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Synthesis and application of transition metal phosphides as electrocatalyst for water splitting

Science Bulletin 2017年第9期62卷 633-644页

作者： Jinzhan Su Jinglan Zhou Lu Wang Cong Liu Yubin Chen International Research Center for Renewable Energy (IRCRE) State Key Laboratory for Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

With continuous research on photocatalytic water splitting, searching for efficient catalyst for hydrogen evolution reaction(HER) becomes popular topic in addition to main catalyst research. Transition metal phosphides are receiving intense attention due to its abundance in the Earth's crust and comparable catalytic properties to noble metals. In this review, the synthesis approaches, HER reaction mechanism,photocatalytic activity, approaches to improve the activity of transition metal phosphides were reviewed and discussed. It was showed that the transition metal phosphides have great potential to reduce the cost of photocatalyst and promising application on water splitting. The stability problem and participation of poisonous reactant and product in its synthesis reaction limit its application and developing in a certain extent, but with the continuous efforts on the development and improvement of the synthesis methods,transition metal phosphides will find wide application in water splitting.

关键词： Transition metal phosphide Electrocatalyst HER Photocatalytic water splitting

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Toward practical photoelectrochemical water splitting and CO_(2) reduction using earth-abundant materials

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Journal of Energy Chemistry 2021年第10期30卷 469-488,I0013页

作者： Yubin Chen Ya Liu Feng Wang Xiangjiu Guan Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Photoelectrochemical(PEC)fuel generation from water splitting and CO_(2)reduction(CO_(2)R)utilizing solar energy holds immense potential to solve the current energy and environmental *** the past decades,numerous studies have been devoted to this fast-growing research field,and it is essential to develop efficient photoelectrodes with earth-abundant materials for the practical application of PEC systems.A thorough review of earth-abundant materials and associated devices for PEC fuel generation is beneficial to uncover the inherent obstacles and pave the way for future ***,we summarize the recent progress of earth-abundant light-absorbers and cocatalysts in the PEC *** unbiased configurations and scaling-up strategies of PEC devices using earth-abundant materials are examined.A comparison between PEC water splitting and CO_(2)R is carried out to promote better understanding of the design principles for practical materials and ***,the prospects on advanced materials,underlying mechanisms,and reaction systems of PEC water splitting and CO_(2)R are proposed.

关键词： Solar energy Photoelectrochemical technology Water splitting CO_(2)reduction Earth-abundant materials

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Extension of the pressure correction method to zero-Mach number compressible flows

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Science China(Technological Sciences) 2009年第6期52卷 1583-1595页

作者： HE YaLing HUANG Jing TAO YuBing TAO WenQuan State Key Laboratory of Multiphase Flow in Power Engineering School of Energy&Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

In the present paper,the classical pressure correction method was extended into low Mach number compressible flow regime by integrating equation of state into SIMPLE *** self-developed code based on this algorithm was applied to predicting the lid-driven cavity flow and shock tube prob-lems,and the results showed good agreement with benchmark solutions and the Mach number can reach the magnitude of as low as *** attenuation of sound waves in viscous medium was then *** results agree well with the analytical solutions given by theoretical *** demonstrated that the present method could also be implemented in acoustics field simulation,which is crucial for thermoacoustic simulation.

关键词： thermoacoustic engine pressure correction method low Mach number compressible flow

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Dynamic simulation of a space gas-cooled reactor power system with a closed Brayton cycle

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Frontiers in Energy 2021年第4期15卷 916-929页

作者： Chenglong WANG Ran ZHANG Kailun GUO Dalin ZHANG Wenxi TIAN Suizheng QIU Guanghui SU Department of Nuclear Science and Technology State Key Laboratory of Multiphase Flow in Power EngineeringShaanxi Key Laboratory of Advanced Nuclear Energy and TechnologyXi’an Jiaotong UniversityXi’an 710049China

Space nuclear reactor power(SNRP)using a gas-cooled reactor(GCR)and a closed Brayton cycle(CBC)is the ideal choice for future high-power space *** investigate the safety characteristics and develop the control strategies for gas-cooled SNRP,transient models for GCR,energy conversion unit,pipes,heat exchangers,pump and heat pipe radiator are established and a system analysis code is developed in this ***,analyses of several operation conditions are performed using this *** full-power steady-state operation,the core hot spot of 1293 K occurs near the upper part of the *** 0.4$reactivity is introduced into the core,the maximum temperature that the fuel can reach is 2059 K,which is 914 K lower than the fuel melting *** system finally has the ability to achieve a new steady-state with a higher reactor *** the GCR is shut down in an emergency,the residual heat of the reactor can be removed through the conduction of the core and radiation heat *** results indicate that the designed GCR is inherently safe owing to its negative reactivity feedback and passive decay heat *** paper may provide valuable references for safety design and analysis of the gas-cooled SNRP coupled with CBC.

