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Under-Deposit Corrosion Behavior and Dynamic Deliquescence Properties of Ammonium Salts Covered on Pipelines and Components in a Crude Oil Distillation Column: Experimental and Theoretical Studies

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SSRN 2022年

作者： Li, Ruidong Chen, Jukai Wang, Yueshe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'An710049 China School of Chemical Engineering & Technology China University of Mining and Technology Xuzhou221116 China

Electrochemical experiments based on the interdigital electrodes of SAE 1020 steel and atomic simulation were performed to investigate the under-deposit corrosion behavior and dynamic deliquescence properties of ammonium salts. In-situ electrochemical measurements demonstrate that the deliquescence of ammonium salts affects the evolution of the interface, and the surface characterization results proved that the critical state of moisture absorption leads to the most severe corrosion. Additional ab initio molecular dynamics simulations suggest that the H transport chain impacted by the hydrolysis of NH4+ leads to a variation in the charge state of the system, which may triggering corrosion. © 2022, The Authors. All rights reserved.

关键词： Steel corrosion

Optimization of crucial parameters for double-layer microchannel heat sink

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2014年第3期35卷 567-570页

作者： Lin, Lin Chen, Yang-Yang Wang, Xiao-Dong School of Mechanical Engineering University of Science and Technology Beijing Beijing 100083 China State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power University Beijing 102206 China Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy North China Electric Power University Beijing 102206 China

As compared with single-layer microchannel heat sink (SL-MCHS), double-layer microchannel heat sink (DL-MCHS) can significantly improve the temperature uniformity of electric elements. This work uses a three-dimensional solid-fluid conjugate model incorporated with a progressive optimization procedure to optimize the cooling performance of a water-cooled, silicon-based DL-MCHS. Four geometric parameters (channel number N, bottom channel height Hc1, upper channel height Hc2, and vertical rib width Wr) and coolant velocity ratio of upper channel to bottom channel, t, are selected as optimized variables. The results show that at a fixed pumping power of 0.05 W and a heat fluxes qw=100 W·cm-2, the optimal geometric structure and coolant velocity ratio for the DL-MCHS are Nopt=70, Hc1,opt=200 μm, Hc2,opt=650 μm, Wr,opt=71.48 μm, and topt=1.85. The thermal resistance of the optimal DL-MCHS is reduced by 11.3% compared to the SL-MCHS, and the maximum temperature difference is reduced to 0.5 K, which is far less than 4.2 K of the SL-MCHS.

关键词： Heat resistance

CO2 Splitting by Solar Two-Step Thermochemical Cycles with Cr, Ni and Li Doped CeO2 Solid Solution

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CO2 Splitting by Solar Two-Step Thermochemical Cycles with C...

IUPAC 9th International Conference on Novel Materials and their Synthesis(NMS-IX) & 23rd International Symposium on Fine Chemistry and Functional Polymers(FCFP-XXIII)(IUPAC第九届新型材料和合成国际会议暨第23届国际精细化工和功能聚合物研讨会)

作者： Y.J.Lu State Key Lab.of Multiphase Flow in Power Engineering Xi''an Jiaotong University28 Xianning West Road Xi''an 710049 China

Experimental research on thermal deviation of high temperature reheater in the single tangential Π type boiler based on radiation spectroscopy analysis 7

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Experimental research on thermal deviation of high temperatu...

7th International Conference on power engineering, ICOPE 2019

作者： Xie, Jianwen Wen, Wubin Yang, Bin Yang, Fei Ping, Li Zhang, Fei Zhang, Jianwen Electric Power Research Institute Co. Ltd. Beijing100025 China Jiangsu Guohua Chenjiagang Power Generation Co. Ltd. Jiangsu Yancheng224631 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Shanghai Boiler Works Ltd. Shanghai200245 China

