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The Performance Study on Hydrogen Production From Medium Temperature Methane Chemical Looping Steam Reforming Using Lithium-based Absorbent

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2025年第5期46卷 1401-1408页

作者： Wang, Xuyun Li, Yang Gai, Zhongrui Rao, Qiong Liu, Mingkai Pan, Ying School of Engineering Science University of Science and Technology of China Hefei230027 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China University of Chinese Academy of Sciences Beijing100049 China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Lithium silicate serves as a novel CO2 absorbent with moderate absorptionregeneration temperature range (500∼700◦C) and excellent cycling stability. In this study, Li2CO3 was selected as the precursor for the preparation of lithium silicate. Additionally, a eutectic co-doping method with potassium elements was employed to enhance its reactivity. Using extrusion-spheronization, we successfully produced absorbent particles with high mechanical strength and cycling stability. The effects of absorption-regeneration temperature, CO2 concentration and particle diameter on the performance of absorbent particles have been studied in detail. Furthermore, mixed with NiO oxygen carriers, sorption-enhanced chemical looping reforming (SE-CLR) experiments were conducted at the range of 500∼650◦C for hydrogen production and in situ CO2 capture factors such as reaction temperatures and oxygen carrier to absorbent mass ratios were then investigated The results showcase that at the optimal reaction temperature of 600◦C, the SE-CLR process effectively lowered the reaction temperature by 25◦C, achieving a 13% increase in methane conversion rate and hydrogen purity and CO2 capture rate above 90% were attained. © 2025 Science Press. All rights reserved.

关键词： Silicates

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Bubble Behavior and Heat Transfer of Nucleate Pool Boiling on Micro-Pin-Finned Surface in Microgravity

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Chinese Physics Letters 2011年第1期28卷 160-163页

作者： WEI Jin-Jia XUE Yan-Fang ZHAO Jian-Fu LI Jing State Key Laboratory of Multiphase Flow in Power Engineering Xi 'an Jiaotong University Xi'an 710049 Key Laboratory of Microgravity (National Microgravity Laboratory)/CAS Institute of Mechanics Chinese Academy of Sciences Heijing 100190

Nucleate pool boiling on micro-pin-finned surface structure is proposed for efficiently cooling electronic compo- nents with high heat flux in microgravity, and was verified by experiments performed utilizing the drop tower Beijing. Micro-pin-fins with tile dimensions of 50 × （30 μm2 （thickness × height） and the space of 50 μm were fabricated on the chip surface by the dry etching technique. FC-72 was used as the working fluid. Nucleate pool boiling of FC-72 on a smooth surface was also tested for comparison. Unlike much obvious deterioration of heat transfer of nucleate pool boiling on the smooth surface in microgravity, constant heater surface temperature of nucleate pool boiling for the micro-pin-finned surface was observed, even though a large coalesced bubble completely covered the surface under microgravity condition. The performance of high efficient heat transfer on micro-pin-finned surface is independent of the gravity, which stems from the sufficient supply of fresh liquid to the heater surface due to the capillary forces.

关键词： Fluid dynamics Surfaces, interfaces and thin films

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Study on Thermo-Conductive Plastic Finned TubeRadiators

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Journal of Thermal Science 1997年第1期6卷 21-26页

作者： Yang Jiehui Cheng Lixin(Chemical engineering School, state key laboratory of multiphase flow in power engineering, Xi’anJiaotong University, Xi’an 710049, China) Chemical Engineering School State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

This paper discusses thermo-conductive plastic finned tube radiators used in water saving type powerstations. First, the development of thermo-conductive plastics is introduced. Second, in order todetermine the rational geometric dimensions of thermo-conductive plastic finned tubes, an objectivefunction which takes the minimum volume of the consumed material for making finned tubes as an ob-ject is introduced. On the basis of the function, the economy comparison between thermaxonductiveplastic finned tubes and metal finned tubes is conducted.

关键词： air-cooling radiator thermo-conductive plastic finned tube optimum geometric parameters economy comparison

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Experimental and Numerical Study on Co-combustion Behaviors and NO_(x) Emission Characteristics of Semi-coke and Coal in a Tangentially Fired Utility Boiler

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Journal of Thermal Science 2021年第4期30卷 1116-1131页

作者： WANG Chang’an FENG Qinqin JIN Liyan WANG Zhichao YAO Wei WANGPengqian DU Yongbo ZHANG Xilai YANG Zhongcan CHE Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China Xi’an Thermal Power Research Institute Co. LTD.Xi’an 710054China

