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Cooperative structure of Li/Ni mixing and stacking faults for achieving high-capacity Co-free Li-rich oxides

Journal of Energy Chemistry 2024年第8期95卷 315-324,I0007页

作者： Zhen Wu Yu-Han Zhang Hao Wang Zewen Liu Xudong Zhang Xin Dai Kunyang Zou Xiaoming Lou Xuechen Hu Lijing Ma Yan Liu Yongning Liu State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101ShandongChina Hefei Advanced Computing Center Operation Management Corp Ltd Hefei 230088AnhuiChina Center for High Performance Computing Network Information CenterXi’an Jiaotong UniversityXi’an 710049ShaanxiChina Wuhan Dongfeng Motor Corporation Ltd Wuhan 430056HubeiChina School of Materials Science and Intelligent Engineering Nanjing UniversitySuzhou 215163JiangsuChina Key Laboratory of MEMS of the Ministry of Education Southeast UniversityNanjing 210096JiangsuChina International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high ***,they commonly face severe structural instability and poor electrochemical activity,leading to diminished capacity and voltage ***,we introduce a Co-free LLO,Li_(1.167)Ni_(0.222)Mn_(0.611)O_(2)(Cf-L1),which features a cooperative structure of Li/Ni mixing and stacking *** structure regulates the crystal and electronic structures,resulting in a higher discharge capacity of 300.6 mA h g^(-1)and enhanced rate capability compared to the typical Co-free LLO,Li_(1.2)Ni_(0.2)Mn_(0.6)O_(2)(Cf-Ls).Density functional theory(DFT)indicates that Li/Ni mixing in LLOs leads to increased Li-O-Li configurations and higher anionic redox activities,while stacking faults further optimize the electronic interactions of transition metal(TM)3d and non-bonding O 2p ***,stacking faults accommodate lattice strain,improving electrochemical reversibility during charge/discharge cycles,as demonstrated by the in situ XRD of Cf-L1 showing less lattice evolution than *** study offers a structured approach to developing Co-free LLOs with enhanced capacity,voltage,rate capability,and cyclability,significantly impacting the advancement of the next-generation Li-ion batteries.

关键词： Co-free Li-rich oxides Li/Ni mixing Stacking faults Electronic structure

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A computational particle fluid-dynamics simulation of hydrodynamics in a three-dimensional full-loop circulating fluidized bed: Effects of particle-size distribution

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Particuology 2020年第2期18卷 134-145页

作者： Hang Zhang Youjun Lu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049ShaanxiChina

A computational particle fluid-dynamics model coupled with an energy-minimization multi-scale(EMMS)drag model was applied to investigate the influence of particle-size distribution on the hydrodynamics of a three-dimensional full-loop circulating fluidized *** particle systems,including one monodisperse and two polydisperse cases,were *** numerical model was validated by comparing its results with the experimental axial voidage distribution and solid mass *** EMMS drag model had a high accuracy in the computational particle fluid-dynamics simulation of the three-dimensional full-loop circulating fluidized *** total number of parcels in the system(Np)influenced the axial voidage distribution in the riser,especially at the lower part of the *** numerical simulation results showed that axial segregation by size was predicted in the two polydisperse cases and the segregation size increased with an increase in the number of size *** axial voidage distribution at the lower portion of the riser was significantly influenced by particle-size ***,radial segregation could only be correctly predicted in the upper region of the riser in the polydisperse case of three solid species.

关键词： Circulating fluidized bed Computational particle fluid dynamics Particle-size distribution Energy-minimization multiscale model Three-dimensional full-loop simulation

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Dissolution characteristics of mixed inorganic salts under supercritical water gasification of oily wastewater for hydrogen production

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International Journal of Hydrogen Energy 2025年 140卷 563-572页

作者： Siqi Rong Fengyuan Yang Anlan Xie Ruoyu Wang Han Jiang Pengyuan Zhao Yong Huang Yunan Chen Liejin Guo State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University No.28 Xianning West Road Xi'an 710049 China Science and Technology on Plasma Dynamics Laboratory Air Force Engineering University Xi'an Shanxi 710038 China

In this study, the solubility characteristics of mixed inorganic chloride salts in supercritical water gasification are investigated experimentally to provide theoretical guidance for the optimization of the design of anti-blockage deposition in the SCWG process of oily wastewater and other high-salt organics. At present, there is a lack of experimental studies on the solubility of mixed inorganic salts in supercritical water, so this study investigates the solubility characteristics of mixed inorganic chloride salts containing NaCl, KCl, and CaCl 2 in supercritical water through real supercritical water experimental conditions. The solubility of the mixed inorganic chloride salts in supercritical water was analyzed in the parameter ranges of 673∼823 K and 22.5–30 MPa, mainly for the experimental conditions. It is found that the solubility of mixed inorganic salts is primarily affected by the temperature, and the solubility decreases with the increase of temperature, while the solubility of each component of mixed inorganic salts has a competitive relationship with each other, and the stronger the ionic bonding ability of inorganic salt ions, the lower the solubility of the mixed supercritical water solution. Finally, the simulation of real oil-containing wastewater with high mineralization found that the non-polarity of the supercritical water system further increased under the environment containing organic matter, which made the solubility of polar inorganic salts decrease.

