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Fabrication of hierarchical MXene-based AuNPs-containing core-shell nanocomposites for high efficient catalysts

Green Energy & Environment 2018年第2期3卷 147-155页

作者： Kaikai Li Tifeng Jiao Ruirui Xing Guodong Zou Qianran Zhao Jingxin Zhou Lexin Zhang Qiuming Peng Hebei Key Laboratory of Applied Chemistry School of Environmental and Chemical Engineering Yanshan University State Key Laboratory of Metastable Materials Science and Technology Yanshan University State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences

MXene is a new type of layered two-dimensional transition metal carbide materials differing from graphene, demonstrating intriguing chemical/physical properties. Here the chemical modification of MXene and next fabrication of core-shell MXene-COOH@(PEI/PAA)_n composites have been investigated. The obtained MXene-based composites were treated with gold nanoparticles to form MXene—COOH@(PEI/PAA)_n@AuNPs nanocomposites, and their catalytic properties for nitro-compounds were studied. The prepared nanocomposites demonstrated good catalytic activity and reproducibility, showing potential applications in composite catalysts and environmental fields.

关键词： MXene Core-shell composite Nitro-compounds Gold nanoparticle Catalytic activity

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先进材料制造中的混合强化（英文）

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engineering 2025年第1期 135-144页

作者：杨超初广文冯鑫李燕斌陈杰王丹段晓霞陈建峰 State Key Laboratory of Biochemical Engineering&Key Laboratory of Green Process and Engineering Institute of Process Engineering Chinese Academy of Sciences School of Chemical Engineering University of Chinese Academy of Sciences State Key Laboratory of Organic–Inorganic Composites Beijing University of Chemical Technology Research Center of the Ministry of Education for High Gravity Engineering and Technology Beijing University of Chemical Technology

The mixing process plays a pivotal role in the design, optimization, and scale-up of chemical reactors. For most chemical reactions, achieving uniform and rapid contact between reactants at the molecular level is crucial. Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors, enabling efficient reaction scaling and boosting the productivity of industrial processes. This review provides a concise introduction to the fundamentals of multiphase mixing, followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials, advanced optical materials, and nanopesticides. These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry. We also explore the challenges and opportunities in this field, offering insights based on our current understanding.

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Comparative studies on fouling of homogeneous anion exchange membranes by different structured organics in electrodialysis

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Journal of Environmental Sciences 2019年第3期31卷 218-228页

作者： Zhijuan Zhao Shaoyuan Shi Hongbin Cao Yujiao Li Bart Van der Bruggen Division of Environment Technology and Engineering CAS key Laboratory of Green Process and Engineering Beijing Research Center of Process Pollution Control State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences University of Chinese Academy of Sciences Department of Chemical Engineering KU Leuven Zhengzhou Institute of Emerging Industrial Technology Faculty of Engineering and the Built Environment Tshwane University of Technology

Five negatively charged organic compounds with different structures, sodium methane sulfonate(MS), sodium benzene sulfonate(BS), sodium 6-hydroxynaphthalene-2-sulfonate(NSS), sodium dodecyl sulfate(SDS), and sodium dodecyl benzene sulfonate(SDBS), were used to examine the fouling of an anion exchange membrane(AEM) in electrodialysis(ED),to explore the effect of molecular characteristics on the fouling behavior on the AEM and changes in the surface and electrochemical properties of the AEM. Results indicated that the fouling degree of the AEM by the different organics followed the order:SDBS > SDS > NSS > BS > MS. SDBS and SDS formed a dense fouling layer on the surface of the AEM, which was the main factor in the much more severe membrane fouling, and completely restricted the transmembrane ion migration. The other three organics caused fouling of the AEM by adsorption on the surface and/or accumulation in the interlayer of the AEM, and exhibited almost no influence on the transmembrane ion migration. It was also concluded that the organics with benzene rings caused more severe fouling of the AEM due to the stronger affinity interaction and steric effect between the organics and the AEM compared with organics with aliphatic chains.

