The premixed flames of DME-hydrogen-air premixed mixture were studied by the outwardly expanding flame and schlieren photography. The influences from equivalence ratio, hydrogen addition and initial pressure on the fl...
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Laminar premixed stoichiometric methane/hydrogen/oxygen/argon flames were investigated with tun- able synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam sampling mass spec- trometry techniques. Th...
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Laminar premixed stoichiometric methane/hydrogen/oxygen/argon flames were investigated with tun- able synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam sampling mass spec- trometry techniques. The methane/hydrogen fuel blends with hydrogen volumetric fraction of 0, 20%, 40%, 60% and 80% were studied. All observed flame species, including stable intermediates and radi- cals in the flames, were detected by measuring photoionization mass spectra and photoionization effi- ciency (PIE) spectra. Mole fraction profiles of major species and intermediates were derived by scan- ning burner at some selected photon energies near ionization thresholds. The influence of hydrogen addition on mole fraction of major species and intermediates was analyzed. The results show that the major species mole fraction of CO, CO2 and CH4 decreases with the increase of hydrogen fraction. The mole fraction of intermediates measured in this experiment decreases remarkably with the increase of hydrogen fraction. This would be due to the increase of H and OH radicals by hydrogen addition and the high diffusivity and activity of H radical promoting the chemical reaction. In addition, the increase of H/C ratio with the increase of hydrogen fraction also leads to the decrease of the mole fraction of car- bon-related intermediates and contributes to the decrease of unburned and incomplete combustion products.
First the flow friction characteristics of nitrogen and helium in stainless steel microtubes, glass microtubes, square glass microchannels, and rectangular silicon microchannels are tested. The data in glass microtube...
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ISBN:
(纸本)0791842924
First the flow friction characteristics of nitrogen and helium in stainless steel microtubes, glass microtubes, square glass microchannels, and rectangular silicon microchannels are tested. The data in glass microtubes with diameters from 50 to 201 microns and in square glass channels with characteristic diameters from 52 to 100 microns show that the friction factors are in good agreement with the conventional predictions. The friction factors in stainless-steel tubes with diameters from 119 to 300 microns are much higher than the conventional ones. The results for two of the four silicon microchannels with characteristic diameters from 26-60 microns are in good agreement while those of the other two channels are larger. This discrepancy is resulted from the large relative surface roughness. Smaller friction factors in glass microtubes with diameters from 10 to 20 microns are obtained due to the rarefaction effect. Second the flow friction experimental data for deionized water flow in glass microtubes with diameters from 50 to 530 microns show that friction factors and transition Reynolds numbers are in good agreement with the conventional predictions. However, the friction factors in stainless steel microtubes with diameters from 50-1570 microns are much higher than the conventional predictions. This discrepancy is attributed to the large surface relative roughness or denser roughness distribution. Numerical simulations considering electroviscous effect are carried out. The simulation results show that the electroviscous effect does not play a significant role in the friction factor for channel dimensions of the order of microns though it does affect the velocity profile and hence it could be neglected in engineering applications for channel dimensions of the order of microns. Third the measured local Nusselt number distribution of deionized water along the axial direction of the stainless steel tubes of 373-1570 microns with uniform heat flux do not accord with th
Particle Image Velocimetry (PIV) technique was employed to study experimentally gas-liquid two-phase flow in an aeration tank. In terms of the PIV principles, an algorithm of PIV based on the Fast Fourier Transforma...
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Particle Image Velocimetry (PIV) technique was employed to study experimentally gas-liquid two-phase flow in an aeration tank. In terms of the PIV principles, an algorithm of PIV based on the Fast Fourier Transformation (FFT) was worked out. The PIV program was developed and verified, and then was used to measure three kinds of states in the testing device. The program was also used to calculate and analyze the related parameters. The experimental data indicate that the bubbles in testing device have the longest resident time and stronger turbulent intensity for the gas-liquid two-phase flow in a special case (Case 3), resulting in great increase of the oxygen transferring speed and efficiency, whereby providing the basis for the selection design of aeration tank.
