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IEEE Transactions on Artificial Intelligence 2022年第3期3卷 470-484页

作者： Jiang, Xiaoyu Ge, Zhiqiang Zhejiang University State Key Laboratory of Industrial Control Technology Institute of Industrial Process Control College of Control Science and Engineering Hangzhou310027 China Peng Cheng Laboratory Shenzhen518000 China

With the rapid development of information technology, intelligent upgrading of the manufacturing industry has broken the closed environment of traditional industrial control systems (ICS);thus, the information security of ICS has been seriously threatened. As part of ICS, the process monitoring system (PMS) is heavily subject to external risks. Data-driven PMSs have been widely used as initial lines of defense to ensure ICS safety. Once the PMS is under attack, the consequences on the whole ICS will be unimaginable. Unfortunately, the safety issues of the PMS have received inadequate attention. This article reveals PMS's vulnerabilities through effective attacks. A novel method called subspace transfer network (STN) is proposed to conduct adversarial and poisoning attacks on the PMS simultaneously. Then the attack task flow is defined and explained to make online adversarial attacks and data poisoning on PMS. Meanwhile, aiming at two poisoning goals, targeted and untargeted attacks of STN are designed, respectively. Finally, the PMS's fragility is verified in two industrial benchmarks. © 2020 IEEE.

关键词： Security of data

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New Insights into Microplastic Contamination in Different Types of Leachates: Abundances, Characteristics, and Potential Sources

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engineering 2024年第6期37卷 62-68页

作者： Lei Zhang Wentao Zhao Liang Zhang Zhenxiao Cai Ruiqi Yan Xia Yu Damià Barceló Qian Sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China PerkinElmer Inc.Shanghai 201203China Maihai Environmental Protection Technology Co. Ltd.SuzhouJiangsu 215000China Department of Environmental Chemistry Institute of Environmental Assessment and Water ResearchSpanish Council for Scientific Research(IDAEA-CSIC)Barcelona 08034Spain

Municipal solid waste(MSW)is an important destination for abandoned *** the waste disposal process,large plastic debris is broken down into microplastics(MPs)and released into the ***,current research only focuses on landfill leachates,and the occurrence of MPs in other leachates has not been ***,herein,the abundance and characteristics of MPs in three types of leachates,namely,landfill leachate,residual waste leachate,and household food waste leachate,were studied,all leachates were collected from the largest waste disposal center in *** results showed that the average MP abundances in the different types of leachates ranged from(129±54)to(1288±184)MP particles per liter(particlesL1)and the household food waste leachate exhibited the highest MP abundance(p<0.05).Polyethylene(PE)and fragments were the dominant polymer type and shape in MPs,*** characteristic polymer types of MPs in individual leachates were ***,the conditional fragmentation model indicated that the landfilling process considerably affected the size distribution of MPs in leachates,leading to a higher percentage(>80%)of small MPs(20–100 lm)in landfill leachates compared to other *** the best of our knowledge,this is the first study discussing the sources of MPs in different leachates,which is important for MP pollution control during MSW disposal.

关键词： Microplastics Landfill leachate Residual waste leachate Household food waste leachate Source

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Excellent Antibacterial Performance of ROS-mediated Cu-doped ZIF-8 and the Mechanism of ROS Generation 18

Excellent Antibacterial Performance of ROS-mediated Cu-doped...

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18th International Conference on Indoor Air Quality and Climate, INDOOR AIR 2024

作者： Chen, Yunfa Zhang, Jingkun Ding, Yan Yin, Hang State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing China Vehicle Emission Control Center Chinese Research Academy of Environmental Sciences Beijing China

ISBN: (纸本)9798331306816

Nowadays, it is necessary to explore efficient antibacterial materials to complement or substitute the conventional antibiotic, to cope with the ever-growing bacterial contamination. Here, a series of Cu-doped ZIF-8 materials are prepared and adopted for disinfection against typical bacteria E. coli and S. aureus in dark. The results show that 5-7 log efficiency can be achieved at a dosage of 15-30 mg mL-1 of 1.35 atomic % Cu doped ZIF-8, and this concentration is also safe as verified by cytotoxicity test. Mechanism investigation shows that Cu(II) is reduced to Cu(I), which would contribute to the effective electron transfer for the reactive oxygen species generation. And these reactive oxygen species would cause oxidative stress and membrane damage on bacteria cells. All these results show the promise of Cu-doped ZIF-8 in the antibacterial applications especially in the environments without any energy input. © 2024 18th Conference of the International Society of Indoor Air Quality and Climate, INDOOR AIR 2024 - Conference Program and Proceedings. All rights reserved.

