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Nucleation growth quenching for superior cluster catalysts

Nano Research 2022年第9期15卷 7933-7939页

作者： Ruyue Wang Feng Cheng Yonggang Wang Dongyu Fan Bohan Deng Yuanzheng Long Haolin Tang Kai Huang Zhaowei Qu Ming Lei Binghui Ge Hui Wu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Information Photonics and Optical Communications School of ScienceBeijing University of Posts and TelecommunicationsBeijing 100876China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Beijing Key Laboratory of Space-ground Interconnection and Convergence Beijing University of Posts and Telecommunications(BUPT)Beijing 100876China Information Materials and Intelligent Sensing Laboratory of Anhui Province Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationInstitutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601China

Cluster catalysts are rapidly growing into an important sub-field in heterogeneous catalysis,owing to their distinct geometric structure,neighboring metal sites,and unique electronic *** the thermodynamics and kinetics of the formation of nanoparticles have been largely investigated,the precise synthesis of clusters in wet chemical methods still faces great *** the study,a quenching strategy of asymmetric temperature in solution for the rapid generation of vacancy-defect rich clusters is *** quenching process can be used to synthesize multitudinous metal compound clusters,including metal oxides,fluorides,oxygen-sulfur compounds,and *** oxygen evolution reaction(OER),IrO_(2)clusters with abundant oxygen vacancies were obtained and uniformly dispersed in the *** to commercial IrO_(2),the prepared IrO_(2)cluster can be directly loaded on carbon paper and used as binder-free electrodes,which exhibit higher OER activity and long-term operational stability in alkaline *** quenching strategy provides a simple and efficient method for the synthesis of clusters,which has tremendous potential for industrial-scale preparation and application,especially can be further applied to flow electrochemical generators.

关键词： rapid-chilling cluster structure transition metal compounds binder-free electrode oxygen evolution reaction

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Graphene/SiC-coated textiles with excellent electromagnetic interference shielding,Joule heating,high-temperature resistance,and pressure-sensing performances

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Journal of advanced Ceramics 2023年第4期12卷 778-791页

作者： Chongjie Wang Qingfang Xu Jinrong Hu Pengjan Lu Han Wu Bingian Guo Rong Tu Kai Liu Meijun Yang Song Zhang Bao-Wen Li Chuanbin Wang Lianmeng Zhang School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Wuhan Tuocai Technology Co. Ltd.Ezhou 436032China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China Zhejiang MTCN Technology Co. Ltd.Huzhou 311103China Wuhan University of Technology Advanced Engineering Technology Research Institute of Zhongshan City Zhongshan 528400China School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China

Multifunctional,wearable,and durable textiles integrated with smart electronics have attracted tremendous ***,it remains a great challenge to balance new functionalities with high-temperature ***,textile-based pressure sensors with excellent electromagnetic interference(EMI)shielding,Joule heating,and high-temperature resistance were fabricated by constructing graphene/SiC(G/SiC)heterostructures on carbon cloth via laser chemical vapor deposition(LCVD).The resultant textiles exhibited excellent EMI efficiency of 74.2 dB with a thickness of 0.45 mm,Joule heating performance within a low working voltage(V)range of 1-3 V,and fast response time within 20 *** properties arose from multiple reflections,interfacial polarization,and high conductivity due to the numerous amounts of nanoscale G/SiC *** importantly,G/SiC/carbon fibers(CFs)demonstrated well high-temperature resistance with a heat resistance index(THri)of 380.2 C owing to the protection of a coating layer on the CFs upon ***,the G/SiC/CFs presented good pressure-sensing performance with high sensitivity(S)of 52.93 kPal,fast response time of 85 ms,and a wide pressure range of up to 186 *** features imply the potential of the G/SiC/CFs as efficient EMI shielding,electrical heater,and piezoresistive sensor textiles.

