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NH4+Deprotonation at Interfaces Induced Reversible H3O+/NH4+Co-insertion/Extraction

Angewandte Chemie 2023年第14期135卷

作者： Meng Huang Qiu He Junjun Wang Xiong Liu Fangyu Xiong Yu Liu Ruiting Guo Yan Zhao Jinlong Yang Liqiang Mai Guangdong Research Center for Interfacial Engineering of Functional Materials College of Materials Science and Engineering Shenzhen University Shenzhen 518060 China College of Physics and Optoelectronic Engineering Shenzhen University Shenzhen 518060 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China College of Materials Science and Engineering Sichuan University Chengdu 610065 China School of Materials Science and Engineering Zhengzhou University Zhengzhou 450001 China Department of Physics City University of Hong Kong Tat Chee Avenue Kowloon 999077 Hong Kong China Department of Materials Science and Engineering National University of Singapore Singapore 117574 Singapore The Institute of Technological Sciences Wuhan University Hubei Wuhan 430072 China

Ion insertions always involve electrode-electrolyte interface process, desolvation for instance, which determines the electrochemical kinetics. However, it′s still a challenge to achieve fast ion insertion and investigate ion transformation at interface. Herein, the interface deprotonation of NH 4 + and the introduced dissociation of H 2 O molecules to provide sufficient H 3 O + to insert into materials′ structure for fast energy storages are revealed. Lewis acidic ion-NH 4 + can, on one hand provide H 3 O + itself via deprotonation, and on the other hand hydrolyze with H 2 O molecules to produce H 3 O + . In situ attenuated total reflection-Fourier transform infrared ray method probed the interface accumulation and deprotonation of NH 4 + , and density functional theory calculations manifested that NH 4 + tend to thermodynamically adsorb on the surface of monoclinic VO 2 , and deprotonate to provide H 3 O + . In addition, the inserted NH 4 + has a positive effect for stabilizing the VO 2 (B) structure. Therefore, high specific capacity (>300 mAh g −1 ) and fast ionic insertion/extraction (<20 s) can be realized in VO 2 (B) anode. This interface derivation proposes a new path for designing proton ion insertion/extraction in mild electrolyte.

关键词： Electrode-Electrolyte Interface Energy Storage Mechanism Proton Insertion Vanadium Dioxide In Situ Characterization

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Inside Cover: Ligand Functionalization and Its Effect on CO2Adsorption in Microporous Metal–Organic Frameworks (Chem. Asian J. 4/2013)

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Chemistry – An Asian Journal 2013年第4期8卷

作者： Hui Liu Yonggang Zhao Zhijuan Zhang Nour Nijem Yves J. Chabal Xiangfang Peng Heping Zeng Jing Li School of Chemistry and Chemical Engineering State Key Laboratory of Luminescent Materials & Devices South China University of Technology Guangzhou 510641 (P.R. China) Key Laboratory of Polymer Processing Engineering of the Ministry of Education South China University of Technology Guangzhou 510641 (P.R. China) Department of Chemistry and Chemical Biology Rutgers The State University of New Jersey Piscataway New Jersey 08854 (USA) Fax: (+1) 732‐445‐5312 Current Address: Institute of Advanced Materials (IAM) Nanjing University of Technology Nanjing 210009 (P.R. China) Department of Materials Science and Engineering University of Texas at Dallas Richardson TX 75080 (USA)

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Adsorption of Co2+ and Sr2+ in aqueous solution by a novel fibrous chitosan biosorbent

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The Science of the total environment 2022年 825卷 153998页

作者： Shuting Zhuang Kunkun Zhu Lejin Xu Jun Hu Jianlong Wang Laboratory of Environmental Technology INET Tsinghua University Beijing 100084 PR China. State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile University Wuhan 430200 PR China. Department of Nuclear Engineering and Technology School of Energy and Power Engineering Huazhong University of Science and Technology Wuhan 430074 PR China. Laboratory of Environmental Technology INET Tsinghua University Beijing 100084 PR China Beijing Key Laboratory of Radioactive Waste Treatment INET Tsinghua University Beijing 100084 PR China. Electronic address: wangjl@***.

In this study, a novel fibrous chitosan biosorbent was prepared using LiOH/KOH/urea/HO (4.5:7:8:80.5 by weight) as spinning solvent. The fibrous chitosan exhibited a higher adsorption capacity and a faster adsorption rate for Co and Sr, compared with spherical chitosan due to its high specific surface area (16.9 m g), uniform fineness (24.1 μm), and good mechanical strength. The adsorption capacity of fibrous chitosan for Co and Sr was 31.3 mg g and 20.0 mg g, respectively, which was higher than that of spherical chitosan (22.5 mg gfor Co and 8.9 mg g for Sr). The coordination between -NH/-OH of chitosan and the nuclide ions was the rate-limiting step. The improvement of adsorption performance was due to the higher specific surface area which increased the exposure degree of functional groups (adsorptive sites). This new wet-spun fibrous chitosan biosorbent showed great potential in the adsorptive removal of nuclides ions from aqueous solution.

