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Crystallographic evidences for twin-assisted eutectic growth in undercooled Ni-18.7 at.%Sn eutectic melts

Journal of materials Science & technology 2023年第4期135卷 65-79页

作者： Fan Zhang Jianbao Zhang Xinlei Lü Ke Hua Yuhong Zhao Haifeng Wang State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsNorthwestern Polytechnical UniversityXi’an 710072China School of Materials Science and Engineering North University of ChinaTaiyuan 030051China

Rapid solidification in undercooled Ni-18.7 at.%Sn eutectic melts was observed in-situ by a high-speed high-resolution camera and the microstructures were characterized in detail by electron backscattering *** the first time,the exact crystallographic orientation relations(ORs)between HCP-Ni_(3)Sn(α-Ni)subsets were *** HCP-Ni_(3)Sn,the{1121}<1126>and/or{1122}<1123>twin ORs(i.e.,HCP-Ni_(3)Sn twins)hold independently on undercooling,whereas forα-Ni,the{111}<112>twin OR is the case at low undercooling and would hold initially at intermediate and high *** roles of twinning and allotropy transformation(i.e.,FCC-Ni_(3)Sn→HCP-Ni_(3)Sn)were integrated to reveal the formation mechanism of HCP-Ni_(3)Sn twins,and a reversed OR transition analysis was carried out for rep-resentative samples from low to high ***,novel twin-assisted eutectic growth was found to occur all *** this basis,we showed that the single nucleation mode of Herlach is followed,and speculated that primary and secondary coupled eutectic dendrite growth and un-coupled growth ofα-Ni and FCC-Ni_(3)Sn might all be the origins of anomalous *** work would shed some lights on the long-time controversies about the nucleation mode and the formation mechanism of anomalous eutectics in undercooled eutectic alloys.

关键词： Twin-assisted eutectic growth Allotropy transformation Nucleation mode Anomalous eutectics Undercooling

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Atomic-resolution Interfacial Microstructure and Thermo-electro-magnetic Energy Conversion Performance of Gd/Bi_(0.5)Sb_(1.5)Te_(3)Composites

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Energy & Environmental materials 2024年第4期7卷 355-363页

作者： Chengshan Liu Wenjie Xu Ping Wei Shaoqiu Ke Wenjun Cui Longzhou Li Dong Liang Xianfeng Ye Tiantian Chen Xiaolei Nie Wanting Zhu Wenyu Zhao Qingjie Zhang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu 528000China

Thermo-electro-magnetic materials with simultaneously large magnetocaloric(MC)and thermoelectric(TE)effects are the core part for designing TE/MC all-solid-state cooling *** MC phase with TE material is an effective ***,the elemental diffusion and chemical reaction occurring at the two-phase interfaces could significantly impair the cooling ***,Gd/Bi_(0.5)Sb_(1.5)Te_(3)(Gd/BST)composites were prepared by a low-temperature high-pressure spark plasma sintering method with an aim to control the extent of interfacial *** reaction of Gd with the diffusive Te and the formation of GdTe nanocrystals were identified at the Gd/BST interfaces by the atomic-resolution *** formed Bi’_(Te)antisite defects and enhanced{000 l}preferential orientation in BST are responsible for the increased carrier concentration and mobility,which leads to optimized electrical *** heterogeneous interface phases,along with antisite defects,favor the phonon scattering enhancement and lattice thermal conductivity *** optimized composite sintered at 693 K exhibited a maximum ZT of 1.27 at 300 ***,the well-controlled interfacial reaction has a slight impact on the magnetic properties of Gd and a high magnetic entropy change is retained in the *** work provides a universal approach to fabricating thermo-electro-magnetic materials with excellent MC and TE properties.