The utilization of powdery semi-coke as a power fuel in pulverized coal-fired power plants has become a new and potential technique to consume the excess powdery *** characteristic of low volatile results in poor combustion performance and high NO_(x) emission,and to co-fire with bituminous coal is a practical strategy to address this ***,the co-combustion characteristics and the inherent interaction between semi-coke and coal remain insufficiently *** addition,the influences of secondary air arrangement,the boiler operation load,and the fuel type on co-combustion process are still unclear,which is urgent to be further *** the present study,experiments and numerical simulations were jointly utilized to inquire into the co-combustion behaviors and NO_(x) emission features of semi-coke and *** results demonstrated that the"out-furnace method"was a suitable choice for small-capacity boiler when the proportion of semi-coke was 33%,due to the limited combinations of the semi-coke injection *** was recommended that semi-coke was preferred to be injected from the middle layers of the furnace under the"in-furnace method"to improve the overall co-combustion *** critical value of the separated over fire air ratio in this study was 27.5%,over which a slight drop of carbon content in fly ash could come ***,the elevation in the proportion of separated over fire air gave rise to the significant decline of NO_(x) *** constricted secondary air arrangement was preferred to be employed due to the high boiler *** separated over fire air and the surrounding air needed to maintain a wide-open degree to prevent the increase of NO_(x) emissions and the coking of *** the load reduction regulation method adopted in this study,the NO_(x) concentration first rose and then dropped,while the burnout ratio decreased obviously as the operation load was *** combinations of coa

关键词： semi-coke numerical simulation co-combustion NOx emission blending method

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Experimental study on dynamic mechanism of vortex evolution in a turbulent boundary layer of low Reynolds number

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Journal of Hydrodynamics 2020年第5期32卷 807-819页

作者： Yan-ang Guo Xiang-rui Dong Xiao-shu Cai Wu Zhou School of Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China Key Laboratory of Multiphase Flow and Heat Transfer in Shanghai Power Engineering Shanghai 200093China

The dynamic mechanism of the vortex generation and evolution process in a fully developed turbulent boundary layer with Reθ=97-194 is experimentally *** this study,a moving single-frame and long-exposure(MSFLE)imaging method and a moving particle image velocimetry/particle tracing velocimetry(M-PIV/PTV)are designed and implemented for measuring the temporal and spatial evolution of vortex cores in both qualitative and quantitative ways,*** the other hand,the Liutex vector,which is a new mathematical definition and identification of the vortex core proposed by Liu’s group,is first applied in the experiment for the structural visualization and quantitative analysis of the local fluid *** results show that an intuitional process of vortex evolution can be clearly observed by tracking the vortex using MSFLE and verify that the roll-up of the shear layer induced by shear instability is the origin of vortex formation in ***,a quantitative investigation in terms of the critical vortex core boundary(size)and its accurate rotation strength is carried out based on the Liutex vector field analysis by M-PIV/*** to statistics of the relation between vortex core size and the rotation strength during the whole process,the physical mechanism of vortex generation and evolution in a turbulent boundary layer of low Reynolds number can be summarized as a four-dominant-state course consisting of the“synchronous linear segment(SL)-absolute enhancement segment(AE)-absolute diffusion segment(AD)-skewing dissipation segment(SD)”.

关键词： Turbulent boundary layer high-and low-speed fluid vortex generation moving single-frame and long-exposure moving particle image velocimetry/particle tracing velocimetry Liutex vector

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Resource utilization of solid waste carbide slag:a brief review of application technologies in various scenes

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Waste Disposal and Sustainable Energy 2022年第1期4卷 1-16页

作者： Hongxia Wang Wanyi Xu Maimoona Sharif Guangxu Cheng Zaoxiao Zhang State Key Laboratory of Multiphase Flow in Power Engineering School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

China is the largest producer and consumer of calcium carbide in the *** calcium carbide industry is an indispensable industry to support the basic life of *** huge production capacity of calcium carbide is accompanied by a large number of solid waste carbide *** to the immature treatment technology of carbide slag,a large number of carbide slag are stacked on-site,resulting in land occupation,air-drying,easy take-off ash,and pollution of the environment and water *** China,calcium carbide is mainly used to produce acetylene and further utilized,80%of which is used to produce polyvinyl chloride(PVC).A large amount of carbide slag is not used,while only a small part is used in the traditional building materials industry,flue gas desulfurization,sewage treatment,etc.,however,the economic benefits are ***,converting the solid waste carbide slag produced by the calcium carbide industry into high value-added CaCO3,CaCl2,CaSO4 whiskers,*** become a potential way to expand the development field of the calcium carbide industry and is environmentally *** paper focuses on summarizing the traditional and emerging high value-added utiliza-tion technologies of carbide slag,and then introduces the application research of carbide slag in carbon emission ***,the defects of these technologies are summarized and further research directions are *** study provides basic guidance for the diversified development of efficient resource utilization of carbide *** abstract Diversified development of calcium carbide industry,resource utilization of solid waste carbide slag and its application of carbon emission reduction have been fully reviewed.

