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Minimizing tin(Ⅱ) oxidation using ethylhydrazine oxalate for high-performance all-perovskite tandem solar cells

Journal of Semiconductors 2025年第5期46卷 88-94页

作者： Jianhua Zhang Xufeng Liao Weisheng Li Yutian Tian Qinyang Huang Yitong Ji Guotang Hu Qingguo Du Wenchao Huang Donghoe Kim Yi-Bing Cheng Jinhui Tong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Art and Design Wuhan University of TechnologyWuhan 430070China School of Information Engineering Wuhan University of TechnologyWuhan 430070China Department of Materials Science and Engineering Korea UniversitySeoul 02841Korea Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China

All-perovskite tandem solar cells(ATSCs) have the potential to surpass the Shockley-Queisser efficiency limit of conventional single-junction devices. However, the performance and stability of mixed tin–lead(Sn–Pb) perovskite solar cells(PSCs), which are crucial components of ATSCs, are much lower than those of lead-based perovskites. The primary challenges include the high crystallization rate of perovskite materials and the susceptibility of Sn^(2+) oxidation, which leads to rough morphology and unfavorable p-type self-doping. To address these issues, we introduced ethylhydrazine oxalate(EDO) at the perovskite interface, which effectively inhibits the oxidation of Sn^(2+) and simultaneously enhances the crystallinity of the perovskite. Consequently, the EDO-modified mixed tin-lead PSCs reached a power conversion efficiency(PCE) of 21.96% with high reproducibility. We further achieved a 27.58% efficient ATSCs by using EDO as interfacial passivator in the Sn-Pb PSCs.

关键词： mixed tin–lead perovskite solar cells ethylhydrazine oxalate Sn^(2+)oxidation all-perovskite tandem solar cells

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Enhancing thermal stability and photoluminescence of red-emitting Sr_(2)Si_(5)N_(8):Eu phosphors via boron doping

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Journal of Materials Science & technology 2021年第35期94卷 130-135页

作者： Hailong Yuan Zhifeng Huang Jianwen Zhang Ziqian Yin Xiangyu Lu Fei Chen Qiang Shen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Materials Science and Engineering Monash UniversityMelbourneVIC 3800Australia

Surface passivation is a common method to improve the resistance of thermal degradation of nitride ***,such a surface passivation generally needs extra processes and decreases the photoluminescence property of the *** this work,both the thermal stability and photoluminescence property of a red phosphor Sr_(2)Si_(5)N_(8):Eu are improved through the addition of *** influence of B on the crystal structure and the valence state of active ions was analyzed by experimental ***-principles calculations were applied to analyze the formation energy of N vacancies,which influence the resistance of thermal ***,combining with experimental characterization and calculations,the enhancing mechanism of thermal stability and photoluminescence by B was studied.

关键词： Nitride phosphors Thermal degradation Red-emitting First-principles calculations Photoluminescence

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Swarming Responsive Photonic Nanorobots for Motile-Targeting Microenvironmental Mapping and Mapping-Guided Photothermal Treatment

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Nano-Micro Letters 2023年第9期15卷 205-223页

作者： Luolin Li Zheng Yu Jianfeng Liu Manyi Yang Gongpu Shi Ziqi Feng Wei Luo Huiru Ma Jianguo Guan Fangzhi Mou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China School of Materials and Microelectronics Wuhan University of TechnologyWuhan 430070People’s Republic of China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070People’s Republic of China School of Chemistry Chemical Engineering and Life ScienceWuhan University of TechnologyWuhan 430070People’s Republic of China

Micro/nanorobots can propel and navigate in many hard-to-reach biological environments,and thus may bring revolutionary changes to biomedical research and ***,current MNRs lack the capability to collectively perceive and report physicochemical changes in unknown *** we propose to develop swarming responsive photonic nanorobots that can map local physicochemical conditions on the fly and further guide localized photothermal *** RPNRs consist of a photonic nanochain of periodically-assembled magnetic Fe_(3)O_(4)nanoparticles encapsulated in a responsive hydrogel shell,and show multiple integrated functions,including energetic magnetically-driven swarming motions,bright stimuli-responsive structural colors,and photothermal ***,they can actively navigate in complex environments utilizing their controllable swarming motions,then visualize unknown targets(e.g.,tumor lesion)by collectively mapping out local abnormal physicochemical conditions(e.g.,pH,temperature,or glucose concentra-tion)via their responsive structural colors,and further guide external light irradiation to initiate localized photothermal *** work facilitates the development of intelligent motile nanosensors and versatile multifunctional nanotheranostics for cancer and inflam-matory diseases.

