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A two-stage reduction process for the production of high-purity ultrafine Ni particles in a micro-fluidized bed reactor

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Particuology 2015年第2期13卷 27-34页

作者： Jun Li Xinwei Liu Li Zhou Qingshan Zhu Hongzhong Li State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of Sciences

A novel two-stage reduction process for synthesis of ultrafine nickel powder with a high purity and low density in a fluidized bed reactor has been developed in this work. The raw ultraflne NiO particles are first pre-reduced using hydrogen at lower temperatures （340-400 ℃）, followed by further reduction at higher temperatures （500-600℃）. The self-agglomeration of Ni particles formed during low-temperature reduction decreases the sintering activity of the newly formed ultrafine Ni particles, leading to good fluidization quality, even for the subsequent high-temperature reduction process. The agglomerated Ni particles have a high Ni content （above 99wt%）, a low density （0.78g/cm^3） and a uniform particle size （approximately 100 μm）. A concept design for a novel two-stage fluidized bed reactor process used to produce high-purity Ni powder was also proposed. This approach may be extended to the synthesis of other ultrafine/nanosized metals or metal oxides through a fluidization method.

关键词： Ultrafine Ni powder Production Fluidized bed reactor Two-stage reduction

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Design and synthesis of porous non-noble metal oxides for catalytic removal of VOCs

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Science China Chemistry 2015年第9期58卷 1359-1366页

作者： Wenxiang Tang Gang Liu Dongyan Li Haidi Liu Xiaofeng Wu Ning Han Yunfa Chen State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences

The design and synthesis of highly active non-noble metal oxide catalysts, such as transition- and rare-earth-metal oxides, have attracted significant attention because of their high efficiency and low cost and the resultant potential applications for the degradation of volatile organic compounds(VOCs). The structure-activity relationships have been well-studied and used to facilitate design of the structure and composition of highly active catalysts. Recently, non-noble metal oxides with porous structures have been used as catalysts for deep oxidation of VOCs, such as aromatic hydrocarbons, aliphatic compounds, aldehydes, and alcohols, with comparable activities to their noble metal counterparts. This review summarizes the growing literature regarding the use of porous metal oxides for the catalytic removal of VOCs, with emphasis on design of the composition and structure and typical synthetic technologies.

关键词： VOCs catalytic oxidation non-noble metal oxides structure-activity relationships synthetic methods

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Cobalt oxide and carbon modified hematite nanorod arrays for improved photoelectrochemical water splitting

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Chinese Chemical Letters 2017年第12期28卷 2207-2211页

作者： Miao Wang Meng Wang Yanming Fu Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an fiaotong UniversityXi'on 710049China

Given the proper band gap, low cost and good stability, hematite （α-Fe2O3） has been considered as a promising candidate for photoelectrochemical （PEC） water splitting, however suffers from the sluggish surface water oxidation reaction kinetics. In this study, a simple dip-coating process was used to modify the surface of α-Fe2O3 nanorod arrays with cobalt oxide （COOx） and carbon （C） for the improved PEC performance, with a photocurrent density at 1.6V （vs. reversible hydrogen electrode, RHE） increased from 0.10 mA/cm2 for the pristine α-Fe2O3 to 0.37 mA/cm2 for the CoOx/C modified α-Fe2O3 nanorods. As revealed by electrochemical analysis, thanks to the synergistic effect of CoOx and C, the PEC enhancement could be attributed to the enhanced charge transfer ability, decreased surface charge recombination, and accelerated water oxidation reaction kinetics. This study serves as a good example for improving PEC water splitting performance via a simple method.

关键词： Hematite nanorodsSurface modificationPhotoelectrochemical water splittingWater oxidationElectrochemical impedance spectroscopy

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An investigation into the heat transfer characteristics of spiral wall with internal rib in a supercritical sliding-pressure operation once-through boiler

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中国高等学校学术文摘·能源与动力工程 2007年第3期1卷 300-304页

作者： TANG Renhu YIN Fei WANG Haijun CHEN Tingkuan The State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

Within the pressure range of 9-28 MPa,mass 200-500 kW/m2,experiments were performed to investigate the heat transfer to water in the inclined upward internally ribbed tube with an inclined angle of 19.5 degrees,a maximum outer diameter of 38.1 mm,and a thickness of 7.5 *** on the experiments,it was found that heat transfer enhancement of the internally ribbed tube could postpone departure from nucleate boiling at the sub-critical ***,the heat transfer enhancement decreased near the critical *** supercritical pressure,the temperature difference between the wall and the fluid increased near the pseudo-critical temperature,but the increase of wall temperature was less than that of departure from nucleate boiling at sub-critical *** pressure is closer to the critical pressure,the temperature difference between the wall and the fluid increased greatly near the pseudo-critical *** transfer to supercritical water in the inclined upward internally ribbed tube was enhanced or deteriorated near the pseudo-critical temperature with the variety of ratio between the mass velocity and the heat *** the rotational flow of the internal groove reduced the effect of natural convection,the internal wall temperature of internally ribbed tube uniformly distributed along the *** maximum internal wall temperature difference of the tube along the circumference was only 10 degrees when the fluid enthalpy exceeded 2 000 J/*** the effect of acute variety of the fluid property on heat transfer,the correlation of heat transfer coefficient on the top of the internally ribbed tube was orovided.

