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Estimation of thermodynamic properties of the ternary molten salt system, LiF-NaF-BeF2, by the modified Peng-Robinson equation

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中国高等学校学术文摘·能源与动力工程 2007年第2期1卷 174-180页

作者： ZHANG Dalin QIU Suizheng SU Guanghui JIA Dounan School of Energy and Power Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The molten salt reactor (MSR), which is one of the generation IV reactors, can meet the demand of transmutation and breeding. The thermodynamic properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the MSR for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF2, over the temperature range from 873.15 to 1 073.15 K at one atmosphere pressure, is described using a modified Peng-Robinson (PR) equation. The densities of the ternary system and its components are estimated by this equation directly, and compared with the experimental data. Based on the equation of state, the other thermodynamic properties such as the enthalpy, entropyand heat capacity at constant pressure are estimated by the residual function method and the fugacity coefficient method respectively. The densities calculated by PR equation are highly in agr eement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by the two different methods are consistent with each other. It can be concluded that the modified PR equation can be applied to evaluate the density of the molten salt system, and it is recommended that it be used as the basis to estimate the enthalpy, entropy and heat capacity of the molten salt system.

关键词： thermodynamic properties molten salt LiF-NaF-BeF2 Peng-Robinson equation

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Stability,acidity and interaction properties of [Bmim][SbF_6] coupled with concentrated sulfuric acid

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Science China Chemistry 2017年第9期60卷 1243-1249页

作者： Honghua Zhang Ruixia Liu Ruirui Zhang Feng Huo Zhiqiang Yang Bin He Suojiang Zhang Yanji Wang School of Chemical Engineering Hebei University of Technology Key Laboratory of Green Process and Engineering Beijing Key Laboratory of Ionic Liquids Clean ProcessState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of Sciences

Ionic liquid coupled with strong acid systems presents considerable promise in some catalytic fields. In the present work, the multiple complex systems composed by 98 wt% concentrated sulfuric acid and [Bmim][SbF6] were investigated in the terms of stability, acidity and interaction properties. It was found that acidolysis of [Bmim][SbF6] occurred in the 98 wt% concentrated sulfuric acid accompanied by HF releasing and SbF6−degrading to [SbF6−y(HSO4)y]−. The species after acidolysis in the multiple complex systems were checked and confirmed by electrospray ionization mass spectrometry (ESI-MS), Fourier transform infrared spectroscopy (FT-IR),1H NMR and19F NMR. Acidity increased slightly with less than 1 wt% [Bmim][SbF6] addition, while decreased with more proportion, which was determined based on the Hammett acidity functions H0, using13C NMR. The strong hydrogen bond S–O–HF of interaction among the multiple complex systems was confirmed by molecular dynamic simulation. © 2017, Science China Press and Springer-Verlag Berlin Heidelberg.

关键词： Electrodeposition Electrospray ionization Fourier transform infrared spectroscopy Hydrogen bonds Ionic liquids Mass spectrometry Molecular dynamics Sulfuric acid

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Experimental and Theoretical Study on CHF of a Ultra-Supercritical Circulating Fluidized Bed Boiler Water-Wall Tube at near-Critical Pressures

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Journal of Thermal Science 2023年第1期32卷 166-182页

作者： WANG Wenyu MA Zhan QING Hao NIE Chao YANG Haoyu BI Lingfeng YANG Dong PAN Wenxiao State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China Department of Mechanical Engineering University of Wisconsin-Madison1513 University AveMadisonWI 53706USA

The experimental and theoretical research on the critical heat flux(CHF)in a uniformly heated water-wall tube of the efficient ultra-supercritical circulating fluidized bed(USCFB)boiler has been *** particular,the experimental pressure varies from 18 MPa to 21 MPa,which is from 0.814Pcr–0.95Pcr(Pcr:critical pressure).The mass flux varies from 310 kg·m^(–2)·s^(–1)to 550 kg·m^(–2)·s^(–1).The inlet sub-cooling temperatures vary from 5°C to 10°*** material of the tube is *** experimental investigation,the near critical pressure CHF test data of water are *** find that the CHF mainly occurs when the vapor qualities are less than 0.4,and it occurs earlier(at lower vapor quality)when the pressure is closer to 22.115 MPa or the mass flux is *** the experimental data,a correlation function for the CHF is established via regression and machine *** established via machine learning greatly improved the regression *** study the CHF phenomenon mechanically,a theoretical model is established based on the near-surface bubble crowding model describing the DNB-type *** the development of the CHF model,the friction resistance coefficient is determined according to our test *** comparison with different experimental results,the near-surface bubble crowding model is well suited to describe DNB-type *** calculation results of the model can provide reference for the optimal design of the USCFB boiler.

