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Tunable Ru-Ru2P heterostructures with charge redistribution for efficient pH-universal hydrogen evolution

InfoMat 2022年第5期4卷 164-173页

作者： Ding Chen Ruohan Yu Ruihu Lu Zonghua Pu Pengyan Wang Jiawei Zhu Pengxia Ji Dulan Wu Jinsong Wu Yan Zhao Zongkui Kou Jun Yu Shichun Mu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshanChina Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhanChina State Key Laboratory of Silicate Materials for Architectures International School of Materials Science and EngineeringWuhan University of TechnologyWuhanChina

Designing synergistic heterogeneous catalytic interfaces is the key to developing highly compatible pH-universal electrocatalysts for complex chemical envi*** theoretical calculation results demonstrate that the Ru-Ru2P heterointerface can not only promote the redistribution of charges,but also reduce the d-band center,and then enhances the adsorption capacity of the key ***,in situ and facile synthesis of Ru-Ru2P heterostructures is severely limited by thermodynamic ***,we propose a molten salt-assisted catalytic synthesis scheme,and successfully build a series of homologous metallic Ru-Ru2P heterostructure catalysts with different molar ratios of Ru to P under atmospheric pressure and low-temperature(400C).The resultant Ru-Ru2P with rich heterostructures show the Pt-like HER performance in different pH ***,it is prominent under alkaline conditions(18 mV@10 mA cm^(2)),which outperforms the Pt catalyst(37 mV@10 mA cm^(2)).Furthermore,Ru-Ru2P heterostructures also show certain potential in the electrolysis of seawater to produce *** work represents a significant supplement of high-efficiency pH-universal HER catalysts,and provides a new light on interface engineering in energy technology fields and beyond.

关键词： DFT calculation heterostructure molten salt-assisted synthesis pH-universal hydrogen evolution ruthenium phosphide

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Atomic Level Dispersed Metal–Nitrogen–Carbon Catalyst toward Oxygen Reduction Reaction: synthesis Strategies and Chemical Environmental Regulation

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Energy & Environmental materials 2021年第1期4卷 5-18页

作者： Hengbo Yin Huicong Xia Shuyan Zhao Kexie Li Jianan Zhang Shichun Mu College of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

For development and application of proton exchange membrane fuel cell(PEMFC) energy transformation technology, the cost performance must be elevated for the catalyst. At present, compared with noble metal-based catalysts, such as Pt-based catalysts, atomically dispersed metal–nitrogen–carbon(M–N–C) catalysts are popularity and show great potential in maximizing active site density, high atom utilization and high activity,making them the first choice to replace Pt-based catalysts. In the preparation of atomically dispersed metal–nitrogen–carbon catalyst, it is difficult to ensure that all active sites are uniformly dispersed, and the structure system of the active sites is not optimal. Based on this, we focus on various approaches for preparing M–N–C catalysts that are conducive to atomic dispersion, and the influence of the chemical environmental regulation of atoms on the catalytic sites in different catalysts. Therefore, we discuss the chemical environmental regulation of the catalytic sites by bimetals, atom clusters, and heteroatoms(B, S, and P). The active sites of M–N–C catalysts are explored in depth from the synthesis and characterization, reaction mechanisms, and density functional theory(DFT)calculations. Finally, the existing problems and development prospects of the current atomic dispersion M–N–C catalyst are proposed in detail.