关键词： thermal power engineering heat transfer supercritical pressure boiler internally ribbed tube departure from nucleate boiling

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Numerical and experimental research of the characteristics of concentration solar cells

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Frontiers in Energy 2021年第2期15卷 279-291页

作者： Zilong WANG Hua ZHANG Binlin DOU Weidong WU Guanhua ZHANG Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093China

The development of automatic tracking solar concentrator photovoltaic systems is currently attracting growing *** concentration photovoltaic systems(HCPVs)combining triple-junction InGaP/lnGaAs/Ge solar cells with a concentrator provide high conversion *** mathematical model for triple-junction solar cells,having a higher efficiency and superior temperature characteristics,was established based on the one-diode equivalent circuit cell model.A paraboloidal concentrator with a secondary optic system and a concentration ratio in the range of 100X–150X along with a sun tracking system was developed in this *** GaInP/GalnAs/Ge triple-junction solar cell,produced by AZUR SPACE Solar Power,was also used in this *** solar cells produced by Shanghai Solar Youth Energy(SY)and Shenzhen Yinshengsheng Technology ***.(YXS)were used as comparison samples in a further comparative study at different concentration ratios(200X–1000X).A detailed analysis on the factors that influence the electrical output characteristics of the InGaP/lnGaAs/Ge solar cell was conducted with a dish-style concentrating photovoltaic *** results show that the short-circuit current(Isc)and the open-circuit voltage(Voc)of multi-junction solar cells increases with the increasing concentration ratio,while the cell efficiency(ηc)of the solar cells increases first and then decreases with increasing concentration *** increasing solar cell temperature,Isc increases,while Voc andηc decrease.A comparison of the experimental and simulation results indicate that the maximum root mean square error is less than 10%,which provides a certain theoretical basis for the study of the characteristics of triple-junction solar cell that can be applied in the analysis and discussion regarding the influence of the relevant parameters on the performance of high concentration photovoltaic systems.

关键词： concentration three-junction solar cell mathematical model electrical properties solar energy

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Proposal and thermodynamic analysis of a steam methane reforming system integrated with thermochemical energy storage and a SCO₂ brayton cycle

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Journal of Energy Storage 2025年 127卷

作者： Fu, Yu Liu, Ming Wang, Zhu Xie, Tao Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Institute of Industrial Catalysis School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an 710049 China

Solar energy is a promising alternative to fossil fuels for providing heat in steam methane reforming (SMR) hydrogen production. However, the variability of solar energy requires effective storage solutions. This study presents a new SMR hydrogen production system that integrates thermochemical energy storage (TCES) utilizing a CaO/CaCO₃ cycle with a SCO₂ Brayton cycle. The system converts fluctuating solar energy into the stable chemical energy of CaO by calcinating CaCO₃ in the solar calciner, with the SMR reaction mainly heated by the exothermic reaction of CaO and CO₂. The SCO₂ Brayton cycle efficiently recovers heat from the high-temperature SMR products. Comprehensive thermodynamic analysis and evaluation models are developed. Results show that the proposed system performs well, achieving energy and exergy efficiencies of 73.49 % and 78.46 %, respectively, under benchmark conditions. The energy storage efficiency of TCES is 81.55 %, and the solar-to-chemical energy efficiency is 48.21 %. Integrating TCES significantly enhances the system's steady operation under fluctuating solar energy conditions. The calciner accounts for the largest share of exergy destruction at 31.63 %, followed by the carbonator at 17.50 %. Sensitive analyses of key operating parameters indicate that higher CaO conversion rate and storage temperature enhance energy storage, energy, and exergy efficiencies. Besides, the energy and exergy efficiencies decrease with the increasing SMR reaction pressure but increase with rising reaction temperature. When the S/C is 2.0, these efficiencies reach their maximum values of 75.42 % and 78.63 %, respectively. © 2025 Elsevier Ltd

关键词： Hydrogen production SCO2 Brayton cycle Solar energy Steam methane reforming Thermochemical energy storage

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Best estimate plus uncertainty analysis of the China advanced large-scale PWR during LBLOCA scenarios

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International Journal of Advanced Nuclear Reactor Design and Technology 2020年 2卷 34-42页

作者： Chang, Yuhao Wang, Mingjun Zhang, Jing Tian, Wenxi Qiu, Suizheng Su, G.H. Department of Nuclear Science and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

