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4th International Conference on Nanochannels, Microchannels and Minichannels, ICNMM2006

作者： Li, Zhuo Tang, Gui-Hua He, Ya-Ling Tao, Wen-Quan State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University China

ISBN: (纸本)0791847608

Recently, a large number of experiments have been conducted to examine the applicability of Navier-Stokes equations to predict the friction factor for the laminar flow of polar fluids in microchannels. However, significant discrepancies still exist between various results. In order to investigate the effect of electric double layer on the pressure-driven flow of polar fluid in smooth rectangular microchannels and to reveal whether continuum model can still be applied, numerical investigations are conducted in this paper. The simulated microchannels are made of silicon engraved substrate with Pyrex cover, and the measured relative roughness of channels is less than 0.5%. Deionized water and tap water with different ion concentration and electrical conductivity are used as the working fluid. The governing equations include the two-dimensional, non-linear Poisson-Boltzmann equation, the modified N-S equation and the electric field Ez equation. The steady state electric field E z equation is coupled with the momentum equation. The FVM (finite volume method) is adopted to discretize the governing equations. The non-uniform grid systems 152×102 is applied and the Reynolds number ranges from 0.1 to 300. Good agreements are achieved between the numerical results and the experimental data available in the literature. The effects of electrical potential, fluid ion concentration, electrical conductivity and the channel dimensions on the EDL profile, and the electroviscous effect and the friction coefficient are presented in detail. The simulation results reveal that the Debye thickness depends on ion concentration greatly. Only when the ratio of Dh/δ (the ratio of channel hydraulic diameter to the Debye thickness) is low, the electroviscous effect should be considered. According to the experimental conditions, the numerical results show that if the ratio of Dh/δ is greater than 15, the predicted friction factors agree well with the macroscale classical law, and the disparities

关键词： Channel flow

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CO₂-to-C₂H₅OH photoconversion by an amorphization-activated catalyst

Chem Catalysis

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Chem Catalysis 2025年第5期5卷

作者： Xue, Fei Zhang, Chunyang Liu, Maochang Liu, Feng Yan, Xueli Liu, Shangheng Peng, Huiping Hu, Zhiwei Pao, Chih-Wen Huang, Wei-Hsiang Yang, Ye Huang, Xiaoqing Xu, Yong i-lab of Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO) Chinese Academy of Sciences (CAS) Suzhou 215123 China State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 China International Research Center for Renewable Energy & State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Max Planck Institute for Chemical Physics of Solids Nothnitzer Strasse 40 Dresden 01187 Germany National Synchrotron Radiation Research Center 101 Hsin-Ann Road Hsinchu 30076 Taiwan Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen 361005 China

CO2 photoconversion into value-added C2 products with high selectivity and efficiency is formidably challenging due to highly energetic and kinetic restriction of C–C coupling. Designing catalysts to overcome those b... 详细信息

CO₂ photoconversion into value-added C₂ products with high selectivity and efficiency is formidably challenging due to highly energetic and kinetic restriction of C–C coupling. Designing catalysts to overcome those barriers is therefore crucial. Here, for the first time, we demonstrate an amorphization strategy to boost photocatalytic CO₂ ethanolization. By integrating amorphous Pd onto Cd_0.9Zn_0.1S nanorods (a-Pd/CZS), an activity of 412.1 μmol g⁻¹ h⁻¹ and a selectivity of 96.5% for CO₂-to-C₂H₅OH photoconversion were achieved without a sacrificial agent with an apparent quantum efficiency (AQE) of 0.87% at 420 nm. The superior performance results from rapid migration of photogenerated electrons to amorphous Pd via interfacial Ohmic junction. In situ characterization and theoretical calculation further reveal that amorphous Pd can optimize CO₂ adsorption/activation and reduce the C–C coupling energy barrier via intensified interaction and stabilization with a ^∗OCCO intermediate, thereby maximizing conversion efficiency and selectivity. This work highlights an efficient photocatalyst for a CO₂-to-C₂ product and inspires high-performance photocatalyst design. © 2025 Elsevier Inc.

