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Enhanced Electrochemical Performances of Ni Doped Cr_(8)O_(21)Cathode materials for Lithium-ion Batteries

Journal of Wuhan University of technology(materials Science) 2023年第6期38卷 1242-1247页

作者： TANG Guoli LIU Hanxing YU Zhiyong YANG Bo KONG Linghua School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070China

Cathode materials,nickel doped Cr_(8)O_(21),were synthesized by a solid-state *** effects of Ni doping on the electrochemical performances of Cr_(8)O_(21) were *** experimental results show that the discharge capacities of the samples depend on the nickel contents,which increases firstly and then decreases with increasing Ni *** Ni_(0.5)Cr_(7.5)O_(21)delivers a first capacity up to 392.6 m Ah·g^(-1)at *** addition,Ni doped sample also demonstrates enhanced cycling stability and rate capability compared with that of the bare Cr_(8)O_(21).At 1 C,an initial discharge capacity of 348.7 m Ah·g^(-1)was achieved for Ni_(0.5)Cr_(7.5)O_(21),much higher than 271.4 m Ah·g^(-1)of the un-doped sample,with an increase of more than 28%.Electrochemical impedance spectroscopy results confirm that Ni doping reduces the growth of interface resistance and charge transfer resistance,which is conducive to the electrochemical kinetic behaviors during charge-discharge.

关键词： Cr_(8)O_(21) cathode material doping electrochemical performances lithium-ion batteries

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Rekindling hopes for lithium-sulfur batteries

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National Science Review 2025年第4期 88-90页

作者： Hongtao Qu Bao-Lian Su Laboratory of Inorganic Materials Chemistry (CMI) University of Namur State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

Lithium-sulfur(Li-S) batteries represent a promising solution for next-generation energy storage due to their high energy density, low cost, and environmental friendliness. However, liquid electrolytebased Li-S batteries are plagued by the‘polysulfide shuttling' effect, leading to severe performance degradation [1,2].

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Fe doping 1T phase MoS_(2)with enhanced zinc-ion storage ability and durability for high-performance aqueous zinc-ion batteries

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Rare Metals 2025年第1期44卷 253-263页

作者： Jing-Yi Liu Rong-Jie Zhe Zhan-Hong Peng Yi-Hui Song Lin-Xuan Yang Chen Qing Jun-Ling Guo Jin-Ping Liu Yunnan Key Laboratory of Opto-Electronic Information Technology College of Physics and Electronic Information TechnologyYunnan Normal UniversityKunming 650000China Country State Center for International Cooperation on Designer Low-Carbon and Environmental Materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China School of Chemistry Chemical Engineering and Life ScienceState Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070China

As a promising cathode material for aqueous zinc-ion batteries,1T-MoS_(2)has been extensively investigated because of its facile two-dimensional ion-diffusion channels and high electrical ***,the limited number of available Zn storage sites,i.e.,limited capacity,hinders its application because the inserted Zn^(2+),which form strong electrostatic interactions with 1T-MoS_(2),preventing subsequent Zn^(2+)***,the approach of enlarging the interlayer distance to reduce electrostatic interactions has been commonly used to enhance the capacity and reduce Zn^(2+)migration ***,an enlarged interlayer spacing can weaken the van der Waals force between 1T-MoS_(2)monolayers,easily disrupting the structural ***,to address this issue,an effective strategy based on Fe doping is proposed for 1T-MoS_(2)(Fe-1T-MoS_(2)).The theoretical calculations reveal that Fe doping can simultaneously moderate the rate of decrease in the adsorption energy after gradually increasing the number of stored atoms,and enhance the electron delocalization on metal-O ***,the experiment results show that Fe doping can simultaneously activate more Zn storage sites,thus enhancing the capacity,and stabilize the structural stability for improved cycling ***,Fe-1T-MoS_(2)exhibits a larger capacity(189 mAh·g^(-1)at 0.1 A·g^(-1))and superior cycling stability(78%capacity retention after 400 cycles at 2 A·g^(-1))than pure 1T-MoS_(2).This work may open up a new avenue for constructing high-performance MoS_(2)-based cathodes.

