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Interfacial Microstructure and Mechanical Behavior of Low-Temperature Diffusion Bonded Mo/SS304 Joints Using Ni xCu 1-x Interlayers

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SSRN 2021年

作者： Jia, Mingyong Chen, Fei Zhang, Lei Huang, Zhifeng Shen, Qiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

To join dissimilar metals with large differences in characteristics, such as molybdenum (Mo) and stainless steels (SS), is essential to take full advantage of their combined performances. In this work, Mo and SS304 have been jointed with Ni interlayer by using a diffusion bonding technique at different bonding temperatures. The results show that a MoNi brittle intermetallic compound is easy to form in the interface of the Mo/SS304 joint with increasing the bonding temperature, which will reduce the shear strength of the joint because a crack is easy to form between Mo and the intermetallic compounds. Meanwhile, Mo/SS304 joints have also been prepared by using NixCu1-x (x=0.45, 0.24, or 0) as an interlayer. The result shows that reducing Ni content can avoid the formation of intermetallic compounds, and the fracture occurs between the interlayer and Mo diffusion zone far away from the Mo side. This work shows that the fracture properties of the Mo/SS304 joint can be modified by changing the composition of the interlayer. The best shear strength of the Mo/SS304 joint is 140 MPa. This work is important for providing an effective approach to join Mo and SS304 using a low-temperature diffusion bonding method. © 2021, The Authors. All rights reserved.

关键词： Intermetallics

Tuning Ferroelectrics to Antiferroelectrics in Multiferroic LaxSr1-xFe12O19 Ceramics

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arXiv

arXiv 2021年

作者： Duan, Cong-Cong Tan, Guo-Long State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

The combination of antiferroelectricity (AFE) and ferromagnetism (FM) in one structure would allow the development of new type of multiferroic candidates, which be applicable not only in magnetoelectric memories but also in novel energy storage devices. Here we propose a novel type of multiferroic candidate LaxSr1-xFe12O19, whose room temperature state could betuned from ferroelectrics (FE) to antiferroelectrics by changing x from 0 to 0.5. The emphasis of this paper will be focused on the La0.5Sr0.5Fe12O19 system, in which full AFE and FM coexist. The pure antiferroelectric behavior in La0.5Sr0.5Fe12O19 ceramics is demonstrated by double polarization-electric field (P-E) hysteresis loops, which are fully separated by a linear antiferroelectric AFE component with zero net polarization. The material of La0.2Sr0.7Fe12O19 with the intermediate composition exhibits a hybrid ferroelectric/antiferroelectric state. The recoverable energy density of the antiferroelectric La0.5Sr0.5Fe12O19 phase reaches Ure∼14.3 J/cm3. This material demonstrates strong magnetoelectric coupling and giant magnetoresistance (GMR) effect. A 1.1T magnetic field generates electronic polarization up to 0.95μC/cm2, reduce the resistance by 117%, enhances dielectric constants by 540% and right shifts the maximum dielectric loss peak by 208 kHz. The combined functional responses provide an opportunity to develop novel multifunctional electric and energy storage devices. © 2021, CC BY.

关键词： Energy storage

Amorphous Titanium Dioxide and Polyaniline Dual Modifying Silicon for Highly Enhanced Lithium-Ion Storage

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SSRN 2024年

作者： Li, Yu Shi, Wen-Hua Yin, Zhi-Wen Wang, Meng Liu, Jing Hu, Zhi-Yi Li, Bei Chen, Li-Hua Su, Bao-Lian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Hubei Wuhan430070 China Wuhan University of Technology Hubei Wuhan430070 China School of Materials Science and Engineering Research Center for Materials Genome Engineering Wuhan University of Technology Hubei Wuhan430070 China University of Namur NamurB-5000 Belgium

Silicon (Si) anode material is promising in the next generation of lithium-ion batteries (LIBs) with high energy densities for its much higher capacity (4200 mAh/g) than that of commercial graphite (372 mAh/g). However, silicon anode material with low electronic conductivity suffers a huge volume variation and accompanies side reactions during alloyed and de-alloyed process. Here, we design an inner amorphous titanium dioxide (TiO2) and an outer flexible conductive polyaniline (PANI) network dual modified Si@TiO2@PANI material for LIBs, where the TiO2 avoids the side reactions and the PANI network layer buffers the volume expansion and increases the electronic conductivity. The as-prepared Si@TiO2@PANI exhibits a high initial discharge capacity of 3050 mAh/g and maintains 1583 mAh/g after 200 cycles at 0.5 A/g. It even delivers the discharge capacity of 1002 mAh/g after 600 cycles at 1 A/g, as well as an excellent rate ability with discharge capacity of 1890, 1260 and 432 mAh/g at the high current density of 1, 2 and 5 A/g, respectively. Our strategy shows that the innovative design of double buffer layers on Si can synergistically promote stability and accelerate kinetics of Li+ transport, offering novel resolution strategy to enhance the performance of Si-based anodes for LIBs. © 2024, The Authors. All rights reserved.