关键词： Anion exchange membrane Different structural organics Membrane fouling Property characterization Fouling mechanism analyses

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Interfacial engineering of transition-metal sulfides heterostructures with built-in electric-field effects for enhanced oxygen evolution reaction

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Chinese Journal of Chemical engineering 2022年第1期35卷 320-328页

作者： Shan Ni Hongnan Qu Huifang Xing Zihao Xu Xiangyang Zhu Menglei Yuan Meng Rong Li Wang Jiemiao Yu Yanqing Li Liangrong Yang Huizhou Liu CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Biochemical EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of SciencesQingdao 266061China

Developing highly efficient,durable,and non-noble electrocatalysts for the sluggish anodic oxygen evolution reaction(OER)is the pivotal for meeting the practical demand in water ***,the current transition-metal electrocatalysts still suffer from low activity and durability on account of poor interfacial reaction *** this work,a facile solid-state synthesis strategy is developed to construct transition-metal sulfides heterostructures(denoted as MS_(2)/NiS_(2),M=Mo or W)for boosting OER *** a result,MoS2/NiS2 and WS2/NiS2 show lower overpotentials of 300 mV and 320 mV to achieve the current density of 10 mA·cm^(-2),and smaller Tafel slopes of 60 ***^(-1) and 83 ***^(-1)in 1 mol·L^(-1) KOH,respectively,in comparison with the single MoS2,WS2,NiS2,as well as even the benchmark *** experiments reveal that the designed heterostructures have strong electronic interactions and spontaneously develop a built-in electric field at the heterointerface with uneven charge distribution based on the difference of band structures,which promote interfacial charge transfer,improve absorptivity of OH-,and modulate the energy level more comparable to the ***,the designed transition-metal sulfides heterostructures exhibit a remarkably high electrocatalytic activity for *** study provides a simple strategy to manipulate the heterostructure interface via an energy level engineering method for OER and can be extended to fabricate other heterostructures for various energy-related applications.

关键词： Oxygen evolution reaction Transition-metal sulfides heterostructures Heterointerface Built-in electric field

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Pyrite oxidation in column at controlled redox potential of 900 mV with and without bacteria

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Rare Metals 2022年第12期41卷 4279-4288页

作者： He-Yun Sun Qiao-Yi Tan Yan Jia Rong-Bo Shu Shui-Ping Zhong Ren-Man Ruan State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of ScienceBejing 100190China Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of ScienceBejing 100190China National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology Institute of Process EngineeringChinese Academy of ScienceBeijing 100190China Institute of Multipurpose Utilization of Mineral Resources Chinese Academy of Geological SciencesChengdu 610041China State Key Laboratory of Gold Extraction Zijin Mining Group Co.Ltd.Shanghang 364200China

Comparisons on the bioleaching and sterile oxidation of pyrite were performed at controlled redox potential of 900 mV(***) and different temperatures of 30 and 60℃.For sterile experiments,the redox potential of irrigation solution was controlled by adding hydrogen peroxide solution(15 wt%),while the redox potential of irrigation solution for bioleaching was elevated by flowing through the packed bed in which bacteria were activated and *** rate of pyrite bioleaching is faster than that of sterile oxidation at temperature of 30℃.The reason is that the potential gradient of leaching solution in bioleaching column is much smaller than that in sterile *** redox potentials of irrigation solution and leaching solution are similar for bioleaching;however,the redox potential difference of irrigation solution and leaching solution for sterile oxidation is about 150 *** temperature increases to 60℃ for sterile oxidation,the rate of pyrite leaching is faster than that of bioleaching at temperature of 30℃,even though the redox potential gradient of leaching solution is *** mineralogy analyses of pyrite residue were performed by scanning electron microscopy-energy-dispersive spectroscopy(SEM-EDS),X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS) *** results confirm that pyrite oxidation might only occur at specific sites with high surface energy on surface and obeys the "indirect mechanism" whether there are bacteria or *** pyrite oxidation rate is not inhibited by inert sulfur on residue surface at elevated redox *** to the conclusions,the way to accelerate pyrite oxidation is proposed.