关键词： amorphization C2H5OH CO2 photocatalytic conversion SDG7: Affordable and clean energy

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Hydrogen production by non-catalytic partial oxidation of coal in supercritical water: Explore the way to complete gasification of lignite and bituminous coal

Hydrogen production by non-catalytic partial oxidation of co...

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作者： Ge, Zhiwei Guo, Simao Guo, Liejin Cao, Changqing Su, Xiaohui Jin, Hui State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an 710049 China

Supercritical water gasification (SCWG) of coal is a promising technology for clean coal utilization. In this paper, hydrogen production by non-catalytic partial oxidation of coal was systematically investigated in supercritical water (SCW) with quartz batch reactors for the first time. The influences of the main operating parameters including residence time, temperature, oxidant equivalent ratio (ER) and feed concentration on the gasification characteristics of coal were investigated. The experimental results showed that H2 yield and carbon gasification efficiency (CE) increased with increasing temperature and decreasing feed concentration. CE increased with increasing ER, and H 2 yield peaked when ER equaled 0.1. CE increased quickly within 1 min and then tended to be stable between 2 and 3 min. In particular, complete gasification of lignite was obtained at 950 C when ER equaled 0.1, as for bituminous coal, at a higher temperature of 980 C when ER equaled 0.2. © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

关键词： Hydrogen production

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Extra contribution to the crystal stability of insensitive explosive TATB: The cooperativity of intermolecular interactions

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Defence Technology（防务技术） 2023年第7期25卷 88-98页

作者： Zhi-xiang Zhang Yi-tao Si Tao Yu Wei-peng Lai Yi-ding Ma Mao-chang Liu Ying-zhe Liu Bo-zhou Wang State Key Laboratory of Fluorine&Nitrogen Chemicals Xi'an Modern Chemistry Research InstituteXi'an710065PR China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an710049PR China

An in-depth analysis on the cooperativity of intermolecular interactions including hydrogen bonding andπ-π stacking in 1,3,5-triamino-2,4,6-trinitrobenzene(TATB) crystal was studied. Two quantities, cooperativity rate and energy, were defined to evaluate the nature and strength of cooperativity in a series of clusters diverging from 1D to 3D prototypes. The origin and mechanism of the cooperative effect were settled to demonstrate that the nature of cooperativity is determined by whether the non-covalent interactions compete or promote with each other, which is manifested by the changing trend of electron transfer. There exists obvious cooperative effect in intra-layer and inter-layer structures as they own the equivalent non-covalent interactions, while anti-cooperative effect is also observed if two interactions correlate with each other. On the whole, in the process of crystal formation, the apparent cooperativity is the check and balance of the two effects, which is capable to support a global interaction among all of molecules and contribute to the stabilization of system. Based on the results, one may get a new insight to understand the relationship between non-covalent interactions and low impact sensitivity.

关键词： Cooperativity Non-covalent interaction Low-sensitivity Explosives Charge transfer

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Performance of vertical axis water turbine with eye-shaped baffle for pico hydropower

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Frontiers in Energy 2022年第4期16卷 683-696页

作者： Zhuohuan HU Dongcheng WANG Wei LU Jian CHEN Yuwen ZHANG Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power EngineeringUniversity of Shanghai for Science and TechnologyShanghai 20093China Department of Mechanical and Aerospace Engineering University of MissouriColumbiaMO 65211USA

t A series of inline pico hydropower systems,which could be used in confined space,especially for water distribution networks(WDNs),was designed and *** turbine with an eye-shaped vertical water baffle was developed to evaluate the hydraulic performance.A three-dimensional dynamic mesh was employed and the inlet velocity was considered as the inlet boundary condition,whereas the outlet boundary was set as the ***,numerical simulations were conducted and the standard k-εturbulence model was found to be the best capable of predicting flow features through the comparison with the experimental *** effects of the opening diameter of the water baffle and installation angle of the rotor on the flow field in the turbine were *** results suggested that the water baffle opening at d=30 mm and the rotor at a 52°angle could achieve the highest efficiency of 5.93%.The proper eye-shaped baffle not only accelerates the fluid flow and generates positive hydrodynamic torque,but also eliminates the flow *** scheme proposed in this paper can be exploited for practical applications in the water pipelines at various conditions and power requirements.

