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Calcium Looping Sorption-Enhanced Electrified Steam Methane Reforming for Efficient Hydrogen Production with Short- and Long-Duration Cooperative Energy Storage

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SSRN 2024年

作者： Song, Huchao Zhang, Xinyue Lin, Xiaolong Bian, Hao Liu, Yinhe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Currently, the dominant hydrogen production technology is steam methane reforming, but both the reforming reaction and the combustion for driving the reaction produce significant CO2 emissions. Sorption-enhanced methane reforming enables the in-situ removal of CO2 produced by the reforming reaction and promotes higher hydrogen yields, however, CO2 emissions from combustion cannot be avoided. Renewable electricity instead of combustion for reaction heating can eliminate combustion carbon emissions and flue gas heat loss, but its dependence on renewable electricity supply prevents continuous and stable operation. This study proposes a sorption-enhanced electrified steam methane reforming technology based on short- and long-duration cooperative energy storage and calcium looping carbon capture. This technology utilizes the CO2 adsorption and energy storage property of the absorbent to absorb CO2 in situ in the reformer and transform renewable electricity to chemical and thermal energy in the regenerator as short- duration energy storage. The energy stored in the absorbent can be used to drive the methane reforming reaction and transformed into chemical energy in hydrogen continuously as long- duration energy storage. Through First law and Second law analysis, this study has found that the novel process improves thermal efficiency by 8.5 percentage points and reduces the exergy loss of the overall process by 53.2% compared with the sorption-enhanced steam methane reforming process. Based on current fuel prices in China, the novel process is more economical than the other steam methane reforming processes simulated in this study. Sensitivity analysis has found that low electricity and high methane prices benefit the economic performance of the novel process. This study may provide a stable, efficient, and economical way of clean hydrogen energy production. © 2024, The Authors. All rights reserved.

关键词： Hydrogen production

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High Concentration of CO and CO2 Inhibits Coal Gasification in Supercritical Water

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SSRN 2024年

作者： Zhang, Rui Zhao, Shuaiqi Huang, Han Zhao, Kunpeng Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Supercritical water gasification technology achieves efficient resource utilization of lignite and produces H2, CO and CO2. In this study, we experimentally investigated the impact of gas product generated from high concentration (>30 wt%) formic acid decomposition on the gasification of Tiebei lignite in the supercritical water. H2 promotes the pyrolysis of carbon structures, the increase in CO promotes CO2 generation through the water-gas shift reactions, and the enrichment of CO2 hinders gas diffusion. We found that high concentration of formic acid(H2, CO and CO2) inhibits the gasification of Tiebei lignite in the supercritical water. Compared with coal gasification in the supercritical water without formic acid, 30wt% formic acid reduces the carbon efficiency of lignite by 7.66%, and the mass conversion of coal by 3.97%. When the concentration of formic acid is 30wt% to 70wt%, the higher concentration of formic acid(H2, CO and CO2), the worse gasification performance of Tiebei lignite. © 2024, The Authors. All rights reserved.

关键词： Water gas shift

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Porous carbon material production from microwave-assisted pyrolysis of peanut shell

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Carbon Research 2023年第1期2卷 1-17页

作者： Qiu, Tianhao Li, Chengxiang Guang, Mengmeng Zhang, Yaning School of Energy Science and Engineering Harbin Institute of Technology Harbin150001 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China

