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Numerical Study of Percolation and Seepage Behaviors in Ion-Adsorption-Type Rare Earth Ore Leaching Process

Mathematical Problems in engineering 2023年第1期2023卷

作者： Dianyu, E. Su, Zhongfang Zeng, Jia Yang, Liuyimei Li, Jing Xu, Qiang Wang, Lin Cui, Jiaxin Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi University of Science and Technology Nanchang330013 China International Institute for Innovation Jiangxi University of Science and Technology Nanchang330013 China Ganjiang Innovation Academy Chinese Academy of Sciences Ganzhou341000 China ARC Research Hub for Computational Particle Technology Department of Chemical and Biological Engineering Monash University ClaytonVIC3800 Australia State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an710049 China Delft University of Technology Delft Netherlands

Ionic rare earth ore is a type of featured rare earth ore in China. Its mining process suffers from a long leaching cycle and considerable consumption of leaching agents. Improving mining efficiency requires a sound physical understanding of the leaching process. In this study, the CFD-based numerical model is used to analyze the physical process of leaching through porous media formed by particles. The simulation results indicate that a lower packing porosity and smaller particles packed granular porous medium result in much larger energy dissipation during seepage, and the energy dissipation increases with seepage velocity. It is found that when the seepage velocity increases to a certain high value, the energy dissipation exceeds the value predicted by Darcy's law, which is mainly caused by liquid turbulence. Additionally, the effect of particle shape is examined. The results show that the granular medium composed of prolate particles causes larger energy dissipation than oblate particles, and spherical particles play the least role. This phenomenon may result from the particle shape affecting the area of the frontal contact surface between particles and liquid. The results provide new insights into the fundamental understanding of percolation and seepage behaviors in the ion-adsorption-type rare earth ore leaching process. © 2023 E. Dianyu et al.

关键词： Energy dissipation

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X-Ray Computed Tomography (Xct) Study of Jetting in a Fluidized Bed: Effects of Two-Component Fluidization

SSRN

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SSRN 2024年

作者： Xiang, Zhong Chen, Xi Liu, Shuguang Heindel, Theodore J. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy and Environment Southeast University Nanjing210096 China Institute of Science and Technology for Carbon Neutrality Southeast University Nanjing210096 China Center for Multiphase Flow Research and Education Department of Mechanical Engineering Iowa State University AmesIA50011 United States

Fluidization of non-spherical particles is commonly found in the biomass and solid waste processing industry, and the jetting characteristic above the aeration plate is critical to the fluidization performance of these particles. In this study, cylindrical particles are used as typical non-spherical particles and co-fluidized with small bed material particles. X-ray computed tomography (XCT) is used to reconstruct the 3D structure of the aeration plate region, allowing for the identification of individual aeration jets. The effects of jet velocity (Uj), cylindrical particle mass fraction (ω), cylindrical particle density (ρi), and the cylindrical particle sphericity () on jet shape and volume are investigated. The experimental results indicate that decreasing the cylindrical particle mass fraction (ω) and particle density (ρi) increases the jet length (L), maximum jet diameter (D), and maximum jet volume (V), but have little effect on the jet half angle (θ). The cylindrical particle density (ρi) is the most sensitive factor for jet shape, while the effect of cylinder particle sphericity () on jet shape is insignificant. A correlation of jet length (L) in a two-component fluidized bed with cylindrical particles and bed material is proposed based on all the experimental results. © 2024, The Authors. All rights reserved.

