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Mn,N co-doped Co nanoparticles/porous carbon as air cathode for highly efficient rechargeable Zn-air batteries Hide Author's Information

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Nano Research 2022年第3期15卷 1942-1948页

作者： Hanzhen Zheng Fei Ma Hongcen Yang Xiaogang Wu Rui Wang Dali Jia Zhixia Wang Niandi Lu Fen Ran Shanglong Peng National&Local Joint Engineering Laboratory for Optical Conversion Materials and Technology School of Physical Science and TechnologyLanzhou UniversityLanzhou 730000China State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals School of Material Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

Oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)are generally catalyzed by precious metals(Pt)and metal oxides(IrO_(2))which still have many shortages including expensive price,poor selectivity and undesirable *** this work,we report a Mn0-doped CoN_(x) on N-doped porous carbon(Mn-CoN_(x)/N-PC)composite from carbonizing metal-organic framework(MOF)derivative as the dual-functional catalyst to boost both the ORR and OER *** to the strong coordination effect between nitrogen and metal elements,the introduction of N can obviously improve the content of Co-N-C active sites for ***,the Mn-doping significantly regulates the electronic structure of the Co element and increases the content of Co^(0) which provide efficient OER active ***-CoN_(x)/N-PC catalyst delivers super dual-functional activity with a half-wave potential of 0.85 V,better than the 20%Pt/C catalyst(0.82 V).When used in Zn-air batteries for testing,Mn-CoN_(x)/N-PC electrocatalyst shows a high power density(145 mW·cm^(−2))and good cycle performance.

关键词： bifunctional electrocatalysts Co-N-C Mn-doped Zn-air batteries

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Application of in-situ characterization techniques in modern aqueous batteries

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Rare Metals 2024年第8期43卷 3553-3575页

作者： Jia-Hao Wu Hong-Wei Cai Zhao-Hui Deng Jean-Jacques Gaumet Yu Bao Wen Luo Department of Physics State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingSchool of Materials Science and EngineeringWuhan University of TechnologyWuhan430070China Laboratoire de Chimie Et Physique:Approche Multi-Echelles Des Milieux Complexes(LCP-A2MC)Institut Jean BarriolUniversitéde Lorraine57070MetzFrance Department of Medicinal Chemistry Hubei College of Chinese MedicineJingzhou 434020China

The development of high-performance aqueous batteries calls for an in-depth knowledge of their chargedischarge redox and failure mechanism,as well as a systematic understanding of the dynamic evolution of microstructure,phase composition,chemical composition,and local chemical environment of the materials for ***-situ characterization technology is expected to understand and reveal the problems faced by aqueous rechargeable batteries,such as the dissolution of electrode materials,the growth of metal negative electrode dendrites,passivation,corrosion,side reactions and a series of *** on this,typical in-situ characterization techniques and their basic mechanisms are summarized,including in-situ optical visualization,in-situ microscopy techniques(in-situ scanning electron microscopy(SEM),in-situ transmission electron microscopy(TEM)),in-situ X-ray techniques(in-situ X-ray diffraction(XRD),in-situ X-ray photoelectron spectroscopy(XPS),in-situ near-edge structural X-ray absorption spectroscopy(XANES)),and in-situ spectroscopy techniques(in-situ Raman spectroscopy,in-situ Fourier transform infrared(FTIR)).Moreover,some emerging techniques concerning aqueous battery research,especially gas evolution and materials dissolution issues,such as in-situ electrochemical quartz crystal microbalance(EQCM).in-situ fiber-optic sensing,in-situ gas chromatography(GC) are *** last,the applications of advanced in-situ characterizations in future research of aqueous batteries are emphasized and discussed,along with some of the remaining challenges and possible solutions.

关键词： Aqueous battery In-situ characterization Phase transformation Solid electrolyte interphase Zinc dendrite growth

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Low-coordination water Prussian white as cathode for high-performance potassium-ion batteries

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Chinese Chemical Letters 2021年第8期32卷 2433-2437页

作者： Yang Xia Wei Jin Yanyuan Qi Hang Li Zelang Jian Wen Chen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China

Prussian whites(PWs) with a three-dimensional framework can accommodate the insertion and extraction of ions with large radius,which have been widely used in potassium ion ***,PWs show the poor cycling performance and inferior rate ability because of high coordinated *** this work,PWs with different water content were synthesized via a coprecipitation method by controlling the reaction *** sample with low-coordination water prohibits the best electrochemical *** shows a high capacity of 120.5 mAh/g at 100 mA/g for potassium-ion batteries(KIBs).It also exhibits a good rate performance,displaying a capacity of 73.2 mAh/g at 500 mA/g.

