The cover image is based on the Original Article Dual-Functionalized Protic Ionic Liquids for Efficient Absorption of NH3 through Synergistically Physicochemical Interaction by Shaojuan Zeng, Yingliang Yang, Lei Yuan ...
The cover image is based on the Original Article Dual-Functionalized Protic Ionic Liquids for Efficient Absorption of NH3 through Synergistically Physicochemical Interaction by Shaojuan Zeng, Yingliang Yang, Lei Yuan et al., https://***/10.1002/jctb.6381 .
Electrocatalytic C−N bond coupling to convert CO 2 and N 2 molecules into urea under ambient conditions is a promising alternative to harsh industrial processes. However, the adsorption and activation of inert gas mol...
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Electrocatalytic C−N bond coupling to convert CO 2 and N 2 molecules into urea under ambient conditions is a promising alternative to harsh industrial processes. However, the adsorption and activation of inert gas molecules and then the driving of the C–N coupling reaction is energetically challenging. Herein, novel Mott–Schottky Bi-BiVO 4 heterostructures are described that realize a remarkable urea yield rate of 5.91 mmol h −1 g −1 and a Faradaic efficiency of 12.55 % at −0.4 V vs. RHE. Comprehensive analysis confirms the emerging space–charge region in the heterostructure interface not only facilitates the targeted adsorption and activation of CO 2 and N 2 molecules on the generated local nucleophilic and electrophilic regions, but also effectively suppresses CO poisoning and the formation of endothermic *NNH intermediates. This guarantees the desired exothermic coupling of *N=N* intermediates and generated CO to form the urea precursor, *NCON*.
Water flooding is the most widely used method to enhance oil recovery. Simulating the influence of particle content on fluid flow in water flooding process can provide instructive significance for oilfield development...
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Water flooding is the most widely used method to enhance oil recovery. Simulating the influence of particle content on fluid flow in water flooding process can provide instructive significance for oilfield development. In this paper, a pore network model was established to simulate the transport process of particles in injected water and fallen particles from the reservoir. It was used to study the influence of particle blockage, deposition and migration on the clogged throats and changes of oil-water relative permeability curves. In the model, four parameters were set, fallen particle diameter, injected particle diameter, fallen particle number and injected particle number. Other parameters were fixed and only a variable was changed to explore the changeable rule of relative permeability curves. It can be generally noted that fallen particle changes have great influence on the relative permeability curves of oil phase and injected particle changes mainly affect the relative permeability curves of water phase. It is of great significance for oilfield development to study the influence of particle transportation on fluid seepage processes.
We report a switchable, templated polymerization system where the strength of the templating effect can be modulated by solution pH and/or ionic strength. The responsiveness to these cues is incorporated through a den...
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We report a switchable, templated polymerization system where the strength of the templating effect can be modulated by solution pH and/or ionic strength. The responsiveness to these cues is incorporated through a dendritic polyamidoamine-based template of which the charge density depends on pH. The dendrimers act as a template for the polymerization of an oppositely charged monomer, namely sodium styrene sulfonate. We show that the rate of polymerization and maximum achievable monomer conversion are directly related to the charge density of the template, and hence the environmental pH. The polymerization could effectively be switched “ON” and “OFF” on demand, by cycling between acidic and alkaline reaction environments. These findings break ground for a novel concept, namely harnessing co-assembly of a template and growing polymer chains with tunable association strength to create and control coupled polymerization and self-assembly pathways of (charged) macromolecular building blocks.
We report Ni/LaHA@ZrO2catalysts prepared by a facile modified successive adsorption and reaction method for CO methanation.N2adsorption,X‐ray diffraction,transmission electron microscopy,scanning electron microscopy,...
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We report Ni/LaHA@ZrO2catalysts prepared by a facile modified successive adsorption and reaction method for CO methanation.N2adsorption,X‐ray diffraction,transmission electron microscopy,scanning electron microscopy,thermogravimetric analysis,H2temperature‐programmed reduction,H2temperature‐programmed desorption,X‐ray photoelectron spectroscopy,thermogravimetric analysis,and inductively coupled plasma atomic emission spectrometry were used to characterize the *** results indicated that the ZrO2nanoparticles were distributed over the surface of the Ni/LaHA@ZrO2catalyst and even partially covered some Ni particles,resulting in the coating exerting a confinement *** excess ZrO2had an adverse effect on the enhancement of CO conversion because of the coverage of the surface Ni particles;however,the Ni/LaHA@ZrO2catalyst displayed much higher CH4selectivity than Ni/LaHA because of the activation of the byproduct CO2molecules by ***,even though20Ni/LaHA@ZrO2‐5exhibited similar CO conversion as20Ni/LaHA,the use of the former resulted in a higher CH4yield than the use of the latter.A107‐h‐lifetime test revealed that the Ni/LaHA@ZrO2catalyst was highly stable with superior anti‐sintering and anti‐coking properties because of its coating structure and the promoter effect of ZrO2.
The dispatching optimization of power grid is to obtain the greatest benefits on the basis of safe and stable operation of the power grid, which is of great significance for the energy-saving, reliability of the power...
The dispatching optimization of power grid is to obtain the greatest benefits on the basis of safe and stable operation of the power grid, which is of great significance for the energy-saving, reliability of the power grid. Therefore, a multi-objective model of power grid dispatching which considers the heat-power coupling characteristics of CHP units is developed in this study. The economic benefit and minimum wind power abandonment are taken as optimizing targets in the model. Meanwhile, the detail operation characteristics of condensing power plants and CHP units are considered in this model based on off-design models of power plant. Besides, the regional heat load and power load are scheduled together. Finally, the AHP-entropy method is used to obtain the weights of the two optimizing targets of economic benefit and wind power abandonment, and the multi-objective is converted into a single-objective.
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