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Chlorine-induced mixed valence of CuO_(x)/C to promote the electroreduction of carbon dioxide to ethylene

Nano Research 2023年第7期16卷 8827-8835页

作者： Xin Wang Ming Miao Bowen Tang Haotian Duan Fulong Zhu Huigang Zhang Xian Zhang Wen-jin Yin Yongzhu Fu College of Chemistry Zhengzhou UniversityZhengzhou 450001China School of Physics and Electronic Science Hunan University of Science and TechnologyXiangtan 411201China State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Qian Xuesen Laboratory of Space Technology China Academy of Space TechnologyBeijing 100094China

Electrochemical conversion of CO_(2)(CO_(2)RR)into high-value fuel is identified as one of the promising approaches to achieve carbon *** synthesis of high-efficiency CO_(2)reduction electrocatalysts with high C_(2):C_(1) selectivity remains a field of intense *** studies have shown that the presence of Cu(I)is beneficial for the reduction of CO_(2)into C_(2)***,the stable presence of Cu(I)remains controversial,especially in the negative potential *** we report a simple and easily scalable catalyst precursor Cu_(2)(OH)_(3)Cl/C,which automatically forms in-situ chlorine-doped Cu/Cu_(2)O heterointerface during *** catalyst not only exhibits a Faradaic efficiency of 33.03%but also provides a long-term stability of Cu^(+),gaining a stable electrolysis of 11 h,with an ethylene/methane ratio over *** experimental results and mechanistic studies confirm that the presence of Cl^(-)inhibits the reduction of Cu^(+),inducing the formation of Cu^(0)/Cu^(+),and reduces the reaction energy of the intermediate ^(*)CO dimerization,thereby facilitating the formation of C_(2)*** work provides a feasible way to synthesize copper ions with long-term and stable positive charge in CO_(2)RR and expands a new way to synthesize ethylene industrial products in the future.

关键词： basic copper chloride chlorine dopant mixed-phase catalysts CO_(2)reduction reaction ethylene

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Magnetically enhancing diffusion for dendrite-free and long-term stable lithium metal anodes

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Green Energy & Environment 2022年第5期7卷 965-974页

作者： Yongxiu Chen Xiangyu Dou Kai Wang Yongsheng Han State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing100190China School of Metallurgy and Materials University of BirminghamBirminghamBT152TTUK

Lithium metal batteries are promising devices for the next-generation energy storage due to their ultrahigh theoretical specific capacity and extremely low electrochemical *** inherent problem is the formation of lithium dendrites in cycling,which has induced safety concerns for almost half a *** understanding the formation mechanism of branching structures,we propose to suppress lithium dendrites by adopting external magnetic fields to induce diffusion enhancement at the interface of the anode,thus attenuating concentration gradient there and reducing the driving force for the formation of dendritic *** diffusion coefficient of lithium ions is dependent on the strength of magnetic fields,confirming the effectiveness of magnetic fields in improving Li^(+) *** employing the magnetic field of0.8 T,the concentration gradients at the growth front becomes nearly half of the control case,which leads to a dendrite-free lithium deposition up to the high current density of 10 mA cm^(-2).Both the Cu|LiCoO_(2) batteries and the symmetric Li | Li coin cells show a long-term stable cycling at high current densities under the assistance of magnetic *** diffusion enhanced technique promises a facile and general approach to suppress dendritic structures in secondary batteries,which may help to develop quick charging strategies.

关键词： lithium diffusion cycling

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Molecular dynamics simulation study onπ-πstacking of Gemini surfactants in oil/water systems

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Chinese Journal of Chemical engineering 2022年第10期50卷 335-346页

作者： Jule Ma Peiwen Xiao Pingmei Wang Xue Han Jianhui Luo Ruifang Shi Xuan Wang Xianyu Song Shuangliang Zhao State Key Laboratory of Chemical Engineering and School of Chemical Engineering East China University of Science and TechnologyShanghai 200237China Research Institute of Petroleum Exploration&Development(RIPED) PetroChinaBeijing 100083China Key Laboratory of Nano Chemistry(KLNC) CNPCBeijing 100083China Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir School of Environmental and Chemical EngineeringChongqing Three Gorges UniversityChongqing 404100China Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology and School of Chemistry and Chemical Engineering Guangxi UniversityNanning 530004China

