The continuous growth of CO2 emissions is one of the global problems facing humanity, and how to convert and exploit the stock of CO2 has become an urgent issue. Biomass as an activity of CO2 thermal reduction medium ...
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Crystallographic defects in noble metal nanocrystals are recognized as highly active catalytic sites,significantly enhancing activities in many important *** their importance,synthesizing noble metal nanocrystals with...
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Crystallographic defects in noble metal nanocrystals are recognized as highly active catalytic sites,significantly enhancing activities in many important *** their importance,synthesizing noble metal nanocrystals with a high density of defects poses a considerable synthetic ***,we present a novel lattice mismatch-induced formation mechanism to create high-density defects in noble metal *** approach takes advantage of lattice mismatch to enable nonepitaxial nucleation and growth of a noble metal on a foreign metal substrate,forming abundant noble metal crystallites with random lattice orientations not dictated by the substrate *** these crystallites grow extensively,they merge,forming numerous grain boundaries and yielding defect-rich noble metal ***-rich alloy nanocrystals can also be synthesized through a subsequent vacancy-diffusion alloying *** take defective PdCu alloy nanocages as an example and demonstrate the effectiveness of crystallographic defects in enhancing catalytic performance of noble metal *** nanocages exhibit superior activity in the electrocatalytic formic acid oxidation reaction,which is 1.6 times greater than their defect-free *** strategy offers a new avenue for creating defect-rich noble metal nanocrystals as highly efficient catalysts for a wide array of catalytic applications.
Carbon dioxide(CO_(2))is one of the main factors contributing to the greenhouse *** dependence on fossil fuels has led to increasing levels of carbon dioxide in the atmosphere every *** it is far from enough to solve ...
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Carbon dioxide(CO_(2))is one of the main factors contributing to the greenhouse *** dependence on fossil fuels has led to increasing levels of carbon dioxide in the atmosphere every *** it is far from enough to solve the climate problem by reducing the consumption of fossil fuels to cut down carbon dioxide *** recent years,a series of researches on Carbon Capture,Utilization and Storage(CCUS)have been carried out in various countries around the ***_(2) is a nontoxic,tasteless and stable gas at normal ***,when it reaches supercritical state after rising temperature and pressure,it has the characteristics of low viscosity,high diffusivity and high density,and is widely used in green,pollution-free and efficient development *** of these unique properties,supercritical carbon dioxide(sCO_(2))has attracted more and more attention from ***_(2) has been widely used in many aspects by virtue of its high solubility and easy *** from previous reviews which only introduced the application of sCO_(2) property,this paper introduces the current research status of the application of the thermodynamic property of carbon dioxide in extraction,dyeing,pharmaceutical,power generation,heat transfer and exploitation of unconventional oil and gas,and mainly analyzes each application in detail from the aspects of working mechanism and improving working ***,the research direction and problems needed to be solved for the application of CO_(2) thermal physics are proposed,which pave the way for other new applications.
In the concept of Fluoride-Salt-cooled high-Temperature Advanced Reactor (FuSTAR), the Printed Circuit Heat Exchanger (PCHE) is mainly considered in its supercritical carbon dioxide (S–CO2) Brayton cycle secondary lo...
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Air Brayton cycle obtains the significant advantages of high efficiency, compact structure, easy medium requirement and so on, which is one of the most suitable choices for the mobile nuclear power conversion system. ...
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An in-depth analysis on the cooperativity of intermolecular interactions including hydrogen bonding andπ-π stacking in 1,3,5-triamino-2,4,6-trinitrobenzene(TATB) crystal was studied. Two quantities, cooperativity ra...
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An in-depth analysis on the cooperativity of intermolecular interactions including hydrogen bonding andπ-π stacking in 1,3,5-triamino-2,4,6-trinitrobenzene(TATB) crystal was studied. Two quantities, cooperativity rate and energy, were defined to evaluate the nature and strength of cooperativity in a series of clusters diverging from 1D to 3D prototypes. The origin and mechanism of the cooperative effect were settled to demonstrate that the nature of cooperativity is determined by whether the non-covalent interactions compete or promote with each other, which is manifested by the changing trend of electron transfer. There exists obvious cooperative effect in intra-layer and inter-layer structures as they own the equivalent non-covalent interactions, while anti-cooperative effect is also observed if two interactions correlate with each other. On the whole, in the process of crystal formation, the apparent cooperativity is the check and balance of the two effects, which is capable to support a global interaction among all of molecules and contribute to the stabilization of system. Based on the results, one may get a new insight to understand the relationship between non-covalent interactions and low impact sensitivity.
Offshore wind turbines(OWTs) suffer wind, wave and earthquake loads. The investigation of OWTs' dynamic response under environmental loads is essential for structural safety assessment. The soil-structure interact...
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Offshore wind turbines(OWTs) suffer wind, wave and earthquake loads. The investigation of OWTs' dynamic response under environmental loads is essential for structural safety assessment. The soil-structure interaction(SSI)significantly affects the responses of OWT under environmental loads. However, there is few systematic research about the difference in the dynamic response of different SSI models under environmental loads. In order to solve the problem, the OWT is modeled by shell element, and several SSI models are built. The wind, wave and earthquake loads are taken into account. Moreover, the dynamic response, fatigue and buckling analysis are performed by ANSYS. The results indicate that SSI cannot be ignored in the dynamic response of the OWT under wind and wave loads. The SSI can decrease the displacement response of the OWT by 19% under wind and wave loads and reduce the fatigue damage of the pile. Multi-layer SSI can strongly influence the OWT's dynamic response under wind and wave loads or earthquake-only load. The vertical earthquake load increases the dynamic response in three ***, in order to simulate real environment, multi-layer SSI, soil damping and vertical SSI must be considered to evaluate the displacement response of the OWT under wind, wave and earthquake loads. The earthquake and gravity loads can cause more obvious response of the OWT than that of only wind and wave loads. The top and bottom of the tower are prone to occur buckling.
In the combined system of lead cooled fast reactor (LFR) and supercritical carbon dioxide (S-CO2) Brayton cycle, the intermediate heat exchanger plays a key role in the whole power system. However, the existing heat e...
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Particle streak velocimetry (PSV) has become one of the important branches of flow filed measurements. It extracts velocity information from particle trajectories captured by single frame long exposure images. Since t...
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Particle streak velocimetry (PSV) has become one of the important branches of flow filed measurements. It extracts velocity information from particle trajectories captured by single frame long exposure images. Since the defocus of moving particle is inevitable during a long exposure time and under a large magnification, a novel three-dimensional (3D) velocity measurement method named defocusing particle streak velocimetry (DPSV) is proposed in this paper. On the one hand, an extension from two-dimensional (2D) to 3D velocity measurement with a monocular system is carried out. The depth information of the particle, which reflects the position in the third dimension, is indicated by the defocusing degree (characteristic parameter σ) of the particle images. The variation of σ along the trajectory is recognized by surface fitting of the gray value distribution of particle images, assuming that σ varies linearly along the trajectory. On the other hand, based on the linear fitting for the straight trajectory, an arc fitting model is developed for curved trajectories which are commonly captured in turbulent flow. The relationship between σ and the particle depth position z is experimentally calibrated using a LED light and a diaphragm. Finally, the DPSV method is verified in a submerged jet flow field as well as in a microchannel flow field to obtain the 3D velocity field with single monocular system.
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