Due to the complex porous structure, biochar usually has good adsorption capacity. Therefore, compared with direct combustion, conversion of peanut shell into biochar by pyrolysis is considered to be an environmentally friendly and efficient method for agricultural solid waste disposal. In this study, biochar production from microwave-assisted pyrolysis of peanut shell was detailed. The yields, surface topographies, and pore structures (pore size distribution and micropore volume) of biochars prepared at different pyrolysis temperatures (700, 750, 800, 850, 900, and 950 °C), microwave powers (350, 400, 450, 500, and 550 W), and residence times (0.5, 1.0, 1.5, 2.0, and 3.0 h) were elaborated. The results showed that the biochar yield gradually decreased and finally stabilized to around 30% while the specific surface area improved within the range of 4.68–67.29 m2/g when the pyrolysis temperature, microwave power, or residence time increased. Biochar with micropore was first obtained at pyrolysis temperature of 800 °C, microwave power of 500 W, and residence time of 2.0 h. This study further proposed quantitative relationships between the pore structures of peanut shell based biochars and experimental conditions (pyrolysis temperature, microwave power and residence time). The results presented in this study can provide guidance for the reuse of peanut shell and the production of porous biochar. The peanut shell biochar prepared in this study can be used in soil remediation, air purification, liquid purification and other fields for its porous structural characteristics. © 2023, The Author(s).

关键词： Waste incineration

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Electrochemical evolution of a metal oxyhydroxide surface on two-dimensional layered metal phosphorus trisulfides enables the oxidation of amine to nitrile

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Carbon Energy 2025年第3期7卷 133-147页

作者： Binglan Wu Karim Harrath Marshet Getaye Sendeku Tofik Ahmed Shifa Yuxin Huang Jing Tai Fekadu Tsegaye Dajan Kassa Belay Ibrahim Xueying Zhan Zhenxing Wang Elisa Moretti Ying Yang Fengmei Wang Alberto Vomiero State Key Laboratory of Chemical Resource Engineering College of ChemistryBeijing University of Chemical TechnologyBeijingChina CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology(NCNST)BeijingChina Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of EducationCollege of Chemistry&Materials ScienceNorthwest UniversityXi'anChina State Key Laboratory of Multiphase Flow in Power Engineering International Research Center for Renewable EnergyXi'an Jiaotong UniversityShaanxiChina Fundamental Science Center of Rare Earths Ganjiang Innovation AcademyChinese Academy of ScienceGanzhouChina Ocean Hydrogen Energy R&D Center Research Institute of Tsinghua University in ShenzhenShenzhenChina Department of Molecular Sciences and Nanosystems Ca'Foscari University of VeniceVenezia MestreItaly Testing and Analysis Center Institute of Chemistry Chinese Academy of SciencesBeijingChina Department of Engineering Sciences and Mathematics Division of Materials ScienceLuleåUniversity of TechnologyLuleåSweden

Selective oxidation of amines to imines through electrocatalysis is an attractive and efficient way for the chemical industry to produce nitrile compounds,but it is limited by the difficulty of designing efficient catalysts and lack of understanding the mechanism of ***,we demonstrate a novel strategy by generation of oxyhydroxide layers on two-dimensional iron-doped layered nickel phosphorus trisulfides(Ni1-xFexPS_(3))during the oxidation of benzylamine(BA).In-depth structural and surface chemical characterizations during the electrocatalytic process combined with theoretical calculations reveal that Ni(1-x)FexPS_(3) undergoes surface reconstruction under alkaline conditions to form the metal oxyhydroxide/phosphorus trichalcogenide(NiFeOOH/Ni1-xFexPS_(3))***,the generated heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53%for benzonitrile(BN)*** calculations further indicate that the as-formed NiFeOOH/Ni1-xFexPS_(3) heterostructure could offer optimum free energy for BA adsorption and BN desorption,resulting in promising BN synthesis.

关键词： 2D layered materials benzylamine oxidation metal phosphorus trichalcogenides surfacereconstructed heterostructure

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Performance Analysis of Low GWP Refrigerants R1234yf and R448A in a Small High and Low-temperature Test Equipment

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Recent Patents on Mechanical engineering 2022年第3期15卷 277-284页

作者： Liqiang, Zhou Zhang, Hua Zilong, Wang Wenjing, Gao School of Energy and Power University of Shanghai for Science and Technology Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093 China

Aim: The article presents an analysis of the feasibility of R1234yf and R448A, two new low GWP refrigerants, as alternatives to R404A in the refrigeration system of small high and low-temperature test equipment. Methods: The physical properties of R448A and R404A are similar. Compared with R404A, the GWP of R1234yf and R448A reduced by 99.9% and 67.7%, respectively. The analysis is based on an experimental comparison of R404A with R448A and R1234yf, comparing the compressor discharge tempera-ture, COP, cooling capacity, and the cooling rate of three refrigeration systems at different ambient temperatures. Results: The experimental results show that the cooling capacity of R448A is better than R404A at a higher condensing temperature. Conclusion: When the charging volume is 230g, and the ambient temperature is 25°C, the COP of the R448A system is increased by about 24.63% compared with the R404A system. © 2022 Bentham Science Publishers.