关键词： gas-cooled space nuclear reactor power closed Brayton cycle system startup and shutdown positive reactivity insertion accident

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Synergy of porous structure and cation doping in Ta3N5 photoanode towards improved photoelectrochemical water oxidation

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Journal of Energy Chemistry 2021年第1期30卷 343-350,I0011页

作者： Yubin Chen Hongyu Xia Xiaoyang Feng Ya Liu Wenyu Zheng Lijing Ma Rui Li International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Herein,a cross-linked porous Ta3N5 film was prepared via a simple solution combustion route followed by a high-temperature nitridation process for photoelectrochemical(PEC) water ***,the metal cations(Mg2+ and Zr4+) were incorporated into the porous Ta3N5 to enhance the PEC *** porous Mg/Zr co-doped Ta3N5 photoanode yielded a photocurrent density of 1.40 mA cm^(-2) at 1.23 V vs RHE,which is 5.6 times higher than that of the dense Ta3N5 *** enhanced performance should be ascribed to the synergistic effect of porous structure and cation doping,which can enlarge the electrochemical active surface area and accelerate the charge transfer by introducing ON substitution ***,Co(OH)2 cocatalyst was loaded on the Mg/Zr-Ta3N5 photoanode to negatively shift the onset potential to 0.45 V vs RHE and further improve the photocurrent density to 3.5 mA cm^(-2)at 1.23 V ***,with a maximum half-cell solar to hydrogen efficiency of 0.45%.The present study provides a new strategy to design efficient Ta3N5 photoelectrodes via the simultaneous control of the morphology and composition.

关键词： Photoelectrochemical water oxidation Ta3N5 Porous structure Doping Solution combustion

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Transient gas/liquid two-phase flow in a pipeline-riser system after the change of inlet flow rates

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multiphase Science and Technology 2020年第2期32卷 25-46页

作者： Zou, Suifeng Liu, Weizhi Xu, Qiang Xie, Xiangdong Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China Wuhan Second Ship Design and Research Institute Wuhan China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Transient gas/liquid two-phase flow caused by the change of inlet gas and/or liquid flow rates was experimentally studied in a 380-meter-long pipeline-riser system with a vertical riser of 21.5 meters in height. Results showed that, for the transient processes with the same median flow rates, the rise of flow rates was likely to result in shorter duration time compared to the fall of flow rates. Apart from the manner of change, the duration time was also closely related to the flow mechanism, which varied with the global flow regime. As a consequence, the transient process lasted a longer time around the transition boundary of stable regime and the severe slugging regime;whereas, the transient process would be shorter if the regime was an irregular oscillation;and the longest transient process was found at very low gas and liquid flow rates. As for the prediction of duration time of both the entire transient process and the transition to undesirable flow regimes, the support vector machine turned out to be much more suitable than the log-linear regression. In addition, some similarities of pressure drop signals were found between the transition to unstable and irregular flow regimes and the steady state of these regimes. Since the method for fast recognition of a steady global flow regime has already been developed, it becomes possible to forecast the transition to these undesirable flow regimes through the modification of the recognition method. © 2020 Begell House Inc.. All rights reserved.

关键词： flow rate

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Numerical Simulation of Transient 3-D Turbulent Hested Jet into Crossflow in a Thick-Wall T-Junction Pipe

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Journal of Thermal Science 2001年第1期10卷 46-51页

作者： Wu Hailing, Chen Tingkuan, Luo Yushan, Wang Haijun (state key laboratory of multiphase flow in Power engineering,Xi’an Jiaotong University, Xi’an 710049, China) State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

The present work is to investigate the transient three-dimensional heated turbulent jet into crossflow in a thickwall T-junction pipe using CFD package. Two cases with the jet-to-crossflow velocity ratio of 0.05 and 0.5 are computed, with a finite-volume method utilizing κ-ε model. Comparison of the steady-state computations with measured data shows good qualitative agreement. Transient process of injection is simulated to examine the thermal shock on the T-junction component. Temporal temperature of the component is acquired by thermal coupling with the fluid. Via analysis of the flow and thermal characteristics, factors causing the thermal shock are studied. Optimal flow rates are discussed to reduce the thermal shock.

