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Full-Spectrum Fluoromethyl Sulfonation via Modularized Multicomponent Coupling

CCS Chemistry 2022年第5期4卷 1526-1534页

作者： Kejie Li Ming Wang Xuefeng Jiang Shanghai Key Laboratory of Green Chemistry and Chemical Process School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062 State Key Laboratory of Elemento-Organic Chemistry Nankai UniversityTianjin 300071

Modular free-assembly construction of mono-,di-,and tri-fluoromethyl sulfones was comprehensively achieved by a combination of halides,a sulfur dioxide surrogate,and *** industrial raw material thiourea dioxide served as the sulfur dioxide source,combined with readily available fluorocarbon sources such as 2-bromo-2-fluoroacetate and chlorodifluoromethane(ClCF_(2)H,Freon)employed as fluoromethyl ***,four methyl sulfone-containing pharmaceuticals were modified into three types of fluoromethyl sulfones,displaying their great potential for drug discovery via the current *** studies further demonstrated that C-F…H-N interactions between thiourea dioxide and halofluorocarbons play a key role in stabilizing monofluoromethyl electrophiles and difluorocarbene species.

关键词： sulfone trifluoromethyl sulfone difluoromethyl sulfone monofluoromethyl sulfone thiourea dioxide

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Biosorbent silver nanoparticles decorated coffee-ground waste composite for cleaning water and antimicrobial applications

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Environmental Science and Pollution Research 2025年第5期32卷 2280-2297页

作者： Al-Ghamdi, Azza A. Ibrahim, Sherif M. Lu, Xingmei Xin, Jiayu El-Sayed, Ibrahim El-Tantawy Galhoum, Ahmed A. Wageh, Swelm. Department of Chemistry College of Science Imam Abdulrahman Bin Faisal University P.O. Box 1982 Dammam31441 Saudi Arabia Renewable and Sustainable Energy Unit Imam Abdulrahman Bin Faisal University P.O. Box 1982 Dammam31441 Saudi Arabia Nuclear Materials Authority P.O. Box 530 El-Maadi Cairo Egypt Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex Systems Innovation Academy for Green Manufacture Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China School of Chemistry and Chemical Engineering University of Chinese Academy of Sciences Beijing100049 China Sino Danish College University of Chinese Academy of Sciences Beijing100049 China Chemistry Department Faculty of Science Menoufia University Shebin El-Kom Egypt Department of Physics Faculty of Science King Abdulaziz University Jeddah21589 Saudi Arabia

A sustainable biosorbent, silver nanoparticles-decorated coffee-ground waste (CWAg), was synthesized through a simple in-situ reduction method. CWAg is extensively characterized via SEM–EDX, PZC, FTIR, XRD, HR-TEM, and XPS analyses. The biosorbent was tested to remove chromium (Cr(VI)) and methylene blue (MB) from wastewater, and its antibacterial properties was evaluated. CWAg demonstrated efficient sorption efficiencies, achieving ⁓149.9 mg/g at 323 K and pH: 2.0 for Cr(VI) and ⁓113.4 mg/g at 293 K and pH: 6.0 for MB, at a biosorbent dose of 1 g/L. The equilibration times were 90 and 120 min for Cr(VI) and MB, with half-sorption times (tHST) of 9.2 and 13.9 min, respectively. The sorption mechanisms were successfully fitted with Sips isotherm and Pseudo-second-order models. Simultaneous sorption of MB and Cr(VI) at pH 2.0 exhibited antagonism, while a synergistic effect was observed at pH 6.0. Desorption and regeneration were achieved using NaOH and HCl solutions for Cr(VI) and MB, respectively. The efficiencies were just reduced by 9–13%. Finally, CWAg exhibited remarkable effectiveness for removing Cr(VI) from complex tannery effluent. Moreover, CWAg demonstrated positive antibacterial effects against both Gram-positive and Gram-negative bacteria, surpassing raw coffee-ground waste, underscoring the significant role of silver nanoparticles in enhancing bacterial inhibition. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Silver nanoparticles

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Depolymerization Performance of Pd/Al2O3on Ether Biomass Model Molecules under Continuous Flow Reaction 3

Depolymerization Performance of Pd/Al2O3on Ether Biomass Mod...