关键词： circulating fluidized bed critical heat flux near-critical pressure bubble crowding machine learning

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Numerical simulation on the frosting and heat transfer characteristics of plate-fin heat exchanger considering confinement effect

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Energy Storage and Saving 2022年第3期1卷 136-147页

作者： Xiaoling Yang Xue Liu Xiaojun Dong Yang Meng Yu Hou Tianwei Lai State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China

In refrigerating industry,frost commonly deposits on the confined cold surfaces of heat exchangers,which affects the heat transfer *** the confined flow path of the heat exchanger,the frosting at downstream is affected by the parameters from the *** this study,a numerical model considering the confinement effect has been proposed to predict frosting characteristics in plate-fin heat ***-diffusion equations for humid air and empirical correlations for local frost density are employed in the numerical *** behavior and heat transfer in the confined channel are investigated with different humid air parameters and cold surface *** results indicate that frost thickness in the confined channel is thicker than that in open space under the same inlet *** frost layer is thicker and fluffier along the confined *** addition,the air temperature difference between inlet and outlet of the confined channel enlarges with *** the same average temperature of upper and lower surfaces,the heat and mass transfer of frosting are enhanced with diminishing temperature difference of upper and lower *** such condition,frosting is mainly influenced by the cold surface with the lower temperature.

关键词： Heat exchanger Frosting Confined channel Numerical simulation Heat transfer

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Temporal and spatial non-uniformity of surface heat transfer during r404a spray cooling in laser surgery 13

Temporal and spatial non-uniformity of surface heat transfer...

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13th International Conference on Liquid Atomization and Spray Systems, ICLASS 2015

作者： Wang, R. Zhou, Z.F. Chen, B. Bai, F.L. Wang, G.X. State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University China

Cryogen spray cooling has been applied to protect epidermis from thermal damage in laser dermatology. However, present cryogen R134a shows insufficient cooling capacity on minimizing the laser energy absorption by the melanin in darkly pigmented human skins. With lower boiling point, R404A has potential to improve the cooling capacity. This paper presents an experimental study on the temporal and spatial variation in surface temperature and heat flux during spray cooling using R404A by a straight tube nozzle with expansion chamber, which significantly improves the atomization effect. The experimental results indicate that the temporal and spatial conditions strongly influence the uniformity of surface heat transfer. There exists a sub-region of uniform cooling with radius of 2 mm around spray center with high transient heat flux above 400 kW/m2, which is conducive for physicians to control the therapy area precisely with enhanced laser energy. © 2015 International Conference on Liquid Atomization and Spray Systems. All rights reserved.

关键词： Laser surgery

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Numerical prediction of spatio-temporal frosting patterns of curved surface considering varying working parameters

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Energy Storage and Saving 2023年第1期2卷 348-358页

作者： Xue Liu Xiaojun Dong Shaohang Yan Yu Hou Tianwei Lai State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China

Accurate numerical prediction of frosting patterns is essential for the efficient layout and timing defrosting of heat exchangers under frosting *** this study,a numerical model is developed to predict the spatio-temporal frosting habits on curved surfaces in combination with the correlations of frost density and thermal *** the model,frost melting is *** verification,the frosting and heat transfer characteristics along the flow path are investigated under various structural and operating *** thickness along the path is mainly affected by the cooling surface temperature,while the heat and mass transfer rates are strongly correlated with the humidity *** proportions of latent heat and sensible heat are distributed more unevenly in parallel flow case than in counter flow *** deposition is facilitated by a smaller radius of curvature of the cooling *** uniform frosting characteristics along the path and smaller heat transfer obstruction are presented with a smaller length-to-height ratio of the flow path.

关键词： Frosting Numerical prediction Heat transfer Curved surface Varying parameter

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Alloy nanocrystals:Synthesis paradigms and implications

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Chinese Journal of Structural Chemistry 2023年第11期42卷 1-5页

作者： Zhaojun Liu Zerui Mu Chuanbo Gao State Key Laboratory of Multiphase Flow in Power Engineering Frontier Institute of Science and TechnologyXi'an Jiaotong UniversityXi'an710054China

*** Noble metal nanocrystals serve as exceptional catalysts across a wide spectrum of industrial processes[1].Moreover,there exists a substantial demand for noble metal catalysts in emerging clean-energy applications,such as water-splitting hydrogen production and fuel *** non-noble transition metals or main-group metals into noble metal nanocrystals can reduce the weight of noble metals in the catalysts,thus remarkably lowering the ***,alloy nanocrystals offer intriguing catalytic properties that surpass those of their monometallic counterparts,thanks to the charge transfer between the constituent components and the expansion or shrinkage of the lattice size[2].

