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Effect of Chemical Composition on Adsorption and Agglomeration Characteristics of Ash Particles After Sulfuric Acid Adsorption 9th

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Effect of Chemical Composition on Adsorption and Agglomerati...

9th International Symposium on Coal Combustion, ISCC 2019

作者： Jiang, Jiahao Yan, Yu Guo, Jin Li, Yuesheng Deng, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China Guangdong Institue of Special Equipment Inspection and Research Foshan528251 China Guangdong Institue of Special Equipment Inspection and Research Shunde Institue of Inspection Foshan528300 China

ISBN: (纸本)9789811616563

The low-low temperature electrostatic precipitator has been applied to enhance the efficiency of power plants. In this paper, the influences of chemical constitutions on the adsorption properties of particulate matters with vitriolic acid and the agglomeration after adsorption are researched. Experiments are conducted on a one-dimensional adsorption system, which simulates the working environment of low-low-temperature electrostatic precipitator. The consequences display that the agglomeration between particulate matters in scanning electron microscopy are loose pellets agglomeration together, adhesion of loose pellets to massive particles, and massive particles agglomeration together. For Na and K, the amounts of elements added have little effect on the adsorption of the sulfuric acid by ash particles. For Mg, Fe, and Ca, when the oxide is used as an additive, the adsorption capacity of ash samples to the vitriolic acid was enhanced and the agglomeration phenomenon of the ash granules was more remarkable with increasing elements amounts. In addition, the change of Mg has great impact on vitriolic acid adsorption and granules agglomeration. © 2022, Tsinghua University Press.

关键词： Adsorption

A large-scale power-to-H 2 -to-power system adopting hydrogen mixed gas turbine for wind accommodation: Process modeling, optimal dispatch and economic feasibility analysis

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International Journal of Hydrogen Energy 2025年 145卷 345-357页

作者： Yanxin Li Xiaoqu Han Yiming Zhang Nikolaos Skordoulias Xuanhua Guo Junjie Yan Sotirios Karellas Emmanuel Kakaras State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Laboratory of Thermal Processes National Technical University of Athens Athens 15780 Greece Qingdao Huaru Energy Technology Company Limited Qingdao 266071 China Mitsubishi Hitachi Power Systems Europe GmbH Schifferstraße 80 Duisburg 47059 Germany

The high percentage of renewable energy penetration poses volatility and intermittency challenges, making it imperative to explore pathways for large-scale green hydrogen production and utilization. In the present work, a novel power-to-H 2 -to-power (PtH2tP) system is proposed for onshore wind accommodation, incorporating hydrogen mixed gas turbines (HMGTs). An innovative methodology integrating economic and carbon emissions assessment with optimal dispatch is developed, in which the HMGT off-design operational characteristics and policy compensation for green hydrogen are considered. A case study in China demonstrates the feasibility of the PtH2tP system in achieving flexible energy conversion and hydrogen self-sufficiency. Particularly, a levelized cost of electricity of 0.0537 €/kWh and carbon emissions of 0.29 kg CO 2 eq/kWh are observed. The fuel consumption of HMGTs and purchased grid electricity are significant contributors to carbon emissions. A comprehensive sensitivity analysis indicates an optimal hydrogen substitution ratio of 31% as the threshold for balancing economics and environmental benefits.

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Co_(2)N Nanoparticles Anchored on N-Doped Active Carbon as Catalyst for Oxygen Reduction Reaction in Zinc–Air Battery

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Energy & Environmental Materials 2022年第3期5卷 935-943页

作者： Xianli Wu Guosheng Han Hao Wen Yanyan Liu Lei Han Xingyu Cui Jiajing Kou Baojun Li Jianchun Jiang Research Center of Green Catalysis College of ChemistryZhengzhou University100 Science RoadZhengzhou 450001China National Engineering Laboratory for Biomass Chemical Utilization Institute of Chemical Industry of Forest ProductsChinese Academy of ForestryNanjing 210042China College of Science Henan Agricultural UniversityZhengzhou 450002China Davidson School of Chemical Engineering Purdue University480 Stadium Mall DriveIN 47906United States State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University28 Xianning West RoadXi'an 710049China

The development of efficient catalytic electrode toward oxygen reduction reaction(ORR)is still a great challenge for the wide use of zinc–air ***,Co_(2)N nanoparticles(NPs)anchored on N-doped carbon from cattail were verified with excellent catalytic performances for *** onset and half-wave potentials over the optimal catalyst reach to 0.96 V and 0.84 V,*** retention rates of 96.8%after 22-h test and 98.8%after running 1600 s were obtained in 1 M methanol *** functional theory simulation proposes an apparently increased electronic states of Co_(2)N in N-doped carbon layer close to the Fermi *** charge density,favorable adsorption,and charge transfer of intermediates originate from the coexistence of Co_(2)N NPs and N atoms in carbon *** superior catalytic activity of composites also was confirmed in zinc–air *** novel catalytic property and controllable preparation approach of Co_(2)Ncarbon composites provide a promising avenue to fabricate metal-containing catalytically active carbon from biomass.