关键词： Refrigerants

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Graph neural network-driven prediction of high-performance CO_(2)reduction catalysts based on Cu-based high-entropy alloys

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Chinese Journal of Catalysis 2025年第4期71卷 197-207页

作者： Zihao Jiao Chengyi Zhang Ya Liu Liejin Guo Ziyun Wang International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityShaanxi 710049China School of Chemical Sciences University of AucklandAuckland 1010New Zealand

High-entropy alloy(HEA)offer tunable composition and surface structures,enabling the creation of novel active sites that enhance catalytic performance in renewable energy ***,the inherent surface complexity and tendency for elemental segregation,which results in discrepancies between bulk and surface compositions,pose challenges for direct investigation via density functional *** address this,Monte Carlo simulations combined with molecular dynamics were employed to model surface segregation across a broad range of elements,including Cu,Ag,Au,Pt,Pd,and *** analysis revealed a trend in surface segregation propensity following the order Ag>Au>Al>Cu>Pd>*** capture the correlation between surface site characteristics and the free energy of multi-dentate CO_(2)reduction intermediates,a graph neural network was designed,where adsorbates were transformed into pseudo-atoms at their centers of *** model achieved mean absolute errors of 0.08–0.15 eV for the free energies of C_(2)intermediates,enabling precise site activity *** indicated that increasing the concentration of Cu,Ag,and Al significantly boosts activity for CO and C_(2)formation,whereas Au,Pd,and Pt exhibit negative *** screening stable composition space,promising HEA bulk compositions for CO,HCOOH,and C_(2)products were predicted,offering superior catalytic activity compared to pure Cu catalysts.

关键词： Density functional theory Machine learning CO_(2)reduction High entropy alloys Graph neural network

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Experimental Study on Condensation Heat Transfer Characteristics inside an Inclined Wave-Finned Flat Tube of Direct Air-Cooling System

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Journal of Thermal Science 2021年第2期30卷 432-440页

作者： WANG Haitao TAO Tao MEI Xuesong WANG Haijun GU Hongfang State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong UniversityXi'an 710049China Shaanxi Key Laboratory of Intelligent Robots School of Mechanical EngineeringXi'an Jiaotong UniversityXi'an 710049China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

In this paper,the condensation heat transfer characteristics of parallel flow and counter flow inside an inclined wave-finned flat tube is investigated *** condensation heat transfer coefficients are analyzed based on the experimental *** of experiments show that condensation heat transfer coefficient decreases as the temperature difference Δt=ts-tw increases and mass flow rate *** parallel flow has a similar development with the counter flow,and the condensation heat transfer coefficient of counter flow is less than that of parallel flow under the same air cooling *** addition,condensation heat transfer coefficient correlations are also obtained under experimental *** calculations agree well with the measured data and the agreement is seen to be within ±4% for the parallel flow and ±5% for the counter flow.

关键词： condensation heat transfer wave-finned fiat tube modified model parallel flow counter flow

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Flocculation of suspended cohesive particles in Rayleigh-Bénard turbulence

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Physical Review Fluids 2025年第2期10卷 024305-024305页

作者： Han Huang Shuaiqi Zhao Rui Zhang Binbin Pei Kunpeng Zhao Bofeng Bai State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Key Laboratory of Mechanics on Disaster and Environment in Western China The Ministry of Education of China Lanzhou University Lanzhou 730000 China