关键词： interfacial reaction magnetocaloric performance thermoelectric performance thermo-electro-magnetic materials

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Tuning Structural and Electronic Configuration of FeN_(4) via External S for Enhanced Oxygen Reduction Reaction

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Energy & Environmental materials 2024年第2期7卷 93-101页

作者： Shidong Li Lixue Xia Jiantao Li Zhuo Chen Wei Zhang Jiexin Zhu Ruohan Yu Fang Liu Sungsik Lee Yan Zhao Liang Zhou Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China Chemical Sciences and Engineering Division Argonne National Laboratory9700 South Cass AvenueLemontIL 60439USA NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070China X-ray Science Division Advanced Photon SourcesArgonne National Laboratory9700 South CassAvenueLemontIL 60439USA State Key Laboratory of Silicate Materials for Architectures International School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China The Institute of Technological Sciences Wuhan UniversityWuhan 430072China Hubei Longzhong Laboratory Xiangyang 441000China

The Fe-N-C material represents an attractive oxygen reduction reaction electrocatalyst,and the FeN_(4)moiety has been identified as a very competitive catalytic active *** tuning of the coordination structure of FeN_(4)has an essential impact on the catalytic ***,we construct a sulfur-modified Fe-N-C catalyst with controllable local coordination environment,where the Fe is coordinated with four in-plane N and an axial external *** external S atom affects not only the electron distribution but also the spin state of Fe in the FeN_(4)active *** appearance of higher valence states and spin states for Fe demonstrates the increase in unpaired *** the above characteristics,the adsorption and desorption of the reactants at FeN_(4)active sites are optimized,thus promoting the oxygen reduction reaction *** work explores the key point in electronic configuration and coordination environment tuning of FeN_(4)through S doping and provides new insight into the construction of M-N-C-based oxygen reduction reaction catalysts.

关键词： coordination structure electronic configuration FeN_(4)moiety oxygen reduction reaction sulfur doping

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Strength-toughness improvement of 13Cr4NiMo martensitic stainless steel with thermal cyclic heat treatment

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Journal of Iron and Steel Research International 2023年第8期30卷 1499-1510页

作者： Jie Xiong Yao-lin Tong Jie-long Peng Sheng-hua Zhang State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materialsand School of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004GuangxiChina Key Laboratory of High Performance Structural Materials and Thermo-Surface Processing Education Department of Guangxi Zhuang Autonomous RegionGuangxi UniversityNanning 530004GuangxiChina

To improve the strength-toughness of 13Cr4NiMo martensitic stainless steel(13-4MSS),a thermal cyclic heat treatment(TCHT)combined with the advantage of tempering was *** microstructures were characterized by scanning electron microscopy,X-ray diffraction and electron backscattered diffraction,and the mechanical behaviors in terms of tensile properties and impact toughness were analyzed in correlation with microstructural *** was found that grains and the martensitic matrix were refined by TCHT through the cyclic quenching transformation and austenite recrystallization,which was conducive to more nucleation quantity of reversed austenite during ***-sphericalcap nucleation model was used to explain the effect of refined grains of TCHT on the nucleation of reversed *** refinement by TCHT improved the brittle fracture stress to reduce the ductile-brittle transition temperature and thus improved the cryogenic impact toughness of *** austenite distributed at the martensitic lath boundary enhances the crack arrest performance and increases the britle fracture *** is concluded that reasonable TCHT plus tempering process significantly improves the strength-toughness of 13-4MSS,reflecting the comprehensive effect of grain refinement and reversed austenite.

关键词： Strength-Toughness 13Cr4NiMo martensitic stainless steel Thermal cyclic heat treatment Grain refinement Reversed austenite

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Light-Programmable Assemblies of Isotropic Micromotors

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Research 2022年第4期2022卷 481-492页

作者： Shengping Che Jianhua Zhang Fangzhi Mou Xia Guo Joshua E.Kauffman Ayusman Sen Jianguo Guan State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and EngineeringWuhan University of Technology122Luoshi RoadWuhan 430070China Department of Chemistry The Pennsylvania State UniversityUniversity ParkPA16802USA

“Life-like”nonequilibrium assemblies are of increasing significance,but suffering from limited steerability as they are generally based on micro/nanomotors with inherent asymmetry in chemical composition or geometry,of which the vigorous random Brownian rotations disturb the local ***,we demonstrate that isotropic photocatalytic micromotors,due to the persistent phoretic flow from the lluminated to shadowed side rrespective of their Brownian rotations,experience lightprogrammable local interactions(reversibly from atraction to repulsion and/or alignment)depending on the direction of the incident ***,they can be organized into a variety of tunable nonequilibrium assemblies,such as apolar solids(i.e.,immobile colloidal crystal),polar liquids(ie.,phototactic colloidal stream),and polar solids(i.e.,phototactic colloidal crystal),which can further be“cut”into a predesigned pattern by utilizing the switching motor-motor interactions at superimposedlight *** work facilitates the development of active matters and motile functional microdevices.

