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2011 2nd International Conference on Mechanic Automation and Control engineering, MACE 2011

作者： Hao, Miaoli Wu, Weitao Qi, Suitao Yang, Bolun Yang, Jianming Zhang, Wei Lv, Jian Department of Chemical Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China Xi'an Modern Chemistry Research Institute Xi'an China

ISBN: (纸本)9781424494392

The isomerization of endo-tetrahydrodicyclopentadiene (THDCPD) to exo-THDCPD over AlCl3 catalyst has been studied in a batch reactor. The effects of temperature, catalyst loading, and the type and amount of solvent on the isomerization rate were investigated. Under the conditions of removing both internal and external diffusion effects, a kinetic model was established and the model parameters were developed. The results showed that the endo- to exo- isomerization of THDCPD can be treated as a first-order reaction. The activation energy E0 and pre-exponential factor obtained from Arrhenius plot are 116 kJ /mol and 3.39×1013 respectively. The simulation results agreed well with the experimental data. © 2011 IEEE.

关键词： Isomerization

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Study of the effective influence distance of longitudinal vortex in narrow rectangular channel

Study of the effective influence distance of longitudinal vo...

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International Conference on Computer Distributed Control and Intelligent Environmental Monitoring

作者： Huang, Jun Huang, Yan-Ping Ma, Jian Wang, Qiu-Wang Key Laboratory of Bubble Physics and Natural Circulation Nuclear Power Institute of China Chengdu China China State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an China

ISBN: (纸本)9780769543505

The heat transfer enhancement of Longitudinal Vortex (LV) is a kind of technology with efficiency is high and resistance is low. The effective influence distance of LV is very important to extend this kind of technology in narrow rectangular channels under water medium. CFX10.0 is used to simulate this question, and three velocity components of water flow have been used to define the strength of LV. The results of this calculate method are compared with the experimental results of thermal infrared imager and phase doppler particle analyzer, and they are reasonable. In this paper range, the effective influence distance of LV is bigger than 33 times of Longitudinal Vortex Generators (LVGs) height. © 2011 IEEE.

关键词： flow of water

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MPS simulation of primary thrombus formation in capillary

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2011年第2期32卷 227-229页

作者： Rong, Shao-Shan Chen, Bin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The adhesion, activation and aggregation of platelets play an important role in the primary thrombus formation. In present paper, platelets, plasma, normal and injured endodermis of the vessel are modeled as particles with different characteristics and simulated by the Moving Particle Semi-implicit (MPS) method. In order to simulate the aggregation and adhesion of platelets on the injured endodermis of the vessel, a mechanical adhesion force model is introduced according to the inter-molecular force and physiological interaction between platelets and endodermis is modeled by the stretch and rotation of a spring. By this method, the formation of primary thrombus at the injured endodermis of horizontal and bending vessel is numerically reproduced. Results show that the thrombus forms quickly and the number of adhered platelets will not increase if thrombus has been formed. Through the analysis of flow field, the platelets go through the vibration, steady and potential break free process. Compared with horizontal vessel, the thrombus formation at the bending vessel is slower.

关键词： Platelets

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Performance comparison and analysis of typical energy conversion cycle

Performance comparison and analysis of typical energy conver...

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International Conference on Computer Distributed Control and Intelligent Environmental Monitoring

作者： Wang, Yuqi Zheng, Lan Yang, Fusheng Meng, Xiangyu Zhang, Zaoxiao School of Chemical Engineering Northwest University Xi'an Shaanxi 710069 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an Shaanxi 710049 China

ISBN: (纸本)9780769543505

The performance of 3 types of energy utilization cycles including the organic Rankine cycle, the single stage static hydrogen compression cycle, and the new multistage continuous hydrogen compression cycle were analyzed. A multi-element valued model was used to evaluate the performance holistically, and the result showed that the integrated superiority achieved 0.721, which indicated the continuous hydrogen compression cycle is considered the best option among the typical compression energy utilization cycles and deserves thorough studying. © 2011 IEEE.

