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Long lifespan Li-Se battery: Advances, challenges and prospects

Journal of Energy Chemistry 2025年 102卷 712-733页

作者： Hongyan Li Thomas L. Madanu Tarek Barakat Wen-Da Dong Alexandru Vlad Xikun Zhang Cheng-Bin Jin Yu Li Bao-Lian Su College of Materials and Chemistry China Jiliang University Hangzhou 310018 Zhejiang China Laboratory of Inorganic Materials Chemistry (CMI) Namur Institute of Structured Matter (NISM) University of Namur 61 rue de Bruxelles B-5000 Namur Belgium State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430074 Hubei China Institute of Condensed Matter and Nanosciences Molecular Chemistry Materials and Catalysis Université catholique de Louvain Louvain-la-Neuve Belgium

Lithium-selenium (Li-Se) batteries have attracted increasing attention as one of the next-generation battery systems due to much higher electronic conductivity and comparable volumetric capacity of Se compared to the popular sulfur cathode. However, its practical application still faces great challenges, especially the rapid capacity decay triggered by the loss of active Se species. A comprehensive review to uncover the in-depth failure mechanism and provide targeted solutions to promote the stable operation of Li-Se batteries is urgently needed. This review systematically summarizes the strategies in the new perspective, focusing on the optimization of Se utilization in Li-Se batteries by keeping a high Se maintenance in the cathode and accelerating the electrochemical kinetics of lithium polyselenides (LiPSe) conversion. On the basis of structural design and Li 2 Se active material introduction to accommodate volume expansion, blocking shuttle transport of LiPSe by physical/chemical adsorption, bonding Se with polymers or cathode electrolyte interphase (CEI) construction, and catalytic design to accelerate the conversion of LiPSe, different strategies for improving the utilization of Se have been evaluated and discussed. To address the inevitable loss of Se, prospects on inactive Se reactivation and Li protection are detailedly proposed and analyzed referring to the chemistry and corrosion science. Additionally, the perspectives on the future design and comprehensive parameter evaluations for the optimization of Li-Se batteries are recommended. This review comprehensively explains the causes and solutions of capacity fading and provides potential efforts for lifespan expansion of batteries, shedding light on the future development of Li-Se batteries.

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Simultaneous optimization of lattice and spin configurations in atomic scale simulation of magnetic materials

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Physical Review B 2025年第13期111卷 134412-134412页

作者： Zhengtao Huang Teng Yang Hanxing Liu Ben Xu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center for Smart Materials and Device Integration School of Material Science and Engineering Wuhan University of Technology Wuhan 430070 People's Republic of China Graduate School of China Academy of Engineering Physics Beijing 100088 People's Republic of China School of Materials Science and Engineering Tsinghua University Beijing 100084 People's Republic of China

Large scale atomistic simulations involving spin-lattice coupling are at the forefront of research in condensed matter physics and materials science. A key challenge lies in determining the ground state configurations of spins and lattices given this strong coupling, complicated by their evolution adherence to distinct governing equations. Unlike first-principles calculations, where the magnetic configuration is naturally determined by minimizing the electronic energy, no existing algorithm can simultaneously optimize both lattice and spin degrees of freedom at the atomic scale. This paper introduces a synergistic optimization framework for lattice and spin optimization in magnetic materials, overcoming the conventional separation approach. Employing a “pseudoatomic” method, the simultaneous optimization of atomic and spin configurations enhances accuracy and speed, enabling both atomic scale precision and large scale calculations. Applied to face-centered-cubic iron and BiFeO3, this approach demonstrates effective convergence, offering a robust tool for complex spin-lattice coupling problems, which paves a path for addressing high-dimensional optimization problems.

关键词： Atoms

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ZrO2-CPS/ZrO2 graded composite ceramics with high osteoinductivity for dental implants fabricated by stereolithography

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Ceramics International 2025年

作者： Wu, Jiaxin Li, Zhi Meng, Xingliang Cheng, Bo Yang, Jing Li, Binbin Wang, Xinyu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen Valley Foshan528200 China Hainan Institute Wuhan University of Technology Sanya572000 China Biomedical Materials and Engineering Research Center of Hubei Province Wuhan University of Technology Wuhan430070 China School of Foreign Languages Wuhan University of Technology Wuhan430070 China Department of Stomatology Zhongnan Hospital of Wuhan University Wuhan430060 China

