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A Lewis acid-catalyzed tandem reaction enabling 2-arylglycerol derivative as a versatile 1,3-biselectrophile for the synthesis of 4H-chromenes and 2-pyridinones

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Chinese Chemical Letters 2023年第9期34卷 147-150页

作者： Shaomin Chen Tianjian Zhang Zhenhua Xu Bo You Minghao Li Yanlong Gu Key Laboratory for Large-Format Battery Materials and System Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering The Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832004China State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical PhysicsLanzhou 730000China

Acid-catalyzed tandem reactions were established by employing a novel class of 2-arylglycerol derivative,5-aryl-1,3-dioxan-5-ol,as versatile 1,*** the reactions,5-aryl-1,3-dioxan-5-ol works like atropaldehydes or 2-aryl malondialdehydes,and can react with 2-naphthols andβ-keto amides,allowing the synthesis of 4H-chromenes and *** yields,good functional group tolerance,broad substrate scope and simple reaction operation make this protocol attractive.

关键词： Lewis acid catalysis 2-Arylglycerol derivative 1,3-Biselectrophile Six-membered heterocycles [3+3]cyclization

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Three dimensional porous frameworks for lithium dendrite suppression

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Journal of Energy Chemistry 2020年第5期29卷 73-89页

作者： Shuyan Ni Shuangshuang Tan Qinyou An Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina

Lithium metal is a promising anode material owing to its very low electrochemical potential and ultrahigh specific ***,the growth of lithium dendrites could result in a short lifespan,low coulombic efficiency,and potential safety hazards during the progress of lithium plating/*** factors drastically hinder its application in lithium metal *** review focuses on the use of three dimensional(3D)porous host frameworks to improve Li plating/stripping behaviors,accommodate the change in volume,and suppress or block lithium dendrite *** 3D porous frameworks,including the conductive carbon-based,metal-based,and lithiophilic inorganic-compound frameworks are introduced and summarized in *** particular functions,relative developments,and optimized strategies of various 3D porous frameworks for lithium deposition/dissolution behaviors are ***,the challenges and promising developments in the field of Li metal anodes will be discussed at the end of this review.

关键词： Lithium metal battery 3D porous frameworks Lithium dendrite Lithium sulfur batteries Lithium oxygen batteries Li plating/stripping

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Visible light triggered exfoliation of COF micro/nanomotors for efficient photocatalysis

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Green Energy & Environment 2023年第2期8卷 567-578页

作者： Kai Feng Liang Zhang Jiang Gong Jinping Qu Ran Niu Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureHubei Engineering Research Center for Biomaterials and Medical Protective MaterialsSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan430074China The State Key Laboratory Breeding Base of Basic Science of Stomatology(Hubei-MOST)&Key Laboratory of Oral Biomedicine Ministry of Education School and Hospital of StomatologyWuhan UniversityWuhan 430079China National Engineering Research Center of Novel Equipment for Polymer Processing Key Laboratory of Polymer Processing EngineeringMinistry of EducationGuangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced ManufacturingSchool of Mechanical and Automotive EngineeringSouth China University of TechnologyGuangzhou510641China

We report a new facile light-induced strategy to disperse micron-sized aggregated bulk covalent organic frameworks(COFs)into isolated COFs *** was achieved by a series of metal-coordinated COFs,namely COF-909-Cu,-Co or-Fe,where for the first time the diffusio-phoretic propulsion was utilized to design COF-based micro/*** mechanism studies revealed that the metal ions decorated in the COF-909 backbone could promote the separation of electron and holes and trigger the production of sufficient ionic and reactive oxygen species under visible light *** this way,strong light-induced self-diffusiophoretic effect is achieved,resulting in good dispersion of *** them,COF-909-Fe showed the highest dispersion performance,along with a drastic decrease in particle size from 5μm to500 nm,within only 30 min light irradiation,which is inaccessible by using traditional magnetic stirring or ultrasonication *** importantly,benefiting from the outstanding dispersion efficiency,COF-909-Fe micro/nanomotors were demonstrated to be efficient in photocatalytic degradation of tetracycline,about 8 times faster than using traditional magnetic stirring *** work opens up a new avenue to prepare isolated nanosized COFs in a high-fast,simple,and green manner.

