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SSRN 2024年

作者： Gai, Jingchun Qiu, Hua Xiong, Cha Zhao, Minghao He, Xinlu Yang, Zhan Feng, Zhiyuan Cehn, Xitao Huang, Zuohua School of Power and Energy Northwestern Polytechnical University Xi’an710072 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

This study experimentally explores the propagation mechanisms of acetylene/air detonation waves within a channel intermittently constrained on one side, utilizing soot foil and high-speed schlieren photography to capture the cellular structure and shock-flame evolution. The experiments revealed that the detonation waves traverse the semi-enclosed channel with various discrete wall configurations on the side in four distinct propagation modes: (I) periodic detonation failure and re-initiation;(II) single extinction and re-initiation;(III) localized extinction and (IV) non-extinction. Mode I occurs exclusively when the open area ratio exceeds 0.85, while detonation tends to favour Mode II when the gaps between discrete walls exceed three times the cell size;otherwise, it tends towards Modes III and IV. The re-initiation mechanism of detonation involves curvature shocks inducing local explosions of reactive mixtures through multiple Mach reflections off the discrete walls. The self-sustained propagation mechanism of the detonation wave is maintained by the interaction of strong transverse shocks reflected from discrete walls with the inherent transverse waves within the detonation structure, sustaining the instability of the cellular detonation. © 2024, The Authors. All rights reserved.

关键词： Detonation

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Improved filtered mesoscale interphase heat transfer model

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Particuology 2021年第4期19卷 176-186页

作者： Yu Li Yaxiong Yu Chi Zhang Zheqing Huang Qiang Zhou School of Chemical Engineering and Technology Xi’an Jiao Tong UniversityXi’an 710049China AVIC Xi’an Flight Automatic Control Research Institute Xi’an 710049China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiao Tong UniversityXi’an 710049China

Mesoscale structures that form in gas-solid flows considerably affect interphase heat transfer.A filtered interphase heat transfer model accounts for the effects of unresolved mesoscale structures is required in coarse-grid *** the literature,researchers obtain the filtered interphase heat transfer coefficient using a correction(Q)to the microscopic interphase heat transfer *** models are based on filtered data in the range 01 is *** percentage can reach approximately 20%when the dimensionless filter size is smaller than 1.028(66.7×the particle diameter).We proposed an improved filtered interphase heat transfer model by considering the data in the range Q<0 and Q>*** evaluated the predictive power of our model in an a priori *** model has much better performance than other models when the dimensionless filter size△<8.222.

关键词： Gas-solid flows Two-fluid model Interphase heat transfer Filtered model Mesoscale

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Evaporation of sub-millimeter flying dinitrogen tetroxide droplet under high temperature and pressure: Experimental measurement and theoretical modeling

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Chinese Journal of Aeronautics 2025年第5期 82-93页

作者： Lihan FEI Wu ZHU Yuyuan ZHANG Peng ZHANG Zuohua HUANG Chenglong TANG State Key Laboratory of Multiphase Flow and Power Engineering Xi'an Jiaotong University Department of Mechanical Engineering City University of Hong Kong

The evaporation behaviors are crucial for the flame location estimation in liquid rocketengines. This work, for the first time, experimentally reports the sub-millimeter droplet evaporationcharacteristics of the corrosive dinitrogen tetroxide（NTO, one prevailing hypergolic oxidizer） athigh ambient pressure up to 4.5 MPa. An in-house corrosion-resistant droplet generator is usedto generate isolated flying droplets of sub-millimeter size, which are then exposed in a gas environ-ment with temperatures between 1 010 K and 1 210 K and pressures in the range between 2.0 MPaand 4.5 MPa, provided by an optical rapid compression machine. Parallelly, a theoretical modelconsidering both the droplet ambient convection and the NTO dissociation is developed. Resultsindicate that firstly, the present theoretical model that considers the transient droplet-ambient con-vection as well as the temperature and pressure dependent rate of dissociation shows good agree-ment with the experimentally observed droplet lifetime. In addition, the flying droplets velocityregress gradually due to momentum exchange with the ambient, which is more prominent at higherpressure. The evaporation caused droplet size reduction is consistent with the classical D2-law pre-diction, in the present temperature and pressure range. Finally, higher temperature and pressureaccelerate the evaporation and an empirical correlation for the temperature and pressure dependentevaporation rate constant is proposed, which shows good agreement with experiment and simula-tion results.