China advanced large-scale Pressurized Water Reactor (PWR) implements series of passive safety systems to provide core cooling and decay heat removal in case of some unexpected accidents. The development of reactor best estimate system analysis codes has realized the transition from conservative safety analysis to Best Estimate plus Uncertainty (BEPU) analysis for the purpose of achieving more realistic results and digging larger safety margins. The BEPU analysis during Large Break Loss of Coolant Accident (LBLOCA) has been widely used for the licensing application of Nuclear Power Plants (NPPs). In this paper, the BEPU analysis of China advanced large-scale PWR was performed under the conditions of LBLOCA scenarios employing RELAP5 code. The models of reactor coolant system with all the passive safety systems were established and the influence of uncertainties of important parameters on the Peak Cladding Temperature (PCT) was evaluated. The results show the obtained PTC (1314 K) through the BEPU analysis is far below the 10CFR50.46 PCT acceptance criteria (1477 K) in case of LBLOCA and is also lower than the conservative calculation value (1348 K), indicating a larger safety margin. This work provides a meaningful evaluation method for China advanced large-scale PWR safety assessment. © 2020 Xi'an Jiaotong University

关键词： Pressurized water reactors

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Simulation of horizontal slug-flow pneumatic conveying with kinetic theory

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中国高等学校学术文摘·能源与动力工程 2007年第3期1卷 336-340页

作者： GU Zhengmeng GUO Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

Wavelike slug-flow is a representative flow type in horizontal pneumatic *** theory was introduced to establish a 3D kinetic numerical model for wavelike slug gas-solid flow in this *** motion of particulate slugs in horizontal pipes was numerically *** formation and motion process of slugs and settled layer were *** characteristics of the flow,such as pressure drop,air velocity distribution,slug length and settled layer thickness,and the detailed changing characteristics of slug length and settled layer thickness with air velocity were *** results indicate that kinetic theory can represent the physical characteristics of the non-suspension dense phase flow of wavelike slug pneumatic *** experiment in this paper introduced a new idea for the numerical calculation of slug-flow pneumatic conveying.

关键词： slug-flow pneumatic conveying kinetic theory simulation

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Novel flow behaviors induced by a solid particle in nanochannels: Poiseuille and Couette

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Chinese Science Bulletin 2014年第20期59卷 2478-2485页

作者： Cheng-Zhen Sun Wen-Qiang Lu Bo-Feng Bai Jie Liu State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University College of Physical Sciences University of Chinese Academy of Sciences

We conducted a molecular dynamics(MD)simulation to address the novel flow behaviors induced by a solid particle in *** basic flows,i.e.,Poiseuille and Couette,are involved in this *** Poiseuille flow,the distribution of number density exhibits fluctuations in the center of channel and near the walls,which are caused by the strong interactions from the atoms of particle and *** stronger external driving forces,the fluid atoms move toward the center of channel and some cavities appear in the fluidic *** external driving forces and bigger particles make the fluid moving quickly in *** Couette flow,the particle rotates under the velocity difference among particle atoms in the shear *** fluid atoms near the walls become infrequent and move to the center of *** velocities of the centrally-located fluid atoms decrease owing to the particle,resulting in an untypical non-linear Couette *** summary,the solid particle brings new fluid–solid interface and interactions,which induce several novel behaviors in nanochannel flows.

关键词：流动行为纳米通道固体粒子 Poiseuille流诱发 Couette流强相互作用固体颗粒

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Numerical study and acceleration of LBM-RANS simulation of turbulent flow

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Chinese Journal of Chemical engineering 2018年第1期26卷 31-42页

作者： Shuli Shu Ning Yang State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of Sciences

The coupled models of LBM （Lattice Boltzmann Method） and RANS （Reynolds-Averaged Navier-Stokes） are more practical for the transient simulation of mixing processes at large spatial and temporal scales such as crude oil mixing in large-diameter storage tanks. To keep the efficiency of parallel computation of LBM, the RANS model should also be explicitly solved; whereas to keep the numerical stability the implicit method should be better for PANS model. This article explores the numerical stability of explicit methods in 2D cases on one hand, and on the other hand how to accelerate the computation of the coupled model of LBM and an implicitly solved RANS model in 3D cases. To ensure the numerical stability and meanwhile avoid the use of empirical artificial lim- itations on turbulent quantities in 2D cases, we investigated the impacts of collision models in LBM （LBGK, MRT） and the numerical schemes for convection terms （WENO, TVD） and production terms （FDM, NEQM） in an explic- itly solved standard k-e model. The combination of MRT and TVD or MRT and NEQM can be screened out for the 2D simulation of backward-facing step flow even at Re = 107. This scheme combination, however, may still not guarantee the numerical stability in 3D cases and hence much finer grids are required, which is not suitable for the simulation of industrial-scale *** we proposed a new method to accelerate the coupled model of LBM with RANS （implicitly solved）. When implemented on multiple GPUs, this new method can achieve 13.5-fold accelera- tion relative to the original coupled model and 40-fold acceleration compared to the traditional CFD simulation based on Finite Volume （FV） method accelerated by multiple CPUs. This study provides the basis for the transient flow simulation of larger spatial and temporal scales in industrial applications with LBM-RANS methods.

关键词： Lattice Boltzmann Method Reynolds-Averaged Navier-Stokes Graphic Processing Units mixing transient simulation

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