关键词： Micro/nanorobots Collective behaviors Responsive photonic crystals On-the-fly sensing Photothermal therapy

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Nucleation growth quenching for superior cluster catalysts

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Nano Research 2022年第9期15卷 7933-7939页

作者： Ruyue Wang Feng Cheng Yonggang Wang Dongyu Fan Bohan Deng Yuanzheng Long Haolin Tang Kai Huang Zhaowei Qu Ming Lei Binghui Ge Hui Wu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Information Photonics and Optical Communications School of ScienceBeijing University of Posts and TelecommunicationsBeijing 100876China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Beijing Key Laboratory of Space-ground Interconnection and Convergence Beijing University of Posts and Telecommunications(BUPT)Beijing 100876China Information Materials and Intelligent Sensing Laboratory of Anhui Province Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationInstitutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601China

Cluster catalysts are rapidly growing into an important sub-field in heterogeneous catalysis,owing to their distinct geometric structure,neighboring metal sites,and unique electronic *** the thermodynamics and kinetics of the formation of nanoparticles have been largely investigated,the precise synthesis of clusters in wet chemical methods still faces great *** the study,a quenching strategy of asymmetric temperature in solution for the rapid generation of vacancy-defect rich clusters is *** quenching process can be used to synthesize multitudinous metal compound clusters,including metal oxides,fluorides,oxygen-sulfur compounds,and *** oxygen evolution reaction(OER),IrO_(2)clusters with abundant oxygen vacancies were obtained and uniformly dispersed in the *** to commercial IrO_(2),the prepared IrO_(2)cluster can be directly loaded on carbon paper and used as binder-free electrodes,which exhibit higher OER activity and long-term operational stability in alkaline *** quenching strategy provides a simple and efficient method for the synthesis of clusters,which has tremendous potential for industrial-scale preparation and application,especially can be further applied to flow electrochemical generators.

关键词： rapid-chilling cluster structure transition metal compounds binder-free electrode oxygen evolution reaction

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Graphene/SiC-coated textiles with excellent electromagnetic interference shielding,Joule heating,high-temperature resistance,and pressure-sensing performances

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Journal of advanced Ceramics 2023年第4期12卷 778-791页

作者： Chongjie Wang Qingfang Xu Jinrong Hu Pengjan Lu Han Wu Bingian Guo Rong Tu Kai Liu Meijun Yang Song Zhang Bao-Wen Li Chuanbin Wang Lianmeng Zhang School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Wuhan Tuocai Technology Co. Ltd.Ezhou 436032China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China Zhejiang MTCN Technology Co. Ltd.Huzhou 311103China Wuhan University of Technology Advanced Engineering Technology Research Institute of Zhongshan City Zhongshan 528400China School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China

Multifunctional,wearable,and durable textiles integrated with smart electronics have attracted tremendous ***,it remains a great challenge to balance new functionalities with high-temperature ***,textile-based pressure sensors with excellent electromagnetic interference(EMI)shielding,Joule heating,and high-temperature resistance were fabricated by constructing graphene/SiC(G/SiC)heterostructures on carbon cloth via laser chemical vapor deposition(LCVD).The resultant textiles exhibited excellent EMI efficiency of 74.2 dB with a thickness of 0.45 mm,Joule heating performance within a low working voltage(V)range of 1-3 V,and fast response time within 20 *** properties arose from multiple reflections,interfacial polarization,and high conductivity due to the numerous amounts of nanoscale G/SiC *** importantly,G/SiC/carbon fibers(CFs)demonstrated well high-temperature resistance with a heat resistance index(THri)of 380.2 C owing to the protection of a coating layer on the CFs upon ***,the G/SiC/CFs presented good pressure-sensing performance with high sensitivity(S)of 52.93 kPal,fast response time of 85 ms,and a wide pressure range of up to 186 *** features imply the potential of the G/SiC/CFs as efficient EMI shielding,electrical heater,and piezoresistive sensor textiles.