Whereas theπ-πstacking interactions at oil/water interfaces can affect interfacial structures hence the interfacial properties,the underlying microscopic mechanism remains largely *** reported an all-atom molecular dynamics(MD)simulation study to demonstrate how the Gemini surfactants with pyrenyl groups affect the interracial properties,structural conformations,and the motion of molecules in the water/n-octane/surfactant ternary *** is found that the pyrenyl groups tend to be vertical to the interface owing to theπ-πstacking ***,a synergistic effect between theπ-πinteraction and steric hindrance is found,which jointly affects the coalescence of liquid ***,the existence of aromatic groups and a moderate number of surfactants helps to form *** work provides a molecular understanding of Gemini surfactants with aromatic groups in microemulsion preparation and applications.

关键词： Surfactants Interface Interfacial tension p-p stacking Microemulsion Molecular simulation

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Resistance to salt stresses by aerobic granular sludge:sludge property and microbial community

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Frontiers of Environmental Science & engineering 2024年第8期18卷 107-116页

作者： Xiao Wu Hui Li Meili Wang Tianying Zhang Jiawei Li Yongdi Liu Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu UniversityChengdu 610041China Institute for Environmental Pollution and Health School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444China School of Life Sciences Southwest UniversityChongqing 400715China State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China Institute of Qinghai-Tibetan Plateau Southwest Minzu UniversityChengdu 610041China

Saline wastewater is regarded as a challenge for wastewater treatment plants because high-salinity conditions negatively affect on traditional biological *** granular sludge(AGS)has gained attention as a promising technology for saline wastewater treatment because of its compact structure and the ability to withstand toxic ***,this study investigated the saltresistance performance,sludge properties and microbial community of AGS under low-salinity and high-salinity conditions,with the saline concentrations ranging from 0 to 50 g/*** results showed that AGS could withstand long-term saline stresses,and the maximum salinity reached 50 g/L within 113 *** salinities of 10,30,and 50 g/L,the chemical oxygen demand(COD)removal efficiencies were 90.3%,88.0%and 78.0%,*** also its maintained strength and aggregation at salinities of 10 and 30 g/*** of extracellular polymeric substances(EPS)by non-halophilic bacteria that enhanced sludge *** compact structure that ensured the microorganisms bioactivity helped to remove organic matters under salinities of 10 and 30 g/*** a salinity of 50 g/L,moderately halophilic bacteria,including Salinicola,Thioclava,Idiomarina and Albirhodobacter,prevailed in the *** dominant microbial communities shifted to moderately halophilic bacteria,which could maintain aerobic granular stabilization and remove organic matters under 50 g/L *** results in this study provide a further explanation for the long-term operation of AGS for treating saline wastewater at different *** is hoped that this work could bring some clues for the mystery of salt-resistance mechanisms.

关键词： Aerobic granular sludge Long-term saline stresses Performance Sludge property Microbial community

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Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts

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Frontiers of Chemical Science and engineering 2021年第2期15卷 288-298页

作者： Jimei Zhang Fuping Tian Junwen Chen Yanchun Shi Hongbin Cao Pengge Ning Shanshan Sun Yongbing Xie School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China College of Chemistry Dalian University of TechnologyDalian 116024China State Key Laboratory of Catalytic Materials and Reaction Engineering Research Institute of Petroleum ProcessingSINOPECBeijing 100083China

A series of Ni/HZSM-5 and Ni/HIM-5 bi-functional catalysts were synthesized and applied to the aqueous-phase hydrodeoxygenation(HDO)of *** Ni dispersibility and particle sizes were shown to be directly related to the porosity and crystal sizes of the parent zeolites,which further influenced the catalytic *** large pores and small crystal sizes of the parent zeolites were beneficial for dispersing Ni and forming small Ni particles,and the corresponding Ni/zeolite catalyst exhibited a higher phenol conversion and selectivity towards ***,the Ni/HIM-5 bi-functional catalyst exhibited a high activity(98.3%)and high selectivity for hydrocarbons(98.8%)when heated at 220°C for 1 h and is thus a new potential catalyst for the HDO of phenolics to form hydrocarbons in the aqueous phase.