关键词： Reactive oxygen species

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Swelling and dissolution behaviors of cellulose in phosphate-based ionic liquids-H2O binary systems: In-situ observation and molecular dynamics simulation

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Journal of Molecular Liquids 2024年 415卷

作者： Cao, Ruimei Long, Yan Li, Tiancheng Lv, Wanxue Wu, Huizheng Wang, Binqi Song, Yuting Gao, Hongshuai Nie, Yi School of Chemical Engineering Zhengzhou University Zhengzhou450001 China Zhengzhou Institute of Emerging Industrial Technology Longzihu New Energy Laboratory Zhengzhou450046 China Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Mesoscience and Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China

Swelling and dissolution of cellulose in ionic liquids (ILs) as the pretreatment processes are key steps for the high-value conversion and utilization of cellulose. However, the molar ratio of H2O to ILs has a significant effect on the swelling and dissolution of cellulose, and its molecular-scale mechanism is still unclear, which limits screening out the suitable ILs and recovery of ILs from coagulation bath in the spinning process. Herein, three phosphate-based ILs were chosen to couple with water as solvents for swelling and dissolution of cellulose by combining in-situ observation and molecular dynamics (MD) simulation. The results show that the redissolution time of swollen cellulose is greatly reduced, especially [Emim]DEP-H2O has the best swelling and dissolution performance for cellulose due to its high β value and low viscosity. Meanwhile, when the molar ratio of IL to H2O was more than 1: -1, the IL-H2O system still has the ability to dissolve cellulose. While with the molar ratio further decreased, cellulose was no longer dissolved and began to swell, and the fiber diameter obtained the maximum swelling rate with 40.1% at a molar ratio of 1:3. Moreover, MD simulation was used to calculate the interaction between IL/water/cellulose, which further illustrated that the combination of IL with water molecular has a significant influence on the behavior of cellulose in IL-H2O systems at the molecular scale. Thus, the potential swelling and dissolution mechanism of cellulose in ILs-H2O binary systems was proposed based on experimental and simulation results. Furthermore, the characterization results of swollen cellulose indicate that the crystal structure and degree of polymerization (DP) were almost unchanged, but the specific surface area and pore size increased significantly, and the thermal stability and heat absorption were decreased, all the results prove that the swelling process increased the accessibility of cellulose and benefited to the subsequent dis

关键词： Spinning (fibers)

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Triple the steady-state reaction rate by decorating the In_(2)O_(3)surface with SiO_(x)for CO_(2)hydrogenation

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Journal of Energy Chemistry 2024年第8期95卷 96-105,I0003页

作者： Hao Wang Chun Yang Xiaoyan Yu Mingrui Wang Runze Yang Xiaowa Nie Ben Hang Yin Alex C.K.Yip Chunshan Song Guanghui Zhang Xinwen Guo State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsPSU-DUT Joint Center for Energy ResearchSchool of Chemical EngineeringDalian University of TechnologyDalian 116024LiaoningChina Department of Chemistry the Chinese University of Hong KongHong Kong 999077China Paihau-Robinson Research Institute the MacDiarmid Institute for Advanced Materials and NanotechnologyVictoria University of WellingtonWellington 6012New Zealand Department of Chemical and Process Engineering The University of CanterburyChristchurch 8041New Zealand