关键词： Calcium carbide Carbide slag Application research High added value Carbon emission reduction

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Effect of Particle Orientation on Heat Transfer in Arrays of Prolate Particles

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Computer Modeling in engineering & Sciences 2023年第8期136卷 1509-1526页

作者： Romana Basit Xinyang Li Zheqing Huang Qiang Zhou School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’anChina State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’anChina

Direct Numerical Simulations have been carried out to study the forced convection heat transfer of flow through fixed prolate particles for a variety of aspect ratios ar={5/4,5/3,5/1}with Reynolds number(Re)up to *** variations of the solid volume fraction c={0.1,0.2,0.3}with four Hermans orientation factors S={−0.5,0,0.5,1}are *** has been found that changes in S cause prominent variations in the Nusselt *** general,Nusselt number increases with the decrease of *** all three aspect ratios,the Nusselt number remains a linear function of S at different c and ***,it is concluded that,for heat transfer from prolate muti-particle system,the effects of orientations cannot be ignored.A new correlation for Nusselt number has been developed for arrays of prolate particles using the simulation data as a function of Re,c,S and ar.

关键词： Direct Numerical Simulation heat transfer lattice Boltzmann method particle orientations prolate particles

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Estimation of particle depth from two defocused images using the Fourier transform

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Particuology 2020年第2期18卷 48-54页

作者： Wu Zhou Xu Luo Benting Chen Yukun Zhang Xiaoshu Cai School of Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai 200093China

Depth from defocus is one technology for depth *** estimate particle depth information from two defocused images captured simultaneously by two coaxial cameras with different imaging *** images are processed with the Fourier transform to obtain the characteristic parameter(i.e.,the standard deviation of the relative blur kernel of these two defocused images).First,we theoretically analyze the functional relationship between the object depth and the standard deviation or variation of the relative blur ***,we verify the relationship *** analyze the influence of particle size,window size and image noise on the calibration curves using both numerical simulations and *** obtain the depth range and accuracy of this measurement system *** the verification experiments,we use a sample of glass microbeads and the irregularly-shaped dust particles on a microscope *** of these experiments present a suitable depth measurement ***,we apply the measuring system to the depth estimation of drops from a small anti-fogging *** results show that our system and image processing algorithm are robust for different types of particles,facilitating the in-line three-dimensional positioning of particles.

关键词： Depth from two defocused images Fourier transform Standard deviation of relative blur kernel Drops depth measurement Sensitivity and accuracy analysis

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Particle convective heat transfer near the wall in a supercritical water fluidized bed by single particle model coupled with CFD-DEM

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Particuology 2023年第2期73卷 47-58页

作者： Tianning Zhang Zhen Wan Youjun Lu State Key Laboratory of Multiphase Flow in Power Engineering(SKLMFPE) Xi'an Jiaotong UniversityXi'an710049ShaanxiChina Xi'an Electronic Engineering Research Institute Xi'an710100ShaanxiChina

Supercritical water fluidized bed(SCWFB)is a promising reactor to gasify biomass or *** optimization design is closely related to wall-to-bed heat transfer,where particle convective heat transfer plays an important *** paper evaluates the particle convective heat transfer coefficient(h_(pc))at the wall in SCWFB using the single particle *** critical parameters in the single particle model which is difficult to get experimentally are obtained by the computational fluid dynamics-discrete element method(CFD-DEM).The contact statistics related to particle-to-wall heat transfer,such as contact number and contact distance,are also *** results show that particle residence time(τ),as the key parameter to evaluate h_(pc),is found to decrease with rising velocity,while increase with larger thermal boundary layer thickness.τfollows a gamma function initially adopted in the gas-solid fluidized bed,making it possible to evaluate h_(pc) in SCWFB by a simplified single particle *** theoretical predicted h_(pc) tends to increase with rising thermal gradient thickness at a lower velocity(1.5 U_(mf)),while first decreases and then increases at higher velocity(1.75 and 2 U_(mf)).h_(pc) occupies 30%-57%of the overall wall-to-bed heat transfer coefficient for a particle diameter of 0.25 *** results are helpful to predict the overall wall-to-bed heat transfer coefficient in SCWFB combined with a reasonable fluid convective heat transfer model from a theoretical perspective.

关键词： Supercritical water Fluidized bed Particle residence time Discrete element method Single particle model

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Numerical simulation of strongly swirling turbulent flows in a liquid-liquid hydrocyclone using the Reynolds stress transport equation model

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Science China(Technological Sciences) 2000年第1期43卷 86-96页

作者：陆耀军周力行沈熊 State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Department of Engineering Mechanics Tsinghua University Beijing 100084 China

The Reynolds stress transport equation model (DSM) is used to predict the strongly swirling turbulent flows in a liquid-liquid hydrocyclone, and the predictions are compared with LDV measurements . Predictions properly give the flow behavior observed in experiments, such as the Rankine-vortex structure and double peaks near the inlet region in tangential velocity profile, the downward flow near the wall and upward flow near the core in axial velocity profiles. In the inlet or upstream region of the hydrocyclone, the reverse flow near the axis is well predicted, but in the region with smaller cone angle and cylindrical section, there are some discrepancies between the model predictions and the LDV measurements. Predictions show that the pressure is small in the near-axis region and increases to the maximum near the wall. Both predictions and measurements indicate that the turbulence in hydrocy-clones is inhomogeneous and anisotropic.

关键词： strongly swirling flows numerical simulation hydrocyclone

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