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Unveiling oscillatory nature for sustainable fuel production

National Science Review 2024年第5期11卷 90-91页

作者： Ning Han Ye Wang Bao-Lian Su Department of Materials Engineering State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials National Engineering Laboratory for Green Chemical Productions of Alcohols Ethers and Esters College of Chemistry and Chemical Engineering Xiamen University Laboratory of Inorganic Materials Chemistry(CMI) University of Namur State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

A century ago, in 1923, Franz Fischer and Hans Tropsch introduced the groundbreaking Fischer–Tropsch (FT) synthesis, a heterogeneous catalytic process used to convert synthesis gas (syngas,CO+H2) into multi-carbon hydrocarbons [1]. Over the past 100 years, FT synthesis has emerged as a pivotal method for converting non-petroleum resources into exceptionally clean fuels or valuable chemicals via syngas [2–4].

关键词： production nature fuel oscillatory sustainable unveiling

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Enhanced Electrochemical Performances of Ni Doped Cr_(8)O_(21)Cathode materials for Lithium-ion Batteries

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Journal of Wuhan University of technology(materials Science) 2023年第6期38卷 1242-1247页

作者： TANG Guoli LIU Hanxing YU Zhiyong YANG Bo KONG Linghua School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070China

Cathode materials,nickel doped Cr_(8)O_(21),were synthesized by a solid-state *** effects of Ni doping on the electrochemical performances of Cr_(8)O_(21) were *** experimental results show that the discharge capacities of the samples depend on the nickel contents,which increases firstly and then decreases with increasing Ni *** Ni_(0.5)Cr_(7.5)O_(21)delivers a first capacity up to 392.6 m Ah·g^(-1)at *** addition,Ni doped sample also demonstrates enhanced cycling stability and rate capability compared with that of the bare Cr_(8)O_(21).At 1 C,an initial discharge capacity of 348.7 m Ah·g^(-1)was achieved for Ni_(0.5)Cr_(7.5)O_(21),much higher than 271.4 m Ah·g^(-1)of the un-doped sample,with an increase of more than 28%.Electrochemical impedance spectroscopy results confirm that Ni doping reduces the growth of interface resistance and charge transfer resistance,which is conducive to the electrochemical kinetic behaviors during charge-discharge.

关键词： Cr_(8)O_(21) cathode material doping electrochemical performances lithium-ion batteries

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Continuous Fe^(3+)releasing enabled complete reconstruction of Ni-based MOF for promoted water oxidation in industrial alkali

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Science China Chemistry 2024年第9期67卷 2949-2957页

作者： Zhaojian Wang Wei Zhang Wenzhong Huang Ruohan Yu Changliang Chen Liqiang Mai Liang Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park Wuhan University of TechnologySanya 572000China Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000China

Most oxygen evolution reaction(OER)electrocatalysts show poor stability under industrial alkaline conditions(20–30 wt.%KOH).Therefore,it is essential to develop stable,efficient,and low-cost OER catalysts for industrial water ***,we present a straightforward approach for the complete electrochemical reconstruction of Ni-BDC,a Ni-based metal-organic framework,for *** method involves the continuous release of Fe^(3+)from Fe foam counter electrode in a high-concentration(6.0 M,25 wt.%)KOH *** continuously Fe^(3+)releasing not only realizes in situ Fe^(3+)doping,but also introduces abundant defects in the obtained catalyst during cyclic voltammetry activation,thereby accelerating the electrochemical *** reconstructed OER catalyst(Fe-doped nickel hydroxide/oxyhydroxide nanosheets supported on Ni foam,Fe-NiO_(x)(OH)y/NF)manifests a low overpotential of 217 mV at 10 mA cm^(-2)and 263 m V at 100 m A cm^(-2)in 1.0 M ***,the Fe-NiO_(x)(OH)_(y)/NF also demonstrates high stability in 30 wt.%*** strategy of regulating the electrochemical reconstruction process sheds light on the construction of stable and efficient OER catalysts for industrial water electrolysis.

