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Defect and Doping Co‑Engineered Non‑Metal Nanocarbon ORR Electrocatalyst

Nano-Micro Letters 2021年第4期13卷 178-207页

作者： Jian Zhang Jingjing Zhang Feng He Yijun Chen Jiawei Zhu Deli Wang Shichun Mu Hui Ying Yang Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China Pillar of Engineering Product Development Singapore University of Technology and Design8 Somapah RoadSingapore 487372Singapore State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200People’s Republic of China

Exploring low-cost and earth-abundant oxygen reduction reaction(ORR)electrocatalyst is essential for fuel cells and metal–air *** them,non-metal nanocarbon with multiple advantages of low cost,abundance,high conductivity,good durability,and competitive activity has attracted intense interest in recent *** enhanced ORR activities of the nanocarbons are normally thought to originate from heteroatom(e.g.,N,B,P,or S)doping or various induced ***,in practice,carbon-based materials usually contain both dopants and *** this regard,in terms of the co-engineering of heteroatom doping and defect inducing,we present an overview of recent advances in developing non-metal carbon-based electrocatalysts for the *** characteristics,ORR performance,and the related mechanism of these functionalized nanocarbons by heteroatom doping,defect inducing,and in particular their synergistic promotion effect are emphatically analyzed and ***,the current issues and perspectives in developing carbon-based electrocatalysts from both of heteroatom doping and defect engineering are *** review will be beneficial for the rational design and manufacturing of highly efficient carbon-based materials for electrocatalysis.

关键词： Defect Doping Electrocatalyst Oxygen reduction reaction Non-metal nanocarbon

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Predictive Damage Evolution and Fracture Behavior in High-Carbon Steel Via Multiscale Simulation and Experiments

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SSRN 2024年

作者： Wang, Huiling Wang, Feng Qian, Dongsheng Dong, Zhaohua Tian, Han Hua, Lin Chen, Jiancheng School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Engineering Research Center for Green Precision Material Forming Wuhan430070 China Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan430070 China

High-carbon steel consisting of soft ferrite and hard cementite is susceptible to micro-defects owing to the mismatched deformation between the ferrite and cementite during cold forming, which seriously deteriorates the fatigue life. However, the investigation of the damage and failure behavior in high-carbon steel during cold deformation remains largely undisclosed, which hinders further control of the microstructure and forming process. The current work investigates the damage evolution and fracture behavior related to the microstructural characteristics of spheroidized ferrite-cementite steel. A multiscale modeling framework is presented by coupling macroscale finite element (FE) simulation, mesoscale representative volume element (RVE) modeling, and nanoscale molecular dynamics (MD) simulation to analyze largescale plastic deformation and damage characteristics. In particular, the Gurson-Tvergaard-Needleman (GTN) damage model is used to predict the fracture behavior of the macroscale FE model. The uncoupled Rice-Tracy law and the maximum principal stress criterion are utilized to simulate the mesoscale damage behavior. The cohesive zone model (CZM) in the form of B-K constitutive law is utilized to simulate the interfacial decohesion. The GTN model parameters are evaluated by the response surface method (RSM). The nanoscale molecular dynamics simulations are conducted to obtain matrix-particle interface strength properties under the mixed loading. The mechanical property of ferrite phase was calibrated by the inverse analysis method based on genetic algorithm (GA). The failure model parameters of two phases are identified by DIC test results. The macroscale simulations accurately predict damage and fracture behavior of high-carbon steel. The results show that the voids preferentially initiate at the two-phase interface with the smallest spacing between particles. Subsequently, voids grow along the boundary of the cementite particles and then coalesce to form a c

关键词： Ferrite

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Strongly Enhancing the Energy Storage Properties and Stability of Amorphous BaTiO3 Thin Films via Ions Doping

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SSRN 2024年

作者： Chang, Ruiling Yao, Zhonghua Xing, Yutong Wang, Jun Hao, Hua Cao, Minghe Liu, Hanxing State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China International School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya572000 China

