Photocatalytic water splitting by solar light and biomass gasification in supercritical water both are considered as the most promising routes for renewable hydrogen production. The waste liquid from biomass gasificat...
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ISBN:
(纸本)9781118205976
Photocatalytic water splitting by solar light and biomass gasification in supercritical water both are considered as the most promising routes for renewable hydrogen production. The waste liquid from biomass gasification in supercritical water contains various organic compounds which can act as electron donors in photocatalytic system. In the present work, we report the hydrogen production by the anaerobic photocatalytic reforming of waste liquid from biomass gasification in supercritical water over CdS sensitized Na 2Ti2O4 (OH)2 nanotubes, Various reaction parameters were investigated, such as different gasification temperature and the pH value of the reaction solution. It was demonstrated that gasification in supercritical water and photocatalytic water splitting can be coupled together.
Solid oxide fuel cells (SOFCs) have received considerable interest nowadays, because they promise greater electrical efficiency than that obtained by a conventional heat engine or other types of low temperature fuel c...
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Ignition delay times were obtained behind the reflected shock waves for the diluted stoichiometric methane/hydrogen blends with hydrogen fractions of 20%, 60%, and 80%. Test temperatures from 980 K to 1820 K and press...
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Ignition delay times were obtained behind the reflected shock waves for the diluted stoichiometric methane/hydrogen blends with hydrogen fractions of 20%, 60%, and 80%. Test temperatures from 980 K to 1820 K and pressures from 0.5 to 2.0 MPa. Results show that increase in hydrogen fraction significantly promotes the ignition of fuel blends due to high activity of hydrogen. Pressure-dependence of auto-ignition for methane/hydrogen was observed in three ignition regimes (methane chemistry dominating ignition, combined chemistry of methane and hydrogen dominating ignition and hydrogen chemistry dominating ignition). An explanation of the interaction between chemistries of methane and hydrogen were given by fuel flux analysis using NUIG Mech C5-49.
The flow patterns and their transitions of oil-water two-phase flow in horizontal pipes were studied. The experiments were conducted in two kinds of horizontal tubes, made of plexiglas pipe and stainless steel pipe wi...
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The flow patterns and their transitions of oil-water two-phase flow in horizontal pipes were studied. The experiments were conducted in two kinds of horizontal tubes, made of plexiglas pipe and stainless steel pipe with 40 mm ID respectively. No. 46 mechanical oil and tap water were used as working fluids. The superflcial velocity ranges of oil and water were: 0.04-1.2m·s-1 and 0.04-2.2m·s-1, respectively. The flow patterns were identified by visualization and by transient fluctuation signals of differential pressure drop. The flow patterns were defined according to the relative distribution of oil and water phases in the pipes. flow pattern maps were obtained for both pipelines. In addition, semi-theoretical transition criteria for the flow patterns were proposed, and the proposed transitional criteria are in reasonable agreement with available data in liquid-liquid systems.
Nanosize WS2 sensitized mesoporous TiO2 was prepared to extend the adsorption of the wide band gap TiO2 into visible light region. Compared with nonporous particle TiO2 substrate, it was found that the existence of me...
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ISBN:
(纸本)9781622765409
Nanosize WS2 sensitized mesoporous TiO2 was prepared to extend the adsorption of the wide band gap TiO2 into visible light region. Compared with nonporous particle TiO2 substrate, it was found that the existence of mesopore is important for larger amount of WS 2 loading and inhibition of the light-induced detachment of WS 2 particles from the TiO2 substrate during photocatalytic reaction, which leads to higher photocatalytic activity and stability. We also found that the rate-determining step for photocatalytic hydrogen production is the transfer of electrons from TiO2 substrate to H+ in solution, when the recombination between electrons and holes within TiO 2 could be neglected. In this case, deposition of Pt at the surface of semiconductor is indispensable for efficient hydrogen production.
The present work reports the renewable hydrogen production by an anaerobic photocatalytic reforming of formic acid over CdS sensitized Na 2Ti2O4(OH)2 nanotubes, the Na 2Ti2O4(OH)2 nanotube was prepared and charactered...
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Ejector refrigeration has the advantage of low capital cost,simple design,reliable operation,long lifespan and almost no *** only weakness is the low efficiency and its intolerance to deviations from design operation ...
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Ejector refrigeration has the advantage of low capital cost,simple design,reliable operation,long lifespan and almost no *** only weakness is the low efficiency and its intolerance to deviations from design operation condition.R134 a used in ejector refrigeration system gives better performance in comparison with many other environmental friendly refrigerants as the generation temperature is from 75℃to 80℃.The present work experimentally investigated the on-design and off-design performance of the ejector with fixed geometry using R134 a as refrigerant,and cycle performance of the ejector refrigeration *** experimental prototype was constructed and the effects of primary flow inlet pressure,secondary flow inlet pressure and ejector back pressure on ejector performance and cycle performance were investigated *** operation conditions are:primary flow inlet pressure from 2.2 MPa to 3.25 MPa,secondary flow inlet pressure from 0.36 MPa to 0.51 MPa,ejector back pressure from 0.45 MPa to 0.67 *** were drawn from the experimental results,and the experimental data can be used for validation of theoretical model for both critical and subcritical mode.
In this paper, the boiler thermal system of a 600MW supercritical lignite-fired power plant was modeled and simulated with the application of GSE simulation software. The model was developed in Jtopmeret according to ...
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In this paper, the boiler thermal system of a 600MW supercritical lignite-fired power plant was modeled and simulated with the application of GSE simulation software. The model was developed in Jtopmeret according to the structural features and divided into steam-water system, flue gas -air system, and direct-fired pulverizing system. Model simulations were implemented in SimExec. The outlet temperature of different devices and sections under BMCR and 75% THA conditions were compared with the reference data. The results show that the simulation model developed had high accuracy and reliability. Further simulations were carried out on the varied load. The boiler efficiency and flue gas extraction amount changed with the load.
Delivery of high energy density in polyanion compound-Na3V2(PO4)3 based on three-electron redox is still challenging because of their controversial multi-electron reaction mechanism and unsatisfactory electrochemical ...
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In this work, an experimental work was investigated on the nano-refrigerant. A domestic R600a refrigerator was selected and instrumented with 19 resistance thermometers and three pressure transducers. R600a/TiO 2 nano...
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ISBN:
(纸本)9868509610
In this work, an experimental work was investigated on the nano-refrigerant. A domestic R600a refrigerator was selected and instrumented with 19 resistance thermometers and three pressure transducers. R600a/TiO 2 nano-refrigerants were used as working fluid without any system reconstruction. The refrigerator performance was then investigated using energy consumption test and freeze capacity test. The results indicate that R600a/TiO2 nano-refrigerant works normally and safely in the refrigerator. The refrigerator performance was better than the pure R600a system, with 9.6% less energy used with 0.5 g/L nano-refrigerant. Thus, using R600a/ TiO2 nano-refrigerant in domestic refrigerators is feasible.
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