关键词： oxygen evolution reaction industrial alkaline conditions metal-organic framework complete reconstruction

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Designing carboxymethyl cellulose based hydrogel electrolyte membranes enhanced by inorganic nanoparticle toward stable zinc anode

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Green Energy & Environment 2025年第3期10卷 537-550页

作者： Xiangye Li Yuan Li Yu Jiang Dahui Wang Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Department of Polymeric Materials EngineeringSchool of Material Science and EngineeringLanzhou University of TechnologyLanzhou730050China

Aqueous zinc metal batteries have garnered substantial attention ascribing to affordability,intrinsic safety,and environmental benignity Nevertheless,zinc metal batteries yet are challenged with potential service life issues resulted from dendrites and side *** this paper,a strategy of nanoparticles doped hydrogel is proposed for constructing carboxymethyl cellulose/graphite oxide hybrid hydrogel electrolyte membranes with exceptional ionic conductivity,anti-swelling property,and simultaneously addressing the dendrites and parasitic *** pivotal functions of the carboxymethyl cellulose/graphite oxide hydrogel electrolyte in mitigating hydrogen evolution and fostering accelerated Zn deposition have been elucidated based on principles of thermodynamic and reaction *** carboxymethyl cellulose/graphite oxide hydrogel electrolyte endows exceptional cycling longevity (800 h at 1 mA cm^(-2)/1 mAh cm^(-2)) for Znjj Zn battery,as well as high Coulombic efficiency for Znjj Cu battery (averagely 99.14%within 439 cycles at 1 mA cm^(-2)/1 mAh cm^(-2)).The assembled Znjj NH_(4)V_(4)O_(10)battery delivers a high reversible specific capacity of 328.5 mAh g^(-1)at 0.1 A g^(-1).Moreover,the device of Znjj NH_(4)V_(4)O_(10)pouch battery remains operational under severe conditions like bending and *** work provides valuable reference in developing inorganic nanoparticle hybrid hydrogel electrolyte for realizing high-performance zinc metal batteries.

关键词： Carboxymethyl cellulose Graphite oxide Hydrogel electrolyte Anti-swelling

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Microstructure evolution,mechanical properties and fracture behavior of Al-xSi/AZ91D bimetallic composites prepared by a compound casting

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Journal of Magnesium and Alloys 2024年第5期12卷 1944-1964页

作者： Guangyu Li Wenming Jiang Feng Guan Junwen Zhu Yang Yu Zitian Fan State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

In this paper,the effect of the Si content on microstructure evolution,mechanical properties,and fracture behavior of the Al-xSi/AZ91D bimetallic composites prepared by compound casting was investigated *** obtained results showed that all the Al-xSi/AZ91D bimetallic composites had a metallurgical reaction layer(MRL),whose thickness increased with increasing Si content for the hypoeutectic Al-Si/AZ91D composites,while the hypereutectic Al-Si/AZ91D composites were *** MRL included eutectic layer(E layer),intermetallic compound layer(IMC layer)and transition region layer(T layer).In the IMC layer,the hypereutectic Al-Si/AZ91D composites contained some Si solid solution and flocculent Mg_(2)Si+Al-Mg IMCs phases not presented in the hypoeutectic Al-Si/AZ91D ***,increasing Si content,the thickness proportion of the T layer increased,forming an inconsistent preferred orientation of the *** shear strengths of the Al-xSi/AZ91D bimetallic composites enhanced with increasing Si content,and the Al-15Si/AZ91D composite obtained a maximum shear strength of 58.6 MPa,which was 73.4% higher than the Al-6Si/AZ91D *** fractures of the Al-xSi/AZ91D bimetallic composites transformed from the T layer into the E layer with the increase of the Si *** improvement of the shear strength of the Al-xSi/AZ91D bimetallic composites was attributed to the synergistic action of the Mg_(2)Si particle reinforcement,the reduction of oxidizing inclusions and the ratio of Al-Mg IMCs as well as the orientation change of the MRL.

关键词： Al/Mg bimetallic composites Si content Mg_(2)Si reinforcement Microstructure Mechanical properties Fracture behavior

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BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)-impregnated Ni-GDC by phase-inversion as an anode of solid oxide fuel cells with on-cell dry methane reforming

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Journal of advanced Ceramics 2024年第6期13卷 834-841页

作者： Yanya Liu Jun Luo Cheng Li Bo Liu Dong Yan Jian Li Lichao Jia School of Materials Science and Engineering State Key Laboratory of Materials Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074China

