检索结果-内蒙古大学图书馆

Multi-scale regulation in S,N co-incorporated carbon encapsulated Fe-doped CO_(9)S_(8) achieving efficient water oxidation with low overpotential

引用

Nano Research 2022年第2期15卷 872-880页

作者： Wenbin Wang Yang Yang Yang Zhao Shuzhe Wang Xiaomeng Ai Jiakun Fang Youwen Liu State Key Laboratory of Materials Processing and Die&Mould Technology and School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Key Lab of Advanced Electromagnetic Engineering and Technology and School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Sulfide compounds provide a type of promising alternative for oxygen evolution reaction(OER)electrocatalysts due to their diversity,intrinsic activities,low-price and ***,the unsmooth mass transport channel,the collapse of the structure and insufficient intrinsic activities limit their potential for OER *** respond,the dense Fe-doped Co_(9)S_(8) nanoparticles encapsulated by S,N co-incorporated carbon nanosheets(Fe-Co_(9)S_(8)@SNC)were proposed and synthesized via fast thermal treatment from ultrathin metal-organic frameworks(MOFs)*** designed catalysts,the nanosheet configuration connected by nanoparticles retained rich access for permeation of electrolyte and precipitation of O_(2) bubbles during OER ***,the outer carbon layer of Co9S8 provided additional catalytic activity while acting as armor to keep the structure *** the atomic scale,the doped Fe regulated the local charge density and the d-band center for facilitating desorption of oxygen *** from this multi-scale regulation strategy,the Fe-Co_(9)S_(8)@SNC displays an ultralow overpotential of 273 mV at 10 mA·cm^(-2) and small Tafel slope of 55.8 mV·dec^(-1),which is even close to the benchmark RuO_(2) *** concept could provide valuable insights into the design of other catalysts for OER and beyond.

关键词： Co9S8 water oxidation electronic structure multi-scale regulation d-band center

来源：评论

学校读者我要写书评

暂无评论

Phase engineering on high-entropy transition metal dichalcogenides and the entropy-enhanced thermoelectric performance

引用

Journal of advanced Ceramics 2024年第12期13卷 1985-1995页

作者： Hongxiang Chen Enhui Zhao Xiaochun Wen Sheng Liu Shiyu Li Jiantao Fu Hengzhong Fan Bing Xiao Yongsheng Zhang School of Materials Science and Engineering Fujian University of TechnologyFuzhou 350118China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Fujian Provincial Key Laboratory of Advanced Materials Processing and Application Fuzhou 350118China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical EngineeringXi’an Jiaotong UniversityXi’an 710049China

High-entropy structures in layered compounds,especially transitional metal dichalcogenides(TMDCs),have powered the field with disordered and versatile chemical compositions,showing great potential in various functional applications,including energy storage and ***,the reported high-entropy phases are mainly 1T phases,2H phases are rare,and approximately 3R phases are still ***,phase engineering of high-entropy TMDCs is achieved by tuning the chemical composition of(Mo_(0.5)W_(0.5))_(1−x)(Nb_(0.5)Ta_(0.5))_(x)Se_(2+δ),0≤x<1,and−0.1≤δ≤0.3.A phase diagram is constructed to guide the synthesis of pure 2H/3R phases over a wide composition/entropy *** increase in VB-group element content and Se overdose facilitated the formation of 3R phases,whereas the opposite occurred for 2H *** first-principles calculations evaluate the stability of phases in different polytypes and compositions,matching well with the composition-dependent crystalline ***,the optimized thermoelectric performance,with a figure of merit(zT=0.36@723 K)in 2H phase of x=0.2,is attributed to the low thermal conductivity(κ)caused by the high-entropy effect,which is one of the highest among(Mo/W)Se_(2)-based *** work enriches high-entropy TMDCs with versatile polytypes,expanding their potential uses for various fields.