关键词： atomic-level catalyst chemical environmental effects metal-nitrogen-carbon oxygen reduction reaction synthesis strategy

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Preparation of Bi_(2)O_(3)/BiOI Step-scheme Heterojunction Photocatalysts and Their Degradation Mechanism of Methylene Blue

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Journal of Wuhan University of technology(materials Science) 2022年第5期37卷 801-806页

作者： JIANG Xuechao TAN Haiyan SHI Xinyu CHENG Xinhua HU Weibing HU Xinhui Key Laboratory of Green Manufacturing of Super-light Elastomer Materials of State Ethnic Affairs Commission School of Chemistry and Environmental EngineeringHubei Minzu UniversityEnshi445000China Guangxi Key Laboratory of Chemistry and Engineering of Forest Products Guangxi University for NationalitiesNanning530006China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Bi_(2)O_(3)/BiOI step-scheme(S-scheme) heterojunction photocatalyst was synthesized by green calcination method, its degradation ability of methylene blue was investigated, and the photocatalytic performance of the Bi_(2)O_(3)/BiOI heterojunction, Bi_(2)O_(3) and BiOI was compared. The structure and morphology of the samples were characterized by X-ray diffraction(XRD), field emission scanning electron microscopy(FESEM), and UV-vis diffuse reflection spectrum (UV-vis DRS). The degradation rate of methylene blue was analysised by spectrophotometry, and the calculation result showed that the degradation rate of methylene blue was 97.8% in 150 minutes. The first order kinetic rate constant of 10%Bi_(2)O_(3)/BiOI is 0.021 8 min^(-1), which are2.37 and 2.68 times of BiOI(0.009 18 min^(-1)) and Bi_(2)O_(3) (0.008 03 min^(-1)) respectively. The calculation result shows that the work function of Bi_(2)O_(3) and BiOI are 3.0 e V and 6.0 e V, respectively, by density functional theory(DFT). When this S-scheme heterojunction is used as a photocatalyst, the weaker electrons in the conduction band of BiOI will be combined with the weaker holes in the Bi_(2)O_(3) valence band under combined effect with built-in electric field and band bending, which will retain stronger photoelectrons and holes between Bi_(2)O_(3) and BiOI. This may be the internal reason for the efficient degradation of tetracycline by Bi_(2)O_(3)/BiOI S-scheme heterostructures.

关键词： step-scheme heterojunction methylene blue antibiotic wastewater treatment photocatalytic degradation charge separation

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Solar fuel generation over nature-inspired recyclable TiO_(2)/g-C_(3)N_(4)S-scheme hierarchical thin-film photocatalyst

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Journal of materials Science & technology 2022年第17期112卷 1-10页

作者： Libo Wang Xingang Fei Liuyang Zhang Jiaguo Yu Bei Cheng Yuhua Ma State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of Geosciences388 Lumo RoadWuhan 430074China College of Chemistry and Chemical Engineering Xinjiang Normal UniversityUrumqi 830054China

Preparation of efficient photocatalysts with ease of recovery in solar fuel generation is highly desired to achieve carbon neutralization in carbon dioxide(CO_(2))*** from the forest with superior light penetration and fast gas transport,a TiO_(2)/g-C_(3)N_(4)composite nanowire arrays(NAs)film with maximized light utilization is *** is achieved by in-situ coating a thin layer of g-C_(3)N_(4)(as the leaf)on the vertically-oriented TiO_(2)arrays(as tree trunks)on Ti foil(as soil).Benefiting from the effective charge separation by S-scheme charge transfer,intimate contact by the in-situ growth as well as the ingenious structure,the composite,readily recyclable,displays exciting performance in photocatalytic CO_(2)*** is beyond doubt that the combination of heterojunction construction and“nature-inspired biomimetic photocatalyst”design promises practical applications and industrial use.

关键词： Carbon neutralization Solar fuels Intimate interfacial contact S-scheme heterojunction Biomimetic photocatalyst

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Bioactive calcium and mangnesium phosphate bone adhesive for enhanced vascularization and bone regeneration

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Journal of materials Science & technology 2023年第33期164卷 246-257页

作者： Jiawei Liu Honglei Kang Wenying Wei Rong Tu Takashi Goto Feng Li Honglian Dai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei ProvinceWuhan University of TechnologyWuhan 430070China Department of Orthopedics Tongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430030China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China New Industry Creation Hatchery Center Tohoku UniversitySendai 980-8579Japan