关键词： Prussian white Potassium ion batteries Low-coordinated water Cathode Reaction temperature

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Suppression mechanisms on proliferation of glioma U251 cells by FePt nanoparticles through intracellular oxidative stress

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Rare Metals 2022年第4期41卷 1202-1209页

作者： Yao-Min Li Li-Hui Meng Yan-Ru Hu Tian-Tian Zhang Zheng-Nan Su Zhi-Yuan Ouyang Wen-Chao Li Jiang-Ling Wan Qing-Zhi Wu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing and Biomedical Materials and Engineering CentreWuhan University of TechnologyWuhan 430070China National Engineering Research Centre for Nanomedicine College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhan 430074China

FePt nanoparticles(NPs)have attracted a great deal of attention in biomedical applications due to their excellent superparamagnetic property and anticancer activity,which display promising potential as the MRI/CT contrast imag-ing agent for cancer detection and *** this study,the suppression mechanism induced by FePt NPs on U251 cells is *** U251 cells are co-cultured with FePt NPs at different concentrations,and the intra-cellular oxidative stress was studied by detecting the activities of various redox enzymes and expression of several apoptosis-related *** cell viability assay shows that the highest suppression on the proliferation of glioma U251 cells is 10.5%±5.6%after treatment with 5μg·ml^(-1)FePt NPs for 24 *** this case,the LDH release remarkably *** cytometry and fluorescence assay show that FePt NPs promote the apoptosis and G0/G1 phase arrest of U251 cells.

关键词： nanoparticles U251 stress

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Thermoelectric Properties of an Individual Suspended Single-Crystalline Sb_(2)Se_(3)Nanowire

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Journal of Thermal Science 2022年第4期31卷 1106-1114页

作者： DU Yanzheng SHI Shaoyi MIAO Tingting MA Weigang MAI Liqiang ZHANG Xing Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering Mechanics Tsinghua UniversityBeijing 100084China Beijing Key Laboratory of Process Fluid Filtration and Separation College of Mechanical and Transportation EngineeringChina University of PetroleumBeijing 102249China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Nanowires exhibit excellent thermoelectric performance,due to the stronger quantum confinement and phonon scattering effect compared to bulk ***,it is a challenge to accurately evaluate the thermoelectric performance of *** this paper,the thermoelectric properties of an individual suspended Sb_(2)Se_(3) nanowire have been characterized by comprehensive T-type method,including thermal conductivity,electrical conductivity,Seebeck coefficient and figure of *** thermal conductivity increases from 0.57 W/(m·K)to 3.69 W/(m·K)with temperature increasing from 80 K to 320 *** lattice vibration dominates the heat conduction process,and due to its flawless crystal structure,the thermal conductivity is not lower than the reported values of bulk Sb_(2)Se_(3).The electrical conductivity increases from 7.83 S/m to 688 S/m in the temperature range of 50 K–320 K,which is a great improvement compared with the corresponding bulk *** 294 K,the Seebeck coefficient of the Sb_(2)Se_(3) nanowire is–1120μV/K and the corresponding figure of merit is 0.064.

关键词： Sb_(2)Se_(3)nanowire thermoelectric properties thermal conductivity Seebeck coefficient electrical conductivity

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Cu-N-C support confinement stabilizes active Co sites in oxygen reduction reaction

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Nano Research 2025年第5期18卷 134-144页

作者： Longyang Zhang Wei Sang Tingting Wang Xiaoyu Wei Zihan Li Cheng Chen Zongkui Kou Shichun Mu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China School of Mathematical and Physical Sciences Wuhan Textile UniversityWuhan 430200China