The superimposed phenomenon of thermal deviation of low and high temperature reheaters was found under the high load condition in a 660MW ultra super-critical Π type boiler. And the discharge temperature deviation between the two sides of steam were more than 15℃ in high temperature reheater. In order to reveal the thermal deviation of high temperature reheater in this boiler, a probe was designed and developed to measure the visible radiation spectrums of coal dust in the high temperature reheater zone by using the servo mechanism of soot blower. The particle concentration and temperature of coal dust were obtained by the parameter fitting method based on Planck's radiation law. The measurement result shows that the burning delay of pulverized coal caused by originally equipped one-level air staged combustion system and enrichment of coal dust under the action of inertia are the main reasons of thermal deviation of high temperature reheater. And the momentum of SOFA to eliminate the rotation is insufficient in this boiler. In order to improve the thermal balance of both sides, a new type of the two-level air staged combustion system was proposed as principle of retrofit scheme. © ICOPE 2019 - 7th International Conference on power engineering, Proceedings. All rights reserved.

关键词： Coal combustion

Investigation of Thermal Radiative Transfer Characteristics of Single Water Droplet

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SSRN 2023年

作者： Zhang, Dan Tu, Maoping Yuan, Yang Han, Wei State Key Laboratory of Multiphase Flow in Power Engineering School of Energy & Power Engineering Xi'an Jiaotong University Shaanxi Xi’an710049 China Xi'an Thermal Power Research Institute Co. Ltd Shaanxi Xi’an710054 China

Directly heat water droplet by thermal radiation was the key process of coupling solar energy to achieve green production in many industrial applications, such as desalination, carbon capture, energy storage, and so on. The radiative transfer of single water droplet for given irradiation, including reflection, absorption, transmission and their dependences on external irradiation, droplet geometry and radiative properties were investigated through a calculation model set up according to zone method. In current study, the ranges of equivalent diameter and length-width ratio of droplet were 0.1-1.0 mm, 1-10 respectively, its absorption coefficient was 10-15000 m-1 and refractive index was 1.2-2.0. Results suggested that, (1) the absorption mode of droplet could be classified into surface absorption (SA) and volumetric absorption (VA) depending on whether its optical thickness was greater than 1. In VA, droplet could get uniform and fast temperature increasing, and its absorptivity and mean temperature increase rate could be simultaneously improved by increasing absorption coefficient. (2) Scattering included reflection and transmission. Compared with incident irradiation, reflection distributed mainly on the same side of droplet's long axis, while transmission mainly on the opposite side. The overall reflectivity increased with rising refractive index, but was independent on droplet size. While its transmissivity increased with enlarging length-width ratio or reducing equivalent diameter. (3) In VA, at least 40% of incident irradiation was scattered out. The total quantity of scattering could be adjusted by changing absorption coefficient in VA or refractive index in SA. The proportion of transmission in scattering could always be increased by reducing refractive index. © 2023, The Authors. All rights reserved.

关键词： Drops

Morphology Construction of Molybdenum Doped Nickel Sulfide Electrocatalyst Induced by Nh4f to Promote Hydrogen Evolution Reaction

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SSRN 2024年

作者： Zhang, Baikai Li, Xiaohui Liu, Maochang Huadian Electric Power Research Institute Co. Ltd. Zhejiang310030 China School of Eenergy and Power Engineering Xi’an Jiaotong University Shaanxi 710049 China State Key Laboratory of Multiphase Flow in Power Engineering China

Here, by varying the mass of NH4F throughout the hydrothermal process, Mo-doped nickel-based sulfide catalysts (Mo-NiS-Fx) with various morphologies (prisms, rods, flakes, and cones) were created. Among these, the flaky Mo-NiS-F1.2 exhibited exceptional performance towards electrochemical hydrogen evolution reaction, surpassing most similar catalysts with an overpotential of 79 mV at 10 mA cm-2 and a Tafel slope of 49.8 mV dec-1. Significantly, Mo-NiS-F1.2 maintained its high activity for hydrogen evolution over 60 h at 10 mA cm-2, making it suitable for widespread commercial application. This work demonstrates the potential of morphology manipulation to enhance catalytic activity. © 2024, The Authors. All rights reserved.