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Boosting photocatalytic water vapor splitting by the integration of porous g-C_(3)N_(4)and carbonized melamine foam

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Science China Materials 2024年第9期67卷 2957-2964页

作者： Shujian Wang Dongjie Liu Chunyang Zhang Jie Huang Shidong Zhao Kejian Lu Biao Wang Hao Peng Yitao Si Maochang Liu International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an710049China School of Chemistry and Chemical Engineering Southeast UniversityNanjing211189China Suzhou Academy of Xi’an Jiaotong University Suzhou215123China Gree Altairnano New Energy Inc. Zhuhai519040China

We report a photothermally-induced liquid-solid/gas-solid-decoupling photocatalytic water-splitting system,where a carbonized melamine foam(CMF)and a porous g-C_(3)N_(4)(PCN)serve as the photothermal substrate and model photocatalyst,***,liquid water is transformed into the gaseous phase over the CMF due to the photothermal effect,and the generated vapor can be split into hydrogen by PCN via the *** unique biphasic photocatalytic system exhibits a high hydrogen production rate of 368.1µmol h^(-1),which is 2.4 and 25.6 times larger than those of the traditional triphasic PCN system(151.7µmol h^(-1))and g-C_(3)N_(4)(CN)system(14.4µmol h^(-1)),*** improved photocatalytic performance is mainly attributed to the optimized energy and mass transfer at the gas-liquid-solid reaction interface,where gas products are rapidly desorbed in the photocatalytic *** work provides a novel strategy to enhance the photocatalytic performance from the perspectives of energy and mass flow.

关键词： photocatalytic photothermal mass transfer g-C_(3)N_(4) gas-solid

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Influence of light-dark cycles on hydrogen production from sugarcane bagasse by Rhodobacter sphaeroides

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International Journal of Hydrogen Energy 2025年 145卷 28-35页

作者： Wen Cao Xuan Wei Jiyan Lu Mengyao Li Jiali Feng State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi PR China College of Biology and Oceanography Weifang University Weifang 261061 Shandong PR China Weifang Municipal Key Laboratory of Agricultural Planting Quantization and Application Weifang 261061 Shandong PR China

Photo-fermentative hydrogen production from lignocellulosic biomass offers a clean, efficient, and eco-friendly alternative for energy generation. Large-scale photo-fermentative hydrogen production, ideally conducted under outdoor conditions is influenced by the daily light-dark cycle. This study examines the effect of a 12-h light-dark cycle (12L/12D) on hydrogen production by Rhodobacter sphaeroides HY01 using sugarcane bagasse (SCB), comparing it with continuous light (CL) conditions. The results show that bacterial growth was not significantly affected by the light-dark cycle. The optical density (OD 660 ) of the culture reached 3.25 under 12L/12D and 3.49 under CL. However, total hydrogen yield decreased substantially under the light-dark cycle, from 6020.11 ± 54.71 mL/L in CL to 4242.73 ± 182.03 mL/L in the 12L/12D condition. Additionally, the rate of hydrogen production was higher under CL (119.78 ± 4.82 mL/(L·h)) compared to 12L/12D (60.97 ± 7.27 mL/(L·h)), while the lag phase was shorter under CL, at 17.25 ± 1.04 h, versus 20.37 ± 3.98 h under 12L/12D. Gas chromatography-mass spectrometry (GC-MS) analysis identified lactic acid, butyric acid, and ethanol as the primary soluble metabolites, with ethanol yield under 12L/12D being approximately half of that under CL. Notably, light conversion efficiency (LCE) for hydrogen production was significantly enhanced under the light-dark cycle, showing a 1.36-fold increase compared to CL conditions. These findings not only contribute to the understanding of the influence of light cycles on biohydrogen production but also support the development of more efficient and cost-effective biohydrogen systems for sustainable energy production.

