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Smart heat isolator with hollow multishelled structures

Green Energy & Environment 2023年第4期8卷 1154-1160页

作者： Kun Wang Lekai Xu Jiao Wang Shaojun Zhang Yanlei Wang Nailiang Yang Jiang Du Dan Wang Henan Province Industrial Technology Research Institute of Resources and Materials Zhengzhou UniversityZhengzhou450001China State Key Laboratory of Biochemical Engineering Key Laboratory of Science and Technology on Particle MaterialsInstitute of Process EngineeringChinese Academy of SciencesBeijing100190China Green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou450000China University of Chinese Academy of Sciences 19A Yuquan RoadBeijing100049China Beijing Key Laboratory of Ionic Liquids Clean Process Institute of Process EngineeringChinese Academy of SciencesBeijing100190China

Safe, green and efficient industrial production has always been the pursuit of the chemical industry. Since thermal energy is the driving force for most of chemical reactions, an ideal reaction tank would have the capacity to automatically regulate heat conduction rate. In detail, this reaction tank should endow an ability that resists the heat loss when the reaction temperature is lower than the target, while accelerating the heat dissipation when the system is overheated. In this case, this smart reactor can not only minimize energy consumption but also reduce safety *** structures are known to reduce heat conductivity. Particularly, the hollow structure with multishells can provide more interfaces and thus further inhibit heat transmission, which would be more favorable for heat isolation. Step forward, by coupling HoMSs with temperature-sensitive polymer, a smart heat isolation material has been fabricated in this work. It performs as a good heat isolator at a relatively lower temperature. A heat insulation effect of 6.5℃ can be achieved for the TSPU/3S–TiO_(2)HoMSs with a thickness of 1 mm under the temperature field of 50℃.The thermal conductivity of composite material would be raised under overheating conditions. Furthermore, this composite displays an unusual two-stage phase transformation during heating. Benefiting from the unique multishelled structure, energy is found to be gradually guided into the hollow structure and stored inside. This localized heat accumulation enables the composite to be a potential coating material for intelligent thermal-regulator and site-defined micro-reactor.

关键词： Hollow multishelled structures Thermal insulation Smart material

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Research progress on preparation and purification of fluorine-containing chemicals in lithium-ion batteries

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Chinese Journal of Chemical engineering 2022年第1期35卷 73-84页

作者： Xiaobin Liu Zhenguo Gao Jingcai Cheng Junbo Gong Jingkang Wang State Key Laboratory of Chemical Engineering School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin Tianjin 300072China

With the development of digital products,electric vehicles and energy storage technology,electronic chemicals play an increasingly prominent role in the field of new energy such as lithium-ion *** chemicals have attracted extensive attention in various *** of high-end electronic chemicals are high purity and low impurity content,which requires a very strict separation and purification *** present,crystallization is a key technology for their separation and purification of electronic *** this work,the representative fluorine-containing compounds in cathode and anode materials,separator and electrolyte of lithium-ion batteries are *** latest technologies for the preparation and purification of four kinds of fluorine-containing battery chemicals by crystallization technology are *** addition,the research prospects and suggestions are put forward for the separation of fluorine-containing battery chemicals.

关键词： Battery chemicals Lithium-ion batteries Crystallization Fluorine-containing chemicals

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Interfacial engineering of transition-metal sulfides heterostructures with built-in electric-field effects for enhanced oxygen evolution reaction

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Chinese Journal of Chemical engineering 2022年第1期35卷 320-328页

作者： Shan Ni Hongnan Qu Huifang Xing Zihao Xu Xiangyang Zhu Menglei Yuan Meng Rong Li Wang Jiemiao Yu Yanqing Li Liangrong Yang Huizhou Liu CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Biochemical EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of SciencesQingdao 266061China