关键词： vertical axis water turbine eye-shaped vertical water baffle pico hydropower

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Noble-metal free plasmonic nanomaterials for enhanced photocatalytic applications—A review

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Nano Research 2022年第12期15卷 10268-10291页

作者： Jinghua Li Yiming Zhang Yalong Huang Bing Luo Li Jing Dengwei Jing International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an710049China

Plasmonic nanomaterial catalysis is currently at the frontier of photocatalysis,overcoming the limitations of wide bandgap semiconductors for light *** localized surface plasmon resonance(LSPR)properties allow broad ultraviolet-visible-near infrared ray(UV-vis-NIR)absorption,making it an ideal material for solar energy *** plasmonic nanostructures rely on precious *** noble metal plasmonic nanomaterials have proven to be one of the strategies for enhancing photocatalytic activity,their expensive cost and limitations in light absorption range have hindered their practical *** a result,noble-metal free plasmonic nanomaterials have risen to the top of the research priority ***,this paper reviews the fundamental principles and classification of the LSPR effect of noble-metal free plasmonic nanomaterials in photocatalytic and their recent applications in hydrogen generation,carbon dioxide reduction,and pollutant *** cases elucidate the possible working mechanism of enhanced photocatalysis by noble-metal free plasmonic ***,the challenges and future opportunities for noble-metal free plasmonic nanomaterials in energy conversion and storage are discussed and envisioned.

关键词： localized surface plasmon resonance(LSPR) noble-metal free plasmonic nanomaterials photocatalysis

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Numerical study of EGR effects on reducing the pressure rise rate of HCCI engine combustion

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中国高等学校学术文摘·能源与动力工程 2010年第3期4卷 376-385页

作者： Gen CHEN Norimasa IIDA Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Graduate School of Science and Technology Keio University Japan Graduate School of Science and Technology Keio University Japan State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The effects of the inert components of exhaust gas recirculation (EGR) gas on reducing the pressure rise rate of homogeneous charge compression ignition engine combustion were investigated numerically by utilizing the CHEMKIN II package and its SENKIN code, as well as Curran's dimethyl ether reaction scheme. Calculations were conducted under constant volume combustion and engine combustion (one compression and one expansion only, respectively) conditions. Results show that with constant fuel amount and initial temperature and pressure, as EGR ratio increases, combustion timings are retarded and the duration of thermal ignition preparation extends non-linearly; peak values of pressure, pressure rising rate (PRR), and temperature decrease; and peak values of heat release rate in both low temperature heat release (LTHR) and high temperature heat release decrease. Moreover, maximum PRR decreases as CA50 is retarded. With constant fuel amount, mixtures with different EGR ratios can obtain the same CA50 by adjusting the initial temperature. Under the same CA50, as EGR ratio increases, the LTHR timing is advanced and the duration of thermal ignition preparation is extended. Maximum PRR is almost constant with the fixed CA50 despite the change in EGR ratio, indicating that the influence of EGR dilution on chemical reaction rate is offset by other factors. Further investigation on the mechanism of this phenomenon is needed.