关键词： Brownian rotation nonequilibrium

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Effect of long-term aging treatment on the tensile strength and ductility of GH 605 superalloy

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Progress in Natural Science:materials International 2022年第3期32卷 375-384页

作者： Yixuan He Xudong Liu Chenxu Xing Zhangchi Bian Qing Zhou Jun Wang Haifeng Wang Jinshan Li State Key Laboratory of Solidification Processing Northwestern Polytechnical University Center of Advanced Lubrication and Seal Materials Northwestern Polytechnical University National Key Laboratory for Precision Hot Processing of Metals Harbin Institute of Technology Harbin

Aging treatment is an effective way to optimize the mechanical properties of Co-based superalloys. In this study,commercial GH 605 superalloy was subjected to aging treatment at 650℃ in a wide time range up to 1000 h. The effects of aging time on the tensile characteristics, microstructure evolution and mechanical properties were systematically investigated at room temperature（RT） and 900℃. The results showed that the volume fractions of M6C and M23C6carbide increased with the aging time. After long-term aging treatment, the yield strength（YS） at RT was enhanced from 490.3 MPa to 805.9 MPa, while the alloy still had high tensile ductility（above 20%）.Microscopic observations by transmission electron microscopy（TEM） indicated that the strengthening mechanism was related to carbide precipitation inside the grains and the change in the dislocation slipping mode. Moreover,long-term aging treatment can increase the elongation from 24.1% to 47.3% at 900℃ accompanied by a slight increase of YS from 299.3 MPa to 313.9 MPa. Based on detailed microstructure analysis the strengthening mechanism can be attributed to the refined grains as well as carbide precipitation inside the grains and around the grain boundaries.

关键词： GH 605 superalloy Long-term aging treatment Carbide Strengthening mechanism

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异价离子取代构建高离子电导率的插层结构

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Science Bulletin 2023年第11期68卷 1134-1142,M0004页

作者：孙宗栋梁嘉宁刘开朗冯昕吴宇赵英鹤梁麒吴劲松李会巧翟天佑 State Key Laboratory of Materials Processing and Die&Mould Technology and School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Nanostructure Research CenterWuhan University of TechnologyWuhan 430070China

在纳米尺度通道内的离子传输是纳米流体学领域研究的重点.二维(2D)材料的本征层状结构为流体离子提供了稳健的纳米传输通道.为实现流体离子在2D材料薄膜内的高效传输,本文开发了一种新颖的异价离子取代插层策略,通过化学气相输运法直接... 详细信息

在纳米尺度通道内的离子传输是纳米流体学领域研究的重点.二维(2D)材料的本征层状结构为流体离子提供了稳健的纳米传输通道.为实现流体离子在2D材料薄膜内的高效传输,本文开发了一种新颖的异价离子取代插层策略,通过化学气相输运法直接合成多种具有高离子电导结构的单晶.将块体单晶置入水中通过手动摇晃即可获得二维纳米片分散液,组装后的薄膜展现出高的锂离子电导率,优于目前多数关于2D材料薄膜水相锂离子电导率的报道.这种在合成过程中直接构筑离子传输结构的策略与目前已有的先剥离2D材料后对纳米片修饰改性的方法完全不同.因此,这种普适性的异价离子取代插层策略将会为更多高离子电导率的2D材料薄膜的开发提供借鉴与参考.

关键词：离子电导率离子取代纳米片离子传输纳米流体材料薄膜传输通道插层结构

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Corrigendum to“Design and fabrication of high-performance self-setting trimagnesium phosphate”[***.28(2023)348-357]

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Bioactive materials 2024年第7期37卷 313-314页

作者： Jiawei Liu Wen Hou Wenying Wei Jian Peng Xiaopei Wu Chenxi Lian Yanan Zhao Rong Tu Takashi Goto Honglian Dai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei ProvinceWuhan University of TechnologyWuhan430070China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou521000China New Industry Creation Hatchery Center Tohoku UniversitySendai980-8579Japan

The authors regret that the supplementary Fig.S12 is *** correction does not affect any of the results and conclusions in the ***.S11 and S12 are studies on hydration kinetics and hydration products of M/P=2 and M/P=4 *** the previous uploaded version,the caption and figures of the Fig.S12 are the same as *** have corrected the error and the correct figures are as *** authors are sorry for not checking the supplementary documents carefully before publication.