关键词： graphene/SiC(G/SiC) electromagnetic interference(EMI)shielding Joule heating pressure-sensing high-temperature resistance

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Single‑Atom Catalysts:Advances and Challenges in Metal‑Support Interactions for Enhanced Electrocatalysis

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Electrochemical Energy Reviews 2022年第1期5卷 145-186页

作者： Yang Mu Tingting Wang Jian Zhang Changgong Meng Yifu Zhang Zongkui Kou School of Chemical Engineering Dalian University of TechnologyDalian 116024LiaoningChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074HubeiChina

Single-atom catalysts(SACs),which contain a single metal atom supported on a well-confined substrate,are among the most promising heterogeneous catalysts owing to their unique advantages,such as high intrinsic activity and selectivity,tunable bonds and coordination,abundant metal-containing active sites,and atomic *** metal-support interactions(MSIs)in SACs exert a substantial influence on the catalytic properties,gaining a profound understanding and recognition of catalytic reactions depends greatly on investigating MSIs both experimentally and ***,the engineer-ing and modulation of MSIs are regarded as one of the most efficient methods to rationally design SACs with disruptively enhanced catalytic *** this review,we track the recent advances in SACs from an MSI *** then discuss the existing MSIs in SACs and elucidate the significant role of strong MSIs in catalytic properties and *** chal-lenges hindering the rational design of supported SACs with strong MSIs,which are currently still far from being completely understood and overcome,are *** addition,the correlation between strong MSIs and electrocatalytic activities in SACs,including an outlook to increase our understanding of MSIs,is ***,the present review provides some perspectives and an in-depth understanding of strong MSIs to advance high-performing SACs.

关键词： Metal-support interaction Single-atom catalysts Electrocatalysis ORR and OER HER and HOR

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Stress corrosion behavior and mechanism of Ti6321 alloy with different microstructures in simulated deep-sea environment

SSRN

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SSRN 2024年

作者： Zhang, Huixia Zhang, Fan Hao, Fuyao Sui, Yongqiang Li, Wenju Li, Xiangbo Hou, Jian Guo, Weimin State Key Laboratory for Marine Corrosion and Protection Qingdao Luoyang Ship Material Research Institute Qingdao China State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

The stress corrosion cracking (SCC) behaviors of Ti-6Al-3Nb-2Zr-1Mo (Ti6321, in wt.%) alloy samples with equiaxed microstructure (EM), bimodal microstructure (BM) and Widmanstätten microstructure (WM) in simulated 3000m deep sea environment were investigated using electrochemical tests, electron backscattered diffraction (EBSD), and so on. The results revealed that WM exhibits the best SCC resistance, which is attributed to its best self-healing ability, and is beneficial for the re-passivation of fresh metal at the crack tip. Besides, there is no obvious micro-texture region in WM, and α phase colonies hinder the dislocation movement, resulting in the lowest crack growth rate. © 2024, The Authors. All rights reserved.

关键词： Titanium alloys

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Cobalt-Free BaFe_(0.6)Zr_(0.1)Y_(0.3)O_(3−δ)Oxygen Electrode for Reversible Protonic Ceramic Electrochemical Cells

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Transactions of Tianjin University 2023年第6期29卷 444-452页

作者： Chenghao Yang Jin Li Ao Hu Jian Pu Bo Chi State Key Laboratory of Materials Processing and Die and Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials MOE Key Laboratory for the Green Preparation and Application of Functional MaterialsFaculty of Materials Science and EngineeringHubei UniversityWuhan 430062China MOE Key Laboratory of Material Chemistry for Energy Conversion and Storage Huazhong University of Science and TechnologyWuhan 430074China

Reversible protonic ceramic electrochemical cells(R-PCECs)are ideal,high-effi ciency devices that are environmentally friendly and have a modular *** paper studies BaFe_(0.6)Zr_(0.1)Y_(0.3)O_(3−δ)(BFZY3)as a cobalt-free perovskite oxygen electrode for high-performance R-PCECs where Y ions doping can increase the concentration of oxygen vacancies with a remarkable increase in catalytic *** cell with confi guration of Ni-BZCYYb/BZCYYb/BFZY3 demonstrated promising performance in dual modes of fuel cells(FCs)and electrolysis cells(ECs)at 650℃with low polarization resistance of 0.13Ωcm^(2),peak power density of 546.59 mW/cm^(2)in FC mode,and current density of−1.03 A/cm^(2)at 1.3 V in EC *** alternative operation between FC and EC modes for up to eight cycles with a total of 80 h suggests that the cell with BFZY3 is exceptionally stable and reversible over the long *** results indicated that BFZY3 has considerable potential as an air electrode material for R-PCECs,permitting effi cient oxygen reduction and water splitting.