Developing highly efficient,durable,and non-noble electrocatalysts for the sluggish anodic oxygen evolution reaction(OER)is the pivotal for meeting the practical demand in water ***,the current transition-metal electrocatalysts still suffer from low activity and durability on account of poor interfacial reaction *** this work,a facile solid-state synthesis strategy is developed to construct transition-metal sulfides heterostructures(denoted as MS_(2)/NiS_(2),M=Mo or W)for boosting OER *** a result,MoS2/NiS2 and WS2/NiS2 show lower overpotentials of 300 mV and 320 mV to achieve the current density of 10 mA·cm^(-2),and smaller Tafel slopes of 60 ***^(-1) and 83 ***^(-1)in 1 mol·L^(-1) KOH,respectively,in comparison with the single MoS2,WS2,NiS2,as well as even the benchmark *** experiments reveal that the designed heterostructures have strong electronic interactions and spontaneously develop a built-in electric field at the heterointerface with uneven charge distribution based on the difference of band structures,which promote interfacial charge transfer,improve absorptivity of OH-,and modulate the energy level more comparable to the ***,the designed transition-metal sulfides heterostructures exhibit a remarkably high electrocatalytic activity for *** study provides a simple strategy to manipulate the heterostructure interface via an energy level engineering method for OER and can be extended to fabricate other heterostructures for various energy-related applications.

关键词： Oxygen evolution reaction Transition-metal sulfides heterostructures Heterointerface Built-in electric field

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Ni nanoparticles encapsulated within H-type ZSM-5 crystals for upgrading palmitic acid to diesel-like fuels

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Chinese Chemical Letters 2022年第2期33卷 803-806页

作者： Yanchun Shi Chen Gao Enhui Xing Jimei Zhang Feng Duan He Zhao Yongbing Xie CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China State Key Laboratory of Catalytic Materials and Reaction Engineering Research Institute of Petroleum ProcessingSinopecBeijing 100083China

Meso-Ni@HZSM-5 bi-functional catalysts were successfully post-encapsulated with about 3-7 nm Ni nanoparticles within HZSM-5 crystals,which exhibited significantly efficient conversion activity(67.4 g[palmitic acid]g[Ni]^(−1)h^(−1))of palmitic acid and 100%selectivity of hydrocarbons with the outstanding stability during recycling application,compared to the impregnated Ni/HZSM-5 catalyst(14.0 g[palmitic acid]g[Ni]^(−1)h^(−1)).

关键词： Post-encapsulation Ni@HZSM-5 Ni nanoparticles Palmitic acid Hydrodeoxygenation Hydrocarbons

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Insight into the effect of gel drying temperature on the structure and desulfurization performance of ZnO/SiO_(2)adsorbents

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Chinese Journal of Chemical engineering 2023年第4期56卷 233-241页

作者： Chao Yang Zhelin Su Yeshuang Wang Huiling Fan Meisheng Liang Zhaohui Chen College of Environmental Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024China State Key Laboratory of Multi-phase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

A series of ZnO/SiO_(2) adsorbents were prepared by a sol-gel method using tetraethyl orthosilicate,ethylene glycol(EG)and nitrates as *** effect of gel drying temperature on the structure and desulfurization performance of the adsorbents were investigated in *** is found that the low drying temperature led to a weak interaction among EG,Si AOH/H_(2)O and the nitrates in the gel system,which caused the oxidation of EG by NO3-and formed zinc glyoxylate complex during the gel calcination process,whereas this oxidation process also occurred at a high drying temperature during the gel drying *** formed zinc glyoxylate complex promoted the generation of monodentate carbonate on the surface of Zn O,which resulted in the inferior desulfurization performance of adsorbents despite they have smaller Zn O *** gel dried at 120°C formed the hydrogen bonds between EG and Si AOH/H_(2)O and a strong interaction between zinc oxo-clusters and NO3-was also found in the gel system,which avoided the oxidation of EG by NO3-during the preparation process and the Zn O nanoparticles with sizes of 6 nm were formed by a combustion *** adsorbent affords a highest sulfur capacity of 104.9 mg·g^(-1) in this *** addition,the gel drying temperature has a significant influence on the textural properties of the adsorbents except their surface area.