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3rd International Conference on Advanced Material and Clean Energy, ICAMCE 2022

作者： Xu, Jinyun Li, Ming Ma, Chao Sun, Yu Li, Minjing Zhong, Guoqiang Zhao, Di Hu, Xudong Su, Han Yan, Zhangyong Cao, Jingran Xu, Chao Zheng, Chunming Sun, Xiaohong School of Chemical Engineering Tianjin Key Laboratory of Green Chemical Technology and Process Engineering State Key Laboratory of Separation Membrane and Membrane Processes Tianjin300387 China School of Materials Science and Engineering Key Laboratory of Advanced Ceramics and Machining Technology Ministry of Education Tianjin300072 China

The ether model molecules BPE (phenylbenzyl ether), diphenyl ether (DPE) and phenoxyethylbenzene (PPE) of lignin were used as degradation raw materials, and Pd-Al2O3 was used as catalyst to react in batch reactor and continuous reactor, respectively. Pd-Al2O3 showed good degradation performance in batch reaction. The catalytic performance of three substances was compared in a flow reactor. The reasons of catalyst deactivation and the products adsorbed on the surface during the hydrogenolysis of BPE were studied. © Published under licence by IOP Publishing Ltd.

关键词： Ethers

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Structural and Interfacial Microenvironment Modulation of Two-Dimensional Layered Niobium Phosphate to Enhance Uranium Adsorption

SSRN

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SSRN 2024年

作者： Zhao, Yue Ni, Shan Liu, Yafeng Wang, Wenjie Meng, Yuan Xing, Huifang Liu, Huizhou Yang, Liangrong Key Laboratory of Green and High-end Utilization of Salt Lake Resources State Key Laboratory of Petroleum Molecular & Process Engineering RIPP SINOPEC CAS Key Laboratory of Green Process and Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China School of Chemical Engineering University of Chinese Academy of Sciences Beijing100049 China

To address the environmental and resource challenges arising from the advancement of the nuclear power industry, it becomes imperative to foster the development of efficient and expeditious materials for uranium adsorption. Here, for the first time, a kind of niobium phosphate with improvement of interlayer spacing and hydrophilicity (NbP-8) is employed by crystal phase modulation for uranium adsorption, which synergistically realizes structural and interfacial microenvironment modulation. Characterizations demonstrate that the expanded interlayer spacing contributes to accommodation of uranyl which increases adsorption capacity, and the enhanced hydrophilicity reduces infiltration time and greatly accelerates the adsorption rate. Consequently, NbP-8 possesses exceptional adsorption capacity of 1470.39 mg g-1, ultra-fast adsorption rate with an equilibrium time of 1 min and high selectivity, delivering one of the best phosphate uranium adsorbents. Moreover, this work opens a new venue for optimizing performance of phosphate by changing the crystal phase to modulate structure and interfacial microenvironment for uranium adsorption. © 2024, The Authors. All rights reserved.

关键词： Hydrophilicity

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Hollow structures as drug carriers:Recognition,response,and release

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Nano Research 2022年第2期15卷 739-757页

作者： Decai Zhao Nailiang Yang Lekai Xu Jiang Du Yang Yang Dan Wang State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Green Catalysis Center and College of ChemistrySchool of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001 China Department of Thoracic Surgery Shanghai Pulmonary HospitalSchool of MedicineTongji UniversityShanghai 200433China School of Materials Science and Engineering Tongji UniversityShanghai 201804China

Hollow structures have demonstrated great potential in drug delivery owing to their privileged structure,such as high surface-to-volume ratio,low density,large cavities,and hierarchical *** this review,we provide a comprehensive overview of hollow structured materials applied in targeting recognition,smart response,and drug release,and we have addressed the possible chemical factors and reactions in these three *** advantages of hollow nanostructures are summarized as follows:hollow cavity contributes to large loading capacity;a tailored structure helps controllable drug release;variable compounds adapt to flexible application;surface modification facilitates smart responsive ***,because the multiple physical barriers and chemical interactions can be induced by multishells,hollow multishelled structure is considered as a promising material with unique loading and releasing ***,we conclude this review with some perspectives on the future research and development of the hollow structures as drug carriers.

关键词： hollow structure drug delivery system carriers spatiotemporal

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Ru(bpy)_(3)^(2+)-sensitized{001}facets LiCoO_(2) nanosheets catalyzed CO_(2) reduction reaction with 100% carbonaceous products

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Nano Research 2022年第2期15卷 1061-1068页

作者： Shuaiyu Jiang Junxian Liu Kun Zhao Dandan Cui Porun Liu Huajie Yin Mohammad Al-Mamun Sean ELowe Weiping Zhang Yu Lin Zhong Jun Chen Yun Wang Dan Wang Huijun Zhao Centre for Catalysis and Clean Energy Gold Coast campusGriffith UniversityQLD 4222Australia Intelligent Polymer Research Institute and ARC Centre of Excellence for Electromaterials Science University of WollongongWollongongNSW 2500Australia Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangzhou Key Laboratory of Environmental Catalysis and Pollution ControlSchool of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China State Key Laboratory of Biochemical Engineering CAS Centre for Excellence in NanoscienceInstitute of Process EngineeringChinese Academy of ScienceBeijing 100190China