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Instantaneous mixing characteristics of binary mixtures differing in density in a gas-solid fluidised bed

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Particuology 2020年第6期18卷 63-71页

作者： Zhen Wan Youjun Lu Hao Wang State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049ShaanxiChina

Characterisations of instantaneous mixing behaviours in fluidised beds with binary mixtures has many *** studied the instantaneous mixing characteristics of binary mixtures in a 2-D quasi gas-solid fluidised bed using a capacitance probe *** method enabled the quantitative assessment of instantaneous mixing behaviours,including mixing index,rate,and *** kinds of binary mixtures of similar size but different density were used for the transient and steady fluidisation experiments in a bubbling fluidised *** mixing curves of initially segregated binary mixtures were acquired,and the instantaneous characteristics for the entire process were *** equation was proposed to describe the mixing process and predict the mixing degree over *** comparing experiments with different working conditions,the effects of superficial gas velocity and density ratio on the mixing in the centre and at the wall of the fluidised bed were *** the stable fluidisation stage,the axial concentration profiles of the mixtures were obtained,and the mechanisms of mixing were *** showed that the mixing level increased logarithmically with time and eventually reached a relatively stable *** the superficial gas velocity and reducing the density ratio promoted mixing and reduced mixing *** superficial gas velocities tended to mix the mixtures well and quickly,regardless of the density ratio of the two components.

关键词： Binary mixtures Fluidised bed Mixing Instantaneous characteristics

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Multiple load short-term forecasting model of integrated energy system based on multiple LSTM networks

Multiple load short-term forecasting model of integrated ene...

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International Conference on Power engineering 2021, ICOPE 2021

作者： Cai, Yanchun Xu, Kaiwen Chong, Daotong Wang, Jinshi Yan, Junjie Liu, Ming State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Accurate short-term load forecasting of integrated energy system can optimize system operation and play an important role in improving system energy efficiency. In this paper, a multiple load short-term forecasting model of integrated energy system based on multiple LSTM networks is proposed. Firstly, the load influencing factors are divided into meteorological characteristic, delay characteristic and periodic characteristic, and the correlation is calculated based on Pearson coefficient. Secondly, a load forecasting model with multiple LSTM network coupling is established to explore the relationship between load and three characteristics, and excavate the complex coupling relationship among cooling, heating and power. The results show that the model has better prediction performance compared with other commonly used models. © 2021 The Japan Society of Mechanical Engineers.

关键词： Long short-term memory

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Comparative experimental study on dynamic characteristics of bubble microlayers in small channel flow boiling and pool boiling 6

Comparative experimental study on dynamic characteristics of...

引用

6th International Conference on Fluid Mechanics and Industrial Applications, FMIA 2022

作者： Shen, Zhongxiang Gao, Ming Dong, Wuhan Zhang, Lixin Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai200093 China

The microlayer present at the bottom of the bubble plays a very important role in heat transfer during nucleation boiling. In this paper, the dynamic characteristics of microlayer at the bottom of boiling bubble in a small channel were studied by laser interferometry method and high speed camera, and the results were compared with pool boiling experiments. The results show that the bubbles have an obvious tendency to slip in the flow boiling. The microlayer interference fringe is deformed and no longer a complete Newtonian ring. By analyzing the thickness distribution of microlayer in different directions in flow boiling and the change of micro-contact angle in the flow direction, it was found that the micro-contact angle in the flow direction became larger with the growth of bubbles. © Published under licence by IOP Publishing Ltd.

关键词： Contact angle

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Study on Variable Condition of Large Temperature Differential Heating System With Integrated Ejector Heat Pump

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2022年第4期43卷 863-869页

作者： Wang, Li-Yuan Liu, Ji-Ping Fu, Yue Liu, Ming Yan, Jun-Jie Key Laboratory of Heat Flow Science and Engineering of Ministry of Education Xi'an Jiaotong University Xi'an710049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

In the case of increasing urban heating demand, reducing the return water temperature of primary heating network can improve the heating capacity and utilize and recycle low-temperature waste heat resources. The ejector heat pump can use the high temperature heat source of the primary heat network to reduce the temperature of the return water, it has the advantages of simple structure, stable and reliable operation. In this paper, a model of ejector heat pump system is established to study the variable operating conditions of ejector heat pump system under central heating regulation. The results show that the ejector heat pump can effectively reduce the primary heat network return water temperature, and the primary network return water temperature can be reduced by 22 degree centigrade under the same primary network water supply temperature. With the increase of water supply temperature of primary network, the temperature of primary network return water, COP of the heat pump system and ejector ejection ratio increase gradually, the exergy efficiency decreases gradually. In the process of heating regulation, with the increases of outdoor temperature, the primary network return water temperature increases continuously, and the exergy efficiency decreases gradually;However, when the outdoor temperature is lower than the local design temperature, the ejector ejection ratio and the COP of the heat pump system decrease sharply. © 2022, Science Press. All right reserved.