关键词： graphene/SiC(G/SiC) electromagnetic interference(EMI)shielding Joule heating pressure-sensing high-temperature resistance

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Single‑Atom Catalysts:Advances and Challenges in Metal‑Support Interactions for Enhanced Electrocatalysis

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Electrochemical Energy Reviews 2022年第1期5卷 145-186页

作者： Yang Mu Tingting Wang Jian Zhang Changgong Meng Yifu Zhang Zongkui Kou School of Chemical Engineering Dalian University of TechnologyDalian 116024LiaoningChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074HubeiChina

Single-atom catalysts(SACs),which contain a single metal atom supported on a well-confined substrate,are among the most promising heterogeneous catalysts owing to their unique advantages,such as high intrinsic activity and selectivity,tunable bonds and coordination,abundant metal-containing active sites,and atomic *** metal-support interactions(MSIs)in SACs exert a substantial influence on the catalytic properties,gaining a profound understanding and recognition of catalytic reactions depends greatly on investigating MSIs both experimentally and ***,the engineer-ing and modulation of MSIs are regarded as one of the most efficient methods to rationally design SACs with disruptively enhanced catalytic *** this review,we track the recent advances in SACs from an MSI *** then discuss the existing MSIs in SACs and elucidate the significant role of strong MSIs in catalytic properties and *** chal-lenges hindering the rational design of supported SACs with strong MSIs,which are currently still far from being completely understood and overcome,are *** addition,the correlation between strong MSIs and electrocatalytic activities in SACs,including an outlook to increase our understanding of MSIs,is ***,the present review provides some perspectives and an in-depth understanding of strong MSIs to advance high-performing SACs.

关键词： Metal-support interaction Single-atom catalysts Electrocatalysis ORR and OER HER and HOR

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Julolidine functionalized benzimidazoline-doped fullerene derivatives for efficient and stable perovskite solar cells

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Interdisciplinary Materials 2024年第3期3卷 369-379页

作者： Yanqing Zhu Chenglong Li JiaHui Chen Yuxi Zhang Jianfeng Lu Min Hu Wangnan Li Fuzhi Huang Yi-Bing Cheng Hyesung Park Shengqiang Xiao State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhanChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina School of Electronic and Electrical Engineering Hubei Province Engineering Research Centre for Intelligent Micro-Nano Medical Equipment and Key TechnologiesWuhan Textile UniversityWuhanChina Hubei Key Laboratory of Low Dimensional Optoelectronic Material and Devices Hubei University of Arts and ScienceXiangyangHubeiChina KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoulRepublic of Korea Department of Integrative Energy Engineering Korea UniversitySeoulRepublic of Korea Hubei Key Laboratory of Fuel Cell WuhanChina

Fullerene derivatives are highly attractive materials in solar cells,organic thermoelectrics,and other ***,the intrinsic low electron mobility and electrical conductivity restrict their potential device performance,such as perovskite solar cells(PSCs).Herein,we successfully enhanced the electric properties and morphology of phenyl-C61-butyric acid methyl ester(PCBM)by n-doping it with a benzimidazoline derivative,9-(1,3-dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)-julolidine(JLBI-H)via a solution *** found the n-doping can not only improve the conductivity and optimize the band alignment but also enable the PCBM to have a constantly strong charge extraction ability in a wide temperature from 173 to 373 K,which guarantees a stable photovoltaic performance of the corresponding PSCs under a wide range of operating *** the JLBI-H-doped PCBM,we improved the efficiency from 17.9%to 19.8%,along with enhanced stability of the nonencapsulated devices following the aging protocol of ISOS-D-1.

关键词： charge extraction electron mobility n-doping PSCs wide operation temperature

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1800℃下具有优异高强度且含氧化物杂质的高熵二硼化物陶瓷

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Science China Materials 2023年第5期66卷 2061-2070页

作者：柳洁杨青青邹冀王为民王新刚傅正义 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Xiangyang 441000China Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 201899China

以硼热/碳热还原合成高熵二硼化物粉体为原料,在2000℃/单轴加压50 MPa条件下,经10分钟放电等离子烧结,成功制备了含有~2 vol%的氧化物和~1 vol%气孔的高熵(Ti_(0.2)Zr_(0.2)Nb_(0.2)Hf_(0.2)Ta_(0.2))B_(2)陶瓷(HEBs).经研究确认,其中... 详细信息