Strengthening the operational durability of oxygen reduction reaction(ORR)catalysts is essential for advancing both fuel cells and metal-air ***,developing highly active and durable catalysts remains a significant *** this study,a catalyst(Co/Cu-N-C)featuring uniformly distributed Co nanoparticles(NPs)and Co/Cu sites has been synthesized via a facile complex-assisted pyrolysis *** observed that Cu-N-C support effectively confines the growth and leaching of Co NPs during both synthesis and ORR catalysis,thereby boosting the stability of the ***,the presence of Co NPs and Cu sites slightly contributes to the ORR activity by optimizing the ^(*)OH *** assembled zinc-air battery(ZAB)demonstrates a superhigh power density of 256.1 mW·cm^(−2)and a long-term operational stability exceeding 500 *** work not only underscores the potential of bimetallic systems and NPs in enhancing catalyst stability but also provides valuable insights for the synthesis of high-performance ORR electrocatalysts.

关键词： metal nitrogen-doped carbon materials(M-N-C) stability oxygen reduction reaction(ORR) zinc-air batteries(ZABs) fuel cells

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Wet-milling synthesis of immobilized Pt/Ir nanoclusters as promising heterogeneous catalysts

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Nano Research 2022年第4期15卷 3065-3072页

作者： Peng Du Kai Huang Xiaoyuan Fan Jingteng Ma Naveed Hussain Ruyue Wang Bohan Deng Binghui Ge Haolin Tang Ru Zhang Ming Lei Hui Wu State Key Laboratory of Information Photonics and Optical Communications&School of Science Beijing University of Posts and TelecommunicationsBeijing 100876China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Institutes of Physical Science and Information Technology Anhui UniversityHefei 230601China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Being a typical state of the art heterogeneous catalyst,supported noble metal catalyst often demonstrates enhanced catalytic ***,a facile synthetic method for realizing large-scale and low-cost supported noble metal catalyst is strictly *** this end,by making use of the strong metal-support interaction(SMSI)and mechanochemical reaction,we introduce an efficient synthetic route to obtain ultrafine Pt and Ir nanoclusters immobilized on diverse substrates by wet chemical *** further demonstrate the scaling-up effect of our approach by large-scale ball-milling production of Pt nanoclusters immobilized on TiO_(2)*** synthesized Pt/Ir@Co_(3)O_(4)catalysts exhibit superior oxygen evolution reaction(OER)performance with only 230 and 290 mV overpotential to achieve current density of 10 and 100 mA·cm^(-2),beating the catalytic performance of Co_(3)O_(4)supported Pt or Ir clusters and commercial Ir/*** is envisioned that the present work strategically directs facile ways for fabricating supported noble metal heterogeneous catalysts.

关键词： heterogeneous catalysts metal clusters wet milling large-scale production strong metal–support interaction

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Pressure-driven metallization with significant changes of structural and photoelectric properties in two-dimensional EuSbTe_(3)

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Rare Metals 2024年第11期43卷 5943-5952页

作者： Zhi-Kai Zhu Zhong-Yang Li Zhen Qin Yi-Ming Wang Dong Wang Xiao-Hui Zeng Fu-Yang Liu Hong-Liang Dong Qing-Yang Hu Ling-Ping Kong Hao-Zhe Liu Wen-Ge Yang Yan-Feng Guo Shuai Yan Xuan Fang Wei He Gang Liu State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materialsand School of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China Center for High Pressure Science and Technology Advanced Research(HPSTAR) Shanghai 201203China School of Physical Science and Technology ShanghaiTech UniversityShanghai 201210China Poly Technologies INCBeijing 100010China ShanghaiTech Laboratory for Topological Physics ShanghaiTech UniversityShanghai 201210China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201204China Sch Sci State Key Lab High Power Semicond LasersChangchun University Science and TechnologyChangchun 130022China Shanghai Key Laboratory of Material Frontiers Research in Extreme Environments(MFree) Shanghai Advanced Research in Physical Sciences(SHARPS)Shanghai 201203China

Two-dimensional materials are widely considered to be highly promising for the development of *** improve the performance of these devices,researchers often employ techniques such as defect ***,pressure is employed as a clean and novel means to manipulate the structural and physical properties of EuSbTe_(3),an emerging two-dimensional *** experimental results demonstrate that the structural phase transformation of EuSbTe_(3)occurs under pressure,with an increase in infrared reflectivity,a band gap closure,and a metallization at *** with X-ray diffraction(XRD)and Raman characterizations,it is evident that the pressure-driven transition from semiconductor Pmmn phase to metallic Cmcm phase causes the disappearance of the charge density ***,at a mild pressure,approximately 2 GPa,the maximum photocurrent of EuSbTe_(3)is three times higher than that at ambient condition,suggesting an untapped potential for various practical applications.