关键词： high-entropy layered compounds crystal structure thermoelectric entropy engineering phase engineering

来源：评论

学校读者我要写书评

暂无评论

Nurturing the marriages of single atoms with atomic clusters and nanoparticles for better heterogeneous electrocatalysis

引用

Interdisciplinary materials 2022年第1期1卷 51-87页

作者： Lei Zhang Jiawei Zhu Xin Li Shichun Mu Francis Verpoort Junmin Xue Zongkui Kou John Wang Department of Materials Science and Engineering National University of SingaporeSingaporeSingapore State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina School of Physical&Mathematical Sciences Nanyang Technological UniversitySingaporeSingapore

Single-atom catalysts,featuring some of the most unique activities,selectivity,and high metal utilization,have been extensively studied over the past *** their high activity,selectivity,especially towards small molecules or key intermediate conversions,they can be synergized together with other active species(typically other single atoms,atomic clusters,or nanoparticles)in either tandem or parallel or both,leading to much better performance in complex catalytic *** there have been reports on effectively combining the multiple components into one single catalytic entity,the combination and synergy between single atoms and other active species have not been reviewed and examined in a systematic ***,in this overview,the key synergistic interactions,binary complementary effects,and the bifunctional functions of single atoms with other active species are defined and discussed in *** integration functions of their marriages are in-vestigated with particular emphasis on the homogeneous and heterogeneous combinations,spatial distribution,synthetic strategies,and the thus-derived outstanding catalytic performance,together with new light shined on the catalytic mechanisms by zooming in several case *** dynamic nature of each of the active species and in particular their interactions in such new catalytic entities in the heterogeneous electrocatalytic processes are visited,on the basis of the in situ/operando ***,we feature the current chal-lenges and future perspectives of these integrated catalytic entities that can offer guidance for advanced catalyst design by the rational combination and synergy of binary or multiple active species.

关键词： atomic clusters binary/multiple synergy heterogeneous catalysis nanoparticles single atoms

来源：评论

学校读者我要写书评

暂无评论

Thermoelectric Properties of an Individual Suspended Single-Crystalline Sb_(2)Se_(3)Nanowire

引用

Journal of Thermal Science 2022年第4期31卷 1106-1114页

作者： DU Yanzheng SHI Shaoyi MIAO Tingting MA Weigang MAI Liqiang ZHANG Xing Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering Mechanics Tsinghua UniversityBeijing 100084China Beijing Key Laboratory of Process Fluid Filtration and Separation College of Mechanical and Transportation EngineeringChina University of PetroleumBeijing 102249China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Nanowires exhibit excellent thermoelectric performance,due to the stronger quantum confinement and phonon scattering effect compared to bulk ***,it is a challenge to accurately evaluate the thermoelectric performance of *** this paper,the thermoelectric properties of an individual suspended Sb_(2)Se_(3) nanowire have been characterized by comprehensive T-type method,including thermal conductivity,electrical conductivity,Seebeck coefficient and figure of *** thermal conductivity increases from 0.57 W/(m·K)to 3.69 W/(m·K)with temperature increasing from 80 K to 320 *** lattice vibration dominates the heat conduction process,and due to its flawless crystal structure,the thermal conductivity is not lower than the reported values of bulk Sb_(2)Se_(3).The electrical conductivity increases from 7.83 S/m to 688 S/m in the temperature range of 50 K–320 K,which is a great improvement compared with the corresponding bulk *** 294 K,the Seebeck coefficient of the Sb_(2)Se_(3) nanowire is–1120μV/K and the corresponding figure of merit is 0.064.

关键词： Sb_(2)Se_(3)nanowire thermoelectric properties thermal conductivity Seebeck coefficient electrical conductivity

来源：评论

学校读者我要写书评

暂无评论

Confined nanospace for enhanced photocatalysis

引用

国家科学评论（英文版） 2021年第3期8卷 3-4页

作者： Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyChina Laboratory of Inorganic Materials Chemistry(CMI) University of NamurBelgium

The world today is very different from how it *** consumption rate of fos-sil fuels compared with the available re-sources and the calamity of global warm-ing frighten *** entire planet is at risk,but these are our *** is the cause and so mankind should find sustainable and green energy solutions to satisfy the needs of society.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Na_(3)Zr_(2)Si_(2)PO_(12) solid-state electrolyte with glass-like morphology for enhanced dendrite suppression

引用

Rare Metals 2022年第12期41卷 4086-4093页

作者： Hang Su Shi-Wei Zhang Yi-Meng Liu Chao Yang Li-Xiao Zhang Sen Xin Ya You State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China CAS Key Laboratory of Molecular Nanostructure and Nanotechnology CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of Sciences(CAS)Beijing 100190China University of Chinese Academy of Sciences International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China