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Sub- and Supercritical Water Flooding for Enhanced Oil Recovery in High Water Cut Heavy Oil Reservoirs: An Experimental Study

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SSRN 2024年

作者： Miao, Yan Zhao, Qiuyang Huang, Zujie Zhao, keyu Zhao, Hao Guo, Liejin Wang, Yechun State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Xinjin Weihua Institute of Clean Energy Research Foshan528216 China

High water cut poses a formidable challenge for heavy oil reservoirs, necessitating a strategy to enhance oil recovery. This study introduces a green-efficient approach - Supercritical Water Flooding (SCWF), suitable for sandstone heavy oil reservoirs with high water cut, compared to conventional subcritical water flooding and steam flooding. A novel experimental system (450°C,30MPa) was established to conduct SCWF experiments for heavy oil from Shengli Oilfield. The results showed that SCWF at 400°C and 25MPa had the recovery factor of 96.27% and the viscosity reduction rate of 61.6% for GD heavy oil. The dynamic process of SCWF is divided into three stages: pressure rising drainage stage, heating and depressurization stage, and miscible flooding stage. Analysis indicates that the high diffusivity, solubility and reactivity of supercritical water make thermal fluid breakthrough, miscible flooding and aquathermolysis reactions become the key mechanisms for high oil recovery and in situ upgrading of SCWF for high water cut heavy oil reservoirs. © 2024, The Authors. All rights reserved.

关键词： Crude oil

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A Web-like Three-dimensional Binder for Silicon Anode in Lithium-ion Batteries

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Energy & Environmental Materials 2024年第1期7卷 21-27页

作者： Liyuan Li Tao Li Yifan Sha Baozeng Ren Lan Zhang Suojiang Zhang CAS Key Laboratory of Green Process and Engineering Beijing Key Laboratory of Ionic Liquids Clean ProcessState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China Langfang Green Industrial Technology Center Langfang 065001China Henan Key Laboratory of Energy Storage Materials and Processes Zhengzhou Institute of Emerging Industrial TechnologyZhengzhou 450003China

Si anode is of paramount importance for advanced energy-dense lithium-ion batteries(LIBs).However,the large volume change as well as stress generates during its lithiation-delithiation process poses a great challenge to the long-term cycling and hindering its *** this work,a composite binder is prepared with a soft component,guar gum(GG),and a rigid linear polymer,anionic polyacrylamide(APAM).Rich hydroxy,carboxyl,and amide groups on the polymer chains not only enable intermolecular crosslinking to form a web-like binder,A2G1,but also realize strong chemical binding as well as physical encapsulating to Si *** resultant electrode shows limited thickness change of merely 9%on lithiation and almost recovers its original thickness on *** demonstrates high reversible capacity of 2104.3 mAh g^(-1)after 100 cycles at a current density of 1800 mA g^(-1),and in constant capacity(1000 mAh g^(-1))test,it also shows a long life of 392 ***,this soft-hard combining web-like binder illustrates its great potential in the future applications.

关键词： anionic polyacrylamide lithium-ion batteries Si anode thickness change web-like binder

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Data-Driven Surrogate Model for the Dynamic Characteristics of Supercritical Units

Data-Driven Surrogate Model for the Dynamic Characteristics ...

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Power System and New Energy Technology Innovation Forum (NPSIF), Boao New Power System International Forum -

作者： Shuai Dong An Zheng Junyao Jiang Wei Gao Ming Liu HUANENG YIMIN COAL-POWER CO. LTD. Hulunbuir China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

ISBN: (数字)9798331504557

ISBN: (纸本)9798331504564

Coal-fired power generation units are characterized by large inertia, strong coupling, and high delay, making dynamic characteristic modeling inherently complex and computationally intensive. To address this, this paper utilizes GSE software to explore the dynamic characteristics of supercritical units. Data-driven approaches are then employed to develop surrogate model for these dynamics, comparing neural networks and support vector regression methods in the process. The study indicates that the surrogate model achieves a relative prediction error of less than 1% for live steam temperature, reheater steam outlet temperature, and power output. For live steam pressure and reheater steam outlet pressure, the model maintains a relative error within 10%.