Indium oxide(In_(2)O_(3)),as a promising candidate for CO_(2)hydrogenation to C_(1) products,often suffers from sintering and activity decline,closely related to the undesirable structural evolution under reaction *** on the comprehension of the dynamic evolution,this study presents an efficient strategy to alleviate the agglomeration of In_(2)O_(3)nanoparticles by the surface decoration with highly dispersed silica species(SiO_(x)).Various structural characterizations combined with density functional theory calculations demonstrated that the sintering resulted from the over-reduction,while the enhanced stability originated from the anchoring effect of highly stable In-OSi bonds,which hinders the substantial formation of metallic In(In^(0))and the subsequent agglomeration.0.6Si/In_(2)O_(3)exhibited CO_(2)conversion rate of10.0 mmol g^(-1)h^(-1)at steady state vs.3.5 mmol g^(-1)h^(-1)on In_(2)O_(3)in CO_(2)*** steady-state activity was also achieved on Pd-modified *** to the traditional Pd/In_(2)O_(3)catalyst,the methanol production rate of Pd catalyst supported on 0.6Si/In_(2)O_(3)was enhanced by 23%,showing the potential of In_(2)O_(3)modified by SiO_(x)in serving as a platform *** work provides a promising method to design new In_(2)O_(3)-based catalysts with improved activity and stability in CO_(2)hydrogenation.

关键词： CO_(2)hydrogenation In_(2)O_(3)sintering Dynamic structural evolution Surface SiO_(x)modification DFT simulations

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Novel magnetic carbon supported molybdenum disulfide catalyst and its application in residue upgrading

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Green Energy & Environment 2021年第6期6卷 952-960页

作者： Xiangyang Zhu Dong Qiao Liangrong Yang Qinling Bi Huifang Xing Shan Ni Menglei Yuan Huizhou Liu Luhai Wang An Ma CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Biochemical EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing100049China c China University of Petroleum Beijing102249China Petrochemical Research Institute PetrochinaBeijing102206China

A novel hybrid material consisted of carbon covered Fe_(3)O_(4)nanoparticles and MoS_(2)nanoflower(FCM)was designed and prepared by micelle-assisted hydrothermal *** techniques,including X-Ray diffraction(XRD),high-resolution transmission electron microscopy(HRTEM)and X-ray photoelectron spectroscopy(XPS)were employed to characterize *** results show that FCM has a flower-like morphology with a 330 nm Fe_(3)O_(4)core as well as 70 nm highly crystalline MoS_(2)*** is superparamagnetic with a saturation magnetization of 35 emu *** hydrocracking of Canadian bitumen residue(CBR)was applied to estimate its catalytic *** results show that FCM exhibits superior catalytic hydrocracking activity compared to bulk MoS_(2)and commercial oil-dispersed Mo(CO)6 by the same Mo *** measurement by elemental analysis,XPS and XRD reveals that the MoS_(2)nanoflower with abundant catalytic active sites and covered carbon layer with anti-coke ability donate to the superior upgrading ***,the catalysts can be easily recovered by the external magnetic *** work provides a novel kind magnetic nanocatalyst which is potential for slurry-phase hydrocracking applications.■2020,institute of process engineering,Chinese Academy of *** services by Elsevier *** behalf of KeAi Communications Co.,*** is an open access article under the CC BY-NC-ND license(http://***/licenses/by-nc-nd/4.0/).

关键词： Magnetic Carbon MoS_(2) Catalyst Heavy oil

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Neuronal double-stranded DNA accumulation induced by DNase II deficiency drives tau phosphorylation and neurodegeneration

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Translational Neurodegeneration 2024年第1期13卷 530-546页

作者： Ling-Jie Li Xiao-Ying Sun Ya-Ru Huang Shuai Lu Yu-Ming Xu Jing Yang Xi-Xiu Xie Jie Zhu Xiao-Yun Niu Dan Wang Shi-Yu Liang Xiao-Yu Du Sheng-Jie Hou Xiao-Lin Yu Rui-Tian Liu State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Department of Neurology the First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052China College of Life Science Ningxia UniversityYinchuan 750021China Department of BigData Beijing Medintell Bioinformatic Technology Co.LTDBeijing 100081China