Promoting mechanical strength and osteoinductivity properties is crucial for dental implants materials. Herein, we synthesized silicocarnotite (CPS) powder via a hydrothermal method, and mixed it with zirconia to create a composite material for preparing four slurries: xCPS-(1−x)ZrO2 (x = 0, 1/6, 1/3, and 1/2 vol%). The optimal printing parameters for each slurry were investigated. Following the printing of the slurries, debinding was performed on them in the temperature range of 25 °C–600 °C in nitrogen atmosphere and 600 °C–1000 °C in air atmosphere, respectively, followed by sintering at 1350 °C for 2 h. The graded zirconia-based composite ceramics prepared using stereolithography (SLA) exhibited excellent mechanical properties, including a flexural strength of 742.37 ± 22.52 MPa, Vickers hardness of 7.29 ± 0.15 GPa, fracture toughness of 5.34 ± 0.29 MPa m1/2, and a relative density of 96.3 %. Compared with zirconia ceramics, the graded composite ceramics displayed higher surface roughness. The graded composite ceramics degraded and released Ca, Si, and P ions, promoting MC3T3-E1 cells proliferation, adhesion, and osteogenic differentiation. These findings suggest that ZrO2-CPS/ZrO2 graded composite ceramics synthesized via SLA holds great potential as dental implants with high osteoinductivity. © 2025

关键词： Fracture toughness

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Ionic Liquid-Grafted Mxene Composite Polymer Electrolytes for High-Performance Solid-state Batteries

SSRN

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SSRN 2025年

作者： Li, Yu Qian, Zhi Qiu, Zhao-Dong Wang, Rui-Qing Wei, Mei-Tong Fei, An-Min Hu, Zhi-Yi Mohamed, Hemdan S.H. Chen, Li-Hua Su, Bao-Lian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Wuhan University of Technology Wuhan430070 China Physics Department Faculty of Science Fayoum University El Gomhoria Street Fayoum63514 Egypt University of Namur NamurB-5000 Belgium

All-solid-state batteries (ASSBs) have obtained much attention due to the high energy density and security. At present, PEO-based solid-state batteries are considered to be one of the most promising candidates for high-performance ASSBs due to the excellent processability and good interfacial stability. However, low ionic conductivity and Li+ transference number seriously hinder their progress in practical applications. Here, a novel filler is developed by embedding ionic liquid (IL) grafted onto the surface of MXene to improve the electrochemical performance of PEO-based solid composite polymer electrolyte (MXene-IL-SPE) for ASSBs. The 2D MXene can significantly reduce the crystallinity of PEO, and the presence of IL not only enhances the dispersion of MXene in the polymer matrix, but also promotes the dissociation of lithium salts and anchors anions. As a result, the MXene-IL-SPE possesses high ionic conductivity (7.19 × 10-4 S cm-1) and Li+ transference number (0.51), together with wide electrochemical window (5.2 V) at 60 °C. The assembled LiFePO4|MXene-IL-SPE|Li full cell exhibits remarkable rate capability and exceptional capacity of 154.8 mAh g-1 over 120 cycles with an impressive 95.3% capacity retention at 0.5 C. This design opens up a new way to prepare high performance CPEs for ASSBs. © 2025, The Authors. All rights reserved.

关键词： Solid-state Batteries

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Effects of Thermal Aging on Microstructure and Mechanical Properties of Interface of Hot Isostatic Pressing Densified Low Alloy Steel with Inconel 690 Cladding

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Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal materials and Engineering 2025年第4期54卷 879-885页

作者： Yu, Lei Cao, Rui Ma, Jinyuan Yan, Yingjie Dong, Hao Wang, Caiqin State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of Technology Lanzhou730050 China School of Materials Science and Engineering Lanzhou University of Technology Lanzhou730050 China Advanced Technology & Materials Co. Ltd Beijing100081 China Hebei Hot Isostatic Pressing Technology Innovation Center Zhuozhou072750 China

The microstructure, micro-hardness, and tensile properties of interface between hot isostatic pressing densified low alloy steel and Inconel 690 cladding were investigated during the aging process at 600 ℃. The results show that the interface region can be divided into four zones from base metal to deposited metal: carbon-depleted zone (CDZ), partial melting zone (PMZ), planar growth zone (PGZ), and brownish feature zone (BFZ). Dimensions of these zones do not significantly change during aging. However, type I carbides noticeably increase in size in the PMZ, and precipitates clearly occur in the PGZ. The main reason for their growth and occurrence is continuous carbon migration. The highest micro-hardness appears in the PGZ and BFZ regions, which is related to carbon accumulation and precipitates in these regions. Tensile failure occurs on the base metal side due to the high strength mismatch between these two materials. The CDZ, composed of only ferrite, has lower strength and fractures at the boundary between CDZ and base metal. The ultimate tensile strength decreases by only 50 MPa after aging for 1500 h, and the interface region maintains high strength without significant deformation. Copyright © 2025, Northwest Institute for Nonferrous Metal Research. Published by Science Press. All rights reserved.