关键词： Aqueous zinc-ion battery 1T-MoS_(2) Fe doping More Zn storage sites Enhanced structural stability

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Enhanced Electrical Properties of Bi_(2−x)Sb_(x)Te_(3) Nanoflake Thin Films Through Interface Engineering

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Energy & Environmental materials 2024年第6期7卷 359-366页

作者： Xudong Wu Junjie Ding Wenjun Cui Weixiao Lin Zefan Xue Zhi Yang Jiahui Liu Xiaolei Nie Wanting Zhu Gustaaf Van Tendeloo Xiahan Sang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070China EMAT(Electron Microscopy for Materials Science) University of AntwerpGroenenborgerlaan 171Antwerp 2023Belgium

The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial *** thermoelectric materials with a simple,structurally-uniform interface provides a facile way to understand how these interfaces influence the transport ***,we synthesized Bi_(2−x)Sb_(x)Te_(3)(x=0,0.1,0.2,0.4)nanoflakes using a hydrothermal method,and prepared Bi_(2−x)Sb_(x)Te_(3) thin films with predominantly(0001)interfaces by stacking the nanoflakes through spin *** influence of the annealing temperature and Sb content on the(0001)interface structure was systematically investigated at atomic scale using aberration-corrected scanning transmission electron *** and Sb doping facilitate atom diffusion and migration between adjacent nanoflakes along the(0001)*** such it enhances interfacial connectivity and improves the electrical transport *** reactions create new interfaces that increase the scattering and the Seebeck *** to the simultaneous optimization of electrical conductivity and Seebeck coefficient,the maximum power factor of the Bi_(1.8)Sb_(0.2)Te_(3) nanoflake films reaches 1.72 mW m^(−1)K^(−2),which is 43%higher than that of a pure Bi_(2)Te_(3) thin film.

关键词： Bi_(2)Te_(3) nanoflakes interface engineering scanning transmission electron microscopy thermoelectric thin film

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Epitaxially Grown Ru Clusters-Nickel Nitride Heterostructure Advances Water Electrolysis Kinetics in Alkaline and Seawater Media

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Energy & Environmental materials 2023年第2期6卷 81-89页

作者： Jiawei Zhu Ruihu Lu Wenjie Shi Lei Gong Ding Chen Pengyan Wang Lei Chen Jinsong Wu Shichun Mu Yan Zhao State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China State Key Laboratory of Silicate Materials for Architectures International School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070China

The epitaxial heterostructure can be rationally designed based on the in situ growth of two compatible phases with lattice similarity,in which the modulated electronic states and tuned adsorption behaviors are conducive to the enhancement of electrocatalytic ***,theoretical simulations first disclose the charge transfer trend and reinforced inherent electron conduction around the epitaxial heterointerface between Ru clusters and Ni_(3)N substrate(cRu-Ni_(3)N),thus leading to the optimized adsorption behaviors and reduced activation energy ***,the defectrich nanosheets with the epitaxially grown cRu-Ni_(3)N heterointerface are successfully ***,by virtue of the superiority of intrinsic activity and reaction kinetics,such unique epitaxial heterostructure exhibits remarkable bifunctional catalytic activity toward electrocatalytic OER(226 mV@20 mA cm^(−2))and HER(32 mV@10 mA cm^(−2))in alkaline ***,it also shows great application prospect in alkaline freshwater and seawater splitting,as well as solar-to-hydrogen integrated *** work could provide beneficial enlightenment for the establishment of advanced electrocatalysts with epitaxial heterointerfaces.

关键词： alkaline water electrolysis bifunctional electrocatalyst epitaxial heterostructure seawater electrolysis solar-to-hydrogen integrated system

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Bioactive citrate-based polyurethane tissue adhesive for fast sealing and promoted wound healing

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Regenerative Biomaterials 2024年第1期3卷 69-81页

作者： Yan Li Jiawei Liu Chenxi Lian He Yang Mingjiang Zhang Youfa Wang Honglian Dai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei ProvinceWuhan University of TechnologyWuhan 430070China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China Shenzhen Research Institute of Wuhan University of Technology Shenzhen 518000China

