检索结果-内蒙古大学图书馆

The role of diffusion in the nucleation of calcium carbonate

Chinese Journal of Chemical engineering 2022年第3期35卷 275-281页

作者： Xiangyu Dou Haoyang Huang Yongsheng Han State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China College of Chemistry and Molecular Engineering Peking UniversityBeijing 100871China

Nucleation widely exists in nature,from cloud formation to haze *** classical nucleation theory(CNT)was created to describe the nucleation process,but it fails to predict many experimental phenomena due to the short consideration of nanoscale phenomena and macroscale *** the attachment and detachment of monomers are considered in the developed model of nucleation,the diffusion of chemicals in the bulk is not valued as supersaturation in the nucleation process so *** we employ simulation and experimental approaches to investigate how the diffusion of ions affects the nucleation of calcium *** diffusion of ions is regulated by the viscosity of solvents and the sonication imposed on the *** is found that the nucleation rates increased exponentially with the diffusion coefficient of ions,which is beyond the prediction of *** abnormal finding might be ascribed to the involvement of cluster aggregation in the nucleation of calcium *** study highlights the significance of chemical diffusion in the nucleation process,which may help to revise the nucleation theory and develop solutions for the rational synthesis of materials,as well as for the control of air pollution.

关键词： Calcium carbonate Nucleation Simulation Diffusion Dynamics

来源：评论

学校读者我要写书评

暂无评论

Molecular level understanding of CO_(2) capture in ionic liquid/polyimide composite membrane

引用

Frontiers of Chemical Science and engineering 2022年第2期16卷 141-151页

作者： Linlin You Yandong Guo Yanjing He Feng Huo Shaojuan Zeng Chunshan Li Xiangping Zhang Xiaochun Zhang Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and EngineeringState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China College of Mathematics and Physics Bohai UniversityJinzhou 121013China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China Zhengzhou Institute of Emerging Industrial Technology Zhengzhou 450001China

Ionic liquid(IL)/polyimide(PI)composite membranes demonstrate promise for use in CO_(2)separation ***,few studies have focused on the microscopic mechanism of CO_(2)in these composite systems,which is important information for designing new *** this work,a series of systems of CO_(2)in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide composited with 4,4-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)-based PI,6FDA-2,3,5,6-tetramethyl-1,4-phenylene-diamine,at different IL concentrations were investigated by all-atom molecular dynamics *** formation of IL regions in PI was found,and the IL regions gradually became continuous channels with increasing IL *** analysis of the radial distribution functions and hydrogen bond numbers demonstrated that PI had a stronger interaction with cations than ***,the hydrogen bonds among PI chains were destroyed by the addition of IL,which was favorable for transporting CO_(2).Furthermore,the self-diffusion coefficient and free energy barrier suggested that the diffusion coefficient of CO_(2)decreased with increasing IL concentrations up to 35 wt-%due to the decrease of the fractional free volume of the composite ***,the CO_(2)selfdiffusion coefficients increased when the IL contents were higher than 35 wt-%,which was attributed to the formation of continuous IL domain that benefitted the transportation of CO_(2).

关键词： carbon dioxide ionic liquid 6FDA-TeMPD composite membrane molecular dynamics simulation

来源：评论

学校读者我要写书评

暂无评论

Experimental Study on Supercritical Water Flooding in High Water Cut Heavy Oil Reservoirs

引用

Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2025年第5期46卷 1528-1533页

作者： Miao, Yan Zhao, Qiuyang Wang, Xuetao Lei, Yuhuan Gao, Yunbo Jin, Hui Guo, Liejin State Key Laboratory of Multiphase Flow Engineering Xi’an Jiaotong University Xi’an710049 China

Elevated water cut obstructs recovery of heavy oil in later stage of heavy oil reservoir exploitation. This paper simulates such scenarios using one-dimensional sandstone cores filled with saturated oil utilizing hot water flooding. Subsequently, we conducted indoor flooding tests for supercritical water flooding, high-pressure hot water flooding, and superheated steam flooding. Results reveal that supercritical water flooding yields the highest recovery rate (96.27%) and superior in-situ upgrading compared to hot water flooding and superheated steam flooding. The mechanism for enhancing oil recovery via 400◦C, 25 MPa supercritical water flooding in a high water cut heavy oil reservoir environment lies in the occurrence of thermal fluid breakthrough phenomenon, miscible flooding, and hydrothermal pyrolysis of heavy oil under supercritical water conditions. © 2025 Science Press. All rights reserved.