关键词： alloy metals noble

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Simulation and Experiment on Elbow Wear in Pneumatic Conveying System

Simulation and Experiment on Elbow Wear in Pneumatic Conveyi...

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International Conference on Power engineering 2021, ICOPE 2021

作者： Xiaole, Chen Qulan, Zhou Du, Wen Qingtian, Liu Na, Li State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University China

Elbow wear, which is most likely occurring in pneumatic conveying, becomes a key factor in development of pneumatic conveying. This paper used 3D DEM-CFD to simulate the elbow wear in pneumatic conveying system. Simulation results show that: elbow wear is linear with material mass flow rate. Elbow wear increases along with the increasement of material particle velocity. When the velocity changes from 0 to 10m/s, the elbow wear increases 3.13 times. Elbow wear increases while the radius of material particles is growing. When the particles radius increases from 0.1mm to 0.5mm, the elbow wear increases 11.13%. This paper also established a complete pneumatic conveying device for experiment. In pneumatic conveying experiment, the pressure loss was measured in situations: different airflow velocity, different velocity of material particles. The results of experiment show the same regular indicated in simulation. © 2021 The Japan Society of Mechanical Engineers.

关键词： Wear of materials

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Chlorine anchored pyrrole-based conjugated porous polymers for ultrahigh capacity and selective Hg(II) capture

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Separation and Purification Technology 2025年 374卷

作者： Bianyan He Jiarui Zhang Yubing Wang Mingtao Li Wei Yan Department of Environmental Science and Engineering Xi’an Key Laboratory of Solid Waste Recycling and Resource Recovery Xi’an Jiaotong University Xi’an 710049 PR China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 PR China

In this study, chlorine anchored pyrrole-based conjugated porous polymers (CPPs) with distinct pore properties were synthesized using the Knoevenagel reaction and the double chain condensation method. The partially crosslinked and partially oxidized structures of the materials exhibit a unique microstructure integrating interconnected nets and molecular hooks. This architecture utilizes pore channels for physical interception of Hg(II), while synergistic chemical immobilization at N, O, and Cl active sites enables multifunctional enhancement of Hg(II) capture efficiency. Among these materials, the maximum adsorption capacity reached 1183 mg·g −1 , demonstrating ultrahigh selectivity. Moreover, the adsorbents maintained > 90 % removal efficiency over 10 adsorption–desorption cycles, confirming excellent reusability. Mechanistic studies revealed that Hg(II) adsorption primarily whin material pores through hydrogen bonding and coordination interactions, and their synergistic interactions. This work highlights the efficiency of the double chain condensation design strategy in advancing conjugated porous polymers for the removal of heavy metals, particularly Hg(II), from wastewater.

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Single-jet Spray Mixing with a Confined Crossflow

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Chinese Journal of Chemical engineering 2013年第1期21卷 14-24页

作者：孙慧娟白博峰严俊杰张海滨 State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

In order to achieve uniform mixing between spray droplets and crossflow, cold-model experiment of a hollow-cone water spray in an air crossflow is investigated via a numerical simulation. The simulation cases are designed by using the orthogonal design method. The Eulerian-Lagrangian formulation is employed for modeling the droplets-crossflow two-phase flow while the realizable k-ε turbulence model is used to describe the turbulence. A new index, mixedness quality, is proposed to assess the overall mixing of the droplets in the crossflow. The simulation results demonstrate that the counter-rotating vortex pair (CVP) imposes a more significant impact on the spatial distribution than on the size distribution of the droplets. Pairs of CVP with smaller scales are preferable for achieving a better mixing. The influencing factors are listed in the following order in terms of the degree of their impact from the greatest to the least: the Sauter diameter of the initial droplets, the mixing tube diameter, the spray angle, the velocity of the inlet crossflow, and the vertical velocity of the initial droplets. A moderate droplet diameter, a smaller tube diameter, a moderate spray angle, a greater crossflow velocity and a moderate vertical velocity of the droplet are favorable for achieving a higher mixedness quality of the jet spray in a confined crossflow.

关键词： mixing jet spray droplets crossflow numerical simulation

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