As a superior alternative to sutures,tissue adhesives have been developed significantly in recent ***,existing tissue adhesives struggle to form fast and stable adhesion between tissue interfaces,bond weakly in wet environments and lack *** this study,a degradable and bioactive citrate-based polyurethane adhesive is constructed to achieve rapid and strong tissue *** hydrophobic layer was created with polycaprolactone to overcome the bonding failure between tissue and adhesion layer in wet environments,which can effectively improve the wet bonding *** citrate-based polyurethane adhesive provides rapid,non-invasive,liquid-tight and seamless closure of skin incisions,overcoming the limitations of sutures and commercial tissue *** addition,it exhibits biocompatibility,biodegradability and hemostatic *** degradation product citrate could promote the process of angiogenesis and accelerate wound *** study provides a novel approach to the development of a fast-adhering wet tissue adhesive and provides a valuable contribution to the development of polyurethane-based tissue adhesives.

关键词： tissue adhesive polyurethane citrate wet adhesion

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Continuous Fe^(3+)releasing enabled complete reconstruction of Ni-based MOF for promoted water oxidation in industrial alkali

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Science China Chemistry 2024年第9期67卷 2949-2957页

作者： Zhaojian Wang Wei Zhang Wenzhong Huang Ruohan Yu Changliang Chen Liqiang Mai Liang Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park Wuhan University of TechnologySanya 572000China Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000China

Most oxygen evolution reaction(OER)electrocatalysts show poor stability under industrial alkaline conditions(20–30 wt.%KOH).Therefore,it is essential to develop stable,efficient,and low-cost OER catalysts for industrial water ***,we present a straightforward approach for the complete electrochemical reconstruction of Ni-BDC,a Ni-based metal-organic framework,for *** method involves the continuous release of Fe^(3+)from Fe foam counter electrode in a high-concentration(6.0 M,25 wt.%)KOH *** continuously Fe^(3+)releasing not only realizes in situ Fe^(3+)doping,but also introduces abundant defects in the obtained catalyst during cyclic voltammetry activation,thereby accelerating the electrochemical *** reconstructed OER catalyst(Fe-doped nickel hydroxide/oxyhydroxide nanosheets supported on Ni foam,Fe-NiO_(x)(OH)y/NF)manifests a low overpotential of 217 mV at 10 mA cm^(-2)and 263 m V at 100 m A cm^(-2)in 1.0 M ***,the Fe-NiO_(x)(OH)_(y)/NF also demonstrates high stability in 30 wt.%*** strategy of regulating the electrochemical reconstruction process sheds light on the construction of stable and efficient OER catalysts for industrial water electrolysis.

关键词： oxygen evolution reaction industrial alkaline conditions metal-organic framework complete reconstruction

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Efficient flexible perovskite solar cells and modules using a stable SnO_(2)-nanocrystal isopropanol dispersion

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Nano Research 2024年第4期17卷 2704-2711页

作者： Zhiwei Su Jing Li Ruixuan Jiang Shujie Zhang Chengkai Jin Feng Ye Bingcan Ke Mengjun Zhou Jinhui Tong Hyesung Park Fuzhi Huang Yi-Bing Cheng Tongle Bu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Material Science and Engineering Wuhan University of TechnologyWuhan 430070China Department of Materials Science and Engineering Graduate School of Semiconductor Materials and Devices EngineeringGraduate School of Carbon NeutralityLow Dimensional Carbon Materials CenterUlsan National Institute of Science and TechnologyUlsan 44919Republic of Korea Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China

The outstanding advantages of lightweight and flexibility enable flexible perovskite solar cells(PSCs)to have great application potential in mobile energy *** to the low cost,low-temperature processibility,and high electron mobility,SnO_(2) nanocrystals have been widely employed as the electron transport layer in flexible *** prepare high-quality SnO_(2) layers,a monodispersed nanocrystal solution is normally ***,the SnO_(2) nanocrystals can easily aggregate,especially after long periods of ***,we develop a green and cost-effective strategy for the synthesis of high-quality SnO_(2) nanocrystals at low temperatures by introducing small molecules of glycerol,obtaining a stable and well-dispersed SnO_(2)-nanocrystal isopropanol dispersion *** to the enhanced dispersity and super wettability of this alcohol-based SnO_(2)-nanocrystal solution,large-area smooth and dense SnO_(2) films are easily deposited on the plastic conductive ***,this contributes to effective charge transfer and suppressed non-radiative recombination at the interface between the SnO_(2) and perovskite *** a result,a greatly enhanced power conversion efficiency(PCE)of 21.8%from 19.2%is achieved for small-area flexible PSCs.A large-area 5 cm×5 cm flexible perovskite solar mini-module with a champion PCE of 16.5%and good stability is also demonstrated via this glycerol-modified SnO_(2)-nanocrystal isopropanol dispersion approach.