关键词： Support vector machines Technological innovation Temperature Accuracy Computational modeling Power system dynamics Neural networks Predictive models Vectors Load modeling

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Alkaline Pulping Catalyzed Ordered Conversion of Bark in Supercritical Water

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SSRN 2023年

作者： Ge, Hui Huang, Yong Liu, Zhaozheng Liu, Fan Chen, Yu-Nan Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University No.28 Xianning West Road Xi’an710049 China

The hydrophilicity of lignocellulosic biomass hinders the application of a high concentration slurry for supercritical water gasification, thereby reducing the efficiency of gasification and energy self-sufficiency. A pretreatment method of alkaline pulping with KOH and NaOH was proposed considering initial pressure to prepare high concentration slurry. In this study, bark as lignocellulosic biomass specimen, whose 30wt% and 40wt% slurries, with favorable rheology and stability, was prepared via alkaline pulping successfully. The most economical conditions were 180 °C and 24% KOH addition. The bark macromolecules were restructured due to the hydrolysis of cellulose and lignin by breaking down the hydrogen bond and ether bond with trivial hydrocarbon matrix loss. The scattered crystal growth being created and a reduction of hydrophilic groups facilitated the uniform premixing of bark and water, which is improved by a stable charge system furtherly. Additionally, metal ions could be deposited onto the bark surface during alkaline pulping. The chemical modification leading by alkaline pulping achieved the premixing of feedstock and water to form bark slurry. The conversion barrier was decreased to fulfill the ordered conversion. Consequently, the commendable catalytic effect of 95.66% gasification efficiency was displayed for 40wt% bark slurry with trivial coke yield. The functional groups of organic matter in the slurry were significantly converted into the gas phase, and lattice oxygen was produced in the solid product. The maximum alkali recovery of 80% was achieved at 580 °C. The successful completion of this research affirms the dominance of the pulping-alkali recovery-gasification method for expanding the application of SCWG of lignocellulosic biomass in large engineering projects. © 2023, The Authors. All rights reserved.

关键词： Chemical modification

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Simulation Study on the Dynamic Characteristics of Natural Circulation Coupled Phase Change Material for Equal Height Difference Passive Containment Cooling System

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SSRN 2024年

作者： Chen, Weixiong Huang, Yufan Wang, Han Yang, Xiaohu Li, Shaodan Zhao, Quanbin Chong, Daotong State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Wuhan Second Ship Design and Research Institute Wuhan430205 China

The passive containment cooling system (PCCS) plays a significant role in ensuring the safety of nuclear power plants. To further reduce peak pressure in the containment during a loss of coolant accident (LOCA), phase change materials (PCMs) are utilized to improve the system’s cooling effectiveness. The dynamic simulation model of PCCS has been developed using Apros software. This article focuses on examining the system’s dynamic characteristics related to various tube startup methods and comparatively analyzing the impact of different PCM thicknesses on heat transfer capacity. The results indicate that post-accident, PCM significantly suppresses peak pressure in the containment. Under the full tube startup method with 4 mm PCM, the peak pressure decreases to 1.75 MPa, whereas under the empty tube startup method, it is reduced to 1.69 MPa. With natural circulation empty tube startup method, PCM can reduce pressure change intensity in the containment but negatively affects natural circulation heat transfer. Although the full tube startup method underperforms the empty tube startup method on suppressing peak pressure, PCM can positively affect natural circulation heat transfer in the early stages of the accident. Empty tube startup offers the advantages of higher heat transfer capacity and lighter weight, making it the optimal choice for ocean nuclear platforms. Additionally, the higher peak power of PCM heat transfer under the empty tube startup method indicates that system can withstand larger thermal shocks. © 2024, The Authors. All rights reserved.

关键词： Thermoelectric equipment

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