关键词： Energy utilization

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Radiant performance of opacifiers in opcifier-loaded silica aerogel-based composites

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Yingyong Jichu yu Gongcheng Kexue Xuebao/Journal of Basic Science and engineering 2012年第SUPPL.期20卷 181-189页

作者： Sun, Duo Wang, Xiaodong Duan, Yuanyuan Zhao, Junjie State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power University Beijing 102206 China Department of Thermal Engineering University of Science and Technology Beijing Beijing 100083 China Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy North China Electric Power University Beijing 102206 China Key Laboratory for Thermal Science and Power Engineering of MOE Department of Thermal Engineering Tsinghua University Beijing 100084 China

Since the opacifier-loaded silica aerogel composites have strong ability to inhibit radiant heat transfer compared to the pure silica aerogel, they can improve effectively the insulation performance at high temperature conditions and have been used extensively as thermal insulation materials in a variety of industrial applications. This paper developed a theoretical model to predict the radiant performance of opacifiers by using the Mie scattering theory, Beer law and a radiant heat transfer equations. The model was used to calculate the radiant performance of carbon black opacifier with various particle diameters and the radiant performance of three opacifiers, carbon black, SiC and ZrO2. The results showed that the opacifier-loaded silica aerogel composites had much higher extinction coefficient than the pure silica aerogel in a range of 3-7.5 μm wave band or in medium and high temperature ranges, which significantly improved the insulation performance of composites. With a fixed opacifier mass fraction, the optimal particle diameter was 2-3 μm for carbon black opacifier. Among the three opacifiers, carbon black opacifier had better opaque property than that of SiC and ZrO2 opacifiers. Due to poor thermostability for carbon black opacifier at high temperature conditions, the optimal material design for opacifier-loaded silica aerogel composites should be as follows: SiC or ZrO2 are added on high temperature side of aerogel and carbon black is added on low temperature side.

关键词： Thermal conductivity

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Effect of SiO_(2)/Al_(2)O_(3)ratio on the conversion of methanol to olefins over molecular sieve catalysts

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Frontiers of Chemical Science and engineering 2011年第1期5卷 79-88页

作者： Qian WANG Lei WANG Hui WANG Zengxi LI Xiangping ZHANG Suojiang ZHANG Kebin ZHOU Graduate University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Multiphase Complex System Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

A series of SAPO-34 molecular sieves with different SiO_(2)/Al_(2)O_(3)ratios have been synthesized for the methanol-to-olefin(MTO)*** physico-chemical properties are characterized by various techniques such as X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),Fourier transform infrared spectroscopy(FT-IR)and N2 *** results are compared with those of the commercial HZSM-5,which show that the crystallinity and particle diameter of SAPO-34 as well as HZSM-5 increase with SiO_(2)/Al_(2)O_(3)*** variation of BET surface area of SAPO-34 is different from that of HZSM-5 and the sample with SiO_(2)/Al_(2)O_(3)ratio of 0.4 exhibits the highest BET surface ***-IR spectra indicate that HZSM-5 has both Brǿnsted and Lewis acid sites and Brǿnsted acid sites are stronger,whereas SAPO-34 samples are dominated only by Lewis acid *** the SiO_(2)/Al_(2)O_(3)ratio increases,propylene and butylenes become the predominant product of the MTO reaction over *** contrast,the main products of this reaction catalyzed by SAPO-34 are ethylene and *** to the product distribution,the reaction mechanism over HZSM-5 catalysts is proposed.

关键词： HZSM-5 SAPO-34 methanol-to-olefin(MTO) SiO_(2)/Al_(2)O_(3)ratio

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Convective heat transfer of air flow in cold cabinet with two-fluid model

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Huagong Xuebao/CIESC Journal 2012年第SUPPL.1期63卷 138-144页

作者： Wei, Min Wang, Limin State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing 100190 China Graduate University of Chinese Academy of Sciences Beijing 100049 China

The convective heat transfer of the cold cabinet was investigated by using two-fluid model after the effectiveness of new model was confirmed. This study includes the influence of wind speeds, wind directions and speeds of air curtain. The results show that the convective heat transfer is improved along with increasing of the wind speed. In a relatively short time, there is a linear relationship between convective heat transfer and time. The wind direction has small effect on heat transfer when it is less than about 15° while has appreciable impact and made an increase of energy consumption by approximately 30% when it reaches 30°. The air curtain, a major constituent of the refrigeration system of cold cabinet, provides a barrier of moving air across a door opening and reduces heat transfer by preventing the penetration of hot air. The simulation shows that there is the minimum speed and the best speed range of air curtain. The air curtain can not be formed when the speed is less than 1.5 m·s-1, while has a large spillover of cold air when it is greater than 3.0 m·s-1. From the above, the best speed of air curtain ranges from 2.6 m·s-1 to 3.0 m·s-1.

