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International Conference on Power engineering 2013, ICOPE 2013

作者： Fu, Jiapeng Luo, Qinlan Chang, Yan Li, Na Zhou, Qulan State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University 710049 China

With the experimental system of thermo-balance, the combustion characteristics of powders of different kinds of coals under various experimental conditions are studied by using the method of thermo-gravimetric analysis and differential scanning calorimetry. Different factors such as heating rate, particle size and additives on the combustion characteristics are investigated. The results show that, with the raise of heating rate , coal combustion TG and DTG curves of different kinds of coal move to higher temperature zone and the combustion rate increases while the characteristics of ignition and burnout is strengthened. With the sample weight increasing, the ignition temperature and coal combustion rate decreases and the burnout temperature increases. With the decrease of particle size of coal powder, combustion characteristics are commonly enhanced firstly and wakened later. Additives such as K2CO3, Ca(OH)2, Fe(NO3)3·9H2O, FeSO4 can promote coal combustion in the low temperature zone(573∼723K).

关键词： Heating rate

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Measurement of laminar burning velocities and Markstein lengths for diethyl ether-air mixtures at different initial pressure and temperature 7

Measurement of laminar burning velocities and Markstein leng...

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7th Asia-Pacific Conference on Combustion, ASPACC 2009

作者： Di, Yage Huang, Zuohua Zhang, Ni Gu, Xiaolei Zheng, Bin Zhang, Zhiyuan State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

Measurement of laminar burning velocities and Markstein lengths were made for the diethyl ether-air mixtures at different equivalence ratios, initial temperatures and pressures by using spherically propagating flame and schlieren photography method. The results show that the stretched flame propagation speeds and unstretched laminar burning velocities are increasing with the increase of the initial temperature. While the Markstein lengths are decreased with the increase of the initial temperature. The stretched flame propagation speeds, the unstretched laminar burning velocities and Markstein lengths are decreased with the increase of the initial pressure. The Markstein lengths are decreased with the increase of the equivalence ratio. Based on the experimental data, a correlation is obtained for the unstretched laminar burning velocity versus the initial temperature and pressure over wide range of equivalence ratios. © 2009 Combustion Institute. All rights reserved.

关键词： Mixtures

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Au@SiO_2 core/shell nanoparticle-decorated TiO_2 nanorod arrays for enhanced photoelectrochemical water splitting

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Chinese Science Bulletin 2014年第18期59卷 2191-2198页

作者： Jianan Chen Miao Yu Yuhao Wang Shaohua Shen Meng Wang Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong University School of Chemical Engineering and Technology Harbin Institute of Technology

To improve the separation efficiency of photoinduced charge carries,Au@SiO2nanoparticles(NPs)with core–shell structure were loaded onto the surface of TiO2nanorods grown on fluorine-doped tin oxide substrate by a facile two-step *** resulted Au@SiO2/TiO2photoanodes were characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy,as well as photoelectrochemical *** with pristine TiO2nanorod film,the Au@SiO2/TiO2films showed remarkable enhancement in photoelectrochemical water splitting,with incident photonto-current conversion efficiency increasing from 31%to37%at 380 nm at 0.7 V versus saturated calomel *** could be interpreted by the effect of metallic surface plasmon resonance of Au@SiO2NPs,which would generate an intense electromagnetic field with spatially nonhomogenous distributed *** a result,the charge carriers generated in the near-surface region of TiO2nanorods could be easily *** modification method based on the effect of metallic surface plasmon resonance for promoted charge carrier separation provides a promising way to develop semiconductor photoelectrodes with high solar water-splitting performance.

关键词：二氧化硅纳米粒子二氧化钛纳米棒电解水表面等离子体共振效应纳米颗粒金属 TiO2薄膜

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Design and simulation of a novel geothermalsolar combined chimney power plant

Design and simulation of a novel geothermalsolar combined ch...

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26th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2013

作者： Cao, Fei Ma, Qiuming Zhao, Liang Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

The solar chimney power plant (SCPP) is dominated by the solar radiation, and therefore its discontinuous operation is an unavoidable problem. In this paper, low temperature geothermal energy is introduced into the SCPP for overcoming this problem. Based on a developed mathematical model, theoretical analyses are carried out to investigate the performance of the geothermal-solar chimney power plant (GSCPP) with main dimensions the same as the Manzanares prototype in Spain. It is found that the GSCPP can attractively run in the full geothermal mode to deliver power continuously, which could solve the problem of the SCPP's running without sunlight in a long time, including at night. In addition, the introducing of geothermal energy into the SCPP can highly improve its power capacity.