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)(BCFN)in a perovskite structure is impregnated consecutively by BCFN solution and BCFN suspension into a phase-inversion prepared NiO–Gd_(0.1)Ce_(0.9)O_(2−δ)(GDC)scaffold as an anode for solid oxide fuel cells(SOFCs)with on-cell dry reforming of methane(DRM).The whole pore surface of the scaffold is covered by small BCFN particles formed by BCFN solution impregnation;the large pores near the scaffold surface are filled by BCFN aerogels with a high specific surface area produced by BCFN suspension impregnation,which act as a catalytic layer for on-cell *** reduction,the anode consists of a Ni–GDC scaffold and BCFN particles with exsolved FeNi3 *** BCFN-impregnated Ni–GDC anode has higher electrical conductivity,electrochemical activity,and resistance to carbon deposition,with which the cell shows maximum power densities between 1.44 and 0.92 W·cm^(−2) when using H_(2) and between 1.09 and 0.50 W·cm^(−2) when using CO_(2)–CH_(4) at temperatures ranging from 750 to 600℃.A stable performance at 400 mA·cm^(−2) and 700℃is achieved using 45%CO_(2)–45%CH_(4)–10%N_(2) for more than 400 h without carbon deposition,benefiting from the impregnated BCFN aerogel with a high specific surface area and water adsorbability.

关键词： aerogel solid oxide fuel cells(SOFCs) phase-inversion dry reforming of methane(DRM) carbon resistance

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Development of prominent bonding strength in Al/Mg bimetal composites prepared by ultrasonic vibration-assisted compound casting:Effects of ultrasonic powers

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Journal of materials Science & technology 2024年第30期197卷 78-93页

作者： Qingqing Li Wenming Jiang Yuancai Xu Linghui Yu Yanqing Niu Zitian Fan State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

In this work,the A356/AZ91D bimetal composites were prepared by ultrasonic vibration-assisted lost foam compound casting,and the effects of ultrasonic powers on interfacial microstructures and mechan-ical properties of the Al/Mg interfaces were *** revealed that the Al/Mg bimetal com-posites without ultrasonic vibration treatment(UVT)were heterogeneous,and the Al/Mg interface was composed of Al-Mg intermetallic compounds(IMCs,i.e.,Al_(3)Mg_(2)and Al_(12)Mg_(17))area and Al-Mg eutec-tic structures(δ-Mg+Al_(12)Mg_(17))*** Mg_(2)Si particles were gathered at the IMCs area and an oxide film that mainly composed of Al_(2)O_(3)was existed between the IMCs area and eutectic structures *** UVT,the oxide film was eliminated and the gathered Mg_(2)Si particles were refined and dispersed by the acoustic cavitation effect,and part of the Al_(3)Mg_(2)and Al-Mg eutectic structures were transformed into the Al_(12)Mg_(17)due to the promoted solute interdiffusion,which improved the homogeneity of the Al/Mg ***,the grains of the Al/Mg interface with UVT under ultrasonic power of 75 W were significantly *** thickness of Al/Mg interface was increased with the increase of the ul-trasonic *** to the excessive heat induced by UVT under the further increased ultrasonic power,the cooling rates and the degree of supercooling were reduced,resulting in the coarsening of interfacial *** microhardness of the Al/Mg interfaces was increased and got more uniform by *** shear strengths of the Al/Mg bimetal composites with UVT were enhanced to 61.4 MPa from 32.4 MPa,with an increase of 89.5%compared with that of the Al/Mg bimetal without *** could be ascribed to the removal of the oxide film,the refinement of the interfacial grains and the dispersed and refined Mg_(2)Si particles achieved by UVT,which hindered the crack propagation during deformation.

关键词： Ultrasonic vibration treatment Al/Mg bimetal composites Compound casting Interfacial microstructure Mechanical properties

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Effects of Mg_(17)Al_(12) phase on microstructure evolution and ductility in the AZ91 magnesium alloy during the continuous rheo-squeeze casting-extrusion process

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Journal of materials Science & technology 2024年第24期191卷 63-79页

作者： Dijia Zhao Shulin Lü Wenbo Guo Shilong Li Jianyu Li Guanghui Guo Wei Guo Shusen Wu State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