关键词： Tensile strength

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Lifecycle Synergistic Prelithiation Strategy of Both Anode and Cathode for High-Performance Lithium-Ion Batteries

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advanced Energy materials 2025年第0期

作者： Zhong, Wei He, Renjie Peng, Linfeng Liu, Wei Peng, Jiayue Zhu, Haolin Xiang, Jingyu Cheng, Shijie Xie, Jia State Key Laboratory of Materials Processing and Die & Mould Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China State Key Laboratory of Advanced Electromagnetic Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China School of Chemistry and Chemical Engineering Huazhong University of Science and Technology Wuhan430074 China

Prelithiation is recognized as an effective technology for addressing the depletion of active lithium, but conventional methods are constrained by their reliance on singular lithium replenishment mechanisms and limited functionality. Herein, a synergistic and comprehensive lifecycle prelithiation technology is introduced as applicable to both anode and cathode. For anode prelithiation, highly reactive biphenyl lithium is leveraged as a lithium replenishing agent, supplemented by functional additives, ethoxy(pentafluoro)cyclotriphosphazene (PFPN) and fluoroethylene carbonate (FEC), to generate a robust SEI enriched with Li3N, LiF, Li3P and Li2O. This approach not only compensates for the initial active lithium loss but also fortifies the structural integrity of the SEI. For cathode prelithiation, the high-capacity lithium replenisher Li2C2O4 and Li2C4O4 comprising B, N double-doped carbon loaded Mo2C-W2C (Mo-W@BNC) heterogeneous catalysts is employed, which exhibits superior catalytic performance in facilitating the release of lithium. The exceptional efficient liberations of lithium are achieved at discharge voltages of 3.78 V and 4.14 V for Li2C2O4 and Li2C2O4, respectively. The prelithiation for both anode and cathode mitigates the initial active lithium loss by 22.6%. Moreover, a singular activation during subsequent usage contributes an additional 0.8 mAh cm−2 of active lithium, achieving a capacity retention of 99.3% after 250 cycles at 0.5C. © 2025 Wiley-VCH GmbH.

关键词： Lithium-ion batteries

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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer processing in Organic Solar Cells

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Nano-Micro Letters 2025年第2期17卷 372-375页

作者： Shuai Xu Youdi Zhang Yanna Sun Pei Cheng Zhaoyang Yao Ning Li Long Ye Lijian Zuo Ke Gao Key Laboratory of Advanced Green Functional Materials College of ChemistryChangchun Normal UniversityChangchun 130032People’s Republic of China Shandong Provincial Key Laboratory for Science of Material Creation and Energy Conversion School of Chemistry and Chemical EngineeringShandong UniversityQingdao 266237People’s Republic of China College of Polymer Science and Engineering Sichuan UniversityChengdu 610065People’s Republic of China State Key Laboratory and Institute of Elemento‑Organic Chemistry Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071People’s Republic of China Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Tianjin Key Laboratory of Molecular Optoelectronic Sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300350People’s Republic of China State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer *** optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture *** approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.

关键词： Organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management

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Tris-based protic ionic liquids with multiple adsorption effects enabling excellent anti-wear and anti-corrosion performances

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Journal of Molecular Liquids 2025年 425卷

作者： Ge, Shanqin Chen, Long Li, Wei Cai, Qingzhao Gong, Genxiang Wu, Junhao Yu, Jinhong Nishimura, Kazuhito Jiang, Nan Cai, Tao School of Materials Science and Chemical Engineering Ningbo University Zhejiang Ningbo315211 China State Key Laboratory of Advanced Marine Materials Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo315201 China Advanced Nano-processing Engineering Lab Mechanical Engineering Kogakuin University Tokyo192-0015 Japan

Molecular additives have garnered widespread attention in the fields of lubrication and corrosion protection due to their designable interfacial film-forming efficiency. Herein, three protic ionic liquids (PILs) with the same cation but different anions have been designed and synthesized. Their physicochemical properties, tribological properties and anti-corrosion properties were systematically investigated. Results demonstrated that under dynamic steel-on-steel friction conditions, the PILs can maximally reduce the running-in period, friction coefficient, and wear rate by 90 %, 40 %, and 97 %, respectively, compared to the commercial ionic liquid, BMIMPF6. Under static copper corrosion conditions, the PILs efficiently adsorb onto the copper surface and formed a dense oxide layer on its surface, thus achieving excellent corrosion protection for the copper substrates. Molecular dynamics (MD) simulation results indicate that the exceptional lubricity of PILs is due to its ability to rapidly adsorb onto the metal surface through multiple interaction sites on both its anionic and cationic components, thereby reducing the running-in period and swiftly establishing a lubricating film. This study provides insights into the development of molecular additives featuring multiple adsorption sites, with potential applications in the fields of tribology and corrosion engineering. © 2025