A new method of investigating catalytic combustion characteristics of pulverized coal was introduced using synthetical thermal analyzer, that is, the referenced DTA. Ignition temperatures of anthracite with K2CO3, Fe2...
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A new method of investigating catalytic combustion characteristics of pulverized coal was introduced using synthetical thermal analyzer, that is, the referenced DTA. Ignition temperatures of anthracite with K2CO3, Fe2O3, CaCO3 and CeO2 addition were 319°C, 410°C, 400°C and 405°C respectively determined by the referenced DTA. The ignition temperatures decreased by catalysts were observed directly from the reference DTA curves. In addition, variations of heat release during pulverized coal combustion were calculated by the referenced DTA curves. The heat releases of anthracite combustion increased by 340.2 J/g, 352.8 J/g, 348.6 J/g and 264.6 J/g, respectively, with K2CO3, Fe2O3, CaCO3 and CeO2 addition. The above results are accordance with those from conventional DTA experiment. However, the referenced DTA is more effective and direct to show catalytic combustion characteristics of pulverized coal.
The photocatalytic performance of ZnO/ZnS hybrid nanocomposite was largely higher than that of the mere ZnO or ZnS nanoparticles,but the complicated procedure and misdistribution of final products limited its large-sc...
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The photocatalytic performance of ZnO/ZnS hybrid nanocomposite was largely higher than that of the mere ZnO or ZnS nanoparticles,but the complicated procedure and misdistribution of final products limited its large-scale *** exploration of a novel synthesis route of ZnO/ZnS hybrid photocatalysts with high catalytic performance is becoming a crucial step for the large-scale application of ZnO/ZnS hybrid photocatalytic *** and characterization of nanosized ZnO/ZnS hybrid photocatalysts were studied in this *** photocatalysts were obtained via microwavehydrothermal crystallization with the help of sodium *** products were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),particle size distribution(PSD),and Fourier transformed infrared spectroscopy(FT-IR).The results indicated that so-synthesized ZnO/ZnS samples consisted of the high pure cubic(sphalerite)ZnS and hexagonal ZnO nanocrystallines with a narrow particle size *** possible formation mechanisms of ZnO/ZnS nanocrystallines were mainly attributed to the superficially protective effect of *** photocatalytic experiments demonstrated that the ZnO/ZnS photocatalysts exhibited a higher catalytic activity for the degradation of acid fuchsine than other monocomponents.
Brownian dynamics simulation is conducted for a dilute surfactant solution under a steady uniaxial elongational flow. A new inter-cluster potential is used for the interaction among surfactant micelles to determine th...
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Brownian dynamics simulation is conducted for a dilute surfactant solution under a steady uniaxial elongational flow. A new inter-cluster potential is used for the interaction among surfactant micelles to determine the micellar network structures in the surfactant solution. The micellar network is successfully simulated. It is formed at low elongation rates and destroyed by high elongation rates. The computed elongational viscosities show elongation- thinning characteristics. The relationship between the elongational viscosities and the mierostructure of the surfactant solution is revealed.
The effect of Ca-Fe-Ce series catalyst on the characteristics of anthracite combustion was investigated by thermo-gravimetric analysis. The results showed that there may be a synergetic effect among the components in ...
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The effect of Ca-Fe-Ce series catalyst on the characteristics of anthracite combustion was investigated by thermo-gravimetric analysis. The results showed that there may be a synergetic effect among the components in the composite catalyst and the composite catalyst exhibits better performance than the single one for the anthracite combustion. The combustion characteristics of anthracite are affected by the dispersion of catalyst, heating rate and combustion atmosphere. The catalytic effect is enhanced by increasing the catalyst dispersion. The reduction degree of ignition temperature increases with the increase of heating rate. The ignition temperature decreases significantly with the increase of O2 concentration.
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