Photosensitized heterogeneous CO_(2) reduction(PHCR)has emerged as a promising means to convert CO_(2) into valuable chemicals,however,challenged by the relatively low carbonaceous product selectivity caused by the competing hydrogen evolution reaction(HER).Here,we report a PHCR system that couples Ru(bpy)32+photosensitizer with{001}faceted LiCoO_(2) nanosheets photocatalyst to simultaneously yield 21.2 and 722μmol·g^(-1)·h^(-1) of CO,and 4.42 and 108μmol·g^(-1)·h^(-1) of CH4 under the visible light and the simulated sunlight irradiations,respectively,with completely suppressed *** experimental and theoretical studies reveal that the favored CO_(2) adsorption on the exposed Li sites on{001}faceted LiCoO_(2) surface is responsible for the completely suppressed HER.

关键词： homogeneous-heterogeneous catalysis system ultrathin LiCoO_(2)nanosheets photocatalytic CO_(2)reduction suppressed hydrogen evolution reaction

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Electroreduction of carbon dioxide to multi-electron reduction products using poly(ionic liquid)-based Cu-Pd catalyst

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Fundamental Research 2022年第6期2卷 937-945页

作者： Xiao-Qiang Li Guo-Yi Duan Xian-Xia Yang Li-Jun Han Bao-Hua Xu Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and EngineeringState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China National Fundamental Research Laboratory of New Hazardous Chemicals Assessment and Accident Analysis Institute of Applied ElectrochemistryBeijing University of Chemical TechnologyBeijing 100029China

Electrocatalytic reduction of CO_(2)(CO_(2)RR)to multi-electron(>2e–)products provides a green and sustainable route for producing fuels and *** the second metal element is a feasible strategy for"managing"the key intermediate on Cu-based materials to further improve the CO_(2)RR catalytic *** this work,palladium,which promises the generation of CO,was introduced into the poly(ionic liquid)-based copper hybrid(Cu@PIL)to construct a novel Cu-Pd bimetallic electrocatalyst(Cu@PIL@Pd).Remarkably,with a small dosage of palladium(2.0 mol%compared with Cu),a high faradaic efficiency(FE)for C_(2+)products(68.7%)was achieved at–1.01 V(with respect to the reversible hydrogen electrode(RHE),the same below)with a high partial current density of 178.3 mA cm^(-2).Meanwhile,high selectivity towards CH4(FE=42.5%)and corresponding partial current density of 172.8 mA cm^(-2)were obtained on the same catalyst at–1.24 V,signifying a significant potential-dependent *** studies reveal that both copper and palladium oxides are reduced to metallic states during the CO_(2)*** presence of the adjoint copper phase and the highly dispersed electrostatic layer promote the generation of CO on the palladium components(both the PdO_(2)phase and the Pd(II)site).Besides,the local CO^(*)was enriched by the significant diffusion resistance of CO in the PIL *** spillover of CO^(*)from Pd sites to the adjoint Cu sites,accompanied by the increased local concentration of CO^(*)around Cu sites,accounted for the observed good CO_(2)RR catalytic performance,especially the high C_(2+)product selectivity.

关键词： CO_(2)conversion Bimetallic catalyst Cu-Pd material Electrolysis High-value products

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Rational design of efficient visible-light photocatalysts(1D@2D/0D)ZnO@Ni-doped BiOBr/Bi heterojunction:Considerations on hierarchical structures,doping and SPR effect

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Journal of Materials Science & Technology 2022年第30期125卷 38-50页

作者： Zhouzheng Jin Jingru Li Yiming Zhang Dan Liu Hui Ding Bhekie B.Mamba Alex T.Kuvarega Jianzhou Gui State Key Laboratory of Separation Membranes and Membrane Processes Tianjin Key Laboratory of Green Chemical Technology and Process Engineeringand School of Material Science and EngineeringTiangong UniversityTianjin 300387China School of Chemical Engineering and Technology Tiangong UniversityTianjin 300387China School of Chemistry Tiangong UniversityTianjin 300387China School of Environmental Science and Engineering Tianjin UniversityTianjin300072China University of South Africa College of ScienceEngineering and TechnologyNanotechnology and Water Sustainability Research UnitFlorida Science Campus 1710South Africa