Amorphous thin films with high power density and breakdown strength satisfy the needs of advanced power electronic systems. Nonetheless, improving the energy storage density of amorphous films is critical for addressing the growing demand for electricity. We apply high spontaneous polarization BaTiO3 as the main component to make (1-x)Ba(Ti0.99Mn0.02)O3-xBiFeO3((1-x)BTM-xBF) thin films. Doping BiFeO3 (BF) synergistically boosts polarization. The introduction of amorphous phases and Mn ions enhances the breakdown strength. The results demonstrate that, at x=0.10, the film can achieve both a high efficiency of 80.3% and an excellent energy storage density of 111.3 J cm-3. Moreover, the film has a strong thermal stability within a broad range of 20°C ~ 160°C, as well as the cycling reliability is as high as 105 times. The present study offers a practical approach to develop film capacitors with outstanding energy storage capabilities. © 2024, The Authors. All rights reserved.

关键词： Amorphous films

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Highly Enhanced Electro-Catalytic Behavior of an Amide Functionalized Cu(Ii) Coordination Polymer on Oer at Large Current Densities

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SSRN 2024年

作者： Afaq, Sheereen Ashiq, Faheem Shoukat, Wseem Malik, Wasif Mahmood Ahmed Ismail, Muhammad Ghafoor, Abdul Ashraf, Zohaib Sajjad, Muhammad Verpoort, Francis Chughtai, Adeel Hussain Institute of Chemical Sciences Bahauddin Zakariya University Multan60800 Pakistan Pakistan Moscow117198 Russia State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center for Chemical and Material Engineering Wuhan University of Technology Wuhan430070 China

Extensive utilization of fossil fuels has led to their swift exhaustion, causing an escalating energy dilemma and significant environmental apprehensions. This situation has spurred advancement of sustainable energy conversion systems. Electrochemical water splitting is viewed as a capable method for generating hydrogen and oxygen intended for diverse electrochemical energy apparatus. A proficient, multifunctional electro-catalyst capable of facilitating both OERs) and HERs is of paramount importance. In this work, we report Cu-MOF electro-catalyst synthesized via the solvothermal route engaging OER activity using nickel foam (NF) in a 1 M KOH solution. Several analytical techniques were used to investigate the electro-catalysts BET, PXRD, FTIR and oxidation states. The water-splitting evaluation of the LOCOM-1 demonstrated exceptional oxygen activity concerning OER (oxygen evolution reaction), showcasing to extent a current density of 10 mAcm-2 a reduced of 286 mV over potential. Additionally, it exhibited a diminished onset potential of 1.37V attributable towards a decreased Tafel slope of 44.50 mVdec-1, and a proton couple electron transfer (PCET) channel that is stable over an extended period of time (1000 cycles of cyclic voltammetry and 40 hours of chronoamperometry). Therefore, this current endeavour might offer a new prospect or pathway for exploring the OER (Oxygen Evolution Reaction). © 2024, The Authors. All rights reserved.

关键词： Potassium hydroxide

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Dynamic response of B4C, TiB2 and TiB2-B4C under shock wave compression

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Ceramics International 2025年

作者： Shu, Zaiqin Jing, Qiang Wan, Mingming Zhang, Jinyong School of Physics and Mechanics Wuhan University of Technology Wuhan430070 China School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China State Key laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Inner Mongolian Metal Materials Research Institute Yantai264003 China

TiB2-B4C (TBC) has been widely utilized in lightweight armor due to its exceptional mechanical properties. The Hugoniot elastic limit (HEL) has been considered as an important dynamic property of ceramics. This paper presents the shock responses of pure B4C, pure TiB2, and TiB2-B4C composite. By microstructure analysis, the amorphization in B4C and dislocations in TiB2 at shock pressures around 37 GPa in the recycled debris were observed. The dislocations in TiB2 are believed to be the reason for ‘two HELs’ in TiB2. The addition of TiB2 has little effect on the shock properties of B4C, while the shock pressure exceeds HEL. Additionally, a failure wave was detected in the ceramics at shock pressures lower than HEL. A damage parameter was defined to quantify the extent of damage in the failure zone. The incorporation of TiB2 into B4C can significantly slow down failure propagation in TBC at pressure lower than HEL. Furthermore, the analysis of the damage parameter suggests that TBC exhibits superior impact resistance compared to pure B4C and TiB2. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Amorphization