关键词： Micro/nanomotor COFs Exfoliation Nanocatalyst Photocatalysis

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Scalable Multilayered Dielectric Polymer Film Exhibiting Significantly Improved High-Temperature Energy Density

SSRN

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SSRN 2024年

作者： Li, Shuxuan Qu, Jie Wang, Jian Li, Xinhui Dai, Xingyao Jiang, Yanda Shen, Zhonghui Li, Bao-Wen Zhang, Xin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and Devices International School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China

Dielectric polymers, serving as crucial dielectric media in high-power-density energy storage devices, play a pivotal part in modern industries and electrical systems. However, the rapid degradation of breakdown strength and charge-discharge efficiency in elevated temperature environment imposes formidable limitations on the utilization of polymer dielectric under extreme conditions. Here, a series of polyetherimide/polysulfone alternating multilayer composite films are prepared using a non-equilibrium processing method, which effectively blocks the development of breakdown paths by the interface barriers in the multilayer structure. The deep trap sites within the interface capture the charge carriers excited at high temperatures, thus decreasing conduction loss and enhancing the efficiency and breakdown field strength of the dielectric polymer. Consequently, excellent capacitive performances including a high energy density of 5.4 J cm-3 with an efficiency exceeding 90% at 200 °C and cycle stability up to 106 cycles have been obtained. Furthermore, the multilayer polymer capacitors (MLPC) constructed from composite films also exhibit significant flexibility and thermal stability. This work provides valuable insights for the advancement of high-temperature energy storage polymers with commercial application value. © 2024, The Authors. All rights reserved.

关键词： Energy storage

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Time-domain Shielding Effectiveness of Cables Based on Metallized Aramid Fibers

Time-domain Shielding Effectiveness of Cables Based on Metal...

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2024 International Applied Computational Electromagnetics Society Symposium, ACES-China 2024

作者： Zhong, Wei Cao, Le Zhang, Tian-Yi Liu, Xu-Qing Xi'an University of Science and Technology College of Electric and Control Engineering Xi'an China Northwestern Polytechnical University State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal Materials Xi'an China

ISBN: (纸本)9798350355581

In this paper, cables with metallized coated aramid shielding materials are prepared, and the time-domain shielding effectiveness of different structures are analyzed in comparison with those of traditional shielding cables. The results show that the time-domain shielding effectiveness inside the cable with metallization-coated aramid fibers as the shielding layer can be increased by 65% compared to the cable with traditional shielding materials. The results indicate that the metallized coated aramid material has superior shielding ability, which provides more reliable technical support for its application in the field of electromagnetic compatibility and promotes the stable operation and development of electronic equipment and communication systems. © 2024 IEEE.

关键词： Cable shielding

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Ceramic Stereolithography in Investment Casting: Recent Progress and Applications 75

Ceramic Stereolithography in Investment Casting: Recent Prog...

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75th World Foundry Congress, WFC 2024

作者： Hu, Kehui Wang, Haoyuan Lu, Zhigang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Department of Mechanical Engineering Tsinghua University Beijing100084 China Key Laboratory of Advanced Materials Processing Technology Ministry of Education Tsinghua University Beijing100084 China State Key Laboratory of Clean and Efficient Turbomachinery Power Equipment Tsinghua University Beijing100084 China

Stereolithography-based ceramic additive manufacturing represents a promising technology for creating complex ceramic components with high precision. The technology's ability to form intricate structures and its compatibility with various ceramics make it particularly advantageous for rapid prototyping and low-volume production. This work discusses the recent progress and applications of stereolithography-based ceramic parts in the investment casting industry, particularly in the production of ceramic cores, shells, integrated core-shells, and filters, highlighting its potential to significantly accelerate production and enhance complexity. © 2024 75th World Foundry Congress, WFC 2024. All rights reserved.

关键词： Investment casting

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Visualization and Monitoring of Shell-making Process in Investment Casting 75

Visualization and Monitoring of Shell-making Process in Inve...

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75th World Foundry Congress, WFC 2024

作者： Feng, Qian Hu, Kehui Lu, Zhigang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Department of Mechanical Engineering Tsinghua University Beijing100084 China Key Laboratory of Advanced Materials Processing Technology Ministry of Education Tsinghua University Beijing100084 China State Key Laboratory of Clean and Efficient Turbomachinery Power Equipment Tsinghua University Beijing100084 China

Shell-making process is a critical step in investment casting for shape control, and breaking through the "black box" of this process remains a challenging issue in its research. This paper introduces blue light scanning technology into the study of investment casting shell processes, using samples with cantilever beam structures as research objects. It explores the influence of cantilever structure inclination angles on shell wall thickness and deformation. The feasibility and effectiveness of this method are demonstrated through numerical simulation results. This approach achieves visualization and digitalization of the layer-by-layer shell preparation process, providing a new technical pathway for investigating shell formation mechanisms. © 2024 75th World Foundry Congress, WFC 2024. All rights reserved.