Bone adhesive is a promising material for the treatment of bone fractures,which is helpful for the fast and effective reduction and fixation of broken ***,the existing adhesives bond weakly to bone tissues,and are non-absorbable,or hard to cure under wet ***,inspired by the cement-based adhesive used in the industry field,we report a bioactive calcium and magnesium phosphate bone adhesive(MPBA)with the properties of facile preparation,robust adhesion,and *** is equipped with similar strength to cancellous bones and shows reliable bonding performance for various interfaces,such as Ti6Al4V,Al2O3,and poly(ether-ether-ketone).MPBA achieves excellent bonding ability for the above interfaces with the bonding strengths of 2.28±0.47,2.32±0.15,and 1.44±0.38 MPa,***,it also shows reliable fixation ability for bovine bone *** bonding behavior to materials and bones suggests that MPBA could be used for both fracture treatment and implant ***,MPBA possesses good biological activity,which could promote the vascularization process and osteogenic ***,in vivo experiments confirmed MPBA can effectively restore bone strength and promote bone regeneration.

关键词： Fracture Calcium magnesium phosphate cement Bone adhesives

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Review on incorporation of alkali elements and their effects in Cu(In,Ga)Se_(2)solar cells

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Journal of materials Science & technology 2022年第1期96卷 179-189页

作者： Yazi Wang Shasha Lv Zhengcao Li State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Key Laboratory of Radiation Beam Technology and Material Modification(MOE) College of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China Key Laboratory of Advanced Materials(MOE) School of Materials Science and EngineeringTsinghua UniversityBeijing 100084Chinaa

Cu(In,Ga)Se_(2)(CIGS)is a promising candidate to replace crystalline silicon solar cells and dominate the photovoltaic market in the *** elements such as sodium(Na),potassium(K),rubidium(Rb),and Cesium(Cs)are commonly accepted as indispensable parts to boost cell efficiencies of CIGS thin-film solar ***,a comprehensive understanding of alkali effects on the electronic and chemical properties of the CIGS layer as well as the underlying mechanisms is of paramount importance for achieving high-performance solar *** paper reviews the development process and incorporation pathways of alkalis and then overviews the roles of different alkali elements and their effects on CIGS cells in ***,the unsolved problems and future development prospects are also ***,the understanding and development of widely adopted alkali-fluoride post-deposition treatments(PDTs)are still underway,and together with newly updated research,it will likely enable the CIGS technology to make the conversion efficiency closer to its theoretical limit.

关键词： Cu(In,Ga)Se_(2)(CIGS) Solar cells Post-deposition treatment(PDT) Alkali effects

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synthesis of highly sinterable MgO powders for IR transparent ceramics

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Ceramics International 2025年

作者： Zhi, Yongli Mei, Bingchu Li, Weiwei Cheng, Jing Luo, Peng State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Jianghuai Advance Technology Center Hefei230000 China

MgO transparent ceramics (TCS) have attracted great interests in the field of infrared window materials due to its wide transmission range, excellent thermal conductivity, and balanced mechanical properties. To date, research on MgO transparent ceramics predominantly relies on commercial MgO powders by spark plasma sintering (SPS). Herein, we report highly sinterable MgO powders synthesized by co-precipitation method, which exhibits pure phase and particle size of 75 nm. When sintered at 950 °C under 45 MPa for 2 h by hot pressed (HP) method, the transmittance of the MgO ceramic sample with the thickness of 2 mm achieved 76.9 % at 0.4 μm and 88.3 % at 5 μm. These optical properties are comparable to or even superior to MgO TCS produced through SPS method. This work shows that the MgO particles synthesized via the co-precipitation method are suitable for producing high optical quality of MgO infrared (IR) transparent ceramics. © 2025

关键词： Thermal conductivity

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Interdisciplinary exploration between magnetism and thermoelectricity

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Science Bulletin 2022年第9期67卷 891-894,M0003页

作者： Cuncheng Li Wenyu Zhao Qingjie Zhang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Thermoelectrics have important applications in power generation and refrigeration through the direct energy conversion between heat and *** performance of thermoelectric(TE)materials can be qualified by dimensionless figure of merit ZT=σa2/κ,whereσ,a andκare the electrical conductivity,Seebeck coefficient and thermal conductivity,respectively.