关键词： Adsorption Biosorbent Fibrous chitosan Nuclide

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Hierarchy Design in Metal Oxides as Anodes for advanced Lithium-Ion Batteries

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Small Methods 2018年第11期2卷

作者： Jun Jin Liang Wu Shaozhuan Huang Min Yan Hongen Wang Lihua Chen Tawfique Hasan Yu Li Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology 122 Luoshi Road 430070 Wuhan Hubei China Energy Research Institute Nanyang Technological University 639798 Singapore Singapore Institute for Integrative Nanoscience Leibniz Institute for Solid State and Materials Research (IFW Dresden) Postfach 27 01 16 01171 Dresden Germany Cambridge Graphene Centre University of Cambridge 9 JJ Thomson Avenue Cambridge CB3 0FA UK Laboratory of Inorganic Materials Chemistry (CMI) University of Namur 61 rue de Bruxelles Namur B-5000 Belgium Clare Hall University of Cambridge Herschel Road Cambridge CB3 9AL UK

Hierarchical structures are ubiquitous in both animals and plants. The coordination of the hierarchical structures and functions makes living organisms function efficiently. This explains why hierarchical metal oxide (HMO)-based micro/nanostructures have recently received huge attention as anodes for application in highly efficient lithium-ion batteries (LIBs). Indeed, hierarchy in such micro/nanostructured HMOs offers high specific surface area, stable structure, short path length, and improved higher packing density to improve the reaction kinetics and Li + /e − transport kinetics, resulting in highly enhanced rate capability and cycling stability for LIBs. This report focuses on the hierarchical design from structural, morphological, porous, and component levels to engineer the HMOs as anodes for LIBs. The advantages of micro/nanostructured HMO-based on three reaction mechanisms (intercalation/deintercalation, conversion, and alloying/dealloying), important challenges ahead, and future perspectives on designing advanced electrode materials for next-generation high-performance LIBs are discussed.

关键词： hierarchy lithium ion batteries micro/nanostructured metal oxides reaction kinetics reaction mechanisms

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Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes

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Nature Catalysis 2024年 1244页

作者： Zechao Zhuang Jiarui Yang Dingsheng Wang Yadong Li Yihang Li Liangdong Fan Ruohan Yu Jinsong Wu Lixue Xia Yan Zhao Zhiquan Lang Jiexin Zhu Jiazhao Huang Jiaou Wang Yu Wang Department of Chemistry Tsinghua University Beijing P. R. China College of Chemistry and Environmental Engineering Shenzhen University Shenzhen P. R. China Interdisciplinary Research Center of Smart Sensors Academy of Advanced Interdisciplinary Research Xidian University Xi’an P. R. China Nanostructure Research Centre Wuhan University of Technology Wuhan P. R. China State Key Laboratory of Silicate Materials for Architectures International School of Materials Science and Engineering Wuhan University of Technology Wuhan P. R. China The Institute of Technological Sciences Wuhan University Wuhan P. R. China Center for Marine Materials Corrosion and Protection College of Materials Xiamen University Xiamen P. R. China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan P. R. China State Key Laboratory of Material Processing and Die & Mould Technology School of Materials Science and Engineering Huazhong University of Science and Technology Wuhan P. R. China Beijing Synchrotron Radiation Facility Institute of High Energy Physics Chinese Academy of Sciences Beijing P. R. China Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai P. R. China

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Enhanced Binding Affinity, Remarkable Selectivity, and High Capacity of CO2by Dual Functionalization of arht‐Type Metal–Organic Framework†

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Angewandte Chemie 2011年第6期124卷

作者： Baiyan Li Zhijuan Zhang Yi Li Kexin Yao Yihan Zhu Zhiyong Deng Fen Yang Xiaojing Zhou Guanghua Li Haohan Wu Nour Nijem Yves J. Chabal Zhiping Lai Yu Han Zhan Shi Shouhua Feng Jing Li State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun 130012 (P.R. China) Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road Piscataway NJ 08854 (USA) Advanced Membranes and Porous Materials Center King Abdullah University of Science and Technology (Saudi Arabia) Department of Materials Science and Engineering University of Texas at Dallas Richardson TX 75080 (USA)

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Graphene Foams: A Bubble‐Derived Strategy to Prepare Multiple Graphene‐Based Porous materials (Adv. Funct. Mater. 23/2018)

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advanced Functional materials 2018年第23期28卷

作者： Rujing Zhang Ruirui Hu Xinming Li Zhen Zhen Zhenhua Xu Na Li Limin He Hongwei Zhu Aviation Key Laboratory of Science and Technology on Advanced Corrosion and Protection for Aviation Material Department 5 P.O. Box 81‐5 AECC Beijing Institute of Aeronautical Materials Beijing 100095 China State Key Lab of New Ceramics and Fine Processing School of Materials Science and Engineering and Center for Nano and Micro Mechanics Tsinghua University Beijing 100084 China International Center for Materials Nanoarchitectonics (WPI‐MANA) National Institute for Materials Science (NIMS) 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan

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Nano‐Ferroelectric for High Efficiency Overall Water Splitting under Ultrasonic Vibration

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Angewandte Chemie 2019年第42期131卷

作者： Ran Su H. Alex Hsain Ming Wu Dawei Zhang Xinghao Hu Zhipeng Wang Xiaojing Wang Fa‐tang Li Xuemin Chen Lina Zhu Yong Yang Yaodong Yang Xiaojie Lou Stephen J. Pennycook College of Science Hebei University of Science and Technology Shijiazhuang 050018 China Materials Science and Engineering North Carolina State University Raleigh NC 27695 USA Frontier Institute of Science and Technology State Key Laboratory for Mechanical behavior of Materials Xi'an Jiaotong University Xi'an 710049 China School of Materials Science and Engineering University of New South Wales Sydney New South Wales 2052 Australia Micro/Nano Science and Technology Center Jiangsu University Zhenjiang 212013 China Department of Energy Science Sungkyunkwan University Suwon 16419 Republic of Korea State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal Materials Northwestern Polytechnical University Xi'an 710072 China Department of Materials Science and Engineering Faculty of Engineering National University of Singapore Singapore 117574 Singapore

Piezocatalysis, converting mechanical vibration into chemical energy, has emerged as a promising candidate for water‐splitting technology. However, the efficiency of the hydrogen production is quite limited. We herein report well‐defined 10 nm BaTiO 3 nanoparticles (NPs) characterized by a large electro‐mechanical coefficient which induces a high piezoelectric effect. Atomic‐resolution high angle annular dark field scanning transmission electron microscopy (HAADF‐STEM) and scanning probe microscopy (SPM) suggests that piezoelectric BaTiO 3 NPs display a coexistence of multiple phases with low energy barriers and polarization anisotropy which results in a high electro‐mechanical coefficient. Landau free energy modeling also confirms that the greatly reduced polarization anisotropy facilitates polarization rotation. Employing the high piezoelectric properties of BaTiO 3 NPs, we demonstrate an overall water‐splitting process with the highest hydrogen production efficiency hitherto reported, with a H 2 production rate of 655 μmol g −1 h −1 , which could rival excellent photocatalysis system. This study highlights the potential of piezoelectric catalysis for overall water splitting.

关键词： Ferroelektrische Phasen Phasenkoexistenz Piezokatalyse Piezoelektischer Effekt Wasserspaltung

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Frontispiece: Interfacially Ordered NiCoMoS Nanosheets Arrays on Hierarchical Ti3C2TxMXene for High-Energy-Density Fiber-Shaped Supercapacitors with Accelerated Pseudocapacitive Kinetics

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Angewandte Chemie International Edition 2024年第36期63卷

作者： Xiaotong Mei Dr. Chao Yang Fangyuan Chen Yuting Wang Dr. Yang Zhang Dr. Zengming Man Prof. Wangyang Lu Prof. Jianhong Xu Prof. Guan Wu National Engineering Lab for Textile Fiber Materials and Processing Technology School of Materials Science and Engineering Zhejiang Sci-Tech University Hangzhou 310018 P. R. China Zhejiang Provincial Innovation Center of Advanced Textile Technology Shaoxing 312000 P. R. China The State Key Laboratory of Chemical Engineering Department of Chemical Engineering Tsinghua University Beijing 100084 P. R. China

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Ferromagnetic materials: Strong Ferromagnetism Achieved via Breathing Lattices in Atomically Thin Cobaltites (Adv. Mater. 4/2021)

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advanced materials 2021年第4期33卷

作者： Sisi Li Qinghua Zhang Shan Lin Xiahan Sang Ryan F. Need Manuel A. Roldan Wenjun Cui Zhiyi Hu Qiao Jin Shuang Chen Jiali Zhao Jia-Ou Wang Jiesu Wang Meng He Chen Ge Can Wang Hui-Bin Lu Zhenping Wu Haizhong Guo Xin Tong Tao Zhu Brian Kirby Lin Gu Kui-juan Jin Er-Jia Guo Beijing National Laboratory for Condensed Matter Physics and Institute of Physics Chinese Academy of Sciences Beijing 100190 China State Key Laboratory of Information Photonics and Optical Communications and Laboratory of Optoelectronics Materials and Devices School of Science Beijing University of Posts and Telecommunications Beijing 100876 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Nanostructure research center Wuhan University of Technology 122 Luoshi Rd. Wuhan 430070 China NIST Center for Neutron Research National Institute of Standards and Technology (NIST) Gaithersburg MD 20899 USA Department of Materials Science and Engineering University of Florida Gainesville FL 32611 USA Eyring Materials Center Arizona State University Tempe AZ 85287 USA School of Physics and Microelectronics Zhengzhou University Zhengzhou 450052 China Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China Songshan Lake Materials Laboratory Dongguan Guangdong 523808 China China Spallation Neutron Source Institute of High Energy Physics Chinese Academy of Sciences Beijing 10049 China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China

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