关键词： Nanocantilevers

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An intrinsically self-healing and anti-freezing molecular chains induced polyacrylamide-based hydrogel electrolytes for zinc manganese dioxide batteries

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Journal of Energy Chemistry 2024年第2期89卷 565-578,I0013页

作者： Haiyang Liao Wenzhao Zhong Chen Li Jieling Han Xiao Sun Xinhui Xia Ting Li Abolhassan Noori Mir F.Mousavi Xin Liu Yongqi Zhang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Mechanical Engineering Hunan University of TechnologyZhuzhou 412007HunanChina School of Materials Science and Engineering Zhejiang University of TechnologyHangzhou 310014ZhejiangChina Department of Chemistry Faculty of Basic SciencesTarbiat Modares UniversityTehran 14117-13116Iran State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200HubeiChina

The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self-healing for meeting the rapid development of flexible and wearable devices in diverse service ***,we design a new hydrogel electrolyte(AF/SH-Hydrogel)with intrinsic anti-freezing/self-healing capabilities by introducing ethylene glycol molecules,dynamic chemical bonding(disulfide bond),and supramolecular interaction(multi-hydrogen bond)into the polyacrylamide molecular *** to the exceptional freeze resistance(84%capacity retention at-20℃)and intrinsic self-healing capabilities(95%capacity retention after 5 cutting/self-healing cycles),the obtained AF/SH-Hydrogel makes the zinc||manganese dioxide cell an economically feasible battery for the state-of-the-art *** Zn||AF/SH-Hydrogel||MnO_(2)device offers a near-theoretical specific capacity of 285 m A h g^(-1)at 0.1 A g^(-1)(Coulombic efficiency≈100%),as well as good self-healing capability and mechanical flexibility in an ice *** work provides insight that can be utilized to develop multifunctional hydrogel electrolytes for application in next generation of self-healable and freeze-resistance smart aqueous energy storage devices.

关键词： Flexible aqueous battery Hydrogel electrolyte Anti-freezing Self-healing Dual-dynamic reversible bond

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Microstructure characteristics and mechanical properties of NbMoTiVWSix refractory high-entropy alloys

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China Foundry 2022年第6期19卷 495-502页

作者： Qin Xu Qi Wang De-zhi Chen Yi-ang Fu Qing-sheng Shi Ya-jun Yin Shu-yan Zhang School of Mechanic and Electrical Engineering Henan University of TechnologyZhengzhou 450001China National Key Laboratory for Precision Hot Processing of Metals Harbin Institute of TechnologyHarbin 150001China State Key Laboratory of Materials Processing and Die&Mould Technology Huazhong University of Science&TechnologyWuhan 430074China Centre of Excellence for Advanced Materials Songshan LakeDongguan 523808GuangdongChina

Refractory high-entropy alloys are considered as potential structural materials for elevated temperature *** obtain refractory high-entropy alloys with high strength,different amounts of Si were added into the NbMoTiVW refractory high-entropy *** effects of Si on the phase constitution,microstructure characteristics and mechanical properties of NbMoTiVWSi_(x) alloys were *** show that when the addition of Si is 0,0.025 and 0.05(molar ratio),the alloys are consisted of primary BCC and secondary BCC in the intergranular *** the addition of Si is increased to 0.075 and 0.1,eutectic structure including silicide phase and secondary BCC phase is *** primary BCC phase shows dendritic morphology,and is refined by adding *** volume fraction of intergranular area is increased from 12.22%to 18.13%when the addition of Si increases from 0 to *** ultimate compressive strength of the NbMoTiVW alloy is improved from 2,242 MPa to 2,532 *** yield strength is also improved by the addition of Si,and the yield strength of NbMoTiVWSi_(0.1) reaches maximum of 2,298 ***,the fracture strain of the alloy is decreased from 15.31%to 12.02%.The fracture mechanism of the alloys is changed from mixed fracture of ductile and quasi-cleavage to cleavage fracture with increasing of *** strengthening of alloys is attributed to the refinement of primary BCC phase,volume fraction increment of secondary BCC phase,and formation of eutectic structure by addition of Si.

关键词： high-entropy alloy second phase microstructure refinement mechanical property strengthening

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Minimal Sintering Shrinkage Aluminum-Based Ceramic Cores Fabricated by Stereolithography 75

Minimal Sintering Shrinkage Aluminum-Based Ceramic Cores Fab...

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75th World Foundry Congress, WFC 2024

作者： Wang, Haoyuan Hu, Kehui Lu, Zhigang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Department of Mechanical Engineering Tsinghua University Beijing100084 China Key Laboratory of Advanced Materials Processing Technology Ministry of Education Tsinghua University Beijing100084 China State Key Laboratory of Clean and Efficient Turbomachinery Power Equipment Tsinghua University Beijing100084 China

This study explores the stereolithography-based fabrication of aluminum-based ceramic cores, aimed at minimizing sintering shrinkage. Stereolithography-based ceramic cores often exhibit significant shrinkage during sintering, limiting their applications. In this work, by adding silica and kyanite into the alumina, high mechanical performance while minimizing shrinkage were achieved. Results demonstrate that cores with 22% silica and 8% kyanite show nearly zero shrinkage, making them suitable for complex, high-precision investment casting applications. © 2024 75th World Foundry Congress, WFC 2024. All rights reserved.

关键词： Kyanite

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