关键词： catalytically active carbon Co2N nanoparticles N-doping oxygen reduction reaction zinc–air battery

Experimental Study of an Aluminum Based Three-Dimensional Thermosyphon Heat Sink with Microscale Enhancement Structure

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SSRN 2024年

作者： Yang, Xiaoping Bu, Shichao Jiang, Zhuye Zhou, Yao Sun, Zhen Zhang, Yonghai Wei, Jinjia School of Chemical Engineering and Technology Xi’an Jiaotong University Shaanxi Xi’an710049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China State Key Laboratory of Mobile Network and Mobile Multimedia Technology ZTE Corporation Hillsides China

Heat dissipation is a significant factor limiting the advancement of electronics. Currently, air cooling remains the most widely used method for heat dissipation due to the advantages of low-cost and easy-maintenance. However, the traditional air-cooling method based on all-solid heat sink fails to meet the fast development in thermal power of electronics because its limitation in area expansion by only solid fins. In this study, an aluminum based three-dimensional thermosyphon (3D-TS) coupling boiling-condensation heat transfer and forced air cooling is proposed to overcome the limitation of conventional air cooling methods. Meanwhile, micro pin-fins structure is used to enhance the boiling heat transfer as well as the performance of the 3D-TS. Using the environmentally friendly refrigerant R1233zd(E) as working fluid, the performance of the 3D-TS is experimentally studied and analyzed under different air volume flow rates. The results show that the total thermal resistance decreases firstly and then increases with the heating power, which is mainly dominated by the boiling mode on the substrate. Moreover, the micro pin-fins greatly enhances the boiling heat transfer on the substrate of the 3D-TS, which enables the 3D-TS to reach a minimum thermal resistance of 0.075 K/W and a maximum thermal dissipating power of 650 W with the temperature of the heating source below 85 °C. The 3D-TS proposed in this work is able to meet the cooling requirements of most high-performance chips. This paper provides valuable reference and guidance for the design and optimization of the phase-change devices. © 2024, The Authors. All rights reserved.

关键词： Aluminum

Experimental Study on Supercritical Water Flooding in High Water Cut Heavy Oil Reservoirs

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2025年第5期46卷 1528-1533页

作者： Miao, Yan Zhao, Qiuyang Wang, Xuetao Lei, Yuhuan Gao, Yunbo Jin, Hui Guo, Liejin State Key Laboratory of Multiphase Flow Engineering Xi’an Jiaotong University Xi’an710049 China

Elevated water cut obstructs recovery of heavy oil in later stage of heavy oil reservoir exploitation. This paper simulates such scenarios using one-dimensional sandstone cores filled with saturated oil utilizing hot water flooding. Subsequently, we conducted indoor flooding tests for supercritical water flooding, high-pressure hot water flooding, and superheated steam flooding. Results reveal that supercritical water flooding yields the highest recovery rate (96.27%) and superior in-situ upgrading compared to hot water flooding and superheated steam flooding. The mechanism for enhancing oil recovery via 400◦C, 25 MPa supercritical water flooding in a high water cut heavy oil reservoir environment lies in the occurrence of thermal fluid breakthrough phenomenon, miscible flooding, and hydrothermal pyrolysis of heavy oil under supercritical water conditions. © 2025 Science Press. All rights reserved.

关键词： Petroleum reservoir evaluation

Editor, Applied Energy Paper Entitled: "Industrialized Bimetallic Nano Oxygen Carrier for Dual-Stage Hydrogen Production from Mid-Temperature Chemical Looping Reforming"

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SSRN 2024年

作者： Tang, Sanli Gai, Zhongrui Li, Yang Liu, Yunlian Liu, Mingkai Pan, Ying Jin, Hongguang Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China University of Chinese Academy of Sciences Beijing100049 China

Chemical looping methane reforming has emerged as a promising avenue to produce blue hydrogen. Among the various oxygen carriers investigated for this process, Fe2O3 and NiO have garnered significant attention due to their affordability and favorable thermodynamic properties. Usually, such oxygen carriers had satisfactory H2 yields only in the oxidation stage with temperatures over 800 °C. This limitation poses challenges for industrial reactor design and product gas separation. In this study, we present a nanoscale Fe/Ni bimetallic oxygen carrier for dual-stage hydrogen generation from mid-temperature chemical looping methane reforming. The lab-scale oxygen carrier can produce H2 in both the reduction and the oxidation steps, reaching 75% overall H2 purity while reducing the temperature to 500-600 °C. Moreover, the 10-kg scale oxygen carrier achieved >90% CH4 conversion, >78% H2 purity and 2.8-3.5 H2 molecules produced per CH4 molecule. Made into beads, the 10-kg scale oxygen carrier still maintained an outlet H2 purity of >70% with redox stability over 150 cycles. These findings contribute to the advancement of chemical looping methane reforming for blue hydrogen production and supply. © 2024, The Authors. All rights reserved.