Background Deoxyribonuclease 2(DNaseⅡ)plays a key role in clearing cytoplasmic double-stranded DNA(dsDNA).Deficiency of DNaseⅡleads to DNA accumulation in the *** dsDNA in neurons is an early pathological hallmark of senescence and neurodegenerative diseases including Alzheimer’s disease(AD).However,it is not clear how DNaseⅡand neuronal cytoplasmic dsDNA influence *** hyperphosphorylation is a key factor for the pathogenesis of *** effect of DNaseⅡand neuronal cytoplasmic dsDNA on neuronal tau hyperphosphorylation remains *** The levels of neuronal DNaseⅡand dsDNA in WT and Tau-P301S mice of different ages were measured by immunohistochemistry and immunolabeling,and the levels of DNaseⅡin the plasma of AD patients were measured by *** investigate the impact of DNaseⅡon tauopathy,the levels of phosphorylated tau,phosphokinase,phosphatase,synaptic proteins,gliosis and proinflammatory cytokines in the brains of neuronal DNaseⅡ-deficient WT mice,neuronal DNaseⅡ-deficient Tau-P301S mice and neuronal DNaseⅡ-overexpressing Tau-P301S mice were evaluated by immunolabeling,immunoblotting or *** performance was determined using the Morris water maze test,Y-maze test,novel object recognition test and open field *** The levels of DNaseⅡwere significantly decreased in the brains and the plasma of AD ***Ⅱalso decreased age-dependently in the neurons of WT and Tau-P301S mice,along with increased dsDNA accumulation in the *** DNA accumulation induced by neuronal DNaseⅡdeficiency drove tau phosphorylation by upregulating cyclin-dependent-like kinase-5(CDK5)and calcium/calmodulin activated protein kinaseⅡ(CaMKⅡ)and downregulating phosphatase protein phosphatase 2A(PP2A).Moreover,DNaseⅡknockdown induced and significantly exacerbated neuron loss,neuroinflammation and cognitive deficits in WT and Tau-P301S mice,respectively,while overexpression of neuronal DNaseⅡexhibited therapeutic ben

关键词： DNaseⅡ Alzheimer’s disease Double-stranded DNA Tau phosphorylation Tauopathy

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Strategic design and fabrication of MXenes-Ti_(3)CNCl_(2)@CoS_(2) core-shell nanostructure for high-efficiency hydrogen evolution

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Nano Research 2022年第7期15卷 5977-5986页

作者： Jizhou Jiang Saishuai Bai Meiqing Yang Jing Zou Neng Li Jiahe Peng Haitao Wang Kun Xiang Song Liu Tianyou Zhai School of Environmental Ecology and Biological Engineering School of Chemistry and Environmental EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationWuhan Institute of TechnologyWuhan 430205China College of Life and Environmental Science Hunan University of Arts and ScienceChangde 415000China Key Laboratory of Rare Mineral Ministry of Natural ResourcesGeological Experimental Testing Center of Hubei ProvinceWuhan 430034China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China Institute of Chemical Biology and Nanomedicine(ICBN) State Key Laboratory of Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

CoS_(2) is considered to be a promising electrocatalyst for hydrogen evolution reaction(HER).However,its further widespread applications are hampered by the unsatisfactory activity due to relatively high chemisorption energy for hydrogen ***,theoretical predictions of first-principles calculations reveal that the introduction of a Cl-terminated MXenes-Ti_(3)CNCl_(2) can significantly reduce the HER potential of CoS_(2)-based materials and the Ti_(3)CNCl_(2)@CoS_(2) core–shell nanostructure has Gibbs free energy of hydrogen adsorption(|ΔGH|)close to zero,much lower than that of the pristine CoS_(2) and Ti_(3)CNCl_(2).Inspired by the theoretical predictions,we have successfully fabricated a unique Ti_(3)CNCl_(2)@CoS_(2) core–shell nanostructure by ingeniously coupling CoS_(2) with a Cl-terminated MXenes-Ti_(3)CNCl_(2).Interface-charge transfer between CoS_(2) and Ti_(3)CNCl_(2) results in a higher degree of electronic localization and a formation of chemical ***,the Ti_(3)CNCl_(2)@CoS_(2) core–shell nanostructure achieves a significant enhancement in HER activity compared to pristine CoS_(2) and Ti_(3)CNCl_(2).Theoretical calculations further confirm that the partial density of states of CoS_(2) after hybridization becomes more non-localized,and easier to interact with hydrogen ions,thus boosting HER *** this work,the success of oriented experimental fabrication of high-efficiency Ti_(3)CNCl_(2)@CoS_(2) electrocatalysts guided by theoretical predictions provides a powerful lead for the further strategic design and fabrication of efficient HER electrocatalysts.