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Ceramizable Cf/BPR composites with enhanced oxidation resistance up to 1670 °C

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Ceramics International 2025年

作者： Li, Junguo Zhao, Chenhan Jiang, Feng Zhang, Shiquan Yang, Suohui Xiang, Qianqian Li, Meijuan zhang, Jian Shen, Qiang School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

Ceramizable carbon fiber/boron-modified phenolic resin (Cf/BPR) composites are cost-effective and suitable for fabricating large-scale components, making them vital for thermal protection systems in aerospace vehicles. However, their thermal resistance requires further improvement. This study investigates the modification of Cf/BPR composites using ZrSi2, Al, and mica to enhance their thermal resistance. High-temperature static oxidation and oxyacetylene ablation tests are conducted to evaluate their high-temperature performance. The role of each filler on oxidation resistance is discussed. The results reveal that when ZrSi2 is added at 33.75 phr, Al at 3.75 phr, and mica at 5 phr, the prepared composite exhibits a flexural strength of 56 MPa after 20 min of static oxidation at 1600 °C, with excellent protection of the carbon fibers. After oxidation at 1670 °C, the flexural strength remains at 45 MPa, despite some degree of carbon fiber ablation. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Carbon fibers

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Large-scale manufacturing sulfide superionic conductor for advancing all-solid-state batteries

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Matter 2025年

作者： Wang, Shuo Lou, Chenjie Wu, Xinbin Lin, Jing Gautam, Ajay Li, Shenghao Huang, Jielei Cheng, Zhu Zhang, Shengnan Zhang, Xin Strauss, Florian Brezesinski, Torsten Luo, Guoqiang Tang, Mingxue Shen, Yang Lin, Yuanhua Nan, Ce-Wen Center of Smart Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China Center for High Pressure Science and Technology Advanced Research Beijing100094 China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing100084 China Kaiserstr. 12 Karlsruhe76131 Germany Department of Radiation Science and Technology Delft University of Technology JB Delft2629 Netherlands

Lithium argyrodites with high ionic conductivities are favorable solid electrolytes (SEs) for all-solid-state batteries (ASSBs). However, their low preparation efficiency and poor cycling performance hinder their large-scale applications. In this work, we demonstrate successful large-scale production (over 1 kg per batch for the first time) of Li5.5PS4.5Cl0.75Br0.75 (LPSCB) by fast dry mixing followed by annealing, which presents high room temperature ionic conductivities of 13 mS cm−1 for cold-pressed and 25 mS cm−1 for sintered pellets. Combining neutron powder diffraction and 6Li → 7Li tracer-exchange nuclear magnetic resonance (NMR) spectroscopy measurements, we show that intercage jumps frequently occur through the 48h-16e-48h pathway in LPSCB, promoting the overall lithium conduction. The assembled ASSBs using LPSCB and a LiNi0.83Co0.11Mn0.06O2 electrode can be cycled for over 2,500 cycles at a 0.5 C rate and 1,800 cycles at a 2 C rate without any capacity degradation. Our results will accelerate the commercialization of sulfide SE for ASSBs. © 2025 Elsevier Inc.

关键词： Neutron powder diffraction

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Ultrahigh Yield Strength Heterostructured Titanium Matrix Composites by Controlling Α Variant Selection

SSRN

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SSRN 2023年

作者： Zhu, Ke Huang, Jin Nie, Wei Liu, Ruxia Xiao, Yong Zhang, Jian Luo, Guoqiang Shen, Qiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Institute for Carbon Neutrality University of Science and Technology Beijing Beijing100083 China School of Material Science and Engineering

Enhancing the strength and plasticity of materials in a synergistic manner is a longstanding challenge in materials science. The content of β-stabilizing element W in Ti alloys is controlled using a chemical boundary engineering (CBE) strategy. Heterostructured Ti-xW composites are designed with α grain boundaries as the outer shell, α/β lamellar organization as the intermediate transition layer, and acicular martensite as the core region. This material exhibits a remarkable compressive yield strength of 2100 MPa, surpassing the majority of reported titanium matrix composites. The exceptional strength primarily arises from the precipitation strengthening of α/β lamellar organization and acicular martensite in the core region. Additionally, the gradient structure resulting from varying concentrations of W elements contributes to hetero-deformation induced (HDI) strengthening. This study holds significant implications for the development and design of high-strength heterostructured titanium matrix composites. © 2023, The Authors. All rights reserved.