In this study,a high-ductility AZ91 magnesium alloy was fabricated by the novel continuous rheo-squeeze casting-extrusion(CRSCE)*** semi-solid slurry was prepared by ultrasonic vibration(UV)treatment,then solidified under pressure,and finally hot *** treatment can reduce the Al element content in primary grains and increase it in secondary *** refined Mg_(17)Al_(12) phase was scattered along secondary grain boundaries and then stretched into narrow,fibrous bands during the hot *** fibrous bands with proper separation distances can accelerate the dynamic recrystallization(DRX)process and suppress the growth of DRXed *** were initiated inside the brittle Mg_(17)Al_(12) phase and tended to propagate along the continuously distributed Mg_(17)Al_(12) phase during the tensile ***,the tiny Mg_(17)Al_(12) phase in the billet and narrow,fibrous bands in as-extruded rods can prevent cracks from spreading and enhance ***,excellent comprehensive mechanical properties were obtained,with an ultimate tensile strength of 326.3 MPa and an elongation of 16.46%.The CRSCE method offers a novel way to fabricate high-ductility and high-alloyed magnesium alloys without *** regulation mechanisms of CRSCE,microstructural hereditary laws,and the effect of the Mg_(17)Al_(12) phase on mechanical properties were further discussed.

关键词： AZ91 magnesium alloy Mg_(17)Al_(12)phase Rheo-squeeze casting Ultrasonic vibration Continuous casting-extrusion Ductility

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The rapid densification behavior of powder metallurgy Ti alloys by induction heating sintering

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Journal of materials Science & technology 2024年第14期181卷 152-164页

作者： Kejia Pan Xiaotao Liu Bao Wang Shuai Gao Shixing Wu Ning Li State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Micropores are decisive to mechanical properties and thermal deformation capabilities of powder met-allurgy(P/M)Ti alloys sintered *** a result,achieving express densification is of prime im-portance and has attracted increasing attention *** heating owns the merits of high effi-ciency,short process,and low cost,and thus has huge potential to be used as a sintering approach for the fabrication of P/M Ti ***,the facilitated densification behavior associated with induction heating sintering remains unclear so *** address it,powder metallurgy Ti6Al4V is manufactured via induction heating sintering with which the underlying sintering mechanism is investigated *** is found that induction heating could generate a fully densified compact in a remarkably shortened time,demonstrating its superior sintering efficiency as compared with conventional resistance furnace *** finite element analysis reveals that the maximum current density during induction heating can reach 10^(6)A m^(–2)though the magnetic field strength is solely 0.02 T,leading to a slight tempera-ture difference of approximately 30℃between the interior and exterior of the ***,the rapid heating essentially starts at sharp corners of particles due to the potent current concentration ef-fect,which facilitates the cracking of the particle surface oxide film and thus enhances the direct contact between ***,the electromigration effect caused by induction current promotes the diffusion capability of elements,giving rise to expedited densification,alloying,and chemical *** work provides not only critical insight into the sintering mechanism of induction heating sintering but also significant guidance for low-cost powder metallurgy materials preparation.

关键词： Titanium alloy Powder metallurgy Induction heating sintering Radiation heating sintering Current field Simulation

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Fullerenes and derivatives as electrocatalysts: Promises and challenges

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Green Energy & Environment 2024年第1期9卷 7-27页

作者： Kun Guo Ning Li Lipiao Bao Xing Lu State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

Carbon-based metal-free nanomaterials are promising alternatives to precious metals as electrocatalysts of key energy storage and conversion *** paramount signiﬁcance are the establishment of design principles by understanding the catalytic mechanisms and identifying the active *** from sp2-conjugated graphene and carbon nanotube,fullerene possesses unique characteristics that are growingly being discovered and exploited by the electrocatalysis *** instance,the well-deﬁned atomic and molecular structures,the good electron afﬁnity to tune the electronic structures of other substances,the intermolecular self-assembly into superlattices,and the on-demand chemical modiﬁcation have endowed fullerene with incomparable advantages as electrocatalysts that are otherwise not applicable to other carbon *** increasing studies are being reported on this intriguing topic,it is necessary to provide a state-of-the-art overview of the recent *** review takes such an initiative by summarizing the promises and challenges in the electrocatalytic applications of fullerene and its *** content is structured according to the composition and structure of fullerene,including intact fullerene(e.g.,fullerene composite and superlattices)and fullerene derivatives(e.g.,doped,endohedral,and disintegrated fullerene).The synthesis,characterization,catalytic mechanisms,and deﬁciencies of these fullerene-based materials are explicitly *** conclude it by sharing our perspectives on the key aspects that future efforts shall consider.

关键词： Fullerene Fullerene derivative Metal-free catalyst Structural defect Electrocatalyst

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