以硼热/碳热还原合成高熵二硼化物粉体为原料,在2000℃/单轴加压50 MPa条件下,经10分钟放电等离子烧结,成功制备了含有~2 vol%的氧化物和~1 vol%气孔的高熵(Ti_(0.2)Zr_(0.2)Nb_(0.2)Hf_(0.2)Ta_(0.2))B_(2)陶瓷(HEBs).经研究确认,其中残留氧化物是固溶少量硼和碳的m-(Hf,Zr)O_(2).室温下HEBs的弹性模量、维氏硬度和断裂韧性分别为508.5 GPa、17.7±0.4 GPa和4.2±0.2 MPa m^(1/2).烧结得到的HEBs具有优良的抗弯强度,特别是其高温强度.HEBs在室温、1600和1800℃下的四点抗折强度分别为400.4±47.0 MPa、695.9±55.9 MPa和751.6±23.2 MPa.对1800℃下断裂的HEBs样品进行了失效分析,在其拉伸和断裂面附近区域,仅在裂纹尖端和孔隙边缘发现了数量有限的位错线的存在,没有观察到位错运动的痕迹.本研究首次报道了高熵二硼化物陶瓷的高温强度,发现其强度直至1800℃并无衰减,并对其高温下的强韧化机制进行了有益的探讨.

关键词： borides high-entropy ceramics high-temperature strength mechanical properties microstructure

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Mechanisms of crack elimination in directed energy deposited MAR M247 superalloy and effects of laser power on microstructural evolution and mechanical properties

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Materials Today Communications 2025年 46卷

作者： Chen, Mingzhang Liu, Xunchen Wang, Yitong Hua, Lin Hu, Zeqi School of Automotive Engineering Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan430070 China Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan430070 China

MAR M247 is a directionally solidified nickel-based superalloy with excellent high-temperature performance, but it suffers from severe cracking issues during the directed energy deposition (DED) process. Currently, much of the research on crack suppression in nickel-based superalloy has focused on IN738 and Hastelloy X, with limited studies specifically addressing the cracking suppression mechanisms for M247. This study investigates the mechanisms of crack elimination in M247 and the influence of laser power on its microstructural evolution and mechanical properties. Thermodynamic calculations indicate that M247 has higher crack sensitivity indices than IN718 and IN738, making crack suppression a critical challenge. By optimizing DED process parameters, particularly by reducing scan speed and increasing laser power, cracks were effectively eliminated. Numerical simulations reveal that these adjustments reduce thermal stress accumulation, thereby mitigating cracking. Microstructural characterization shows that increasing laser power minimizes internal defects, promotes a trend toward oriented grain growth, decreases transverse grain boundaries perpendicular to the deposition direction, reduces disorientation, promotes texture evolution, and increases Schmid factors. While tensile strength and microhardness remain largely unaffected, ductility is significantly improved. This paper provides valuable insights into crack elimination and mechanical property enhancement in additive manufactured nickel-based superalloy. © 2025 Elsevier Ltd

关键词： Tensile strength

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Idea of macro-scale and micro-scale prestressed ceramics

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Interdisciplinary Materials 2024年第6期3卷 897-906页

作者： Junfeng Gu Shuai Fu Hang Ping Wei Ji Ji Zou Hao Wang Weimin Wang Fan Zhang Hanxing Liu Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina School of Materials Science and Engineering Wuhan University of TechnologyWuhanChina

The brittleness of ceramics restricts their engineering *** is promising to solve the problem,yet still lacks enough attention and ex-tensive *** work proposes the idea of macro-scale and micro-scale prestressed ceramics:to form compressive prestress in macro-or micro-scale range in the ceramics by designed additional force,which offsets the fracture stress at the crack tips,then enhances the strength of *** macro-scale prestressed ceramic has a designed long-range ordering stress distribution in a large scale,similar to the reinforced concrete and tempered *** micro-scale ceramic has a designed short-range ordered stress dis-tribution,similar to that in the natural *** constructing the macro-scale and micro-scale prestressed ceramics are *** research interests and challenges are prospected for developing the mechan-ical properties of ceramics.

关键词： macro-scale micro-scale prestressed ceramics strength

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