关键词： Martensitic transformations

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Electrical Properties and Degradation Behavior of Bnt-Bt-Ln Ceramics

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SSRN 2023年

作者： Xu, Qi Yan, Xuerui He, Xin Dong, Shengde Ma, Luxiang Hai, Chunxi Zhou, Yuan Liu, Hanxing College of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu610059 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China

Dielectric capacitors are widely used in pulse power systems, electric vehicles, aerospace and defense technology as critical electronic components. Due to the miniaturization and diversification of electronic components, higher requirements are put on the electrical properties and the service life of dielectric capacitors. In this paper, the phase structure, microstructure, dielectric, ferroelectric and failure behavior of (1-x)(Bi0.5Na0.5TiO3-BaTiO3)-xLiNbO3 (BNT-BT-LN, x = 0.01, 0.03, 0.05, 0.07, 0.10) lead-free ceramics were investigated. All the samples exhibited perovskite phase with no secondary impurity. With increasing LiNbO3 concentration, the average grain size gradually increases from 0.78 μm to 1.75 μm. For the composition x = 0.07, the temperature coefficient of capacitance (TCC150°C) was lower than 15% in the range of 35 °C - 400 °C with moderate permittivity (Εr 150 °C = 2050) and low dielectric loss (tanδ150 °C = 0.005). The RC constant is above 19.3 s up to 245 °C. Through Highly Accelerated Life Test (HALT), the mean time to failure (TTF) empirical formula for BNT-BT-LN dielectrics is established. It indicates that the degradation of the insulation resistance process is caused by the electromigration of oxygen vacancies and the TTF is predicted to reach 4.67×106 h at 7 kV/mm and room temperature. © 2023, The Authors. All rights reserved.

关键词： Lithium compounds

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Preface to Special Issue for 2nd Chinese Symposium on Photocatalytic materials (CSPM2)

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Chinese Journal of Catalysis 2021年第1期42卷 1-2页

作者： Jiaguo Yu Zhaosheng Li Shifu Chen State Key Laboratory of Advanced Technology for Material Synthesis and Processing Wuhan University of TechnologyChina College of Engineering and Applied Sciences Nanjing UniversityChina Key Laboratory of Clean Energy and Green Circulation Huaibei Normal UniversityChina

With the ever-increasing consumption of fossil fuels and the increment in environmental pollution problems,developing sustainable and renewable energy sources and environmentally friendly purification methods has become an appeal investigation all over the *** can provide promising solutions to these issues,by utilizing solar light to reduce CO2 into hydrocarbon fuels,to split water into hydrogen and to mineralize organic pollutants into inorganic ***,a huge obstacle to the application of this technology is its low photocatalytic *** improvement on the performance of photocatalytic materials is urgently ***,this investigation topic was within the scope of The 2nd Chinese Symposium on Photocatalytic materials(CSPM2)held at Nanjing Jinling Riverside Hotel,Nanjing,China on November 8-11,*** conference was organized by Nanjing University,Huaibei Normal University,Changsha University,Fuzhou University and Wuhan universityof technology,and supported by National Natural Science Foundation of China(NSFC),Nanjing University,Huaibei Normal University,Changsha University,Wuhan University of technology,Beijing Perfectlight and *** are more than 420 experts and students attending this symposium,and 12 plenary lectures,17 keynote lectures,9 invited lectures,12 oral lectures and 115 posters ***,18 excellent posters were selected.

关键词： utilizing Nanjing increment

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