关键词： theoretical predictions Ti_(3)CNCl_(2)@CoS_(2)core-shell nanostructure electronic non-localization hydrogen evolution

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Developing hierarchical CdS/NiO hollow heterogeneous architectures for boosting photocatalytic hydrogen generation

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Nano Research 2022年第3期15卷 2003-2012页

作者： Chonghai Deng Fan Ye Tao Wang Xiaohui Ling Lulu Peng Hong Yu Kangzhe Ding Hanmei Hu Qiang Dong Huirong Le Yongsheng Han School of Energy Materials and Chemical Engineering Hefei UniversityHefei 230601China Anhui Province Key Laboratory of Advanced Building Materials Anhui Jianzhu UniversityHefei 230601China The Future Lab Tsinghua UniversityBeijing 100084China State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

The hierarchical binary CdS/NiO hollow heterogeneous architectures(HHAs)with p–n heterojunction are constructed by a facile microwave-assisted wet chemical process for high-efficient photocatalytic hydrogen evolution reaction(HER)from *** as-designed CdS/NiO HHAs are composed of hexagonal n-type CdS nanoparticles with a size in the range of 20–40 nm attaching to cubic p-type NiO hollow microspheres(HMSs)which are aggregates of porous nanoplates with a thickness of about 20 *** photocatalytic water splitting over CdS/NiO HHAs is significantly increased under simulated solar irradiation,among which the most active sample of CdS/NiO-3(the mass ratio of CdS to NiO is 1:3)exhibits the fastest photocatalytic HER rate of 1.77 mmol∙g^(−1)∙h^(−1),being 16.2 times than that of pure *** boosted photocatalytic HER could be attributed to the synergistic effect on the proportional p–n heterojunction with special hierarchical hollow and porous morphology,an enhancement of visible light absorption,and an improvement of photoinduced charge separation as well as the photo-stability given by the composite *** work shows a viable strategy to design the heterojunction with special morphology for the efficient hydrogen generation by water splitting utilizing solar energy.

关键词： CdS nanoparticls NiO hollow microspheres p-n heterojunction hierarchical structure photocatalytic hydrogen evolution

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Optimising the oil phases of aluminium hydrogel-stabilised emulsions for stable,safe and efficient vaccine adjuvant

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Frontiers of Chemical Science and engineering 2022年第6期16卷 973-984页

作者： Lili Yuan Xiao-Dong Gao Yufei Xia Key Laboratory of Carbohydrate Chemistry and Biotechnology Ministry of EducationSchool of BiotechnologyJiangnan UniversityWuxi 214122China State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Innovation Academy for Green Manufacture Chinese Academy of SciencesBeijing 100190China

To increase antibody secretion and dose sparing,squalene-in-water aluminium hydrogel(alun^-stabilised emulsions(ASEs)have been developed,which offer increased surface areas and cellular interactions for higher antigen loading and enhanced immune ***,the squalene(oil)in previous attempts suffered from limited oxidation resistance,thus,safety and stability were *** a clinical translational perspective,it is imperative to screen the optimal oils for enhanced emulsion ***,because of the varying oleic to linoleic acid ratio,soybean oil,peanut oil,and olive oil were utilised as oil phases in the preparation of aluminium hydrogel-stabilised squalene-in-water emulsions,which were then screened for their stability and ***,the underlying mechanisms of oil phases and emulsion stability were unravelled,which showed that a higher oleic to linoleic acid ratio increased anti-oxidative capabilities but reduced the long-term storage stability owing to the relatively low zeta potential of the prepared *** a result,compared with squalene-in-water ASEs,soybean-in-water ASEs exhibited comparable immune responses and enhanced *** optimising the oil phase of the emulsion adjuvants,this work may offer an alternative strategy for safe,stable,and effective emulsion adjuvants.

关键词： pickering emulsion vaccine adjuvant alum-stabilised emulsion oleic to linoleic acid ratio stability

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