关键词： Geothermal energy

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A calculation method for evaluating thermal loss of solar cavity receiver

A calculation method for evaluating thermal loss of solar ca...

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2009 Asia-Pacific Power and Energy engineering Conference, APPEEC 2009

作者： Jiabin, Fang Jinjia, Wei Xunwei, Dong Yueshe, Wang State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

ISBN: (纸本)9781424424870

One of the most important components of solar thermal power system is the solar central receiver, which performance is in direct relation to the efficiency of the whole power generation system. The calculation of internal surface heat flux and thermal efficiency of receiver therefore plays a very important role in receiver design. A calculation method of heat loass of a cavity receiver is put forward in this paper. The first step of this method is to use the Monte Carlo method to simulate the track of solar beam and compute surface heat flux inside the receiver. The second step is to employ the correlations of flow boiling heat transfer to figure out the convective heat transfer coefficient inside the tubes and then the wall temperature of the boiling tubes laid inside the receiver. The last step is to simulate the air flow field inside the receiver to calculate convective thermal loss of the receiver. As every step can not be independently done, all steps are coupled and an iterative scheme is needed. Internal surface heat flux and thermal efficiency of the receiver can be finally gained with this method, and the result can provide theoretical guide for receiver design. © 2009 IEEE.

关键词： Monte Carlo methods

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Layered sphere-shaped TiO_2 capped with gold nanoparticles on structural defects and their catalysis of formaldehyde oxidation

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Journal of Environmental Sciences 2016年第1期28卷 77-85页

作者： Chunyan Ma Guanglong Pang Guangzhi He Yang Li Chi He Zhengping Hao Department of Environmental Nano-materials Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy and Power Engineering Xi'an Jiaotong University

We describe here a one-step method for the synthesis of Au/TiO2 nanosphere materials,which were formed by layered deposition of multiple anatase TiO2 *** Au nanoparticles were stabilized by structural defects in each TiO2 nanosheet,including crystal steps and edges,thereby fixing the Au-TiO2 perimeter *** transfer occurred along the gaps between these TiO2 nanosheet layers and in contact with catalytically active sites at the Au-TiO2 *** doped Au induced the formation of oxygen vacancies in the Au-TiO2 *** vacancies are essential for generating active oxygen species（-＊O^-） on the TiO2 surface and Ti^3＋ ions in bulk *** ions can then form Ti^3＋-O^--Ti^4＋species,which are known to enhance the catalytic activity of formaldehyde（HCHO） *** studies on structural and oxygen vacancy defects in Au/TiO2 samples provide a theoretical foundation for the catalytic mechanism of HCHO oxidation on oxide-supported Au materials.

关键词： Layered Au/TiO2 nanospheres Structural defects Oxygen vacancy defects Reaction mechanism Formaldehyde oxidation

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Experimental and modeling study of low temperature ignition characteristics of methylcyclohexane/ethanol binary fuel 12

Experimental and modeling study of low temperature ignition ...

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12th Asia-Pacific Conference on Combustion, ASPACC 2019

作者： Liu, Yang Tang, Chenglong Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

The purpose of this work is to investigate the effect of ethanol blending into methylcyclohexane during the ignition at low temperatures. The ignition delay times of the binary fuels with ethanol blending ratio varied from 0% to 100% at = 1.0, Pc = 20 bar, Tc = 680 - 890 K were measured with the rapid compression machine, and the mechanism of Bissoonauth et al. (Proc Combust Inst 2018) well predicts the experimental results. Based on the high quality of the model, the effects of ethanol blending on the pressure and heat release are studied. Both of the maximum pressure and the heat release during the ignition decrease with the ethanol blending ratio increases. The interaction of MCH and ethanol happens in the competition of active radicals like OH, and MCH dominates the ignition process as it occupies about two thirds of the OH to form the fuel radical. © Asia-Pacific Conference on Combustion, ASPACC *** right reserved.