关键词： Titanium dioxide

Electronic Correlations and Hund’s Rule Coupling in Trilayer Nickelate La4Ni3O10

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arXiv

arXiv 2024年

作者： Huo, Zihao Zhang, Peng Zhang, Zihan Duan, Defang Cui, Tian Key Laboratory of Material Simulation Methods & Software of Ministry of Education State Key Laboratory of Superhard Materials College of Physics Jilin University Changchun130012 China MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics School of Physics Xi’an Jiaotong University Xi’an710049 China Institute of High Pressure Physics School of Physical Science and Technology Ningbo University Ningbo315211 China

Trilayer Ruddlesden–Popper phase La4Ni3O10 has been observed with Tc of ~ 30 K at high pressure in recent experiment, which further expanded the family of nickelate superconductors. In this study, we explored the effects of electronic correlations in La4Ni3O10 using density function theory plus dynamical mean–field theory at ambient and high pressures. Our derived spectral functions and Fermi surface of ambient pressure phase are nicely consistent with the experimental results by angle–resolved photoemission spectroscopy, which emphasized the importance of electronic correlations in La4Ni3O10. We also found the electronic correlations in pressured La4Ni3O10 are both orbital–dependent and layer–dependent due to the presence of Hund’s rule coupling. There is a competition between the Hund’s rule coupling and the crystal–field splitting, and therefore the Ni–O layers with weaker crystal-field splitting energy would have stronger electronic correlations. Copyright © 2024, The Authors. All rights reserved.

关键词： Photoacoustic spectroscopy

A multi-band and polarization-independent perfect absorber based on Dirac semimetals circles and semi-ellipses array

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Chinese Physics B 2021年第9期30卷 574-578页

作者： Zhiyou Li Yingting Yi Danyang Xu Hua Yang Zao Yi Xifang Chen Yougen Yi Jianguo Zhang Pinghui Wu Joint Laboratory for Extreme Conditions Matter Properties Southwest University of Science and TechnologyMianyang 621010China State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050China College of Physics and Electronics Central South UniversityChangsha 410083China College of Science Zhejiang University of TechnologyHangzhou 310023China Department of Physics and Electronic Engineering Jinzhong UniversityJinzhong 030619China Research Center for Photonic Technology Key Laboratory of Information Functional Material for Fujian Higher EducationQuanzhou Normal UniversityQuanzhou 362000China

We design a four-band terahertz metamaterial absorber that relied on the block Dirac semi-metal(BDS).It is composed of a Dirac material layer,a gold reflecting layer,and a photonic crystal slab(PCS)medium *** structure achieved perfect absorption of over 97%at 4.06 THz,6.15 THz,and 8.16 *** high absorption can be explained by the localized surface plasmon resonance(LSPR).And this conclusion can be proved by the detailed design of the surface ***,the resonant frequency of the device can be dynamically tuned by changing the Fermi energy of the *** to the advantages such as high absorption,adjustable resonance,and anti-interference of incident angle and polarization mode,the Dirac semi-metal perfect absorber(DSPA)has great potential value in fields such as biochemical sensing,information communication,and nondestructive detection.

关键词： metamaterials terahertz block Dirac semi-metal localized surface plasmon resonance

Densification and Properties of W-Ag Matrix Composites by Designed Dual-Metal-Layer Coated Powders

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SSRN 2022年

作者： Luo, Guoqiang Guo, Jingwei Hu, Jianian Li, Peibo Sun, Yi Shen, Qiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China State Key Laboratory of Precision Blasting Jianghan University Wuhan430070 China Chaozhou Branch of Chemistry Chemical Engineering Guangdong Laboratory Chaozhou521000 China

In this study, W-Ag matrix composites were fabricated by a relatively low temperature (750 °C) via designing dual-metal-layer (Cu and Ag) coated W powders. The effects of Cu and Ag coated W powders on the densification, microstructure and properties of the composites were investigated. The results indicated that the Cu-Ag coating promotes the sintering process and favors the low-temperature densification of W-Ag matrix composites. Moreover, the Cu-Ag coating benefited the formation of Cu-Ag solution and improved the interfacial bonding. The hardness of W-Ag matrix composites was increased to 260.0 HV by adjusting the composition of the material, and compressive strength can reach 799 MPa. The electrical conductivity can improve to 45.0% IACS. © 2022, The Authors. All rights reserved.