关键词： Pyrite column leaching Temperature Controlled redox potential Bacteria

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Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO_2 electrodes in the oxidation of 4-chlorophenol

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Journal of Environmental Sciences 2007年第11期19卷 1380-1386页

作者： KONG Jiang-tao SHI Shao-yuan ZHU Xiu-ping NI Jin-ren Key Laboratory of Water and Sediment Sciences Ministry of Education of China Department of Environmental Engineering Peking University Beijing 100871 China State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing 100080 China

Ti/Sb-SnO2 anodes were prepared by thermal decomposition to examine the influence of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol. The physicochemical properties of the Sb-SnO2 coating were markedly influenced by different amounts of Sb dopant. The electrodes, which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks, compared with Ti/Sb-SnO2 electrodes containing 10% or 15% Sb dopant, which exibited larger mud cracks and pores on the surface. However, the main microstructure remained unchanged with the addition of the Sb dopant. No new crystal phase was observed by X-ray diffraction （XRD）. The electrochemical oxidation of 4-chlorophenol on the Ti/SnO2 electrode with 5% Sb dopant was inclined to electrochemical combustion; while for those containing more Sb dopant, intermediate species were accumulated. The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm^2 for 180 min; and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%, respectively.

关键词： 4-chlorophenol cyclic voltammogram electrochemical oxidation Sb dopant Ti/Sb-SnO2 electrode

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Significant enhancement in local thermal conductivity of erythritol at interface with nanoparticles due to their interaction

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Nano Research 2024年第8期17卷 7726-7736页

作者： Ning Cao Yanhui Feng Kening Yan Zihan Liu Jiawei Wan Lin Qiu School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Biochemical Engineering Key Laboratory of Biopharmaceutical Preparation and DeliveryInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

When nano-fillers are used to enhance the thermal conductivity of organic phase change materials(PCMs),the naturally formed interface is considered to hinder thermal transport of the composite ***,the effect of the interface on the thermal properties of surrounding PCM has not been fully *** this paper,three composite PCMs(Ery@SiC,Ery@SiO_(2) and Ery@Si_(3)N_(4))were prepared by melt-blending *** local thermal conductivity and reduced Young’s modulus(E^(*))of the erythritol at the interface and far away from the interface in the composite PCMs were simultaneously measured by scanning thermal microscopy(SThM).The results revealed significant enhancement in local thermal conductivity of erythritol at the interface and its obvious positive correlation with E^(*).For different composite PCMs,molecular dynamics(MD)simulations suggested that the increase in intrinsic thermal conductivity and E^(*)of erythritol is attributed to the increase in interaction energy between erythritol and nanoparticles,as more erythritol phonon vibrations transform from localized mode to delocalized mode and erythritol has a higher density at the *** findings will provide new ideas for the design of PCM for energy storage.

关键词： scanning thermal microscopy phase change materials thermal conductivity reduced Young’s modulus interaction energy phonon participation ratio

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Near Infrared Light-Based Non-Contact Sensing System for Robotics Applications

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Advanced Materials 2025年 e2414481页

作者： Wang, Ran Cheng, Yu Zhang, Qiran Li, Haoran Wang, Yangyang Liu, Jiaqi Xing, Ruirui Ma, Jinming Jiao, Tifeng State Key Laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Applied Chemistry Hebei Key Laboratory of Nanobiotechnology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse Yanshan University No.438 Hebei Street Qinhuangdao066004 China Department of Materials Science and Engineering Southern University of Science and Technology No. 1088 Academy Avenue Guangdong Shenzhen518055 China State Key Laboratory of Biopharmaceutical Preparation and Delivery Institute of Process Engineering Chinese Academy of Sciences No. 1 North Second Street Zhongguancun Beijing100190 China