关键词： Ethanol

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Manipulating metal-oxygen local atomic structures in singlejunctional p-Si/WO_(3) photocathodes for efficient solar hydrogen generation

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Nano Research 2021年第7期14卷 2285-2293页

作者： Wu Zhou Chung-Li Dong Yiqing Wang Yu-Cheng Huang Lingyun He Han-Wei Chang Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityShaanxi 710049China Department of Physics Tamkang UniversityTamsui 25137TaiwanChina

Self-passivation in aqueous solution and sluggish surface reaction kinetics significantly limit the photoelectrochemical(PEC)performances of silicon-based ***,a WO_(3) thin layer is deposited on the p-Si substrate by pulsed laser deposition(PLD),acting as a photocathode for PEC hydrogen *** to bare p-Si,the single-junctional p-Si/WO_(3) photoelectrodes exhibit excellent and stable PEC performances with significantly increased cathodic photocurrent density and exceptional anodic shift in onset potential for water *** is revealed that the WO_(3) layer could reduce the charge transfer resistance across the electrode/electrolyte interface by eliminating the effect of Fermi level pinning on the surface of *** importantly,by varying the oxygen pressures during PLD,the collaborative modulation of W–O bond covalency and WO6 octahedral structure symmetry contributes to the promoted charge carrier transport and ***,a large band bending at the p-Si/WO_(3) junction,induced by the optimized O vacancy contents in WO_(3),could provide a photovoltage as high as~500 mV to efficiently drive charge transfer to overcome the water reduction ***,by manipulating W–O local atomic structures in the deposited WO_(3) layer,a great improvement in PEC performance could be achieved over the singlejunctional p-Si/WO_(3) photocathodes for solar hydrogen generation.

关键词： silicon local atomic structure water splitting photocathodes hydrogen generation

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Base-or acid-assisted polystyrene plastic degradation in supercritical CO_(2)

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Waste Disposal and Sustainable Energy 2023年第2期5卷 165-175页

作者： Yanbing Liu Jinwen Shi Liuhao Mao Bingru Lu Xing Kang Hui Jin International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong University28 West Xianning RoadXi’an710049ShaanxiChina

Plastic has caused serious"white pollution"to the environment,and the highly inert characteristics of plastic bring a major challenge for *** fluids have unique physical properties and have been widely used in various *** this work,supercritical CO_(2)(Sc-CO_(2))with mild conditions was selected and assisted by NaOH/HCl solution to degrade polystyrene(PS)plastic,and the reaction model was designed using response surface methodology(RSM).It was found that,regardless of the types of assistance solutions,the factors affecting PS degradation efficiencies were reaction temperature,reaction time,and NaOH/HCl *** the temperature of 400℃,time of 120 min,and base/acid concentration of 5%(in weight),0.15 g PS produced 126.88/116.99±5 mL of gases with 74.18/62.78±5 mL of H2,and consumed 81.2/71.5±5 mL of CO_(2).Sc-CO_(2)created a homogeneous environment,which made PS highly dispersed and uniformly heated,thus promoting the degradation of ***,Sc-CO_(2)also reacted with the degradation products to produce new CO and more CH_(4)and C_(2)H_(x)(x=4,6).Adding NaOH/HCl solution not only improved the solubility of PS in Sc-CO_(2),but also provided a base/acid environment that reduced the activation energy of the reaction,and effectively improved the degradation efficiencies of *** short,degrading PS in Sc-CO_(2)is feasible,and better results are obtained with the assistance of base/acid solution,which can provide a reference for the disposal of waste plastics in the future.

关键词： Plastic degradation Polystyrene Supercritical CO_(2) NaOH HCl

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Highly selective and stable hydrogenation of heavy aromatic-naphthalene over transition metal phosphides

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Science China Chemistry 2015年第4期58卷 738-746页

作者： Muhammad Usman Dan Li Chunshan Li Suojiang Zhang Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex SystemsInstitute of Process Engineering University of Chinese Academy of Sciences

The present study reports a highly selective and stable catalytic approach for producing tetralin, an important chemical, solvent, and H2 storage material. Transition metal phosphides （MOP, Ni2P, Co2P, and Fe2P） were prepared by wet impregnation and temperature-programmed reduction and characterized by X-ray diffraction （XRD）, energy dispersive X-ray spectroscopy （EDX）, EDX mapping, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, brunauer-emmett- teller （BET）, temperature-programmed desorption of ammonia （NH3-TPD）, and fourier transform infrared spectroscopy of pyridine （pyridine-FTIR）. Of all the transition metal phosphides MoP was formed at a lower reduction temperature, which resuited in smaller particle size that enhanced the overall surface area of the catalyst. The existence of weak, moderate, and Lewis acidic sites over MoP were responsible for its high tetralin selectivity （90%） and stability during the 100 h reaction on-stream in a fixed-bed reactor.

关键词： coal tar naphthalene transition metal phosphides selective hydrogenation tetralin

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