关键词： conductivity Seebeck electrical

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Minimizing tin(Ⅱ) oxidation using ethylhydrazine oxalate for high-performance all-perovskite tandem solar cells

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Journal of Semiconductors 2025年第5期46卷 88-94页

作者： Jianhua Zhang Xufeng Liao Weisheng Li Yutian Tian Qinyang Huang Yitong Ji Guotang Hu Qingguo Du Wenchao Huang Donghoe Kim Yi-Bing Cheng Jinhui Tong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Art and Design Wuhan University of TechnologyWuhan 430070China School of Information Engineering Wuhan University of TechnologyWuhan 430070China Department of Materials Science and Engineering Korea UniversitySeoul 02841Korea Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China

All-perovskite tandem solar cells(ATSCs) have the potential to surpass the Shockley-Queisser efficiency limit of conventional single-junction devices. However, the performance and stability of mixed tin–lead(Sn–Pb) perovskite solar cells(PSCs), which are crucial components of ATSCs, are much lower than those of lead-based perovskites. The primary challenges include the high crystallization rate of perovskite materials and the susceptibility of Sn^(2+) oxidation, which leads to rough morphology and unfavorable p-type self-doping. To address these issues, we introduced ethylhydrazine oxalate(EDO) at the perovskite interface, which effectively inhibits the oxidation of Sn^(2+) and simultaneously enhances the crystallinity of the perovskite. Consequently, the EDO-modified mixed tin-lead PSCs reached a power conversion efficiency(PCE) of 21.96% with high reproducibility. We further achieved a 27.58% efficient ATSCs by using EDO as interfacial passivator in the Sn-Pb PSCs.

关键词： mixed tin–lead perovskite solar cells ethylhydrazine oxalate Sn^(2+)oxidation all-perovskite tandem solar cells

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微束等离子体重熔Mg-12Dy-1.1Ni合金的显微组织和腐蚀性能

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Journal of Central South University 2023年第1期30卷 20-34页

作者：姜静陈思琦顾家睿毕广利黄健康李元东陈体军马颖 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(Lanzhou University of Technology) Lanzhou 730050China School of Material Science and Engineering Lanzhou University of TechnologyLanzhou 730050China

本文研究了微束等离子体重熔(MPRMed)Mg-12Dy-1.1Ni (wt%)合金的显微组织和腐蚀性能。铸态合金主要由α-Mg相、具有18R-LPSO结构的片层状Mg12DyNi相和Mg24Dy5相组成。经微束等离子体重熔后,铸态合金的晶粒尺寸显著细化至11μm,18R-LPSO... 详细信息

本文研究了微束等离子体重熔(MPRMed)Mg-12Dy-1.1Ni (wt%)合金的显微组织和腐蚀性能。铸态合金主要由α-Mg相、具有18R-LPSO结构的片层状Mg12DyNi相和Mg24Dy5相组成。经微束等离子体重熔后,铸态合金的晶粒尺寸显著细化至11μm,18R-LPSO相体积分数由18.3%增加至26.0%,并呈连续网状分布。电化学和浸泡实验结果表明,在0.1 mol/L NaCl溶液中,MPRMed合金的失重速率(0.31 g/(cm2·d))和腐蚀电流密度(605.3μA/cm2)均低于铸态合金,其中腐蚀电流密度较铸态合金减少了38.5%。该MPRMed合金优异的耐腐蚀性能主要源自于其均匀的显微组织、致密的腐蚀产物和连续分布的18R-LPSO相。

关键词： Mg-Dy-Ni合金微束等离子重熔显微组织 LPSO相腐蚀性能

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