Simultaneously integrating heterogeneous interface,element doping,and metal decorating was a promising strategy to promote the visible-light-driven photocatalytic ***,we demonstrated a facile solvothermal route for Ni-doped BiOBr/Bi^(0) with ZnO 3D hierarchical heterojunction(denoted as Z@B/BiNi).The optimal photocatalysts of Z@B/Bi-Ni sample presented a remarkable catalytic performance of high concentrations of tetracycline solution(40 mg/L)than those of the Z@B/Bi,Z@B,BOB and ZnO photocatalysts toward the visible-light-driven *** enhanced photocatalytic mechanism can be proposed as follows:(ⅰ)3D hierarchical heterojunction provided more active sites and accelerated the separation of charge carriers for photocatalytic TC;(ⅱ)formation of oxygen vacancies on the surface over Z@B/Bi-Ni by in-situ reduction of Bi^(0) and Ni doping could serve as the active sites for oxygen activation to adsorb free O_(2) and generate more superoxide radicals;(ⅲ)SPR effect of Bi metal were beneficial to carrier separation and also act as the active site to trap O_(2) *** work clarified the role of unique morphologies,surface plasmonic resonance(SPR)effect of metal Bi,and Ni doping in Z@B/Bi-Ni,and its photocatalytic reaction mechanism was proposed by a series of experiments,characterization and DFT calculations,arousing a new perspective to design hierarchical heterojunction photocatalysts.

关键词： Hierarchical heterojunction Oxygen vacancies Doping Ni SPR effect Photocatalysis

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Dissolution and reconstruction of organic ligands in electrocatalysts for efﬁcient OER

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Science Bulletin 2024年第21期69卷 3311-3313页

作者： Lisong Chen Jianlin Shi State Key Laboratory of Petroleum Molecular and Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical ProcessesSchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062China State Key Laboratory of High Performance Ceramics and Superﬁne Microstructures Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China Institute of Eco-Chongming Shanghai 202162China

Electrocatalytic water splitting is a highly promising method for green hydrogen production,which is highly important for sustainable and low-carbon societal *** tremendous scientiﬁc and technological efforts dedicated to thisﬁeld,its practical application faces challenges owing to heavy energy consumption,mostly from the elevated potentials needed for the oxygen evolution reaction(OER)at the anode[1].Strategies such as developing efﬁcient OER electrocatalysts and using sacriﬁcial agents or electrosynthesis-assisted water splitting have emerged,collectively known as‘‘electrocatalytic hydrogen production trilogy”[2,3].While the latter two strategies show potential,especially the last one,they are still in the early development ***,there is a pressing need for efﬁcient OER electrocatalysts to promote the commercialization of electrocatalytic water splitting.

关键词： splitting collective latter

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Gas-phase synthesis of Ti_(2)CCl_(2) enables an efficient catalyst for lithiumsulfur batteries

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The Innovation 2024年第1期5卷 33-40页

作者： Maoqiao Xiang Zihan Shen Jie Zheng Miao Song Qiya He Yafeng Yang Jiuyi Zhu Yuqi Geng Fen Yue Qinghua Dong Yu Ge Rui Wang Jiake Wei Weiliang Wang Haiming Huang Huigang Zhang Qingshan Zhu Chuanfang John Zhang State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of the Chinese Academy of SciencesBeijing 100049China Innovation Academy for Green Manufacture Chinese Academy of SciencesBeijing 100190China China Nuclear Power Engineering Co. Ltd.117 West Third Ring RoadNorth SectionBeijing 100840China College of Materials Science&Engineering Sichuan UniversityChengdu 610065China State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China School of Physics Guangdong Province Key Laboratory of Display Material and TechnologyCenter for Neutron Science and TechnologySun Yat-sen UniversityGuangzhou 510275China Solid State Physics&Material Research Laboratory School of Physics and Materials ScienceGuangzhou UniversityGuangzhou 510006China

MXenes have aroused intensive enthusiasm because of their exotic properties and promising ***,to date,they are usually synthesized by etching *** synthetic technologies provides more opportunities for innovation and may extend unexplored ***,we report a bottom-up gas-phase synthesis of Cl-terminated MXene(Ti_(2)CCl_(2)).The gas-phase synthesis endows Ti_(2)CCl_(2) with unique surface chemistry,high phase purity,and excellent metallic conductivity,which can be used to accelerate polysulfide conversion kinetics and dramatically prolong the cyclability of Li-S ***-depth mechanistic analysis deciphers the origin of the formation of Ti_(2)CCl_(2) and offers a paradigm for tuning MXene chemical vapor *** brief,the gas-phase synthesis transforms the synthesis of MXenes and unlocks the hardly achieved potentials of MXenes.

关键词： synthesis phase lithium

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