关键词： aqueous-phase hydrodeoxygenation phenol hydrocarbons Ni/HIM-5 bi-functional catalyst

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Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent prediction based on a back propagation neural network

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Frontiers of Environmental Science & engineering 2023年第8期17卷 69-79页

作者： Xinwan Zhang Guangyuan Meng Jinwen Hu Wanzi Xiao Tong Li Lehua Zhang Peng Chen National Engineering Laboratory for Industrial Wastewater Treatment School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China Continuing Education Center Bozhou UniversityBozhou 236800China State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Flow-through electrodes have been demonstrated to be effective for electroreduction of Cr(VI),but shortcomings are tedious preparation and short ***,porous titanium available in the market was studied as a flow-through electrode for Cr(VI)*** addition,the intelligent prediction of electrolytic performance based on a back propagation neural network(BPNN)was *** studies revealed that Cr(VI)electroreduction was a diffusion-controlled *** of the flow-through mode achieved a high limiting diffusion current as a result of enhanced mass transfer and favorable *** of Cr(VI)in the flow-through system was 1.95 times higher than in a parallel-plate electrode *** the influent(initial pH 2.0 and 106 mg/L Cr(VI))was treated at 5.0 V and a flux of 51 L/(h·m2),a reduction efficiency of~99.9%was obtained without cyclic electrolysis *** served as the supporting electrolyte and pH regulator,as reactive CrSO72−species were formed as a result of feeding HSO4−.Cr(III)was confirmed as the final product due to the sequential three-electron transport or disproportionation of the *** developed BPNN model achieved good prediction accuracy with respect to Cr(VI)electroreduction with a high correlation coefficient(R2=0.943).Additionally,the electroreduction efficiencies for various operating inputs were predicted based on the BPNN model,which demonstrates the evolutionary role of intelligent systems in future electrochemical technologies.

关键词： Flow-through electrode Hexavalent chromium Heavy metals Neural network Artificial intelligence

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Coupled effects of particle overall regularity and sliding friction on the shear behavior of uniformly graded dense sands

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Journal of Rock Mechanics and Geotechnical engineering 2022年第3期14卷 873-885页

作者： Jiayan Nie Shiwei Zhao Yifei Cui Yu Wang State Key Laboratory of Hydroscience and Engineering Tsinghua UniversityBeijing100084China South China Institute of Geotechnical Engineering South China University of TechnologyGuangzhou510640China Key Laboratory of Mountain Hazards and Surface Process Institute of Mountain Hazards and EnvironmentChinese Academy of SciencesChengdu610041China University of Chinese Academy of Sciences Beijing100049China

Particle morphology has been regarded as an important factor affecting shear behaviors of sands,and covers three important aspects,*** form(overall shape),local roundness(large-scale smoothness),and surface texture(roughness)in terms of different observation *** features of different aspects can be independent of each other but might have coupled effects on the bulk behavior of sands,which has been not explored thoroughly *** paper presents a systematic investigation of the coupled effects of the particle overall regularity(OR)and sliding friction on the shear behavior of dense sands using three-dimensional(3D)discrete element method(DEM).The representative volume elements consisting of ideal spheres and irregular clumps of different mass proportions are prepared to conduct drained triaxial compression simulations.A well-defined shape descriptor named OR is adopted to quantify particle shape differences of numerical samples at both form and roundness aspects,and the particle sliding friction coefficient varies from 0.001 to 1 to consider the surface roughness effect equivalently in *** stress-strain relationships as well as peak and critical friction angles of these assemblies are examined ***,contact network and anisotropic fabric characteristics within different granular assemblies are analyzed to explore the microscopic origins of the multi-scale shape-dependent shear *** study helps to improve the current understanding with respect to the influence of the particle shape on the shear behavior of sands from different shape aspects.