关键词： Energy utilization

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Modularized dry coal beneficiation technique based on gas-solid fluidized bed

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Journal of Central South University 2011年第2期18卷 374-380页

作者：赵跃民李功民骆振福梁春成唐利刚陈增强邢洪波 School of Chemical Engineering and Technology China University of Mining and Technology Tangshan Shenzhou Manufacturing Co. Ltd. State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of Sciences

A 40-60 t/h modularized dry coal beneficiation process with a novel method to control the bed was designed around a gas-solid fluidized bed separator. Furthermore, the hydrodynamics of medium-solids consisting of wide-size-range magnetite powder （0.3-0.06 ram） and 〈1 mm fine coal were numerically studied. The simulation results show that the fluidization performance of the wide-size-range medium-solid bed is good. The separation performance of the modularized system was then investigated in detail using a mixture of 〈0.3 mm magnetite powder （mass fraction of 0.3-0.06 mm particles is 91.38 %） and 〈1 mm fine coal as solid media. The experimental results show that at separation densities of 1.33 g/cm^3 or 1.61 g/cm^3, 50-6 mm coal can be separated effectively with probable error, E, values of 0.05 g/cm^3 and 0.06 g/cm^3, respectively. This technique is beneficial for saving water resources and for the clean utilization of coal.

关键词： dry coal beneficiation modularization gas-solid fluidized bed wide-size-range medium-solids

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Molecular Simulation on Microstructure of Ionic Liquids in Capture of CO2

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过程工程学报 2011年第4期11卷 652-659页

作者：岳振国刘晓敏赵玉灵张晓春吕兴梅张锁江 State Key Laboratory of Multiphase Complex System Institute of Process Engineering CAS Beijing 100190 China Graduate University of Chinese Academy of Sciences Beijing 100049 China

Molecular dynamic simulation is used to study the microstructure of four kinds of ionic liquids(ILs),[Emim]PF6,[Emim][Tf2N],[PC6,6,6,14]PF6 and [PC6,6,6,14][Tf2N] in the capture process of *** distribution function(RDF) and spatial distribution function(SDF) are used to analyze the microscopic properties of these *** calculated results show that the space distribution of CO2 around ILs determines the capability of ionic liquids for capturing *** on the analysis of SDF,CO2 and PF6-are overlapped partially around [Emim]+ in [Emim]PF6-CO2 *** the anion is [Tf2N]-,cations are mainly distributed on one side of [Tf2N]-near N atom,and CO2 is concentrated on two sides near the fluoroalkylgroup(?CF3),and there is little overlapped district between cation and *** [PC6,6,6,14]PF6-CO2 mixture,layered structure is found and CO2 is much nearer to PF6-than [PC6,6,6,14]+.Based on the analysis of RDF,in the phosphonium-based ILs,the highest distribution densities of anions and CO2 around cations are about 6 and 3 times as their average ones respectively,while in the imidazolium-based ILs,they are about 3 and 2 respectively,this means that the distributions of CO2 and anions around the imidazolium-based ILs are more evenly distributed than those around the phosphonium-based ILs.

关键词： ionic liquid molecular dynamics simulation CO2 capture microstructure

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Anomalous enhancement in thermal conductivity of nanofluid induced by solid walls in a nanochannel

Anomalous enhancement in thermal conductivity of nanofluid i...

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作者： Sun, Chengzhen Lu, Wen-Qiang Bai, Bofeng Liu, Jie State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an 710049 China College of Physical Sciences Graduate University Chinese Academy of Sciences Beijing 100049 China

Thermal conductivity of Ar-Cu nanofluid confined between two parallel walls (in a nanochannel) is calculated by equilibrium-molecular-dynamics (EMD) simulation through Green-Kubo formula. The results show that the vibration of nanoparticle in the channel height direction (z-direction) is inhibited due to the presence of solid boundaries and accordingly the thermal conductivity of the confined nanofluid is obviously anisotropic. Anomalous enhancement in the thermal conductivity perpendicular to the z-direction (λ) appears as a result of the strong coupling interactions between the fluid atoms, especially the nanoparticle atoms, and the wall atoms. The thermal conductivity λ of the nanofluid confined in the channel of width h = 5.148 nm increases with the increase of the nanoparticle diameter for the strengthened couplings. The nanoparticle volume fraction effect on the thermal conductivity of the confined nanofluid is more obvious than that in macroscale. In addition, the thermal conductivity λ of the nanofluid with diameter of nanoparticle d = 1.370 nm decreases with the channel width increasing owing to the weakened couplings resulted by a longer interacting distance. © 2011 Elsevier Ltd. All rights reserved.

关键词： Molecular dynamics

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