关键词： Hydrogen production

Novel Fast Predesign Methodology of Centrifugal Compressor Used for Pemfcs Based on 1d Loss Mechanism and Interpretable Machine Learning Models

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SSRN 2024年

作者： Chen, Zhikai Sun, Jieshuai Chen, Ziying Spence, Stephen Peng, Xueyuan Feng, Jianmei School of Energy and Power Engineering Xi'an Jiaotong University Xi'An710049 China School of Mechanical Manufacturing and Biomedical Engineering Trinity College Dublin Dublin 2 Ireland State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'An710049 China

The significant challenge of balancing accuracy, time, and cost has consistently compelled designers to develop more efficient and economical predesign methods. To tackle this issue, a novel predesign method amalgamating one-dimensional (1D) loss model with gradient boosting decision tree (GBDT) model has been proposed. A high-precision 1D loss model was developed and experimentally tested for rapid performance assessment. Furthermore, two machine learning models, named Extreme Gradient Boosting (XGBoost) and Light Gradient Boosting Machine (LightGBM), were trained, and compared to construct surrogate models. Hyperparameter optimization was executed utilizing a Bayesian algorithm to identify the optimal hyperparameter set. Additionally, the Sobol sensitivity analysis and Shapley Additive Explanations (SHAP) based interpretability were used to explore the paramount factors affecting the model's outputs and the interactions among the sensitive parameters. The findings underscore that the blade outlet angle, impeller outlet diameter, impeller outlet width, inlet shroud diameter, and blade inlet angle(shroud) are the most five important parameters influencing the model's indexes. Some beneficial design guidelines are distilled from their feature importance and interactions. and The implement of new design yields powerful evidence for the developed prior knowledge with an increase of 2.5830% in isentropic efficiency and a reduction of 1.5202% in power consumption. © 2024, The Authors. All rights reserved.

关键词： Sensitivity analysis

Investigation on the Effect of Hydrothermal Reaction with Cuso4 on Rheological Property of Heavy Oil

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SSRN 2023年

作者： Zhou, Yantao Zhao, Qiuyang Wang, Xuetao Miao, Yan Song, Zhiwei Jin, Hui Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Xinjin Weihua Institute of Clean Energy Research Foshan528216 China

The rheological property is one of important physical properties evaluating heavy oil and asphalt. This work investigated the rheological changes during hydrothermal reaction with CuSO4. The results showed that the addition of CuSO4 at a high reaction temperature had an effect similar to asphalt modifiers, increasing the viscosity and elasticity. Further analysis suggested that the Cu atoms from CuSO4 entered heavy oil molecules, enhancing the interaction attraction between oil molecules. While, at a low reaction temperature, the CuSO4 acted as a catalyst, reducing both viscosity and elasticity. Based on these findings, this work proposed a novel and potential asphalt modification method, which changed the association effect between oil molecules by the chemical reaction to adjust the rheological properties permanently. This method would not fail due to the separation of modifiers and can adjust performance by changing reaction conditions. © 2023, The Authors. All rights reserved.

关键词： Transition metals

A Three-Dimensional Curve Interface Reconstruction Algorithm for Two-Phase Fluid flow

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SSRN 2024年

作者： Chen, Yujie Gong, Junhua Sun, Dongliang Han, Dongxu Wang, Peng Yu, Bo Tao, Wen-Quan School of Mechanical Engineering Beijing Institute of Petrochemical Technology Beijing102617 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China Key Laboratory of Thermo–Fluid Science and Engineering Ministry of Education School of Energy & Power Engineering Xi’an Jiaotong University Shaanxi 710049 China

The curve interface reconstruction algorithm has received significant attention in the context of two-dimensional two-phase flow. However, it remains absent in the three-dimensional scenario. This paper proposes a novel three-dimensional curve interface reconstruction (CIR) algorithm to address this challenge within structured meshes for the first time. Specifically, a portion of the spherical surface is employed to reconstruct the three-dimensional curve interface segment, with the radius and center coordinates determined by curvature and mass conservation constraints, respectively. To enhance curvature accuracy, a sphere-based iterative reconstruction (SIR) algorithm is proposed to calculate the reconstructed distance function (RDF) for the three-dimensional curve interface. Various tests involving the reconstruction and interface capture of spherical, ellipsoidal, and cubic objects demonstrate that the coupled SIR and CIR (SIR-CIR, simplified by SCIR) method achieves high accuracy, particularly with coarse mesh resolutions. Additionally, the SCIR method offers the advantages of straightforward implementation and coding for interface reconstruction in two-phase flow research. This advantage results in reduced computational costs compared to the coupled volume-of-fluid and level set (VOSET) method, which also utilizes an iterative method to solve RDF. © 2024, The Authors. All rights reserved.

关键词： Spheres