关键词： Fluidization

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Activated Overall Water Splitting Over a Ni-Fe Layered Double Hydroxide Electrocatalyst by V Doping and Sulfuration

SSRN

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SSRN 2023年

作者： Wu, Wentong Peng, Lei Min, Boya Huang, Jie Liu, Saiya Lu, Kejian Lu, Shijian Jing, Dengwei Zheng, Mingsheng Liu, Maochang International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China No. 8 Oil Production Plant of PetroChina Changqing Oilfield Company Shaanxi Xi’an710016 China Carbon Neutrality Institute Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization China University of Mining and Technology Jiangsu Xuzhou221008 China Gree Altairnano New Energy Inc Zhuhai519040 China School of Chemistry and Biological Engineering University of Science and Technology Beijing Beijing100083 China

Ni-Fe layered double hydroxide (NiFe-LDH) is regarded as one of the promising non-noble electrocatalyst. However, the limited number of active sites and poor electrical conductivity impede its further development. Herein, we report the synthesis of a Ni foam supported NiFe-LDH electrocatalyst modified by V doping and vulcanization (NiFeV-S/NF). This modification endows the catalyst excellent property toward hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and overall water splitting. Only 211 mV and 127 mV of the overpotentials are required to achieve the current density of 10 mA cm-2 for OER and HER in 1 M KOH electrolyte, respectively. Particularly, the prepared NiFeV-S/NF could serve as a bifunctional electrocatalyst for overall water splitting, with a cell voltage of 1.573 V to reach a current density of 10 mA cm-2. In principle, the success relies on the intrinsically improved conductivity, increased specific surface area and the number of active sites, as well as the heterojunction structure of the catalyst. Therefore, this work provides a new idea for the design and preparation of more efficient noble-metal-free bifunctional electrocatalysts. © 2023, The Authors. All rights reserved.

关键词： Electrocatalysts

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Au [email protected] @ZnIn 2 S 4 nanosheets with significantly enhanced visible-light photocatalytic H 2 evolution: The effect of different Au positions on the transfer of electron-hole pairs

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Applied Catalysis B: Environmental 2021年 282卷

作者： Siman Mao Jian-Wen Shi Guotai Sun Dandan Ma Chi He Zengxin Pu Kunli Song Yonghong Cheng State Key Laboratory of Electrical Insulation and Power Equipment Center of Nanomaterials for Renewable Energy School of Electrical Engineering Xi'an Jiaotong University Xi'an 710049 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi China

Herein, a new type of photocatalysts, Au [email protected] @ZnIn 2 S 4 nanosheets ( [email protected] @ZIS), is elaborately designed for the photocatalytic H 2 evolution from water splitting, where Au nanodots (NDs) are anchored in the pore space of thiol-functionalized UiO66 metal-organic framework (MOF) and ZnIn 2 S 4 nanosheets are wrapped around the UiO66 MOF containing Au NDs. It is found that the different Au positions have a grateful effect on the transfer of photogenerated charge carriers. In [email protected] @ZIS, the photoexcited electrons transfers from ZnIn 2 S 4 to UiOS and then to Au NDs, establishing a smooth transmission channel of electrons. As expected, the optimal sample (Au 4 @ [email protected] 40 ) presents a high photocatalytic H 2 production rate of 391.6 μmol/h (10 mg of catalyst) under visible light irradiation, which is 435.1, 61.2 and 10.2 times higher than that of the pure UiOS, ZnIn 2 S 4 and [email protected] , respectively.

关键词： Photocatalysis Hydrogen evolution Metal-organic framework Thiol- functionalization Au nanodots

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Expression of SALL4 in the synovial tissue of refractory rheumatoid arthritis patients

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Rheumatology & Autoimmunity 2024年第1期4卷 59-61页

作者： Ru Fan Zeqiong Liang Yujie Bu Fen Zhang Xing Cen Yuqing Liu Fenping Lian Fengwu Chen Shengxiao Zhang Junwei Chen Department of Rheumatology The Second Hospital of Shanxi Medical UniversityTaiyuanChina State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'anShaanxiChina Key Laboratory of Cellular Physiology at Shanxi Medical University Ministry of EducationTaiyuanChina Shanxi Provincial Key Laboratory of Rheumatism Immune Microecology The Second Hospital of Shanxi Medical UniversityTaiyuanChina