关键词： Water temperature

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Dynamic performance analysis of different schemes of solar tower power plant

Dynamic performance analysis of different schemes of solar t...

引用

International Conference on Power engineering 2021, ICOPE 2021

作者： Wang, Yaqian Chen, Weixiong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

In this paper, solar power tower stations with different configurations of steam generators are proposed, and a detailed dynamic model of one-dimensional distributed parameters is established and verified. The response characteristics of the two systems under the disturbance of the main controllable variables are calculated, and the results are analyzed and compared. It is concluded that, compared with steam turbines, steam generation systems have significant thermal inertia, and different steam generation system schemes will have a significant impact on the dynamic performance of the system. For a natural circulation-driven system, the energy balance and power output are more sensitive to the hot salt mass flow rate, and mass balance would be adjusted by the feedwater mass flow. For a once-through-driven system, the energy balance is controlled by hot salt mass flow, but the mass balance and power output should be adjusted by the feedwater mass flow. © 2021 The Japan Society of Mechanical Engineers.

关键词： Solar energy

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Balancing electron transfer and intermediate adsorption ability of metallic Ni-Fe-RE-P bifunctional catalysts via 4f-2p-3d electron interaction for enhanced water splitting

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Journal of Energy Chemistry 2024年第7期94卷 458-465页

作者： Hong-Rui Zhao Cheng-Zong Yuan Chenliang Zhou Wenkai Zhao Lunliang Zhang Cong-Hui Li Lei Xin Fuling Wu Shufeng Ye Xiaomeng Zhang Yunfa Chen School of Rare Earths University of Science and Technology of ChinaHefei 230026AnhuiChina Jiangxi Province Research Institute of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou 341119JiangxiChina State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Balancing electron transfer and intermediate adsorption ability of bifunctional catalysts via tailoring electronic structures is crucial for green hydrogen production,while it still remains challenging due to lacking efficient ***,one efficient and universal strategy is developed to greatly regulate electronic structures of the metallic Ni-Fe-P catalysts via in-situ introducing the rare earth(RE)atoms(Ni-Fe-RE-P,RE=La,Ce,Pr,and Nd).Accordingly,the as-prepared optimal Ni-Fe-Ce-P/CC self-supported bifunctional electrodes exhibited superior electrocatalytic activity and excellent stability with the low overpotentials of 247 and 331 mV at 100 mA cm^(-2) for HER and OER,*** the assembled electrolyzer,the Ni-Fe-Ce-P/CC as bifunctional electrodes displayed low operation potential of 1.49 V to achieve a current density of 10 mA cm^(-2),and the catalytic performance can be maintained for 100 *** results combined with density functional theory(DFT)calculation reveal that Ce doping leads to electron decentralization and crystal structure distortion,which can tailor the band structures and d-band center of Ni-Fe-P,further increasing conductivity and optimizing intermediate adsorption *** work not only proposes a valuable strategy to regulate the electron transfer and intermediate adsorption of electrocatalysts via RE atoms doping,but also provides a deep under-standing of regulation mechanism of metallic electrocatalysts for enhanced water splitting.

关键词： RE atoms Electron transfer Adsorption energy Oxygen evolution Hydrogen evolution

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Simulation and design of a heat-integrated double-effect reactive distillation process for propylene glycol methyl ether production

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Chinese Journal of Chemical engineering 2022年第12期52卷 103-114页

作者： Ran An Shengxin Chen Shun Hou Yuting Zhu Chunhu Li Xinbao Zhu Ruixia Liu Weizhong An Department of Chemical Engineering Ocean University of ChinaQingdao 266100China Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and EngineeringState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China College of Chemical Engineering Nanjing Forestry UniversityNanjing 210037China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

A double-effect reactive distillation(DERD)process was proposed for the production of propylene glycol methyl ether from propylene oxide and methanol to overcome the shortcoming of low selectivity and high-energy consumption in the tubular plug-flow reactor.A single-column reactive distillation(RD)process was conducted under optimized operating conditions based on sensitivity analysis as a *** results demonstrated that the proposed DERD process is able to achieve more than 95%selectivity of the desired *** that,a design approach of the DERD process with an objective of the minimum operating cost was proposed to achieve further energy savings in the RD *** proposed DERD configuration can provide a large energy-savings by totally utilization of the overhead vapor steam in the high-pressure RD column.A comparison of the single-column RD process revealed that the proposed DERD process can reduce the operating cost and the total annual cost of 25.3%and 30.7%,respectively,even though the total capital cost of DERD process is larger than that of the RD process.

关键词： Propylene oxide Reactive distillation Heat integration Propylene glycol monomethyl ether Process simulation

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