This study compares the degradation of diethyl phthalate (DEP) by the electro-peroxone (E-peroxone) process with three different carbon-based cathodes, namely, carbon-polytetrafluorethylene (carbon-PTFE), carbon felt,...
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This study compares the degradation of diethyl phthalate (DEP) by the electro-peroxone (E-peroxone) process with three different carbon-based cathodes, namely, carbon-polytetrafluorethylene (carbon-PTFE), carbon felt, and reticulated vitreous carbon (RVC). Results show that the three cathodes had different electrocatalytic activity for converting sparged O2 to H2O2, which increased in order of carbon felt, RVC, and carbon-PTFE. The in-situ generated H2O2 then reacts with sparged O3 to yield OH, which can in turn oxidize ozone-refractory DEP toward complete mineralization. In general, satisfactory total organic carbon removal yields (76.4-91.8%) could be obtained after 60min of the E-peroxone treatment with the three carbon-based cathodes, and the highest yield was obtained with the carbon-PTFE cathode due to its highest activity for H2O2 generation. In addition, the carbon-PTFE and carbon felt cathodes exhibited excellent stability over six cycles of the E-peroxone treatment of DEP solutions. Based on the intermediates (e.g., monoethyl phthalate, phthalic acid, phenolics, and carboxylic acids) identified by HPLC-UV, plausible reaction pathways were proposed for DEP mineralization by the E-peroxone process. The results of this study indicate that carbon-based cathodes generally have good electrocatalytic activity and stability for application in extended E-peroxone operations to effectively remove phthalates from water.
With the development of science and technology, the hardware and software design of transformer intelligent measurement and control terminal is very important. Based on the hardware and software appization of internet...
With the development of science and technology, the hardware and software design of transformer intelligent measurement and control terminal is very important. Based on the hardware and software appization of internet of things, the design scheme of hardware and software structure is given. Supported by high-performance operating system, the terminal device can be upgraded flexibly through APP application software. The intelligent terminal pair can realize full data collection, full control and full fusion, and real-time exchange of key operation data with the power distribution master station. The intelligent terminal can support 5G communication and realize full compatibility of communication conditions downward.
We constructed a frequently updated, near-real-time global powergeneration dataset: Carbon Monitor-power since January, 2016 at national levels with near-global coverage and hourly-to-daily time resolution. The data ...
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