To the Editor,Rheumatoid arthritis(RA)synovitis is characterized by synovial inflammation,characterized by synovial proliferation,neovascularization,and leukocyte infiltration into the joint space,1 leading to irreversible cartilage and bone damage.2 This synovial inflammation stimulates the formation of pannus,which is an invasive tumor-like mass,ultimately contributing to the pathogenesis of *** shares several similarities with cancer,including joint pain,swelling,and stiffness,which are accompanied by hypoxia in the synovial tissue and tumor environment.3 Spalt-like transcription factor 4(SALL4)plays an essential role in the occurrence and development of tumors.4 However,SALL4 expression in synovial tissue of RA is yet to be *** study aimed to investigate SALL4 expression in synovial tissue derived from patients with RA,using immunohistochemical techniques.

关键词： SALL4 patients inflammation

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Efficiency enhancement in photoelectrochemical water splitting: Defect passivation and boosted charge transfer kinetics of zinc oxide nanostructures via chalcopyrite/chalcogenide mix sensitization

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Physical Review Materials 2021年第12期5卷 125403-125403页

作者： Cigdem Tuc Altaf Nazrin Abdullayeva Ozlem Coskun Alihan Kumtepe İpek Deniz Yildirim Emre Erdem Maochang Liu Ali Bozbey Ertan Agar Mehmet Sankir Nurdan Demirci Sankir Micro and Nanotechnology Graduate Program TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey Faculty of Engineering and Natural Sciences Sabanci University Orhanli Tuzla 34956 Istanbul Turkey International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 People's Republic of China Department of Electrical and Electronics Engineering TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey Department of Mechanical Engineering Energy Engineering Graduate Program University of Massachusetts Lowell Lowell Massachusetts 01854 USA Department of Materials Science and Nanotechnology Engineering TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey

ZnO thin films in nanorod (NR) and nanoflower (NF) morphologies were used as photoelectrode scaffolds for efficient visible-light-driven photoelectrochemical (PEC) water splitting process, where their decoration with copper indium gallium sulfide (CIGS) and indium sulfide (In2S3) layers resulted in significant PEC performance enhancement. ZnO NF/CIGS/In2S3 photoelectrodes exhibited a remarkably high PEC efficiency (∼6.0% applied bias photon-to-current efficiency, 83% incident photon-to-current efficiency) due to the negligible dark current, while ZnO NR/CIGS/In2S3 generated a photocurrent density of ***–2 at 0.4 V (vs Ag/AgCl), being one of the highest performances reported in the literature for copper-based chalcopyrite photoelectrodes so far. The interfacial photoelectrode-electrolyte charge transport dynamics, investigated via intensity-modulated photocurrent spectroscopy, exhibited a sevenfold increase in charge transfer efficiencies with a significant drop in surface recombination kinetics for ZnO NF after CIGS/In2S3 decoration. The obtained results show consistency with numerically modeled electric field distribution profiles and electron paramagnetic resonance results of ZnO NF, rationalizing the enhanced charge transfer rates for decorated samples and confirming the defect passivating nature of CIGS/In2S3.

关键词： Electrochemical properties Photoconductivity

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Non-Hermitian delocalization in a 2D photonic quasicrystal

arXiv

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arXiv 2023年

作者： Zhang, Zhaoyang Liang, Shun Septembre, Ismaël Yu, Jiawei Huang, Yongping Liu, Maochang Zhang, Yanpeng Xiao, Min Malpuech, Guillaume Solnyshkov, Dmitry Key Laboratory for Physical Electronics and Devices The Ministry of Education Shaanxi Key Lab of Information Photonic Technique School of Electronic Science and Engineering Faculty of Electronics and Information Xi’an Jiaotong University Xi’an710049 China Institut Pascal PHOTON-N2 Université Clermont Auvergne CNRS Clermont INP Clermont-FerrandF-63000 France International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Department of Physics University of Arkansas FayettevilleAR72701 United States National Laboratory of Solid State Microstructures School of Physics Nanjing University Nanjing210093 China Paris75231 France