关键词： Petroleum reservoir evaluation

来源：评论

学校读者我要写书评

暂无评论

Novel Catalyst Coatings on Gas Diffusion Layers for Improved Proton Exchange Membrane Water Electrolysis: A Microscopic Analysis of D-Orbital Electron Interactions in Co0.75Ru0.21Ir0.04O0.9

SSRN

引用

SSRN 2024年

作者： Wang, Weiding Wang, Hao Zhang, Yan Yang, Suyi Wang, Baoyuan Dong, Wenxuan Li, Lubing Zhang, Lei Su, Jinzhan Guo, Liejin International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering School of Energy & Power Engineering Xi’an Jiaotong University Xi’an710049 China

Proton exchange membrane water electrolysis (PEMWE) has emerged as a reliable water splitting technology in recent years. The oxygen evolution reaction (OER) at the anode, is the rate-determining step in water electrolysis, and therefore, the kinetic and mass transfer performance of the oxygen evolution reaction should be further studied. Efficient electron and water transfer between the catalyst layer (CL) and gas diffusion layer (GDL) is crucial for optimizing PEMWE performance. In this work, Ru-core modified materials were successfully synthesized via a hydrothermal method and then spray-coated onto the surface of the gas diffusion layer. Physical and electrochemical characterization showed that 0.10 mg cm-2 was the optimal dosage of the coating. The single cell with this optimal coating exhibited a well-promoted and outstanding performance that a cell voltage of 1.71 V@1 A cm-2 and an overpotential of 222 mV@10 mA cm-2. This enhancement was primarily attributed to the improved ohmic and mass transfer properties. Specifically, the promotion of kinetic and mass transfer performance was due to the attraction of the empty d-orbitals of Ru, Co, and Ir, which enhanced electron transmission between the catalyst layer (CL) and gas diffusion layer. Physical analysis revealed that the reductive gaseous products caused Co (Ⅲ) to transform to Co (Ⅱ) and the formation of Co3O4 and RuO2 was well-protected by the Co (II)-rich Co3O4 phase due to its reductivity nature. Additionally, the effusion of gaseous products from the solid phase accelerated pore formation, thereby increasing the specific surface area of the material. © 2024, The Authors. All rights reserved.

关键词： Electrolysis

来源：评论

学校读者我要写书评

暂无评论

Core-shell gold-copper nanoparticles:Evolution of copper shells on gold cores at different gold/copper precursor ratios

引用

Chinese Journal of Structural Chemistry 2023年第11期42卷 32-39页

作者： Shaonan Tian Yu Zhang Qing Zeng Junyu Zhong Hui Liu Lin Xu Jun Yang State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing100190China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing100049China State Key Laboratory of Bio-fibers and Eco-textiles Qingdao UniversityQingdao266071China School of Chemistry and Materials Science Jiangsu Key Laboratory of New Power BatteriesJiangsu Collaborative Innovation Centre of Biomedical Functional MaterialsNanjing Normal UniversityNanjing210023China

Core-shell nanostructures usually exhibit tunable catalytic properties in comparison with their single core or shell counterpart due to electronic interaction and lattice strain between the core and shell ***,we report the intriguing evolution of copper(Cu)shells on the gold(Au)cores at different Au/Cu precursor ratios during the synthesis of core-shell Au-Cu nanoparticles at an organic medium via seed-mediated growth *** brief,at relatively low Cu ratios,quasi-spherical Au-Cu nanoparticles with conventional core-shell structures are the majority products,in which the Cu shell thickness increases with the increase of Cu precursor *** dif-ference is that at high Cu ratios,the Cu shells no longer increase their thickness,but evolve into a dendritic ***,the core-shell Au-Cu nanoparticles with dendritic Cu shells could be transformed into interesting Au-Cu cage-bell structures after a ripening process at elevated ***,through galvanic replacement reaction with Pt precursors,the thin Cu shells could be converted into CuPt alloy shells on the Au cores,which exhibit enhanced activity towards methanol oxidation reaction with satisfactory durability,in comparison with that of commercial Pt/C catalysts.