关键词： numerical simulation low jet-to-crossflow velocity ratio thick-wall T-junction pipe thermal shock

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Facile synthesis of palladium hierarchical nanosheet assemblies: unraveling the aggregation-induced synergistic effect for enhanced methanol oxidation reaction activity

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CrystEngComm 2025年

作者： Han, Lijuan Min, Yuanyuan Wang, Yingying Liu, Feng Liu, Maochang Zheng, Yiqun School of Chemistry Chemical Engineering and Materials Jining University Shandong Qufu 273155 China Health Management Department Shandong Vocational College of Light Industry Shandong Zibo 255300 China International Research Center for Renewable Energy National Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'an 710049 China

This study presents a facile strategy for synthesizing hierarchical palladium (Pd) nanosheet assemblies with enhanced methanol oxidation reaction (MOR) activity. The nanostructures were engineered through a one-pot co-reduction approach, where sodium tetrachloropalladate(ii) was co-reduced by ascorbic acid and citric acid in an ice water bath. Mechanism studies suggested that the dendritic seeds formed at early stages directed the hierarchical assembly of Pd nanosheets, where the lamellar micelle structure of octadecyltrimethylammonium group guides the anisotropic 2D growth of Pd nanosheets. Due to the interconnected, porous nanosheet networks with high electrochemically active surface areas, electrochemical evaluations revealed an aggregation-induced synergistic effect, where the densely packed nanosheet assemblies exhibited a mass activity of 276.1 mA mg_Pd⁻¹ and a specific activity of 1.92 mA cm⁻²—values 2.1 times and 4 times higher, respectively, than those of benchmark Pt/C catalysts. Density functional theory (DFT) simulations suggest that the tensile lattice strain of Pd enhances the adsorption ability of adsorbed species during the MOR and consequently boosts catalytic activity. This work not only advances the design of high-performance MOR catalysts but also elucidates the critical role of nanoscale aggregation in amplifying electrocatalytic performance. © 2025 The Royal Society of Chemistry.

关键词： Nanosheets

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High-Quality Critical Heat Flux in Horizontally Coiled Tubes

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Journal of Thermal Science 1995年第3期4卷 205-211页

作者： Weimin Ma Mingyuan Zhang Xuejun Chen (state key laboratory of multiphase flow in PoWer engineering, Xi’an Jiaotong Universityt Xi’an 710049, China) State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

An investigation on the high-quality dryout in two electrically heated coiled tubes with horizontally helix axes is reported. The temperature profiles both along the tube and around the circumference are measured, and it is found that the temperature profiles around the circumference are not idelltical for the cross-sections at different parts of the coil. The 'local condition hypothesis' seems applicable under present conditions, and the critical heat flux qcr decreases with increasing critical quality xcr The CHF increases as mass velocity and ratio of tube diameter to coil diameter (d/D) increases, and it seems not to be effected by the system pressure. The CHF is larger with coils than that with straight tubes, and the difference increases with increasing mass velocity and d/D.

关键词： horizoatally coiled tube critical heat flux.

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Preparation of biochar adsorption material from walnut shell by supercritical CO_(2)pretreatment

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Biochar 2024年第1期6卷 168-185页

作者： Zitong Zhuang Yanbing Liu Wenwen Wei Jinwen Shi Hui Jin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China.

In order to treat dyes in the wastewater of the printing industry and to reutilize walnut shell(WS)waste gener-ate economic benefits,supercritical carbon dioxide(SC-CO_(2))pretreatment technology was developed to prepare porous biochar as a precursor for adsorption *** experiments were conducted at the temperatures of 200,300,and 400℃with durations of 20,40,and 60 min,and a control group was set up using N_(2)***,KOH activation was employed to prepare biochar adsorption *** biochars were analyzed and characterized using TGA,BET,SEM,FT-IR,and XRD,and the liquid and gas phase products of the pretreatment process were analyzed semi-quantitatively and quantitatively using GC-MS and gas *** blue(MB)dye was selected as an indicator to measure the adsorption capacity of biochar,and adsorption kinetics were analyzed based on the *** results indicate that pretreatment with SC-CO_(2)effectively enhanced the performance and yield of the activated *** highest specific surface area increased by 18%,and the maximum adsorption of MB increased by 23%compared to the N_(2)control *** yield increased by 8-262%and the specific surface area increased by 50-192%compared to the direct activation of walnut shell(WS).During the pretreatment processes for the preparation of biochar adsorption material with the best specific surface area,phenol-enriched bio-oil was produced as a by-product which has economic value.

关键词： Supercritical carbon dioxide Walnut shell Biochar Methylene blue adsorption

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