关键词： Protonic ceramic cells Oxygen electrode Perovskite oxides Cobalt-free Oxygen vacancies

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1800℃下具有优异高强度且含氧化物杂质的高熵二硼化物陶瓷

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Science China materials 2023年第5期66卷 2061-2070页

作者：柳洁杨青青邹冀王为民王新刚傅正义 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Xiangyang 441000China Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 201899China

以硼热/碳热还原合成高熵二硼化物粉体为原料,在2000℃/单轴加压50 MPa条件下,经10分钟放电等离子烧结,成功制备了含有~2 vol%的氧化物和~1 vol%气孔的高熵(Ti_(0.2)Zr_(0.2)Nb_(0.2)Hf_(0.2)Ta_(0.2))B_(2)陶瓷(HEBs).经研究确认,其中... 详细信息

以硼热/碳热还原合成高熵二硼化物粉体为原料,在2000℃/单轴加压50 MPa条件下,经10分钟放电等离子烧结,成功制备了含有~2 vol%的氧化物和~1 vol%气孔的高熵(Ti_(0.2)Zr_(0.2)Nb_(0.2)Hf_(0.2)Ta_(0.2))B_(2)陶瓷(HEBs).经研究确认,其中残留氧化物是固溶少量硼和碳的m-(Hf,Zr)O_(2).室温下HEBs的弹性模量、维氏硬度和断裂韧性分别为508.5 GPa、17.7±0.4 GPa和4.2±0.2 MPa m^(1/2).烧结得到的HEBs具有优良的抗弯强度,特别是其高温强度.HEBs在室温、1600和1800℃下的四点抗折强度分别为400.4±47.0 MPa、695.9±55.9 MPa和751.6±23.2 MPa.对1800℃下断裂的HEBs样品进行了失效分析,在其拉伸和断裂面附近区域,仅在裂纹尖端和孔隙边缘发现了数量有限的位错线的存在,没有观察到位错运动的痕迹.本研究首次报道了高熵二硼化物陶瓷的高温强度,发现其强度直至1800℃并无衰减,并对其高温下的强韧化机制进行了有益的探讨.

关键词： borides high-entropy ceramics high-temperature strength mechanical properties microstructure

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Idea of macro-scale and micro-scale prestressed ceramics

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Interdisciplinary materials 2024年第6期3卷 897-906页

作者： Junfeng Gu Shuai Fu Hang Ping Wei Ji Ji Zou Hao Wang Weimin Wang Fan Zhang Hanxing Liu Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina School of Materials Science and Engineering Wuhan University of TechnologyWuhanChina

The brittleness of ceramics restricts their engineering *** is promising to solve the problem,yet still lacks enough attention and ex-tensive *** work proposes the idea of macro-scale and micro-scale prestressed ceramics:to form compressive prestress in macro-or micro-scale range in the ceramics by designed additional force,which offsets the fracture stress at the crack tips,then enhances the strength of *** macro-scale prestressed ceramic has a designed long-range ordering stress distribution in a large scale,similar to the reinforced concrete and tempered *** micro-scale ceramic has a designed short-range ordered stress dis-tribution,similar to that in the natural *** constructing the macro-scale and micro-scale prestressed ceramics are *** research interests and challenges are prospected for developing the mechan-ical properties of ceramics.

关键词： macro-scale micro-scale prestressed ceramics strength

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Engineering surface framework TiO6 single sites for unprecedented deep oxidative desulfurization

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National Science Review 2024年第5期11卷 303-314页

作者： Shen Yu Zhan Liu Jia-Min Lyu Chun-Mu Guo Xiao-Yu Yang Peng Jiang Yi-Long Wang Zhi-Yi Hu Ming-Hui Sun Yu Li Li-Hua Chen Bao-Lian Su Laboratory of Living Materials at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Nanostructure Research Center Wuhan University of Technology School of Chemistry Chemical Engineering and Life ScienceWuhan University of Technology Laboratory of Inorganic Materials Chemistry University of Namur

Catalytic oxidative desulfurization（ODS） using titanium silicate catalysts has emerged as an efficient technique for the complete removal of organosulfur compounds from automotive fuels. However, the precise control of highly accessible and stable-framework Ti active sites remains highly challenging. Here we reveal for the first time by using density functional theory calculations that framework hexa-coordinated Ti（TiO6） species of mesoporous titanium silicates are the most active sites for ODS and lead to a lower-energy pathway of ODS. A novel method to achieve highly accessible and homogeneously distributed framework TiO6active single sites at the mesoporous surface has been developed. Such surface framework TiO6species exhibit an exceptional ODS performance. A removal of 920 ppm of benzothiophene is achieved at60°C in 60 min, which is 1.67 times that of the best catalyst reported so far. For bulky molecules such as4,6-dimethyldibenzothiophene（DMDBT）, it takes only 3 min to remove 500 ppm of DMDBT at 60°C with our catalyst, which is five times faster than that with the current best catalyst. Such a catalyst can be easily upscaled and could be used for concrete industrial application in the ODS of bulky organosulfur compounds with minimized energy consumption and high reaction efficiency.