关键词： Discrete element method(DEM) Overall regularity(OR) Particle sliding friction Peak and critical friction angles Fabric anisotropy Dense sands

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Heterogeneous multi-player imitation learning

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Control Theory and Technology 2023年第3期21卷 281-291页

作者： Bosen Lian Wenqian Xue Frank L.Lewis Department of Electrical and Computer Engineering Auburn UniversityAuburnAL 36849USA State Key Laboratory of Synthetical Automation for Process Industries and International Joint Research Laboratory of Integrated Automation Northeastern UniversityShenyang 110819LiaoningChina UTA Research Institute University of Texas at Arlington(UTA)Fort WorthTX 76118USA

This paper studies imitation learning in nonlinear multi-player game systems with heterogeneous control input *** propose a model-free data-driven inverse reinforcement learning(RL)algorithm for a leaner to find the cost functions of a N-player Nash expert system given the expert's states and control *** allows us to address the imitation learning problem without prior knowledge of the expert's system *** achieve this,we provide a basic model-based algorithm that is built upon RL and inverse optimal *** serves as the foundation for our final model-free inverse RL algorithm which is implemented via neural network-based value function *** analysis and simulation examples verify the methods.

关键词： Imitation learning Inverse reinforcement learning Heterogeneous multi-player games Data-driven model-free control

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Brief review of hydrocarbon-reforming catalysts map for hydrogen production

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Energy Reviews 2023年第3期2卷 51-62页

作者： Qunwei Guo Jiaqi Geng Jiawen Pan Lu Zou Yunfeng Tian Bo Chi Jian Pu School of Materials Science and Engineering State Key Laboratory of Material Processing and Die&Mould TechnologyHuazhong University of Science&TechnologyWuhanHubei430074PR China Key Laboratory of Green Chemical Engineering Process of Ministry of Education School of Chemical Engineering and PharmacyWuhan Institute of TechnologyWuhanHubei430073PR China Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization School of Materials Science and PhysicsChina University of Mining and TechnologyXuzhou221116PR China

Hydrogen energy,the cleanest fuel,presents extensive applications in renewable energy technologies such as fuel ***,the transition process from carbon-based(fossil fuel)energy to desired hydrogen energy is usually hindered by inevitable scientific,technological,and economic obstacles,which mainly involves complex hydrocarbon reforming ***,this paper provides a systematic and comprehensive analysis focusing on the hydrocarbon reforming ***,recent related studies are summarized to clarify the intrinsic difference among the reforming *** to objectively assess the activated catalyst and deactivation mechanism,the rate-determining steps of reforming process have been emphasized,summarized,and ***,the effect of metals and supports on individual reaction processes is discussed followed by the metalsupport *** tendency and research map could be established to promote the technology development and expansion of hydrocarbon reforming *** review could be considered as the guideline for academics and industry designing appropriate catalysts.

关键词： Hydrogen production Reforming mechanism Metal-support interaction Metal catalysts Supports properties

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FedAWS: A Federated Tuning Approach with Adaptive Weight Shrinking for Pre-trained Foundation Models 13

FedAWS: A Federated Tuning Approach with Adaptive Weight Shr...

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13th IEEE Data Driven Control and Learning Systems Conference, DDCLS 2024

作者： Cheng, Yubin Song, Zhihuan Jiang, Xiaoyu Yao, Le Zhejiang University State Key Laboratory of Industrial Control Technology Institute of Industrial Process Control College of Control Science and Engineering Hangzhou310027 China School of Mathematics Hangzhou Normal University Hangzhou China

ISBN: (纸本)9798350361674

In recent years, pre-trained foundation models have developed rapidly and have been applied to various downstream tasks through fine-tuning methods. However, due to the existence of data silos, the lack of data for fine-tuning has become a vital issue preventing the application of the foundation model to industry. In addition, the high complexity of the network makes the foundation model prone to overfitting when used for data-constrained industrial tasks. Therefore, a federated tuning approach with adaptive weight shrinking, named FedAWS, is proposed for collaborative fine-tuning between factories. FedAWS adaptively selects the weight-shrinking factor to reduce overfitting and improve the generalization of the global model without relying on additional data sets or human experience. The case study on an industrial dataset demonstrates the effectiveness of FedAWS. This successful validation provides a new way for inter-factory collaboration to apply the foundation model to industry, thus facilitating the efficient utilization of industrial data. © 2024 IEEE.

关键词： Federated Learning Fine-tuning Foundation Model Weight Shrinking

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