关键词： Hydrogen

Stability and Emission Characteristics of Ammonia/Air Premixed Swirling Flames with Rotating Gliding Arc Discharge Plasma

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SSRN 2022年

作者： Ju, Rongyuan Wang, Jinhua Zhang, Meng Mu, Haibao Zhang, Guanjun Yu, Jinlu Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi’an Jiaotong University Xi’an710049 China School of Aeronautics Engineering Air Force Engineering University Xi’an710038 China

Ammonia received increased attention as a carbon-free fuel and hydrogen carrier. Poor combustion stability and high NOx emission are the main issue for ammonia combustion. Effects of rotating gliding arc (RGA) discharge plasma on the flame stability and NOx emission of NH3/air premixed swirling flames were investigated. The discharge characteristics of the RGA were studied. The flame stabilization mechanisms by plasma were revealed and analyzed according to the flame structure transition and the distribution of key intermediate OH radicals. The NOx emissions were measured by the Gasmet DX4000 Fourier Transform Infrared (FTIR) gas analyzer. Results showed that the RGA discharge plasma can enhance the stability and extend the lean blow-off (LBO) limits from 0.6 to approximately 0.43-0.57. A hysteresis phenomenon about the transition between the lift-off flame and the attached flame was observed without plasma and disappeared with plasma activation. The plasma reduces NO and NO2 emissions mainly due to the kinetic and cracking effects of plasma. Extremely low NO emission below 300 ppm can be observed for very lean ammonia flames with an equivalence ratio (f) lower than 0.6, which are stabilized by plasma, while a large amount of unburned NH3 emission is accompanied. © 2022, The Authors. All rights reserved.

关键词： Ammonia

Polarity switching from p- to n-type in a single thermoelectric donor-acceptor copolymer by p-type doping

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Research Square

Research Square 2021年

作者： Wang, Jing Wang, Yizhuo Li, Qing Li, Zhanchao Xu, Liqing Li, Kuncai Wang, Hong Frontier Institute of Science and Technology Xi’an Jiaotong University Xi’an710054 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710054 China

The transport mechanism of organic materials is still far away from being well understood and controlled although conducting polymers have been discovered since 1977. It is rare to see conducting polyers possessing high bipolar (p- and n-type) electrical conductivities within a single bulk doped organic polymer without the assistant of gate voltage. Here, we report a novel approach to provide high performance n-type materials by p-type doping. More importantly, the bipolar electrical conductivities of the donor-acceptor conducting polymer are high, resulting high bipolar power factors among the solution-processable ambipolar D-A copolymers. A fully organic p-n junction is created in a planar film, exhibiting a high rectification ratio of 2 x 102 at ±5 V with a high current density of 3 A/cm2. Structural and spectroscopic tests have been performed to provide a fundamental understanding of the polarity switching mechanism. The results open the opportunity of making p- and n-type modules with a single conducting polymer for future modern organic electronics. © 2021, CC BY.

关键词： Conducting polymers

Preliminary Conceptual Design with Neutronics and Thermal-Hydraulics Assessments of Fustar

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SSRN 2023年

作者： Zhou, Xingguang Zhang, Dalin Li, Xinyu Lv, Xindi Jiang, Dianqiang Tian, Wenxi Qiu, Suizheng State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Lab. of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi'an Jiaotong University Xi'An710049 China

The fluoride-salt-cooled high-temperature advanced reactor (FuSTAR) is an advanced small modular reactor, which aims to the electric supplement and clean heat production to western China. In this study, neutronics and thermal-hydraulics analysis are also carried out, and established the core layout and material ratio under the near-critical condition. The parameters of the designed core are evaluated quantitatively from various aspects. The results show that FuSTAR has sufficient shutdown depth, the equilibrium cycle is 3.24 years, and the discharge burnup depth is 106 GWd/MtU. The analysis of 1/6 core porous media shows that the peak fuel temperature under normal operating condition is 1009.3 K, which is far below the limit of 1573 K. Relevant design and analysis results can provide the reference for the subsequent small modular FHR design and construction. © 2023, The Authors. All rights reserved.

关键词： Computational fluid dynamics