Rechargeable batteries based on solid-state electrolytes are of great interest and importance for the next-generation energy storage due to their high energy output and improved *** building the solid-state batteries,Na_(3)Zr_(2)Si_(2)PO_(12)(NZSP)represents a promising candidate as it features high chemical stability against air exposure and a high Na^(+)*** pellets were usually calcined at a high temperature,and the high volatility of Na and P elements easily led to the formation of impurity *** this work,the effects of calcination temperature and stoichiometry on the phase purity and ionic conductivity of the NZSP electrolyte were *** an elevated sintering temperature,the NZSP electrolyte showed a high ionic conductivity owing to decreased porosity,and the highest ionic conductivity at 30℃was observed to be 2.75×10^(-5)S·cm^(-1)with an activation energy of 0.41 *** the stoichiometry,the introduction of 5 mol%excessive P results in formation of more Na_(3)PO_(4) and glass-like phase at the grain boundary,which caused the blurred grain boundary and reduced grain barrier,and effectively suppressed Na dendrite growth,then accounted for improved cycling performance of a Na‖Na symmetric *** work provided insights on reasonable design and preparation of NZSP electrolyte towards practical realization of solid-state Na-metal batteries.

关键词： Na_(3)Zr_(2)Si_(2)PO_(12)(NZSP) Natrium superionic conductor(NASICON)solid-state electrolytes Grain boundary Ionic conductivity Glass-like morphology

来源：评论

学校读者我要写书评

暂无评论

Multifunctional 2-(2-hydroxyphenyl)benzoxazoles: Ready synthesis,mechanochromism, fluorescence imaging, and OLEDs

引用

Chinese Chemical Letters 2024年第10期35卷 223-227页

作者： Kangmin Wang Liqiu Wan Jingyu Wang Chunlin Zhou Ke Yang Liang Zhou Bijin Li Chongqing Key Laboratory of Natural Product Synthesis and Drug Research School of Pharmaceutical SciencesChongqing UniversityChongqing 401331China jiangsu Key Laboratory of Advanced Catalytic Materials&Technology School of Petrochemical EngineeringChangzhou UniversityChangzhou 213164China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

Triphenylamine(TPA)-containing 2-(2-hydroxyphenyl)benzoxazoles(2a-2c)have been synthesized via a highly efficient rhodium-catalyzed C–H/C–H cross-coupling *** 2a is a novel mechanofluorochromic material with blue-shifted mechanochromic *** 2b and 2c presented opposite mechanochromic *** 2b,the enol-form emission enhanced,and the ketoform emission blue-shift after *** contrast,2c exhibited the weak enol-form emission disappeared and the keto-form emission slightly red-shift after grinding *** estrone-containing2b-based water-dispersed nanoparticles(NPs)exhibit apparent dual-emission and were applied for fluorescence *** addition,bis(TPA)-containing 2c-based devices exhibit dual-emission with good performance and a singlet exciton yield of 92%,which breaks through the theoretical upper limit of 25%in conventional fluorescent *** is one of the highest exciton utilization values recorded for the ESIPT molecules with a dual emission system.

关键词： Rhodium-catalyzed 2-(2'-Hydroxyphenyl)benzoxazoles Mechanochromism Fluorescence images OLEDS

来源：评论

学校读者我要写书评

暂无评论

Sound absorption model of thin woven fabric with tortuosity effects by equivalent circuit method 2

Sound absorption model of thin woven fabric with tortuosity ...

引用

2023 2nd International Conference on Acoustics, Fluid Mechanics and Engineering, AFME 2023

作者： Tang, Xiaoning Zhu, Shubing State Key Laboratory for New Textile Materials and Advanced Processing Technology School of Textile Science and Engineering Wuhan Textile University Hubei Wuhan430200 China

The fabric has been widely used as a noise-reduction material. This paper presents a revised equivalent circuit model to simulate the acoustical behavior of woven fabric with backing an air gap, with a special focus on including a tortuosity parameter. The simulated sound absorption of three fabrics with and without the tortuosity parameter was experimentally validated. The equivalent circuit model including the tortuosity parameter predicts the absorption curve better, particularly at the local minima in comparison to the existing models without the tortuosity effects. It is beneficial to the structural design of woven fabric with enhanced sound absorption. © Published under licence by IOP Publishing Ltd.