关键词： Microstructure

High-Pressure And High-Temperature synthesis of Black Phosphorus-Graphite Anode material for Lithium-Ion Batteries

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SSRN 2023年

作者： Cheng, Zhikang Tu, Bingtian Wu, Ye Huang, Haijun School of Science Wuhan University of Technology Hubei Wuhan430070 China Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Demonstration Zone Hubei Xiangyang441000 China State Key Lab of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Hubei Wuhan430070 China

Phosphorus-based materials with a high theoretical specific capacity and a fast charge-discharge rate are considered as promising anode materials for high energy density lithium-ion batteries (LIBs). Red phosphorus (RP) and black phosphorus (BP) are two main allotropes to be used as anode materials. However, huge volume expansion during charge-discharge processes hinders the application of RP and BP in LIBs. Composites of phosphorus and carbon-based materials have been extensively fabricated to withstand volume expansion of phosphorus and improve cycle performance. Here, composites of BP and graphite (BP-G) with three P-G mass ratios (8 : 2, 7 : 3, and 6 : 4) have been synthesized by a facile and scalable high-pressure and high-temperature (HPHT) method using RP and graphite composites (RP-G) prepared by ball milling as precursors. Their microstructure and bonding configurations have been analyzed by various characterization techniques. Among three RP-G composites, 7RP-3G exhibits the most excellent cycling stability, a high reversible capacity of 1331 mAh/g after 200 cycles at a current density of 0.78 A/g. However, RP-G composites show poor stability at high current densities. Among three BP-G composites, 6BP-4G shows the best cycle stability at high current densities, a reversible capacity of 634.6 mAh/g after 500 cycles at a current density of 2.6 A/g. Although, the reversible specific capacities of BP-G composites after long cycles are lower than those of RP-G, BP-G composites show more stable cycle performance than RP-G, especially at high current densities. The present work illustrates a direct and facile method to synthesize BP-G composites, and sheds light to explore new synthetic route of BP-based composites. © 2023, The Authors. All rights reserved.

关键词： Lithium-ion batteries

In Situ Programming Acid-Base Pair Proton-Conductive Channels of Perfluorosulfonic Acid Membrane for Fuel Cells

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SSRN 2022年

作者： Zhang, Wenxing Zhao, Shengqiu Wang, Rui Zhang, Aojie Huang, Yi Tang, Haolin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen Valley Foshan528200 China State Key Laboratory of Automotive Safety and Energy School of vehicle and Mobility Tsinghua University Beijing100084 China

The development of rapid and dependable proton transport channels is crucial for proton exchange membrane fuel cells (PEMFCs) operating in low humidity conditions. Herein, an NH-Zr framework rich in basic sites was constructed in situ in a perfluorosulfonic acid solution, and PFSA-NH-Zr hybrid proton exchange membranes were prepared. The introduced NH-Zr framework successfully induced proton conducting groups (-SO3H) reorganization along the NH-Zr framework, resulting in the formation of fast ion transport channels. Meanwhile, under low humidity, the acid-base pairs between N-H (N-H-Zr framework) and -SO3H (PFSA) promoted the protonation/deprotonation and the subsequent proton leap via the Grotthuss processes. Especially, the hybrid membrane PFSA-NH-Zr-1 with suitable NH-Zr content had a promising proton conductivity of 0.031 S/cm at 80°C, 40% RH, and 0.292 S/cm at 80°C, 100% RH, which were approximately 33% and 40% higher than the pristine PFSA membrane (0.023 S/cm and 0.209 S/cm), respectively. In addition, the maximum power density of the hybrid PEM was 0.726 W/cm2, which was nearly 20% higher than the pristine PFSA membrane (0.604 W/cm2) under 80°C, 40% RH. This work established a referable strategy for developing high-performance proton exchange membranes under low RH conditions. © 2022, The Authors. All rights reserved.

关键词： Proton conductivity

ZIF-8/LiFePO4 derived Fe-N-P Co-doped carbon nanotube encapsulated Fe2P nanoparticles for efficient oxygen reduction and Zn-air batteries

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Nano Research 2020年第3期13卷 818-823页

作者： Huihui Jin Huang Zhou Pengxia Ji Chengtian Zhang Jiahuan Luo Weihao Zeng Chenxi Hu Daping He Shichun Mu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China Department of Chemical and Environmental Engineering Anyang Institute of TechnologyAnyang 455000China

Iron-based oxygen reduction reaction(ORR)catalysts have been the focus of research,and iron sources play an important role for the preparation of efficient ORR ***,we successfully use LiFePO4 as ideal sources of Fe and P to construct the heteroatom doped Fe-based carbon *** obtained Fe-N-P co-doped coral-like carbon nanotube arrays encapsulated Fe2P catalyst(C-ZIF/LFP)shows very high half-wave potential of 0.88 V in alkaline electrolytes toward ORR,superior to Pt/C(0.85 V),and also presents a high half-wave potential of 0.74 V in acidic electrolytes,comparable to Pt/C(0.8 V).When further applied into a home-made Zn-air battery as cathode,a peak power density of 140 mW·cm^-2 is reached,exceeds commercial Pt/C(110 mW·cm^-2).Besides,it also presents exceptional durability and methanol resistance compared with Pt/***,the preparation method of such a high-performance catalyst is simple and easy to optimize,suitable for the large-scale ***’s more,it opens up a more sustainable development scenario to reduce the hazardous wastes such as LiFePO4 by directly using them for preparing high-performance ORR catalysts.

关键词： LiFePO4 waste utilization ZIF-8 heteroatoms-doped oxygen reduction reaction