关键词： Tribology

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Dual-Aspect Control of Lithium Nucleation and Growth with Hydroxyapatite and Liquid Crystal Polymers for High-Performance Lithium Metal Batteries

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advanced Energy materials 2025年第0期

作者： Miao, Xiang Wu, Zhouhan Hu, Wei Guo, Lin Nan, Ce-Wen School of Chemistry Beijing Advanced Innovation Center for Biomedical Engineering Beihang University Beijing100191 China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing100084 China Institute for Advanced Materials and Technology University of Science and Technology Beijing Beijing100083 China

Lithium (Li) metal is a promising anode material for next-generation high-energy-density batteries. However, safety concerns and the limited lifespan due to Li dendrite formation hinder its practical application. The complex dendrite formation process involves nonuniform nucleation and radial growth, requiring a holistic strategy to simultaneously regulate both processes. In this work, a dual-aspect control strategy is developed by designing a protective layer composed of hydroxyapatite (HA) and a liquid crystal polymer (LCP). Electrochemical, microstructural, and computational analyses revealed that HA provides homogenous Li0 adsorption sites, enhancing Li nucleation kinetics and uniformity. Meanwhile, the LCP self-assembles into cation-selective channels, promoting Li-ion diffusion and regulating growth direction. This dual-aspect control significantly improved Li plating kinetics and mitigated Li dendrite formation. Benefiting from this strategy, the symmetric cell achieved a critical current density of 5 mA cm−2 and maintained a lifespan of 500 h at 3 mA cm−2. Furthermore, in Li–sulfur batteries, the cell exhibited exceptional high-rate cycling performance (>10 mA cm−2) with an average capacity decay rate of only 0.056% over 1000 cycles. These results highlight the effectiveness of dual-aspect control in suppressing Li dendrites and improving high-rate cycling stability. © 2025 Wiley-VCH GmbH.

关键词： Liquid crystals

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Low Pressure Chemical Vapor Deposited Perovskite Enables all Vacuum-Processed Monolithic Perovskite-Silicon Tandem Solar Cells

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advanced Energy materials 2025年

作者： Zhang, Yuxi Zhu, Yanqing Sun, Jingsong Hu, Min Chen, Jiahui Duan, Bingxin Hu, Shenghan Hou, Peiran Tan, Wen Liang Ku, Zhiliang Yang, Weiguang Lu, Jianfeng State Key Laboratory of Silicate Materials for Architectures Wuhan University of Technology Wuhan430070 China Zhejiang Baima Lake Laboratory Co. Ltd. Zhejiang Hangzhou310000 China School of Electronic and Electrical Engineering Hubei Province Engineering Research Center for Intelligent Micro-Nano Medical Equipment and Key Technologies Wuhan Textile University Wuhan430200 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China ClaytonVIC3168 Australia Solar Technology Co. Ltd. Jiangsu Taizhou225500 China

Low-pressure chemical vapor deposition (CVD) is a promising technique for metal halide perovskite photovoltaics fabrication due to its low manufacturing cost, conformal coverage, and high scalability for industry-scale fabrication. However, the lack of knowledge of the reaction kinetics makes the solar cell performance lag behind its solution-processed counterpart. Herein, the perovskite formation and crystal growth process in the CVD process are studied by unraveling the mechanism of ion diffusion via tracking the vapor–solid reaction with various semi-in-situ characterizations. It is found that Cs+ can migrate along the perovskite lattice and uniformly distribute in the vertical direction of the final perovskite film even changing the deposition order of CsBr and PbI2 in the solid source, whereas this order can significantly affect the growth kinetics and the bandgap of the perovskite. Depositing CsBr before PbI2 results in a faster conversion of inorganic precursors to perovskite phase, yielding a wider bandgap perovskite. Finally, we fabricated semi-transparent perovskite cells using all-vapor deposition process, which showed a champion efficiency of 18.7% and it retained ≈94% of its initial performance after 200 h of continuous operation. Moreover, using this all-vapor deposition process, we achieved a champion efficiency of 26.9% for monolithic perovskite-silicon tandem solar cells. © 2025 Wiley-VCH GmbH.

关键词： Low pressure chemical vapor deposition

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