关键词： hydration correction kinetics

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Data-driven design of novel lightweight refractory high-entropy alloyswith superb hardness and corrosion resistance

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npj Computational materials 2024年第1期10卷 536-548页

作者： Tianchuang Gao Jianbao Gao Shenglan Yang Lijun Zhang State Key Laboratory of Powder Metallurgy Central South UniversityChangshaHunanChina State Key Laboratory of Materials Processing and Die&Mould Technology Huazhong University of Science and TechnologyWuhanHubeiChina National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqingChina

Lightweight refractory high-entropy alloys(LW-RHEAs)hold significant potential in the fields of aviation,aerospace,and nuclear energy due to their low density,high strength,high hardness,and corrosion ***,the enormous composition space has severely hindered the development of novel LW-RHEAs with excellent comprehensive *** this paper,an machine learning(ML)-based alloy design strategy combined with a multi-objective optimization method was proposed and applied for a rational design of Al-Nb-Ti-V-Zr-Cr-Mo-Hf *** quantitative relation of“composition-structure-property”was first established by ML ***,feature analysis reveals that Cr content greater than 12 at.

关键词： corrosion alloys resistance

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Enabling simultaneous reprocessability and fire protection via incorporation of phosphine oxide monomer in epoxy vitrimer

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Journal of materials Science & technology 2024年第29期196卷 224-236页

作者： Zhenyu Huang Wenyu Wu Klingler Daniele Roncucci Carolina Polisi Valentin Rougier Sandro Lehner Milijana Jovic Daniel Rentsch Sithiprumnea Dul Karin Brändli Hedlund Véronique Michaud Zhengzhou Wang Sabyasachi Gaan Department of Polymeric Materials School of Materials Science and EngineeringTongji UniversityShanghai201804China Laboratory for Advanced Fibers Empa Swiss Federal Laboratories for Materials Science and TechnologyLerchenfeldstrasse 5St.Gallen9014Switzerland Laboratory for Processing of Advanced Composites(LPAC) Ecole Polytechnique Fédérale de Lausanne(EPFL)1015 LausanneSwitzerland Laboratory for Functional Polymers Empa Swiss Federal Laboratories for Materials Science and TechnologyÜberlandstrasse 1298600 DübendorfSwitzerland Institute for Materials technology and plastics processing OST-Eastern Switzerland University of Applied Sciences8640 RapperswilSwitzerland Key Laboratory of Advanced Civil Engineering Materials Tongji UniversityShanghai201804China

The conception of epoxy thermosets with both reprocessability and flame retardancy delineates a new horizon in polymer science,offering a material solution that is not only superior in fire safety but is also environment ***,a flame-retardant epoxy vitrimer(EV)was prepared using partially bio-based IADPPO(diphenylphosphine oxide itaconic anhydride)and citric acid as curing reagents via a solvent-free *** incorporation created covalent adaptable networks(CANs)in the matrix which promote reprocessability and *** EV exhibits excellent thermal stability with high initial decomposition temperature(T_(- 5wt%)∼308℃)and high glass transition temperature(T_(g)∼107℃),similar to the blank EV(115℃).The flame retardancy,mechanical properties,transesterification-based reprocessability,and flame-retardant mechanism were *** EV containing 3 wt%phosphorus(EV IADPPO 3P)achieved UL-94 V0 classification with a limiting oxygen index(LOI)of 27%,while the virgin sample Blank EV(without phosphorus)burned ***,increased flexural strength of 79%was observed for EV IADPPO 3P compared to Blank ***,the flame-retardant EV showed high malleability and reparability that could be thermomechanically reprocessed without sacrificing the thermal,mechanical,and flame-retardant ***,the newly developed epoxy vitrimer is not only fire-safe but fulfills the sustainability goals of today’s society.

关键词： Epoxy vitrimer Covalent adaptable networks Flame retardancy Reparable and reprocessable Bio-based thermoset

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