关键词： electrostatic interactions framework hexa-coordinated Ti site oxidative desulfurization mesoporous materials self-assembly

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Cobalt doping boosted electrocatalytic activity of CaMn3O6 for hydrogen evolution reaction

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Nano Research 2022年第4期15卷 2870-2876页

作者： Qun Li Kaisi Liu Siwei Gui Jiabin Wu Xiaogang Li Zaifang Li Hongrun Jin Hui Yang Zhimi Hu Wenxi Liang Liang Huang Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China China-Australia Institute for Advanced Materials and Manufacturing Jiaxing UniversityJiaxing 314001China State Key Laboratory of Material Processing and Die&Mold Technology Department of MechanicsSchool of Aerospace EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The development of earth-abundant-metal-based electrocatalysts with high efficiency and long-term stability for hydrogen evolution reaction(HER)is crucial for the clean and renewable energy ***,we report a molten-salt method to synthesize Co-doped CaMn_(3)O_(6)(CMO)nanowires(NWs)as effective electrocatalyst for *** as-obtained CaMn_(3-x)Co_(x)O_(6)(CMCO)exhibits a small onset overpotential of 70 mV,a required overpotential of 140 mV at a current density of 10 mA·cm^(-2),a Tafel slope of 39 mV·dec^(-1)in 0.1 M HClO_(4),and a satisfying long-term *** characterizations combined with density functional theory(DFT)calculations demonstrate that the obtained HER performance can be attributed to the Co-doping which altered CMO’s surface electronic structures and *** the simplicity of synthesis route and the abundance of the pertinent elements,the synthesized CMCO shows a promising prospect as a candidate for the development of earth-abundant,metal-based,and cost-effective electrocatalyst with superior HER *** results also establish a strategy of rational design and construction of novel electrocatalyst toward HER by tailoring band structures of transition metal oxides(TMOs).

关键词： CMCO nanowires hydrogen evolution reaction electronic structure dopant

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FeNi@CNS nanocomposite as an efficient electrochemical catalyst for N_(2)-to-NH_(3) conversion under ambient conditions

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Journal of materials Science & technology 2022年第8期103卷 59-66页

作者： Tayiba Ilyas Fazal Raziq Nasir Ilyas Liuxin Yang Sharafat Ali Amir Zada Syedul Hasnain Bakhtiar Yong Wang Huahai Shen Liang Qiao School of Physics University of Electronic Science and Technology of ChinaChengdu 610054China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 10084China Department of Chemistry Abdul Wali Khan University of MardanMardanKPK 23200Pakistan Laboratory of Living Materials at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Institute of Nuclear Physics and Chemistry Chinese Academy of Engineering PhysicsMianyang 621900China

The electrocatalytic nitrogen reduction reaction(NRR)has emerged as a promising renewable energy source and a feasible strategy as an alternative to Haber-Bosch ammonia(NH_(3))***,finding an efficient and cost-effective robust catalyst to activate and cleave the extremely strong triple bond in nitrogen(N_(2))for electrocatalytic NRR is still a ***,a FeNi@CNS nanocomposite as an efficient catalyst for N_(2) fixation under ambient conditions is *** FeNi@CNS nanocomposite was prepared by a simple water bath process and *** FeNi@CNS is demonstrated to be a highly efficient NRR catalyst,which exhibits better NRR performance with exceptional Faradaic efficiency of 9.83%and an NH_(3) yield of 16.52μg h^(−1) cm^(−2) in 0.1 M Na_(2)SO_(4) aqueous ***,high stability and reproducibility with consecutive 6 cycles for two hours are also demonstrated throughout the NRR electrocatalytic process for 12 ***,the FeNi@CNS catalyst encourages N_(2) adsorption and activation as well as effectively suppressing competitive ***,this earth-abundant FeNi@CNS catalyst with a subtle balance of activity and stability has excellent potential in NRR industrial applications.

关键词： Electrocatalytic nitrogen reduction Transition-metal alloy FeNi@CNS catalyst N_(2)fixation to NH_(3)

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