Quasicrystals show long-range order, but lack translational symmetry. So far, theoretical and experimental studies suggest that both Hermitian and non-Hermitian quasicrystals show localized eigenstates. This localization is due to the fractal structure of the spectrum in the Hermitian case and to the transition to diffusive bands via exceptional points in the non-Hermitian case. Here, we present an experimental study of a dodecagonal (12-fold) photonic quasicrystal based on electromagnetically-induced transparency in a Rb vapor cell. The transition to a quasicrystal is obtained by superposing two honeycomb lattices at 30◦ with a continuous tuning of their amplitudes. Non-Hermiticity is controlled independently. We study the spatial expansion of a probe wavepacket. In the Hermitian case, the wavepacket expansion is suppressed when the amplitude of the second lattice is increased (quasicrystal localization). We find a new regime, where increasing the non-Hermitian potential in the quasicrystal enhances spatial expansion, with the C12 symmetry becoming visible in the wavepacket structure. This real-space expansion is due to a k-space localization on specific quasicrystal modes. Our results show that the non-Hermitian quasicrystal behavior is richer than previously thought. The localization properties of the quasicrystals can be used for beam tailoring in photonics, but are also important in other fields. Copyright © 2023, The Authors. All rights reserved.

关键词： Quasicrystals

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Thermodynamic Analysis on of Skid-Mounted Coal-bed Methane Liquefaction Device using Cryogenic Turbo-Expander

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IOP Conference Series: Materials Science and engineering 2017年第1期278卷

作者： Shuangtao Chen Lu Niu Qiang Zeng Xiaojiang Li Fang Lou Liang Chen Yu Hou State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 PR China Xinjiang Coal Research Institute Urumqi 830091 PR China

Coal-bed methane (CBM) reserves are rich in Sinkiang of China, and liquefaction is a critical step for the CBM exploration and utilization. Different from other CBM gas fields in China, CBM distribution in Sinkiang is widespread but scattered, and the pressure, flow-rate and nitrogen content of CBM feed vary significantly. The skid-mounted liquefaction device is suggested as an efficient and economical way to recover methane. Turbo-expander is one of the most important parts which generates the cooling capacity for the cryogenic liquefaction system. Using turbo-expander, more cooling capacity and higher liquefied fraction can be achieved. In this study, skid-mounted CBM liquefaction processes based on Claude cycle are established. Cryogenic turbo-expander with high expansion ratio is employed to improve the efficiency of CBM liquefaction process. The unit power consumption per liquefaction mole flow-rate for CBM feed gas is used as the object function for process optimization, compressor discharge pressure, flow ratio of feed gas to turbo-expander and nitrogen friction are analyzed, and optimum operation range of the liquefaction processes are obtained.

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Optimization design of flue gas temperature for Low-Low Temperature Electrostatic Precipitator

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Journal of Physics: Conference Series 2019年第1期1300卷

作者： Ke Sun Yu Yan Jiahao Jiang Lei Deng State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China Huadian Electric Power Research Institute Co. LTD. Hangzhou 310030 China

Low temperature corrosion is one of the key issues in application of low-low temperature electrostatic precipitator. The concentration of SO3 affects the acid dew point temperature of flue gas. The exhaust temperature after the air preheater should be higher than the acid dew point temperature. The residual heat of flue gas is fully utilized by the low-temperature economizer. The efficiency of low-low temperature electrostatic precipitator is improved by the comprehensive effect of the condensation of SO3 on the surface of the fine particles, the decrease of the specific resistance of the particles and the agglomeration of the fine particles.

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Corrigendum to “Entrainment at T-junction: A review work” [Prog. Nucl. Energy 70 (January 2014) 221–241]

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Progress in Nuclear Energy 2014年 71卷 279-279页

作者： Zhaoming Meng Laishun Wang Wenxi Tian Suizheng Qiu Guanghui Su School of Nuclear Science and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University No. 28 Xianning West Road Xi'an 710049 China

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