关键词： Acoustic wave absorption

来源：评论

学校读者我要写书评

暂无评论

Stable operation of polymer electrolyte-solid-state batteries via lonepair electron fillers

引用

Nano Research 2023年第11期16卷 12727-12737页

作者： Hongbin Liu Qing Sun Jun Cheng Hongqiang Zhang Xiao Xu Yuanyuan Li Zhen Zeng Yue Zhao Deping Li Jingyu Lu Lijie Ci State Key Laboratory of Advanced Welding and Joining School of Materials Science and EngineeringHarbin Institute of Technology(Shenzhen)Shenzhen 518055China School of Science Harbin Institute of Technology(Shenzhen)Shenzhen 518055China Research Center for Carbon Nanomaterials Key Laboratory for Liquid–Solid Structural Evolution&Processing of Materials(Ministry of Education)School of Materials Science and EngineeringShandong UniversityJinan 250061China College of Materials and Chemistry China Jiliang UniversityHangzhou 310018China

Due to the increasing demand and wide applications of lithium-ion batteries,higher requirements have been placed on the energy density and *** solid-state electrolytes have gained significant popularity due to their excellent interface compatibility and ***,their applications have been greatly restricted by the high crystallinity at room temperature,which hinders the transport of lithium ***,we utilize inorganic tubular fillers with abundant lone-pair atoms to reduce the crystallinity of the polyethylene oxide(PEO)solid-state electrolyte membrane and improve its ionic conductivity at room temperature,enabling stable operation of the *** tubular lone-pair-rich inorganic fillers play a key role in providing avenues for both internal and external charge *** surface lone-pair electrons facilitate the dissociation and transport of lithium ions,while the internally tubular electron-rich layer attracts ions into the cavities,further enhancing the ion *** 100 cycles at room temperature,the lithium battery loaded with this solid-state electrolyte membrane delivers a specific capacity of 141.6 mAh·g−1,which is 51.3%higher compared to the membrane without the fillers.

关键词： nanotube filler polymer electrolyte ion transport room temperature(RT)operation

来源：评论

学校读者我要写书评

暂无评论

Zr_(2)SeB and Hf_(2)SeB:Two new MAB phase compounds with the Cr_(2)AlC-type MAX phase(211 phase)crystal structures

引用

Journal of advanced Ceramics 2022年第11期11卷 1764-1776页

作者： Qiqiang ZHANG Yanchun ZHOU Xingyuan SAN Wenbo LI Yiwang BAO Qingguo FENG Salvatore GRASSO Chunfeng HU Key Laboratory of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Science and Technology on Advanced Functional Composite Laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China Hebei Key Lab of Optic–Electronic Information and Materials College of Physics Science and TechnologyHebei UniversityBaoding 071002China State Key Laboratory of Green Building Materials China Building Materials AcademyBeijing 100024China

The ternary or quaternary layered compounds called MAB phases are frequently mentioned recently together with the well-known MAX ***,MAB phases are generally referred to layered transition metal borides,while MAX phases are layered transition metal carbides and nitrides with different types of crystal structure although they share the common nano-laminated structure *** order to prove that MAB phases can share the same type of crystal structure with MAX phases and extend the composition window of MAX phases from carbides and nitrides to borides,two new MAB phase compounds Zr_(2)SeB and Hf_(2)SeB with the Cr_(2)AlC-type MAX phase(211 phase)crystal structure were discovered by a combination of first-principles calculations and experimental verification in this ***-principles calculations predicted the stability and lattice parameters of the two new MAB phase compounds Zr_(2)SeB and Hf_(2)*** they were successfully synthesized by using a thermal explosion method in a spark plasma sintering(SPS)*** crystal structures of Zr_(2)SeB and Hf_(2)SeB were determined by a combination of the X-ray diffraction(XRD),scanning electron microscopy(SEM),and high-resolution transmission electron microscopy(HRTEM).The lattice parameters of Zr_(2)SeB and Hf_(2)SeB are a=3.64398Å,c=12.63223Åand a=3.52280Å,c=12.47804Å,*** the atomic positions are M at 4f(1/3,2/3,0.60288[Zr]or 0.59889[Hf]),Se at 2c(1/3,2/3,1/4),and B at 2a(0,0,0).And the atomic stacking sequences follow those of the Cr_(2)AlC-type MAX *** work opens up the composition window for the MAB phases and MAX phases and will trigger the interests of material scientists and physicists to explore new compounds and properties in this new family of materials.

关键词： Zr_(2)SeB and Hf_(2)SeB MAB phase MAX phase first-principles calculations thermal explosion synthesis

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：