关键词： Sol-gel method Drying temperature H_(2)S removal Zinc-silica composites Hydrogen bonds

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Simulation of the L-valve in the circulating fluidized bed with a coarse-grained discrete particle method

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Particuology 2024年第7期90卷 266-280页

作者： Ruixiang Tang Zheng Zou Ji Xu Junwu Wang Qingshan Zhu Hongzhong Li State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesP.O.Box 353Beijing100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing100049China Innovation Academy for Green Manufacture Chinese Academy of SciencesBeijing100190China

Stable and controllable solid flow is essential in circulating fluidized bed (CFB) systems. The L-valve is a typical non-mechanical valve that can provide flexible solid feeding. The investigation of the solid circulation rate and the hydrodynamic characteristics of the L-valve is crucial to its design and operation. The gas-solid flow in the L-valve of a full-loop CFB is studied with the coarse-grained discrete particle method (EMMS-DPM). Good agreements on the solid circulation rate and the pressure drop through the L-valve are achieved between the simulated and experimental data. The solid circulation rate increases linearly with the aeration velocity until the stable particle circulation of the CFB is destroyed. The flow patterns in the horizontal section of L-valve are gas-solid slug flow above the stationary solid layer and the moving solid layer, respectively. The effects of L-valve geometric parameters on the solid flow characteristics are also investigated. The results indicate that reducing the diameter and length of the horizontal section of L-valve can improve the solid transport efficiency, especially at low aeration velocity. Besides, the solid conveying capacity and flow stability are improved when the sharp bend of L-valve is modified to be a gradual bend.

关键词： L-valve Circulating fluidized bed Full loop Discrete particle method Gas-solid flow

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Self-healing of active site in Co(OH)_(2)/MXene electrocatalysts for hydrazine oxidation

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Journal of Materials Science & Technology 2024年第36期203卷 108-117页

作者： Kun Xiang Yongjing Wang Zechao Zhuang Jing Zou Neng Li Dingsheng Wang Tianyou Zhai Jizhou Jiang School of Environmental Ecology and Biological Engineering School of Chemistry and Environmental EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China Department of Chemistry Tsinghua UniversityBeijing 100084China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The development of efficient hydrazine oxidation reaction(HzOR)catalysts is important for the construc-tion of remarkable energy storage and conversion ***,after a period of electrochemical reaction,the active site of the catalyst will be irreversibly reduced or inactivated,and how to recover the active site is a major ***,we report 2D Co(OH)_(2)/Ti_(3)C_(2)(OH)_(x)MXene composites with rapid re-construction and self-healing behaviors as efficient and stable electrocatalysts during HzOR *** experimental and theoretical results indicate that the introduction of Ti_(3)C_(2)(OH)_(x)MXene can effectively reduce the dehydrogenation barrier of Co(OH)_(2),from 0.584 eV to 0.481 eV to form the real catalytic active center Co(OH)***,Co(OH)O/Ti_(3)C_(2)(OH)_(x)MXene composites with metal-like conductiv-ity not only present spontaneous adsorption capacity of N_(2)H_(4),but also can modulated rate-determining step of dehydrogenation of∗N_(2)H_(4)to∗N_(2)H_(3)(0.54 eV)compared with Co(OH)***,the electrophilic oxygen of Co(OH)O/Ti_(3)C_(2)(OH)_(x)can spontaneously obtain electrons and protons from N_(2)H_(4),achieving the oxidation of N_(2)H_(4)while reducing Co(OH)O to Co(OH)_(2),thus completing the self-healing of the efficient catalyst.

关键词： Hydrazine oxidation Self-healing Reconstruction Co(OH)_(2)/MXene Electrocatalysis

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Comparative catalytic study on butene/isobutane alkylation over LaX and CeX zeolites: The influence of calcination atmosphere

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Chinese Journal of Chemical engineering 2022年第6期35卷 173-183页

作者： Zhiqiang Yang Ruirui Zhang Honghua Zhang Hongguo Tang Ruixia Liu Suojiang Zhang School of Chemical Engineering&Technology Tianjin UniversityTianjin 300072China Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex SystemsCAS Key Laboratory of Green Process and EngineeringInstitute of Process EngineeringChinese Academy of Sciences100049 BeijingChina School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