关键词： tin oxide isopropanol dispersion colloid stability flexible perovskite solar cells

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Pt–C interactions in carbon-supported Pt-based electrocatalysts

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Frontiers of Chemical Science and Engineering 2023年第11期17卷 1677-1697页

作者： Yu-Xuan Xiao Jie Ying Hong-Wei Liu Xiao-Yu Yang School of Chemical Engineering and Technology Sun Yat-sen UniversityZhuhai 519082China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing&Shenzhen Research Institute&Joint Laboratory for Marine Advanced Materials in Pilot National Laboratory for Marine Science and Technology(Qingdao) Wuhan University of TechnologyWuhan 430070China

Carbon-supported Pt-based materials are highly promising *** carbon support plays an important role in the Pt-based catalysts by remarkably influencing the growth,particle size,morphology,dispersion,electronic structure,physiochemical property and function of *** review summarizes recent progress made in the development of carbon-supported Pt-based catalysts,with special emphasis being given to how activity and stability enhancements are related to Pt–C interactions in various carbon supports,including porous carbon,heteroatom doped carbon,carbon-based binary support,and their corresponding electrocatalytic ***,the current challenges and future prospects in the development of carbon-supported Pt-based catalysts are discussed.

关键词： Pt-C interactions Pt-based materials carbon support electrocatalysis

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Construction of dendritic Pt–Pd bimetallic nanotubular heterostructure for advanced oxygen reduction

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Interdisciplinary materials 2024年第6期3卷 907-918页

作者： Mingwei Wang Zhiyi Hu Jieheng Lv Zhiwen Yin Zhewei Xu Jingfeng Liu Shihao Feng Xiaoqian Wang Jiazhen He Sicheng Luo Dafu Zhao Hang Li Xuemin Luo Qi Liu Damin Liu Baolian Su Dongyuan Zhao Yong Liu International School of Materials Science and Engineering(ISMSE) State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhanChina Department of Chemistry Laboratory of Inorganic Materials ChemistryUniversity of NamurNamurBelgium Department of Chemistry Laboratory of Advanced MaterialsShanghai Key Lab of Molecular Catalysis and Innovative MaterialsState Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghaiChina

Compositions and morphologies of Pt-based electrocatalysts have great impact on the electrocatalytic activity and stability of oxygen reduction reaction(ORR).Herein,we report a novel design of one-dimensional(1D)Pt-Pd dendritic nanotubular heterostructures(DTHs)by controlling the degree of Pt 2+-Pt reduction reaction and Pd-Pt galvanic replacement reaction with uniform Pd nanowires as sacrificial *** obtained Pt-Pd bimetallic DTHs catalyst exhibited uniform and dense Pt dendritic nanobranches on the surface of 1D hollow Pt-Pd alloy nanotubes,possessing superior catalytic activity for ORR compared to state-of-the-art commercial Pt/C ***,the Pt_(4)Pd DTHs catalyst showed efficient mass activity(MA,1.05 A mg_(Pt)^(−1))and specific activity(SA,1.25 mA cm_(Pt)^(−2))at 0.9 V(***),and the catalyst exhibited high stability with 90.4%MA retention after 20000 potential *** Pt-Pd bimetallic DTHs configuration combines the advantages of 1D hollow nanostructures and dense Pt dendritic nanobranches,which results in rich electrochemical active surface sites,fast charge transport,and multiple dendritic anchoring points contact on carbon support,thus boosting its catalytic activity and stability towards electrocatalysis.

关键词： dendritic hollow heterostructures electrocatalysis one-dimensional nanowires oxygen reduction proton exchange membrane fuel cells

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