With the development of artificial intelligence and the Internet of Things, non-contact sensors are expected to realize complex human-computer interaction. However, current non-contact sensors are mainly limited by accuracy and stability. Herein, an intelligent infrared photothermal non-contact sensing system is developed that provides long-distance and high-accuracy non-contact sensing. A black phosphorus (BP)-based composite organogel is designed, which exhibits excellent photothermal properties and environmental stability, as the active material. This material can detect patterns created by near-infrared (NIR) light through various patterned masks monitored by an infrared thermal imager. The constructed non-contact sensing system is capable of accurately recognizing 26 letters with an impressive accuracy rate of 99.4%. Furthermore, even small size non-contact sensors can maintain high sensitivity and stability across a wide temperature range, at long working distances, and under different current intensities and dark conditions, demonstrating exceptional robustness. Combined with machine learning method, it is demonstrated that the non-contact sensing system excels in pattern recognition and human-computer interaction. These features highlight its potential applications in intelligent robotics and remote control systems. © 2025 Wiley-VCH GmbH.

关键词： Intelligent robots

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N-doped carbon quantum dots as fluorescent probes for highly selective and sensitive detection of Fe^3+ ions

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Particuology 2018年第6期16卷 94-100页

作者： Xiangyi Deng Yali Feng Haoran Li Zhuwei Du Qing Teng Hongjun Wang School of Civil and Resource Engineering University of Science and Technology Beijing Beijing 100083China State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of SciencesBeijing 100190China

To investigate the effect of nitrogen on the photoluminescence properties of carbon quantum dots (CO Ds), N-doped carbon quantum dots (N-CQDs)were synthesized by one-step hydrothermal treatment using biomass tar as the carbon *** an inevitable organic pollutant,the unsaturated bonds in biomass tar,such as carboxylic acids,aldehydes,and aromatics,are favorable for formation of the graphitic carbon *** obtained N-CQDs are spherical with an average particle size of 2.64nm and the crystal lattice spacing is 0.25nm,corresponding to the (100)facet of graphitic *** N-CQDs emit bright blue photoluminescence under 365nm ultraviolet light,and they have excellent water solubility and stability with a high quantum yield of 26.1%.Coordination between the functional groups on the N-CQD surface and Fe^3+ ions is promoted because of the improved electronic properties and surface chemical reactivity caused by N atoms,leading to a significant fluorescence quenching effect of the N-CQDs in the presence of Fe^3+ions with high selectivity and *** is a linear relationship between In (Fo/F)and the Fe^3+ concentration in the N-CQD concentration range 0.06-1400μmol/L with a detection limit of 60nmol/L, showing that the *** have great potential as a fluorescent probe for Fe^3+detection.

关键词： N-doped carbon quantum dots Fe^3+ion detection Fluorescence quenching Biomasstar

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Recovery of valuable metals from a low-grade nickel ore using an ammonium sulfate roasting-leaching process

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International Journal of Minerals,Metallurgy and Materials 2012年第5期19卷 377-383页

作者： Xin-wei L iu Ya-li Feng Hao-ran L i Zhi-chao Yang Zhen-lei Cai Civil and Environmental Engineering School University of Science and Technology Beijing 100083 China National Key State Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Science Beijing 100190 China

Metal leaching from a low-grade nickel ore was investigated using an ammonium sulfate roasting-water leaching process. The nickel ore was mixed with ammonium sulfate, followed by roasting and finally leaching with water. During the process the effects of the amotmt of ammonium sulfate, roasting temperature, and roasting time on the leaching recovery of metal elements were analyzed. The optimum technological parameters were determined as follows： ammonium sulfate/ore ratio, 0.8 g/g; roasting temperature, 400℃; and roasting time, 2 h. Under the optimum condition the leaching recoveries ofNi, Cu, Fe, and Mg were 83.48%, 76.24%, 56.43%, and 62.15%, respectively. Furthermore, the dissolution kinetics of Ni and Mg from the nickel ore was studied. The apparent activation energies for the leaching reaction of Ni and Mg were 18.782 and 10.038 ***1-1, which were consistent with the values of diffusion control reactions. Therefore, the results demonstrated that the leaching recoveries of Ni and Mg were controlled by diffusion.

关键词： nickel ore treatment ammonium sulfate roasting leaching kinetics diffusion

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