Lanthanum-containing(LaX)and cerium-containing X zeolites(CeX)were prepared by a doubleexchange,double-calcination *** changing the calcination atmospheres between nitrogen and air,the Ce^(IV) contents in CeX zeolites were adjusted and their impacts on physicochemical properties and catalytic performance in isobutane alkylation were *** crystallinity of CeX zeolite was found to be negatively correlated with the Ce^(IV) *** i s believed to be due to the water formed during the oxidation of Ce^(III),which facilitates the framework *** a consequence,calcining in air resulted in a great elimination of strong Brønsted acid sites while under nitrogen protection,this phenomenon was mostly hindered and the sample’s acidity was *** tested in a continuously flowed slurry reactor,the catalyst lifetime for isobutane alkylation was found to be linearly related to the strong Brønsted acid *** addition,Ce^(3+)was found more benefit for the hydride transfer compared with La^(3+),which is ascribed to the stronger polarization effect on the CH bond of ***,the decline of hydride transfer activity can be slowed down by the catalytic cracking of the bulky *** on the product distribution,a new catalytic cycle of dimethylhexanes(DMHs)involving a direct formation of isobutene rather than tert-butyl carbocation was proposed in isobutane alkylation.

关键词： CeX zeolite Calcination atmosphere Isobutane alkylation Brønsted acid Hydride transfer

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Graph-guided masked autoencoder for process anomaly detection

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process Safety and Environmental Protection 2024年 186卷 1345-1357页

作者： Jia, Mingwei Xu, Danya Yang, Tao Yao, Yuan Liu, Yi Institute of Process Equipment and Control Engineering Zhejiang University of Technology Hangzhou310023 China State Key Laboratory of Synthetical Automation for Process Industries Northeastern University Shenyang110819 China Department of Chemical Engineering National Tsing Hua University Hsinchu300044 Taiwan

Developing an accurate and reliable anomaly detection model is of great significance for safe operation in the process industry. To minimize false positives, it is crucial to accurately model the intricate topological and nonlinear connections among variables. In this study, a process anomaly detection method based on graph-guided masked autoencoder (GGMAE) is proposed by introducing the concept of the graph to the process industry. GGMAE first constructs a topology graph according to the process flowchart. Then, the patch and mask mechanism forces GGMAE to learn the process intrinsic information to reconstruct the input according to the variable topological relationship and temporal characteristics. Additionally, Kullback-Leibler divergence is used as the loss to ensure that the distribution of input and output is consistent. Experiments on two publicly available anomaly detection benchmarks demonstrate the superiority of GGMAE over existing methods. Visualization of the results demonstrates the physically compliant reconstruction logic. © 2024 The Institution of Chemical Engineers

关键词： Anomaly detection

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A review of low-carbon technologies and projects for the global cement industry

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Journal of Environmental Sciences 2024年第2期136卷 682-697页

作者： Yangyang Guo Lei Luo Tingting Liu Liwei Hao Yinming Li Pengfei Liu Tingyu Zhu CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China State Key Laboratory of Solid Waste Reuse for Building Materials Beijing Building Materials Academy of Sciences ResearchBeijing 100041China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou 341000China

Carbon dioxide(CO_(2))emissions from the cement industry account for 26%of the total industrial emissions,and the need to develop low-carbon techniques within the cement industry is extremely ***-carbon projects and technologies for the cement industry in different regions and countries have been thoroughly reviewed in this manuscript,and the low-carbon development concept for each county has been *** developing countries such as China and India,energy saving and efficiency enhancement are currently the key points,while for developed countries and regions such as Europe,more efforts have been focused on carbon capture,utilization,and storage(CCUS).Global CCUS projects have been previously conducted,and the majority of CCUS projects are currently performed in Europe where major projects such as the CEMCAP,CLEANKER,and IEILAC projects represent the latest research progress in cement production technologies and low-carbon technologies for the global cement *** development of low-carbon cement technologies has changed from focusing on the end point to instead focusing on the source and process through the exploration of hydrogen and solar energies,and more disruptive and original technologies are expected to be developed,particularly in the cement industry in China.

关键词： Cement industry CO_(2)emissions Low carbon development Projects Carbon capture utilization and storage

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