关键词： Pressure Phase transition Metallization Photoresponse Two-dimensional(2D)

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Internal magnetic-field-enhanced photogenerated charge separation in ferromagnetic TiO_(2)surface heterojunctions

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Journal of materials Science & technology 2023年第29期160卷 240-247页

作者： Guojing Wang Shirong Xiong Yonghui Chen Chunchang Wang Shasha Lv Ke Jia Yunjie Xiang Jianbo Liu Chong Liu Zhengcao Li School of Materials and Energy Lanzhou UniversityLanzhou 730000China State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials(MOE)School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Laboratory of Dielectric Functional Materials School of Physics and Material ScienceAnhui UniversityHefei 230601China Key Laboratory of Beam Technology Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China School of Materials and Energy Southwest UniversityChongqing 404100China

The use of the internal magnetic field of ferromagnets can effectively promote charge separation and transfer(CST)in photoelectrochemical energy ***,photoelectrochemical materials with a ferromagnetic field are scarce,and the internal magnetic field is negligible in nonferromagnetic *** address this issue,we propose a rational method for preparing ferromagnetic TiO_(2)powder using controllable oxygen vacancies in anatase TiO_(2)with co-exposed{001}and{101}***,an ex-cellent saturation magnetisation of 0.0014 emu/g in TiO_(2)is achieved owing to an asymmetric and uneven charge *** with that of nonferromagnetic TiO_(2),the efficiency of photocatalytic hydro-gen generation of ferromagnetic TiO_(2)is improved by 0.64 *** enhancement of photocatalytic hy-drogen generation is due to the different forces exerted on the electrons and holes in the magnetic field,which significantly improve the photogenerated CST efficiency of ferromagnetic TiO_(2).This result high-lights the significant role of the synergistic regulation of the crystal structure and defects in regulating the ferromagnetic characteristics of *** findings of this study provide guidance for leveraging point defects to promote CST for high-efficiency solar-energy conversion systems.

关键词： Photocatalysis TiO_(2){001}-{101}surface heterojunctions Oxygen vacancies Ferromagnetic

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Niobium oxyphosphate nanosheet assembled two-dimensional anode material for enhanced lithium storage

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Journal of Energy Chemistry 2021年第2期30卷 268-275,I0009页

作者： Bo Wen Ruiting Guo Xiong Liu Wen Luo Qiu He Chaojiang Niu Jiashen Meng Qi Li Yan Zhao Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070HubeiChina Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528216GuangdongChina

The development of high-capacity and high-rate anodes has become an attractive endeavor for achieving high energy and power densities in lithium-ion batteries(LIBs).Herein,a new-type anode material of reduced graphene oxide(rGO) supported niobium oxyphosphate(NbOPO_4) nanosheet assembled twodimensional composite material(NbOPO_4/rGO) is firstly fabricated and presented as a promising highperformance LIB anode ***-depth electrochemical analyses and in/ex situ characterizations reveal that the intercalation-conversion reaction takes place during the first discharge process,followed by the reversible redox process between amorphous NbPO_4 and Nb which contributes to the reversible capacity in the subsequent ***,the lithiation-generated Li3 PO_4,behaving as a good lithium ion conductor,facilitates ion *** rGO support further regulates the structural and electron/ion transfer properties of NbOPO_4/rGO composite compared to neat NbOPO_4, resulting in greatly enhanced electrochemical *** a result,NbOPO_4/rGO as a new-type LIB anode material achieves a high capacity of 502.5 mAh g^(-1) after 800 cycles and outstanding rate capability of 308.4 mAh g^(-1) at 8 A g^(-1).This work paves the way for the deep understanding and exploration of phosphate-ba sed high-efficiency anode materials for LIBs.

关键词： 2D nanomaterials Niobium oxyphosphate High-rate anode Lithium storage mechanism Lithiation-induced amorphization

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