). The thermal shock experiment shows that the thermal shock resistance property of the gradient coating is better than that of the non-gradient coating. The measurements of thermal residual stresses in different coating schemes are carried out by hole-drilling method, the results show that compressional stress presents on 1Cr18Ni9Ti substrate and tensile stress presents on 2Cr13 substrate.
Taking the running parameters of boiler drum in 8 typical working conditions as data of boundary conditions, the transient thermal stress, mechanical stress and total stress of a 300MW boiler drum is calculated by fin...
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Taking the running parameters of boiler drum in 8 typical working conditions as data of boundary conditions, the transient thermal stress, mechanical stress and total stress of a 300MW boiler drum is calculated by finite element method. The results show that when the vapor pressure is close to or higher than the normal working vapor pressure, the temperature difference on the boiler wall has little influence on the total stresses. The vapor pressure in boiler drum is the main influential factor to the total stresses, and there is a proportion relationship between them. With the relationship, the maximum stress in the drum can be calculated.
The transient stress field analysis aims at the thermal and mechanical response of LPG vessel under pool fire surrounding environment. Finite element analysis method is used to calculate the stress field. Thermal boun...
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The transient stress field analysis aims at the thermal and mechanical response of LPG vessel under pool fire surrounding environment. Finite element analysis method is used to calculate the stress field. Thermal boundary conditions of LPG vessel are determined according to heat transfer theory and calculated by the software PLGS99. The results show that the maximum whole stress of the vessel appears near the highest surface where liquid can reach, the maximum thermal stress is much greater than the maximum mechanical stress and fluctuation of liquid surface is the main reason of high stress. The highest position of the LPG vessel which liquid can reach should be protected as it is the most dangerous place.
BaCO3 whiskers exhibiting different morphologies were fabricated by a simple precipitation reaction of barium ch/oride with sodium carbonate in the absence and presence of poly-（styrene-alt-maleic acid） （PSMA） as ...
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BaCO3 whiskers exhibiting different morphologies were fabricated by a simple precipitation reaction of barium ch/oride with sodium carbonate in the absence and presence of poly-（styrene-alt-maleic acid） （PSMA） as a crystal growth modifier at room temperature. The as-prepared products were characterized by scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, and X-ray diffraction （XRD）. The influences of experimental parameters on the size and morphology of BaCO3 whiskers were investigated and discussed. It was found that the as-prepared BaCO3 whiskers are single crystals with diameter ranging from 100 to 300 run, and grow along the crystallographic a-axis or [100] direction. BaCO3 whiskers with different morphologies, such as branching and dendritic structure, can be obtained depending on the experimental conditions. With increasing PSMA concentration, the diameter of BaCO3 whiskers decreases.
The thermal shock resistance and anti- aluminum erosion of TiB2 - BN multiphase ceramics composites were studied. The experimental results show that the TiB2-BN multiphase ceramic possesses a good thermal shock resist...
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The thermal shock resistance and anti- aluminum erosion of TiB2 - BN multiphase ceramics composites were studied. The experimental results show that the TiB2-BN multiphase ceramic possesses a good thermal shock resistance at high temperatures （ 1000, 1200, 1400, 1500 ℃ ）, with the increasing in thermal shocking temperature, the electro-conductivity of TiB2-BN ceramics increases. The metal aluminum has a great influence on the properties of TiB2 - BN ceramics and the main reason is that the aluminum reacts seriously with BN. It is suggested that the content of BN should be reduced to the greatest extent.
Nanocrystalline WC-Co composite powder and coated tungsten diamond by using vacuum vapor deposition were consolidated by the spark plasma sintering （SPS） process to prepare diamond-enhanced WC-Co cemented carbide co...
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Nanocrystalline WC-Co composite powder and coated tungsten diamond by using vacuum vapor deposition were consolidated by the spark plasma sintering （SPS） process to prepare diamond-enhanced WC-Co cemented carbide composite materials. The interface microstructures between coated tungsten diamond and WC-Co cemented carbide matrix were investigated by scanning electron microscopy （SEM） and energy dispersive X-ray spectroscopy （EDXS）. The results showed that there is a transitional layer between the diamond and the matrix, in which the carbon content is 62.97wt.%, and the content of cobalt in the transitional zone is 6.19wt.%; the content of cobalt in the WC-Co cemented carbide matrix is 6.07wt.%, in which the carbon content is 15.95wt.%, and the content of cobalt on the surface of diamond is 7.30wt.%, in which the carbon content is 80.38wt.%. The transitional zone prevents the carbon atom of the diamond from spreading to the matrix, in which the carbon content does coincide with the theoretical value of the raw nanocomposite powders, and the carbon content forms a graded distribution among the matrix, transitional zone, and the surface of diamond; after the 1280℃ SPS consolidated process the diamond still maintains a very good crystal shape, the coated tungsten on the surface of the diamond improves thermal stability of the diamond and increases the bonding strength of the interface between the diamond and the matrix.
A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics we...
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A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics were characterized by X-ray diffraction, scanning electron microscope, and microwave dielectric properties measurements. These samples were identified as single phase and adopted A4B3O12-type cation-deficient hexagonal perovskite structure, which can be described as consisting of identical perovskite-like blocks, three corner-sharing BO6 octahedra thick, separated by layers of vacant octahedral. These ceramics have high dielectric constants in the range of 48-42, high quality factors (Q×f) up to 38 000 GHz, and low temperature coefficient of resonant frequencies (τf) in the range of (-40-+6)×10-6℃-1. With increasing content of La and Ti, the dielectric constants slightly decrease butτf gradually increases.
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