关键词： Core-shell nanostructure Seed-mediated growth Electronic interaction Lattice strain Methanol oxidation reaction

来源：评论

学校读者我要写书评

暂无评论

Excellent Antibacterial Performance of ROS-mediated Cu-doped ZIF-8 and the Mechanism of ROS Generation 18

Excellent Antibacterial Performance of ROS-mediated Cu-doped...

引用

18th International Conference on Indoor Air Quality and Climate, INDOOR AIR 2024

作者： Chen, Yunfa Zhang, Jingkun Ding, Yan Yin, Hang State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing China Vehicle Emission Control Center Chinese Research Academy of Environmental Sciences Beijing China

ISBN: (纸本)9798331306816

Nowadays, it is necessary to explore efficient antibacterial materials to complement or substitute the conventional antibiotic, to cope with the ever-growing bacterial contamination. Here, a series of Cu-doped ZIF-8 materials are prepared and adopted for disinfection against typical bacteria E. coli and S. aureus in dark. The results show that 5-7 log efficiency can be achieved at a dosage of 15-30 mg mL-1 of 1.35 atomic % Cu doped ZIF-8, and this concentration is also safe as verified by cytotoxicity test. Mechanism investigation shows that Cu(II) is reduced to Cu(I), which would contribute to the effective electron transfer for the reactive oxygen species generation. And these reactive oxygen species would cause oxidative stress and membrane damage on bacteria cells. All these results show the promise of Cu-doped ZIF-8 in the antibacterial applications especially in the environments without any energy input. © 2024 18th Conference of the International Society of Indoor Air Quality and Climate, INDOOR AIR 2024 - Conference Program and Proceedings. All rights reserved.

关键词： Reactive oxygen species

来源：评论

学校读者我要写书评

暂无评论

Experimental Investigation of the Photovoltaic Thermal (Pvt) Integrated with Ground Heat Exchanger (Ghe) Using Volcanic Tuff Stones

SSRN

引用

SSRN 2024年

作者： Alqatamin, Ahmad Jinzhan, S.U. International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China

This study investigates the combination of photovoltaic thermal (PVT) and ground heat exchanger (GHE) using volcanic tuff stones as a heat storage material if the combination of PVT and GHE technologies provides the potential for energy generation increased efficiency and performance. Volcanic tuff stones known for their high thermal conductivity and heat retention, act as an effective means of heat exchange in the system. The objective of the study is to investigate the electrical, thermal performance and efficiency of this integrated system. Where the ground heat exchanger comprises a single hole filled with volcanic tuff stones arranged strategically, featuring gaps between them to facilitate heat exchange. The hole dimensions are specified as 2.5 meters in length, 2 meters in width, and 3 meters in depth. A fan is situated at the exit square duct (400*400 mm) to extract ambient air. Experimental data was collected from the PVT-GHE system to evaluate its efficiency in harnessing solar energy and providing space heating or other heating applications and compared it with a traditional PVT system. The results show that integrating GHE into PVT systems dramatically decreases solar cell temperature and improves electrical efficiency. A PVT system with GHE had the maximum electrical efficiency at 17.99%, compared to 17.52% in a PVT system without GHE. In addition, the greatest possible electrical power in a PVT system with GHE was 65 W, but in a PVT system without GHE, it was 61W. Also, the outlet air temperature from GHE was consistently higher than the ambient temperature throughout the days of the experiment, with an average difference of about 10 ºC. © 2024, The Authors. All rights reserved.

关键词： Solar energy

来源：评论

学校读者我要写书评

暂无评论

Review, Numerical Validation, and Experiment Verification for Definite Solution Analogy Theory (Dsat) in Thermal-Hydraulic Scaling

SSRN

引用

SSRN 2024年

作者： Li, Xinyu Zhang, Dalin Jiang, Dianqiang Zhou, Xingguang Lv, Xindi Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University Xi’an710049 China China