We employ a four-way coupled numerical approach to investigate the dynamics of suspended cohesive particles in Rayleigh-Bénard turbulence. The Stokes drag, cohesive, and direct contact forces between primary particles are captured in detail, yielding the phenomena of flocs' aggregation, breakage, and deformation. The momentum and thermal exchange between primary particles and the fluid are considered based on the Source-in-Cell method. We found that the initial increase of the average floc size indicates a temporary flocculation phase, which is followed by an equilibrium phase where the average floc size becomes stable, reflecting the balance between aggregation and breakage. Different from the traditional perspective, which attributed the local accumulation of particles to their gravity, we found that the suspended particles still tend to accumulate in the bottom hot boundary layer region. This accumulation is primarily driven by the temperature-induced variation in aggregation strength and the nonuniform spatial distribution of floc inertia. Additionally, the stronger cohesion yields a reduction in momentum intensity of the thermal plumes, primarily due to the more pronounced weakening of fluid momentum by the larger flocs.

关键词： Momentum

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Analysis of Different Control Strategies Considering Individual Regulation of Heat User 3

Analysis of Different Control Strategies Considering Individ...

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3rd International Conference on Electrical engineering and Mechatronics Technology, ICEEMT 2023

作者： Xun, Zhiwei Wang, Huijie Wang, Liyuan Yang, Long Gao, Yunfang Liu, Ming Guoneng Jinjie Energy Co. Ltd Yulin China Xi'an Jiaotong University Xi'an China Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an China

ISBN: (纸本)9798350303698

In the process of outdoor temperature change, it is beneficial to improve the comfort of thermal users to formulate adjustment and control strategies according to the actual needs of each user. In this paper, different adjustment modes are established according to the thermal comfort of users, and the control strategies of rising and cooling within 0, 30 and 60 minutes are proposed, and the indoor temperature control effect and heating energy consumption of each adjustment mode under different control strategies are analyzed. The results show that: in different modes, when the rise and cooling time increase, compared with the design room temperature, the indoor temperature difference under the control mode is smaller, but the time needed to reach stability is longer. At the same time, the total heat load is unchanged, but the total pump work decreases. © 2023 IEEE.

关键词： Energy utilization

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Advances in thermal-related analysis techniques for solid-state lithium batteries

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InfoMat 2023年第4期5卷 77-116页

作者： Jianan Wang Kai Yang Shiyi Sun Qianyue Ma Gong Yi Xin Chen Ze Wang Wei Yan Xinhua Liu Qiong Cai Yunlong Zhao Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy and Power EngineeringXi'an Jiaotong UniversityXi'anthe People's Republic of China Department of Chemical&Process Engineering Faculty of Engineering and Physical SciencesUniversity of SurreyGuildfordUK Advanced Technology Institute University of SurreyGuildfordUK School of Transportation Science and Engineering Beihang UniversityBeijingthe People's Republic of China

Solid-state lithium batteries(SSLBs)have been broadly accepted as a promising candidate for the next generation lithium-ion batteries(LIBs)with high energy density,long duration,and high *** intrinsic non-flammable nature and electrochemical/thermal/mechanical stability of solid electrolytes are expected to fundamentally solve the safety problems of conventional ***,thermal degradation and thermal runaway could also happen in *** example,the large interfacial resistance between solid electrolytes and electrodes could aggravate the joule heat generation;the anisotropic thermal diffusion could trigger the uneven temperature distribution and formation of hotspots further leading to lithium dendrite *** research efforts have been devoted to exploring solid electrolytes with outstanding performance and harmonizing interfacial incompatibility in the past *** have been fewer comprehensive reports investigating the thermal reaction process,thermal degradation,and thermal runaway of *** review seeks to highlight advanced thermal-related analysis techniques for SSLBs,by focusing particularly on multiscale and multidimensional thermal-related characterization,thermal monitoring techniques such as sensors,thermal experimental techniques imitating the abuse operating condition,and thermalrelated advanced *** perspectives are proposed to bridge fundamental studies to technological relevance for better understanding and performance optimization of SSLBs.

关键词： characterization monitoring simulation solid-state batteries thermal technique

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