关键词： HCCI engine combustion EGR DME CA50 PRR

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Technological innovations on direct carbon mitigation by ordered energy conversion and full resource utilization

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Carbon Neutrality 2022年第1期1卷 598-619页

作者： Liejin Guo Zhisong Ou Ya Liu Zhiwei Ge Hui Jin Guobiao Ou Mengmeng Song Zihao Jiao Wenhao Jing State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityNo.28Xianning West RoadXi’an 710049People’s Republic of China

Coal consumption leads to over 15 billion tons of global CO_(2) emissions annually,which will continue at a considerable intensity in the foreseeable *** remove the huge amount of CO_(2),a practically feasible way of direct carbon mitigation,instead of capturing that from dilute tail gases,should be developed;as intended,we developed two innovative supporting technologies,of which the status,strengths,applications,and perspective are discussed in this *** is supercritical water gasification-based coal/biomass utilization technology,which orderly converts chemical energy of coal and low-grade heat into hydrogen energy,and can achieve poly-generation of steam,heat,hydrogen,power,pure CO_(2),and *** other one is the renewables-powered CO_(2) reduction techniques,which uses CO_(2) as the resource for carbon-based fuel *** combining the above two technical loops,one can achieve a full resource utilization and zero CO_(2) emission,making it a practically feasible way for China and global countries to achieve carbon neutrality while creating substantial domestic benefits of economic growth,competitiveness,well-beings,and new industries.

关键词： Carbon neutrality Coal utilization Direct carbon mitigation Supercritical water gasification Renewable energy CO_(2)reduction

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Gold/oxide heterostructured nanoparticles for enhanced SERS sensitivity and reproducibility

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Rare Metals 2020年第7期39卷 834-840页

作者： Qi-Kui Fan Ting-Zhuo Liu Hou-Shen Li Shu-Meng Zhang Kai Liu Chuan-Bo Gao Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710054China College of Chemistry and Material Science Shandong Agricultural UniversityTaian 271018China

In surface-enhanced Raman scattering(SERS),it is highly desirable to obtain Raman signals with high sensitivity and reproducibility from noble metal nanoparticle substrates,which remains a great challenge due to the inhomogeneity of the plasmonic coupling that is sensitive to the interparticle *** this work,we report that the interparticle plasmonic coupling could be circumvented by first synthesizing Au/metal or nonmetal oxide heterostructured nanoparticles and then depositing them uniformly onto the substrates,leading to high reproducibility of the Raman *** plasmonic coupling has been found at the Au/oxide interface,which enables high sensitivity of the SERS analysis that accompanies the excellent signal *** different oxides investigated(SiO2,TiO2 and Fe2O3),the Au/Fe2O3 heterostructured nanoparticles demonstrate the highest Raman enhancement *** believe our strategy opens a promising route to fabricate SERS substrates that are capable of sensitively and quantitatively detecting molecules of interest in a much reliable manner.

关键词： Gold nanoparticles Au/oxide heterostructures Hot spots Surface-enhanced Raman scattering Reproducibility

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Experimental and modeling study on auto-ignition of DME/ n -butane blends under engine relevant pressure

Experimental and modeling study on auto-ignition of DME/ n -...

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SAE 2014 World Congress and Exhibition

作者： Jiang, Xue Zhang, Yingjia Pan, Lun Man, Xingjia Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong University Xi'an 710049 China

In this study, the ignition delay times of DME/n-C4H 10 fuel blends (neat DME, 50/50 and neat n-C4H 10) diluted with argon were measured behind reflected shock waves. The experiments were performed in the temperature range of 1250 - 1600 K, at pressure of 2.0 MPa and equivalence ratios from 0.5 to 2.0. A latest kinetic mechanism NUIG Aramco Mech 1.3 was validated against the present ignition data and used to conducted chemical kinetic analysis. Different equivalence-ratio- dependent was exhibited at different temperature regimes for DME, n-C 4H10, and their blend. Fuel flux analysis, sensitive analysis and mole fraction analysis were carried out for understanding the interaction between the ignition chemistries of DME and n-C4H 10. Copyright © 2014 SAE International.

关键词： Shock waves

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