The new generation of reactor technology: Fluoride-Salt-cooled high-Temperature Advanced Reactor (FuSTAR), mainly applied to the steady supply of stable electricity and high-temperature process heat for remote, underground, and arid areas. So far, the design of the heat transport system and Passive Residual Heat Removal System (PRHRS) of FuSTAR has been finished, but the scaling and experiment verification still needs to be carried out. In this study, the Definite Solution Analogy Theory (DSAT) was used for scaling analysis, and the scaling experiment platform of PRHRS was built. DSAT was verified through numerical simulation and experiment results, which can support the design and optimization of the PRHRS. The numerical test results show that the similar distribution of physical fields in dimensionless space on the prototype and experiment is realized under the DSAT framework. The steady-state experiment results show that the prototype of PRHRS can take away more than 1% of the decay heat of the total thermal power and has a margin of about 15% under a stable natural cycle. The maximum deviation between the measured temperature and the calculated value with DSAT is more than 4°C. The transient experiment results show that the maximum deviation of dimensionless solutions is less than 4%, which proves the high accuracy of DSAT and the PRHRS based on this framework can effectively remove the decay heat in the reactor. This work can be used to extend the scaling method of thermal-hydraulic in high dimensional space and transient conditions. © 2024, The Authors. All rights reserved.

关键词： Fluorine compounds

来源：评论

学校读者我要写书评

暂无评论

Experimental Study on Stable Jet Impact Process Under Simulated Pipeline Rupture 21

Experimental Study on Stable Jet Impact Process Under Simula...

引用

21st IEEE Student Conference on Research and Development, SCOReD 2023

作者： Tao, Zhang Qincheng, Bi Jinle, Zhao Teng, Wang Jingrong, Chen Fan, Feng Xi'an Jiaotong University State Key Lab Multiphase Flow Power Engn Shaanxi Xi'an China North China Electric Power University School of Energy Power and Mechanical Engineering Bao'ding Hebei China

ISBN: (纸本)9798350318821

In this study, an advanced experimental system was utilized that incorporated heating, jetting, recycling, and cooling capabilities to ensure the successful execution of stable jet impact experiment that simulating a pipeline complete rupture. High-temperature resistant tempered glass was employed in the experimental system to realize the visibility. During the experiment, 8mm pipes/nozzles of varying lengths were employed as the test sections, and jetting phenomena when the import status is single-phase cold water or two-phase mixture at 0-2MPa were obtained by high-resolution photos. Additionally, the shape of the jet cone and the impact force exerted on the target plate were meticulously analyzed after the working fluid under different state parameters jetting into an atmospheric pressure environment through pipes/nozzles. The research also focused on the variation trend in the magnitude of the jet-impact force, as a function of inlet pressure and temperature, target plate distances, and length-to-diameter ratios. The research findings revealed that cold water(below 100°C), sub-cooled water(above 100°C but not reaching saturation temperature), and two-phase steam-water mixture exhibited distinct jet cone shapes during the jetting process, resulting in varying distributions of the jet force. Furthermore, the distance from the spout to the target plate and the length-to-diameter ratio significantly influenced the magnitude of the jet impact force. © 2023 IEEE.

关键词： Pipelines

来源：评论

学校读者我要写书评

暂无评论

Advanced Nonflammable Localized High-Concentration Electrolyte For High Energy Density Lithium Battery

引用

Energy & Environmental Materials 2022年第4期5卷 1294-1302页

作者： Mengmin Jia Chi Zhang Yawei Guo Linshan Peng Xiaoyan Zhang Weiwei Qian Lan Zhang Suojiang Zhang CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an 710049China Langfang Institute of Process Engineering Chinese Academy of SciencesHebei 065001China

The key to realize long-life high energy density lithium batteries is to exploit functional electrolytes capable of stabilizing both high voltage cathode and lithium *** emergence of localized high-concentration electrolytes(LHCEs)shows great promise for ameliorating the above-mentioned interfacial *** this work,a lithium difluoro(oxalate)borate(LiDFOB)based nonflammable dual-anion LHCE is designed and *** in the mixture of trimethyl phosphate(TMP)/1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)),the continuously consumption of LiDFOB is suppressed by simply introducing lithium nitrate(LiNO_(3)).Meantime,as most of the TMP molecular are coordinated with Li^(+),the electrolyte does not show incompatibility issue between neither metal lithium nor graphite ***,it demonstrates excellent capability in stabilizing the interface of Ni-rich cathode and regulating lithium deposition *** Li||LiNi_(0.87)Co_(0.08)Mn_(0.05)O_(2)(NCM87)batteries exhibit high capacity retention of more than 90%after 200 cycles even under the high cutoff voltage of 4.5 V,1 C *** study offers a prospective method to develop safe electrolytes suitable for high voltage applications,thus providing higher energy densities.

关键词： dual-anion lithium metal battery localized high-concentration electrolyte nonflammable phosphate

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：